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Boronic acids [[electronic resource] ] : preparation and applications in organic synthesis, medicine and materials / / edited by Dennis G. Hall ; with a foreword by Akira Suszuki
| Boronic acids [[electronic resource] ] : preparation and applications in organic synthesis, medicine and materials / / edited by Dennis G. Hall ; with a foreword by Akira Suszuki |
| Edizione | [2nd completely rev. ed.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2011 |
| Descrizione fisica | 1 online resource (729 p.) |
| Disciplina | 547.05671 |
| Altri autori (Persone) | HallDennis G. <1968-> |
| Soggetto topico |
Organic acids
Organoboron compounds Organic acids - Therapeutic use Organoboron compounds - Therapeutic use Organic acids - Synthesis Organoboron compounds - Synthesis |
| ISBN |
1-283-60404-3
9786613916495 3-527-33214-6 3-527-63934-9 3-527-63932-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Boronic Acids: Preparation and Applications in Organic Synthesis, Medicine and Materials; Foreword; Contents to Volume 1; Contents to Volume 2; Preface; List of Contributors; 1 Structure, Properties, and Preparation of Boronic Acid Derivatives: Overview of Their Reactions and Applications; 1.1 Introduction and Historical Background; 1.2 Structure and Properties of Boronic Acid Derivatives; 1.2.1 General Types and Nomenclature of Boronic Acid Derivatives; 1.2.2 Boronic Acids; 1.2.2.1 Structure and Bonding; 1.2.2.2 Physical Properties and Handling; 1.2.2.3 Safety Considerations
1.2.2.4 Acidic Character1.2.2.5 Chemical Stability; 1.2.3 Boronic Acid Derivatives; 1.2.3.1 Boroxines (Cyclic Anhydrides); 1.2.3.2 Boronic Esters; 1.2.3.3 Acyloxy- and Diacyloxyboronates; 1.2.3.4 Dialkoxyboranes and Other Heterocyclic Boranes; 1.2.3.5 Diboronyl Esters; 1.2.3.6 Azaborolidines and Other Boron-Nitrogen Heterocycles; 1.2.3.7 Dihaloboranes and Dihydroalkylboranes; 1.2.3.8 Trifluoro- and Trihydroxyborate Salts; 1.3 Preparation of Boronic Acids and Their Esters; 1.3.1 Arylboronic Acids; 1.3.1.1 Electrophilic Trapping of Arylmetal Intermediates with Borates 1.3.1.2 Transmetalation of Aryl Silanes and Stannanes1.3.1.3 Coupling of Aryl Halides with Diboronyl Reagents; 1.3.1.4 Direct Boronation by Transition Metal-Catalyzed Aromatic C-H Functionalization; 1.3.1.5 Cycloadditions of Alkynylboronates; 1.3.1.6 Other Methods; 1.3.2 Diboronic Acids; 1.3.3 Heterocyclic Boronic Acids; 1.3.4 Alkenylboronic Acids; 1.3.4.1 Electrophilic Trapping of Alkenylmetal Intermediates with Borates; 1.3.4.2 Transmetalation Methods; 1.3.4.3 Transition Metal-Catalyzed Coupling between Alkenyl Halides/ Triflates and Diboronyl Reagents; 1.3.4.4 Hydroboration of Alkynes 1.3.4.5 Alkene Metathesis1.3.4.6 Diboronylation and Silaboration of Unsaturated Compounds; 1.3.4.7 Other Methods; 1.3.5 Alkynylboronic Acids; 1.3.6 Alkylboronic Acids; 1.3.7 Allylic Boronic Acids; 1.3.8 Chemoselective Transformations of Compounds Containing a Boronic Acid (Ester) Substituent; 1.3.8.1 Oxidative Methods; 1.3.8.2 Reductive Methods; 1.3.8.3 Generation and Reactions of a-Boronyl-Substituted Carbanions and Radicals; 1.3.8.4 Reactions of a-Haloalkylboronic Esters; 1.3.8.5 Other Transformations; 1.3.8.6 Protection of Boronic Acids for Orthogonal Transformations 1.4 Isolation and Characterization1.4.1 Recrystallization and Chromatography; 1.4.2 Solid Supports for Boronic Acid Immobilization and Purification; 1.4.2.1 Diethanolaminomethyl Polystyrene; 1.4.2.2 Other Solid-Supported Diol Resins; 1.4.3 Analytical and Spectroscopic Methods for Boronic Acid Derivatives; 1.4.3.1 Melting Points, Combustion Analysis, and HPLC; 1.4.3.2 Mass Spectrometry; 1.4.3.3 Nuclear Magnetic Resonance Spectroscopy; 1.4.3.4 Other Spectroscopic Methods; 1.5 Overview of the Reactions of Boronic Acid Derivatives; 1.5.1 Metalation and Metal-Catalyzed Protodeboronation 1.5.2 Oxidative Replacement of Boron |
