Pubbl/distr/stampa	San Diego [etc.], : Academic Press, [1995]
Descrizione fisica	v. : ill. ; 24 cm
Disciplina	547.06
Collana	Methods in Enzymology
Soggetto non controllato	TIOLI - CHIMICA BIOLOGICA
ISBN	0121821528
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	251: Part A ; 252: Part B
Altri titoli varianti	Biothiols.
Record Nr.	UNINA-9910673597303321

Autore	Breslow David S.
Edizione	[99th ed.]
Pubbl/distr/stampa	New York : , : Interscience Publishers, , [1966]
Descrizione fisica	1 online resource (814 p.)
Disciplina	547.06
Collana	Chemistry of Heterocyclic Compounds
Soggetto topico	Organosulfur compounds
ISBN	1-282-30161-6 9786612301612 0-470-18683-6 0-470-18833-2
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	MULTI-SULFUR AND SULFUR AND OXYGEN FIVE- AND SIX-MEMBERED HETEROCYCLES; CONTENTS OF PART TWO; 6. C24S2 Ring Systems; I. C2O2S2; A. 1,3, 2,4-Dioxadithiane; 1. Preparation; 2. Mechanism of Formation; 3. Reactions; B. 1,3,2,4-Dioxadithiin; II. C,-C202S, 5H-Cyclopenta-l,3,2,4 -dioxaclithiin; III. Cz02S2-Cz0,S2 1,3,2,4-Dioxadithihd5,6- 1,3,2,4-dioxadithh .; IV. C,O, -C, 1,3,2,4 -Benzodioxadithiin; 7. C8S4 Ringsystems; I. C2S4; A. s-Tetrathiane; B. Spiro Derivatives; 1. C,-C,-C S, 6,7,13,14-Tetrathiadispiro f4.2.4.2jL-tetradecane; 2. C2S4-C,-C, 7,8,15,16-Tetrathiadispiro [5.2.5.2]-hexadecane II. C,N,S-C2S4 2,3,4,8-Tetrathia-6, '7-diazabicyclo 13.2.11 octane8. C,O,SRingSystems; I. 1,3,2-Dioxathia Compounds; A. CSO2S; 1. lY3,2-Dioxathiane; a. Sulfite Esters; (1) Preparation; (2) Structure and Physical Properties; (3) Reactions; b. Sulfate Esters; (1) Preparation and Properties; (2) Reactions; c. Spiro Derivatives; 2. 4H- 1,3,2-Dioxathiin; B. C,0-C302S 4H-Fur43,2-d]-l1 3,2-dioxathiin; C. C3O2S-C5O; 1. 4H, 8H-Pyrano(3, 2-d]-1,3, 2-dioxathiin; 2. 48,5H-Pyran44,3-d]-1,3,2-dioxathiin; D. c@~s-c6-c, Naphthdl, 8-de]-1,3,2-dioxathiin; E. c,o2s-c6-c,-c6; 1. Anthrdl, 9-de]-1,3,2-dioxathiin 2. 4,10-Ethan0-4H-11aphthtZ, 3-d]-1,3,2- dioxathiin3. Decahydro-5,9-methanobenzocycl&tene-4a, 11 (W)-diol Cyclic Sulfite; F. Cyclic Sulfites of Steroids and Related Com- pounds; II. 1,3,4-Dimthia Compounds C,O,S-C, 2,4,1- Benzodioxathiin; IIl. 1,3, 5-Dioxathia Compounds C302S 1,3,5- Dioxathiane; 9. C3OS2 Ring Systems; I. 1,2,6-Oxadithia Compounds; A. C3W2 1,2,6-Oxadithiane and 3H-1,2,6-oxadithiin; 1. 1,2,6-0xadithiane; 2. 