| Record Nr. | UNINA-9910137968003321 |
| Weinheim, : Wiley-VCH, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Boronic acids : preparation and applications in organic synthesis, medicine and materials / / edited by Dennis G. Hall ; with a foreword by Akira Suszuki
| Boronic acids : preparation and applications in organic synthesis, medicine and materials / / edited by Dennis G. Hall ; with a foreword by Akira Suszuki |
| Edizione | [2nd completely rev. ed.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2011 |
| Descrizione fisica | 1 online resource (729 p.) |
| Disciplina | 547.05671 |
| Altri autori (Persone) | HallDennis G. <1968-> |
| Soggetto topico |
Organic acids
Organoboron compounds Organic acids - Therapeutic use Organoboron compounds - Therapeutic use Organic acids - Synthesis Organoboron compounds - Synthesis |
| ISBN |
1-283-60404-3
9786613916495 3-527-33214-6 3-527-63934-9 3-527-63932-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Boronic Acids: Preparation and Applications in Organic Synthesis, Medicine and Materials; Foreword; Contents to Volume 1; Contents to Volume 2; Preface; List of Contributors; 1 Structure, Properties, and Preparation of Boronic Acid Derivatives: Overview of Their Reactions and Applications; 1.1 Introduction and Historical Background; 1.2 Structure and Properties of Boronic Acid Derivatives; 1.2.1 General Types and Nomenclature of Boronic Acid Derivatives; 1.2.2 Boronic Acids; 1.2.2.1 Structure and Bonding; 1.2.2.2 Physical Properties and Handling; 1.2.2.3 Safety Considerations
1.2.2.4 Acidic Character1.2.2.5 Chemical Stability; 1.2.3 Boronic Acid Derivatives; 1.2.3.1 Boroxines (Cyclic Anhydrides); 1.2.3.2 Boronic Esters; 1.2.3.3 Acyloxy- and Diacyloxyboronates; 1.2.3.4 Dialkoxyboranes and Other Heterocyclic Boranes; 1.2.3.5 Diboronyl Esters; 1.2.3.6 Azaborolidines and Other Boron-Nitrogen Heterocycles; 1.2.3.7 Dihaloboranes and Dihydroalkylboranes; 1.2.3.8 Trifluoro- and Trihydroxyborate Salts; 1.3 Preparation of Boronic Acids and Their Esters; 1.3.1 Arylboronic Acids; 1.3.1.1 Electrophilic Trapping of Arylmetal Intermediates with Borates 1.3.1.2 Transmetalation of Aryl Silanes and Stannanes1.3.1.3 Coupling of Aryl Halides with Diboronyl Reagents; 1.3.1.4 Direct Boronation by Transition Metal-Catalyzed Aromatic C-H Functionalization; 1.3.1.5 Cycloadditions of Alkynylboronates; 1.3.1.6 Other Methods; 1.3.2 Diboronic Acids; 1.3.3 Heterocyclic Boronic Acids; 1.3.4 Alkenylboronic Acids; 1.3.4.1 Electrophilic Trapping of Alkenylmetal Intermediates with Borates; 1.3.4.2 Transmetalation Methods; 1.3.4.3 Transition Metal-Catalyzed Coupling between Alkenyl Halides/ Triflates and Diboronyl Reagents; 1.3.4.4 Hydroboration of Alkynes 1.3.4.5 Alkene Metathesis1.3.4.6 Diboronylation and Silaboration of Unsaturated Compounds; 1.3.4.7 Other Methods; 1.3.5 Alkynylboronic Acids; 1.3.6 Alkylboronic Acids; 1.3.7 Allylic Boronic Acids; 1.3.8 Chemoselective Transformations of Compounds Containing a Boronic Acid (Ester) Substituent; 1.3.8.1 Oxidative Methods; 1.3.8.2 Reductive Methods; 1.3.8.3 Generation and Reactions of a-Boronyl-Substituted Carbanions and Radicals; 1.3.8.4 Reactions of a-Haloalkylboronic Esters; 1.3.8.5 Other Transformations; 1.3.8.6 Protection of Boronic Acids for Orthogonal Transformations 1.4 Isolation and Characterization1.4.1 Recrystallization and Chromatography; 1.4.2 Solid Supports for Boronic Acid Immobilization and Purification; 1.4.2.1 Diethanolaminomethyl Polystyrene; 1.4.2.2 Other Solid-Supported Diol Resins; 1.4.3 Analytical and Spectroscopic Methods for Boronic Acid Derivatives; 1.4.3.1 Melting Points, Combustion Analysis, and HPLC; 1.4.3.2 Mass Spectrometry; 1.4.3.3 Nuclear Magnetic Resonance Spectroscopy; 1.4.3.4 Other Spectroscopic Methods; 1.5 Overview of the Reactions of Boronic Acid Derivatives; 1.5.1 Metalation and Metal-Catalyzed Protodeboronation 1.5.2 Oxidative Replacement of Boron |
| Record Nr. | UNINA-9910817010203321 |
| Weinheim, : Wiley-VCH, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Boronic acids [[electronic resource] ] : preparation and applications in organic synthesis and medicine / / edited by Dennis G. Hall
| Boronic acids [[electronic resource] ] : preparation and applications in organic synthesis and medicine / / edited by Dennis G. Hall |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (577 p.) |
| Disciplina | 547.05671 |
| Altri autori (Persone) | HallDennis |
| Soggetto topico |
Organic acids
Organoboron compounds Organic acids - Therapeutic use Organoboron compounds - Therapeutic use Organic acids - Synthesis Organoboron compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-52116-3
9786610521166 3-527-60682-3 3-527-60654-8 1-60119-357-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Boronic Acids; Table of Contents; Preface; List of Authors; List of Abbreviations; 1 Structure, Properties, and Preparation Of Boronic Acid Derivatives. Overview of Their Reactions and Applications; 1.1 Introduction; 1.2 Structure and Properties of Boronic Acid Derivatives; 1.2.1 General Types and Nomenclature of Boronic Acid Derivatives; 1.2.2 Boronic Acids; 1.2.2.1 Structure and Bonding; 1.2.2.2 Physical Properties and Handling; 1.2.2.3 Safety Considerations; 1.2.2.4 Acidic Character; 1.2.2.5 Chemical Stability; 1.2.3 Boronic Acid Derivatives; 1.2.3.1 Boroxines; 1.2.3.2 Boronic Esters
1.2.3.3 Dialkoxyboranes and other Heterocyclic Boranes1.2.3.4 Diboronyl Esters; 1.2.3.5 Azaborolidines and other Boron Heterocycles; 1.2.3.6 Dihaloboranes and Monoalkylboranes; 1.2.3.7 Trifluoroborate Salts; 1.3 Synthesis of Boronic Acids and their Esters; 1.3.1 Arylboronic Acids; 1.3.1.1 Electrophilic Trapping of Arylmetal Intermediates with Borates; 1.3.1.2 Transmetallation of Aryl Silanes and Stannanes; 1.3.1.3 Coupling of Aryl Halides with Diboronyl Reagents; 1.3.1.4 Direct Boronylation by Transition Metal-catalyzed Aromatic C-H Functionalization; 1.3.1.5 Other Methods 1.3.2 Diboronic Acids1.3.3 Heterocyclic Boronic Acids; 1.3.4 Alkenylboronic Acids; 1.3.4.1 Electrophilic Trapping of Alkenymetal Intermediates with Borates; 1.3.4.2 Transmetallation Methods; 1.3.4.3 Transition-metal Catalyzed Coupling between Alkenyl Halides/Triflates and Diboronyl Reagents; 1.3.4.4 Hydroboration of Alkynes; 1.3.4.5 Alkene Metathesis; 1.3.4.6 Other Methods; 1.3.5 Alkynylboronic Acids; 1.3.6 Alkylboronic Acids; 1.3.7 Allylic Boronic Acids; 1.3.8 Chemoselective Transformations of Compounds containing a Boronic Acid (Ester) Substituent; 1.3.8.1 Oxidative Methods 1.3.8.2 Reductive Methods1.3.8.3 Generation and Reactions of α-Boronyl-substituted Carbanions and Radicals; 1.3.8.4 Reactions of (α-Haloalkyl)boronic Esters; 1.3.8.5 Other Transformations; 1.4 Isolation and Characterization; 1.4.1 Chromatography and Recrystallization; 1.4.2 Solid Supports for Boronic Acid Immobilization and Purification; 1.4.2.1 Diethanolaminomethyl Polystyrene; 1.4.2.2 Other Solid-supported Diol Resins; 1.4.2.3 Soluble Diol Approaches; 1.4.3 Analytical and Spectroscopic Methods for Boronic Acid Derivatives; 1.4.3.1 Melting Points and Combustion Analysis 1.4.3.2 Mass Spectrometry1.4.3.3 Nuclear Magnetic Resonance Spectroscopy; 1.4.3.4 Other Spectroscopic Methods; 1.5 Overview of the Reactions of Boronic Acid Derivatives; 1.5.1 Metallation and Metal-catalyzed Protodeboronation; 1.5.2 Oxidative Replacement of Boron; 1.5.2.1 Oxygenation; 1.5.2.2 Amination; 1.5.2.3 Halogenation; 1.5.3 Carbon-Carbon Bond forming Processes; 1.5.3.1 Palladium-catalyzed Cross-coupling with Carbon Halides (Suzuki Coupling); 1.5.3.2 Allylation of Carbonyl Compounds; 1.5.3.3 Uncatalyzed Additions to Imines and Iminiums 1.5.3.4 Rhodium-catalyzed Additions to Aldehydes and Alkenes |