3H-1,2,6-Oxadithiin; B. c@8,-C,-c6 Naphwl, B - c ~ ] [I, 2,610xadithiin; II. 1,2,4-Oxadithia Compounds; C3oS2 1,2,4-Oxadithiane; III. 1,3,4-oxadithia Compounds C,06,-C6 -C, Naphth[ 1,2-e] [ 1,3,4]oxadithiin and Spiro [naphthalene-1(W), 3'-naphtMl, 2-e] [ 1,3,4]oxadithiin]IV. 1,3,5dkadithia Compounds; C,OS, 1,3, fi-oxadithiane; 10. C3S3 Ring Systems; I. 1,2,3-Trithia Compounds 1,2,3-Trithiane and Related Spiro Derivatives; II. 1,3,5-Trithia Compounds; A. s-Trithiane; 1. Preparation; 2. Structure; 3. Reactions; a. General Properties; b. Complexes with Heavy Metal Salts; c. Thermal Reactions; d. Halogenation'; e. Oxidation; f. Miscellaneous Reactions; g. Methylene Derivative; 4. Uses; B. C,S,-C@,-C,S, 2,4,6,8,9,10-HWthia-adarnantane C. C,S,-C,NS-C,NS 4,6,1O-Trithia-l-azaadaman-tane11. C4O6 Ring Systems; I. o-Oxathia Compounds; A. C,oS o-Oxathiane and o-oxathiin; 1. o-Oxathiane; a. Preparation; b. Properties, Reactions, and Uses; 2. Dihydro-o-oxathiin; 3. o-Oxathiin; B. C,-C,OS 5H-Cyclopentfc] [ 1,210xathiin; C. C4OS-C6; 1. l,%-Benzoxathiin; 2. 2,l-Benzoxathiin; 3. 2,3-Benzoxathiin; D. C4oS-C,-C6; 1. W-NaphNl, 2-4-2, &oxathiin; 2. 3H-Naphtql, 8-cd]-[lJ 2I-oxathiin; 3. Dibenz[ ce]-[ 1, 21 -oxathiin; E. c,~-c6-c6-c6; 1. Benzo[c]aaphth[2,l-e]-[ 1,2]-01mthiin 2. Benzo[c]naphth[1, 2-e]-[1, 2]-oxathiin and Benzo[c]naphth[2, 3-e]-[1, 2]-oxathiin
Record Nr.	UNINA-9910144283803321

Pubbl/distr/stampa	Weinheim, Germany : , : Wiley-VCH, , [2021]
Descrizione fisica	1 online resource (xxv, 446 pages) : illustrations
Disciplina	547.06
Soggetto topico	Organosulfur compounds
Soggetto genere / forma	Electronic books.
ISBN	3-527-82380-8 3-527-82381-6 3-527-82379-4
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Cover -- Title Page -- Copyright -- Contents -- Introduction -- Chapter 1 Synthesis of Sulfur‐Containing Polymers Through Multicomponent Polymerizations -- 1.1 Introduction -- 1.2 Multicomponent Polymerizations of Elemental Sulfur -- 1.2.1 Multicomponent Polymerization of Sulfur, Dialdehydes, and Diamines -- 1.2.2 Multicomponent Polymerization of Sulfur, Diynes, and Aliphatic Amines -- 1.2.3 Multicomponent Polymerization of Sulfur, Benzyl Diamines, and Aliphatic Diamines -- 1.2.4 Multicomponent Polymerization of Sulfur, Diarylacetic Acids, and Aliphatic/Aromatic Diamines -- 1.2.5 Multicomponent Polymerization of Sulfur, Diisocyanides, and Aliphatic Diamines -- 1.3 Cu(I)‐Catalyzed Multicomponent Polymerizations of Sulfonyl Azides/Hydrazides -- 1.3.1 Multicomponent Polymerization of Sulfonyl Azides, Alkynes, and Amines/Alcohols -- 1.3.2 Multicomponent Polymerization of Sulfonyl Azides, Alkynes, and Other Monomers -- 1.3.3 Multicomponent Polymerization of Sulfonyl Hydrazide, Alkynes, and Diphenyl Dichalcogen -- 1.3.4 Topological Polymers Prepared from Sulfonyl Azides and Alkyne‐Based MCPs -- 1.4 Multicomponent Polymerizations with Thiol‐Related Monomers -- 1.4.1 One‐Pot Multicomponent Tandem Polymerization of Alkyne, Carbonyl Chloride, and Thiol -- 1.4.2 Multicomponent