| Record Nr. | UNINA-9910144324903321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Boronic acids : preparation and applications in organic synthesis and medicine / / edited by Dennis G. Hall
| Boronic acids : preparation and applications in organic synthesis and medicine / / edited by Dennis G. Hall |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (577 p.) |
| Disciplina | 547.05671 |
| Altri autori (Persone) | HallDennis |
| Soggetto topico |
Organic acids
Organoboron compounds Organic acids - Therapeutic use Organoboron compounds - Therapeutic use Organic acids - Synthesis Organoboron compounds - Synthesis |
| ISBN |
1-280-52116-3
9786610521166 3-527-60682-3 3-527-60654-8 1-60119-357-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Boronic Acids; Table of Contents; Preface; List of Authors; List of Abbreviations; 1 Structure, Properties, and Preparation Of Boronic Acid Derivatives. Overview of Their Reactions and Applications; 1.1 Introduction; 1.2 Structure and Properties of Boronic Acid Derivatives; 1.2.1 General Types and Nomenclature of Boronic Acid Derivatives; 1.2.2 Boronic Acids; 1.2.2.1 Structure and Bonding; 1.2.2.2 Physical Properties and Handling; 1.2.2.3 Safety Considerations; 1.2.2.4 Acidic Character; 1.2.2.5 Chemical Stability; 1.2.3 Boronic Acid Derivatives; 1.2.3.1 Boroxines; 1.2.3.2 Boronic Esters
1.2.3.3 Dialkoxyboranes and other Heterocyclic Boranes1.2.3.4 Diboronyl Esters; 1.2.3.5 Azaborolidines and other Boron Heterocycles; 1.2.3.6 Dihaloboranes and Monoalkylboranes; 1.2.3.7 Trifluoroborate Salts; 1.3 Synthesis of Boronic Acids and their Esters; 1.3.1 Arylboronic Acids; 1.3.1.1 Electrophilic Trapping of Arylmetal Intermediates with Borates; 1.3.1.2 Transmetallation of Aryl Silanes and Stannanes; 1.3.1.3 Coupling of Aryl Halides with Diboronyl Reagents; 1.3.1.4 Direct Boronylation by Transition Metal-catalyzed Aromatic C-H Functionalization; 1.3.1.5 Other Methods 1.3.2 Diboronic Acids1.3.3 Heterocyclic Boronic Acids; 1.3.4 Alkenylboronic Acids; 1.3.4.1 Electrophilic Trapping of Alkenymetal Intermediates with Borates; 1.3.4.2 Transmetallation Methods; 1.3.4.3 Transition-metal Catalyzed Coupling between Alkenyl Halides/Triflates and Diboronyl Reagents; 1.3.4.4 Hydroboration of Alkynes; 1.3.4.5 Alkene Metathesis; 1.3.4.6 Other Methods; 1.3.5 Alkynylboronic Acids; 1.3.6 Alkylboronic Acids; 1.3.7 Allylic Boronic Acids; 1.3.8 Chemoselective Transformations of Compounds containing a Boronic Acid (Ester) Substituent; 1.3.8.1 Oxidative Methods 1.3.8.2 Reductive Methods1.3.8.3 Generation and Reactions of α-Boronyl-substituted Carbanions and Radicals; 1.3.8.4 Reactions of (α-Haloalkyl)boronic Esters; 1.3.8.5 Other Transformations; 1.4 Isolation and Characterization; 1.4.1 Chromatography and Recrystallization; 1.4.2 Solid Supports for Boronic Acid Immobilization and Purification; 1.4.2.1 Diethanolaminomethyl Polystyrene; 1.4.2.2 Other Solid-supported Diol Resins; 1.4.2.3 Soluble Diol Approaches; 1.4.3 Analytical and Spectroscopic Methods for Boronic Acid Derivatives; 1.4.3.1 Melting Points and Combustion Analysis 1.4.3.2 Mass Spectrometry1.4.3.3 Nuclear Magnetic Resonance Spectroscopy; 1.4.3.4 Other Spectroscopic Methods; 1.5 Overview of the Reactions of Boronic Acid Derivatives; 1.5.1 Metallation and Metal-catalyzed Protodeboronation; 1.5.2 Oxidative Replacement of Boron; 1.5.2.1 Oxygenation; 1.5.2.2 Amination; 1.5.2.3 Halogenation; 1.5.3 Carbon-Carbon Bond forming Processes; 1.5.3.1 Palladium-catalyzed Cross-coupling with Carbon Halides (Suzuki Coupling); 1.5.3.2 Allylation of Carbonyl Compounds; 1.5.3.3 Uncatalyzed Additions to Imines and Iminiums 1.5.3.4 Rhodium-catalyzed Additions to Aldehydes and Alkenes |