Polymerizations with Cyclic Dithiocarbonate -- 1.4.3 Multicomponent Polymerizations with Cyclic Thiolactone -- 1.5 The Applications of Sulfur‐Containing Polymers Prepared from MCP -- 1.5.1 Chemosensors -- 1.5.2 Metal Ion Removal/Enrichment -- 1.5.3 Cell Imaging -- 1.6 Conclusion -- Acknowledgments -- References -- Chapter 2 Carbon Disulfide Derived Polymers -- 2.1 Introduction -- 2.2 Synthesis of Thiiranes (Episulfides) -- 2.3 Copolymerization Reactions -- 2.3.1 Copolymerization of Carbon Disulfide and Episulfides -- 2.3.2 Copolymerization of Carbon Disulfide and Epoxides. 2.3.2.1 Scrambling Mechanism for Sulfur/Oxygen Atoms -- 2.3.2.2 NMR Scrambling Studies -- 2.3.2.3 Mixed Species Scrambling -- 2.4 Other Related CS2‐Based Polymers -- 2.5 Concluding Remarks -- Acknowledgments -- References -- Chapter 3 Carbonyl Sulfide Derived Polymers -- 3.1 Introduction -- 3.1.1 Overview of COS -- 3.1.2 Preparation of COS -- 3.1.2.1 Direct Reaction of CO and Sulfur -- 3.1.2.2 Using Carbon Disulfide (CS2) -- 3.1.2.3 Laboratory Preparation of COS -- 3.1.3 Environmental and Safety Considerations -- 3.1.4 COS Chemistry -- 3.1.4.1 Dissociation -- 3.1.4.2 Hydrolysis -- 3.1.4.3 Oxidation -- 3.1.4.4 Reduction -- 3.1.4.5 Reaction with SO2 -- 3.1.4.6 Reaction with Ammonia and Amines -- 3.1.4.7 Miscellaneous Reactions -- 3.1.4.8 The Claus Reaction -- 3.2 Metal Catalysts for COS Copolymerization -- 3.2.1 Zinc‐Cobalt(III) Double‐Metal Cyanide Complex -- 3.2.2 Catalysts Centered with Chromium (Cr) -- 3.2.3 Catalyst Centered with Iron (Fe) and Cobalt (Co) -- 3.2.4 Alkoxy Metal Salts -- 3.3 Organocatalysts for COS Copolymerization -- 3.3.1 TEB‐Organic Base Pair -- 3.3.2 Dual‐Site Lewis Pair -- 3.3.3 Thiourea‐Organic Base Pairs -- 3.3.4 Supramolecular Anion -- 3.4 Oxygen‐Sulfur Exchange Reaction -- 3.5 Utilization of O/S ER for Poly(thioether)s -- 3.5.1 COS‐Epoxides Route to Poly(thioether)s -- 3.5.2 CS2‐Epoxides Route to Poly(thioether)s -- 3.5.3 Repurposing Poly(monothiocarbonate)s to Poly(thioether)s -- 3.6 Crystalline COS‐Derived Polymers -- 3.7 COS‐Derived Block Polymers -- 3.8 Properties of COS‐Derived Polymers -- 3.8.1 Thermal Properties -- 3.8.2 Crystalline Properties -- 3.8.3 Optical Properties -- 3.8.4 Electronic Properties -- 3.9 Summary and Outlook -- References -- Chapter 4 Thiol‐Based Click Polymerizations for Sulfur‐Containing Polymers -- 4.1 Introduction -- 4.2 Thiol‐Ene Click Polymerization. 4.2.1 Radical‐Initiated Thiol‐Ene Click Polymerization -- 4.2.2 Thiol‐Ene Michael Addition Click Polymerization -- 4.3 Thiol‐Yne Click Polymerization -- 4.3.1 Radical‐Initiated Thiol‐Yne Click Polymerization -- 4.3.2 Base‐Mediated Thiol‐Yne Click Polymerization -- 4.3.3 Metal‐Catalyzed Thiol‐Yne Click Polymerization -- 4.3.4 Spontaneous Thiol‐Yne Click Polymerization -- 4.4 Other Thiol‐Based Click Polymerizations -- 4.4.1 Thiol‐Epoxy Click Polymerization -- 4.4.2 Thiol‐Isocyanate Click Polymerization -- 4.4.3 Thiol‐Halogen Click Polymerization -- 4.5 Conclusion -- Acknowledgments -- References -- Chapter 5 Synthesis of Polythioesters -- 5.1 Introduction -- 5.2 Synthesis of Aromatic Polythioesters -- 5.3 Synthesis of Semi‐aromatic Polythioesters -- 5.4 Synthesis of Aliphatic Polythioesters -- 5.5 Summary and Concluding Remarks -- Acknowledgments -- References -- Chapter 6 Polymers with Sulfur‐Nitrogen Bonds -- 6.1 Introduction -- 6.2 Synthesis of Sulfur‐Nitrogen Containing Polymers -- 6.2.1 Poly(sulfenamide)s -- 6.2.2 Poly(diaminosulfide)s -- 6.2.3 Poly(aminodisulfide)s and Poly(diaminodisulfide)s -- 6.2.3.1 Poly(aminodisulfide)s -- 6.2.3.2 Poly(diaminodisulfide)s -- 6.2.4 Poly(oxothiazene)s -- 6.2.5 Poly(sulfonylimidate)s -- 6.2.6 Poly(sulfonylamidine)s -- 6.3 Applications of Polymers with Sulfur‐Nitrogen Bond -- 6.3.1 Biomedical Applications -- 6.3.2 Metal‐Ion Detection -- 6.3.3 Flame Retardant Chemicals Based on Polymers with Sulfur‐Nitrogen Bonds -- 6.3.4 Energy Storage Applications -- 6.4 Conclusion and Outlook -- References -- Chapter 7 Thioester Functional Polymers -- 7.1 Introduction -- 7.2 Thioesters: Structural Features, Reactivities, and Reactions -- 7.3 Preparation of Thioester Containing Structures -- 7.3.1 Access to Thioester Containing Polymers: Thioesters in the Side Chain. 7.3.2 Access to Thioester Containing Polymers: Thioester in the Chain End -- 7.3.3 Access to Thioester Containing Polymers via Polymerization Process -- 7.3.4 Access to Thioester‐Bearing Structures via Post‐modification Approach -- 7.4 Post‐Polymerization Modification of Thioesters -- 7.5 Conclusion and Outlook -- References -- Chapter 8 Thiophene‐Based Polymers: Synthesis and Applications -- 8.1 Introduction -- 8.2 Development of Synthetic Methods -- 8.2.1 Oxidative Polymerization and Electrochemical Polymerization -- 8.2.2 Transmetalation Polymerization -- 8.2.2.1 Polymerization with Ni Catalysis -- 8.2.2.2 Polymerization with Pd Catalysis -- 8.2.2.3 Suzuki Coupling Method -- 8.2.2.4 Stille Coupling Method -- 8.2.2.5 Direct Arylation Method -- 8.2.3 Other Polymerization Methods -- 8.2.3.1 Photoinitiated Polymerization -- 8.2.3.2 Solid‐State Polymerization -- 8.2.3.3 Acid‐Catalyzed Polymerization -- 8.3 Applications of Polythiophene and Its Derivatives -- 8.3.1 Organic Thin‐Film Transistors -- 8.3.2 Organic Photovoltaics -- 8.3.3 Organic Light‐Emitting Diodes -- 8.3.4 Biological Applications -- 8.4 Conclusions and Future Scope -- References -- Chapter 9 High Refractive Index Sulfur‐Containing Polymers (HRISPs) -- 9.1 Introduction -- 9.2 Basics of Optics -- 9.2.1 Absorption and Refraction -- 9.2.2 Refractive Index -- 9.2.2.1 Refractive Index Determination -- 9.2.3 Dispersion -- 9.2.4 Birefringence -- 9.3 High Refractive Index Polymers (HRIPs) -- 9.3.1 General Strategies and Applications -- 9.4 Sulfur‐Containing HRIPs -- 9.4.1 Polyimides and Polyamides -- 9.4.2 Poly(meth)acrylates and Polythioacrylates -- 9.4.3 Polycarbonates and Polyesters -- 9.4.4 Thermosets -- 9.4.5 Inverse Vulcanization -- 9.5 Conclusion and Outlook -- References -- Chapter 10 Selenium‐Containing Dynamic Polymers: From Synthesis to Functions -- 10.1 Introduction. 10.2 Synthesis of Selenium‐Containing Polymers -- 10.2.1 Step Growth Polymerization -- 10.2.2 Radical Polymerization -- 10.2.3 Ring‐Opening Polymerization -- 10.2.4 Synthesis of Dendrimer and Hyperbranched Selenium‐Containing Polymer -- 10.3 Selenium‐Containing Dynamic Covalent Chemistry -- 10.3.1 Diselenide Bond -- 10.3.2 Se S Bond -- 10.3.3 Se Te Bond -- 10.3.4 Se N Bond -- 10.4 Selenium‐Containing Dynamic Materials -- 10.4.1 Selenium‐Containing Elastomer -- 10.4.2 Selenium‐Containing Surface/Interface Materials -- 10.4.3 Selenium‐Containing Nanomaterials -- 10.5 Conclusion and Outlook -- Acknowledgments -- References -- Chapter 11 Poly(disulfide)s -- 11.1 Introduction -- 11.2 Synthesis of Poly(disulfide)s -- 11.2.1 Oxidative Polymerization of Dithiols -- 11.2.2 Ring‐Opening Polymerization (ROP) of Cyclic Disulfide -- 11.2.3 Photo‐Induced Disulfide Metathesis -- 11.2.4 Fragmentation Polymerization -- 11.2.5 Self‐Organizing Surface‐Initiated Polymerization (SOSIP) -- 11.2.6 Thiol‐Disulfide Exchange Reaction -- 11.3 Amphiphilic PDS and Drug Delivery Application -- 11.4 Cell‐Penetrating Poly(disulfide)s -- 11.5 Summary and Outlook -- References -- Chapter 12 Reduction‐Responsive Disulfide‐Containing Polymers for Biomedical Applications -- 12.1 Introduction -- 12.2 Disulfide‐Containing Topological Polymers -- 12.2.1 Systems with the Disulfide Linkages -- 12.2.2 Disulfide‐Containing Linear Polymers -- 12.2.2.1 Linear Polymers with Cleavable Backbones -- 12.2.2.2 Linear Polymers with Cleavable Side Chains -- 12.2.3 Disulfide‐Containing Dendritic Polymers -- 12.2.3.1 Disulfide‐Containing Hyperbranched Polymers -- 12.2.3.2 Disulfide‐Containing Dendrimers -- 12.2.4 Disulfide‐Containing Polypeptides and Proteins -- 12.2.5 Disulfide‐Containing Polymeric Nanoparticles -- 12.2.5.1 Disulfide Linker for Amphiphilic Polymers. 12.2.5.2 Disulfide Linker for Nano‐Assemblies.
Record Nr.	UNINA-9910555275303321