| Record Nr. | UNINA-9910877631603321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Functionalization of Carborane via Carboryne Intermediates / / by Da Zhao
| Functionalization of Carborane via Carboryne Intermediates / / by Da Zhao |
| Autore | Zhao Da |
| Edizione | [1st ed. 2016.] |
| Pubbl/distr/stampa | Singapore : , : Springer Singapore : , : Imprint : Springer, , 2016 |
| Descrizione fisica | 1 online resource (XVII, 170 p. 126 illus., 5 illus. in color.) |
| Disciplina | 547.05671 |
| Collana | Springer Theses, Recognizing Outstanding Ph.D. Research |
| Soggetto topico |
Organic chemistry
Physical chemistry Catalysis Organic Chemistry Physical Chemistry |
| ISBN | 981-10-1569-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Introduction -- Regioselective Insertion of ο-Carborynes into α-C−H Bond of Tertiary Amines -- Synthesis of Carborane-Functionalized Heterocycles: Dearomative [2 + 2] Cycloaddition and sp2 C–H Insertion Reaction -- Reaction of ο-Carboryne with Nitrones: A Formal [5 + 2] Cycloaddition -- 1,3-Dehydro-ο-Carborane: Generation and Reaction with Arenes -- Ene Reaction of 1,3-Dehydro-ο-Carborane -- Cage Boron Arylation of ο-Carborane via Metal-Free, Visible-Light-Mediated Radical Coupling -- Conclusion -- Experimental Section. |
| Record Nr. | UNINA-9910254057903321 |
Zhao Da
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| Singapore : , : Springer Singapore : , : Imprint : Springer, , 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organometallic compounds of boron / edited by K. Smith
| Organometallic compounds of boron / edited by K. Smith |
| Pubbl/distr/stampa | London ; New York : Chapman and Hall, 1985 |
| Descrizione fisica | xi, 304 p. : ill. ; 29 cm |
| Disciplina | 547.05671 |
| Altri autori (Persone) | Smith, K. |
| Collana | Chapman and Hall chemistry sourcebooks |
| Soggetto topico | Organoboron compounds - Handbooks |
| ISBN | 041226790X (pbk.) |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991004014869707536 |
| London ; New York : Chapman and Hall, 1985 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
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Synthesis and Application of Organoboron Compounds / / edited by Elena Fernández, Andrew Whiting
| Synthesis and Application of Organoboron Compounds / / edited by Elena Fernández, Andrew Whiting |
| Edizione | [1st ed. 2015.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015 |
| Descrizione fisica | 1 online resource (VII, 331 p. 492 illus., 14 illus. in color.) |
| Disciplina | 547.05671 |
| Collana | Topics in Organometallic Chemistry |
| Soggetto topico |
Organometallic chemistry
Catalysis Chemical engineering Organometallic Chemistry Industrial Chemistry/Chemical Engineering |
| ISBN | 3-319-13054-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- Preface -- Contents -- Boryl Anions -- 1 Introduction: History of Boryl Anions Before 2006 -- 2 Chemistry of Boryl Anions -- 2.1 Base-Stabilized Boryl Anions -- 2.2 N-Heterocyclic Boryl Anions -- 2.3 Boryl Anion Derivatives as a Counterpart of Carboanions -- 2.4 Base-Coordinated Diborane(4) as Boryl Anion Equivalents -- 3 Chemistry of Boryl-Transition Metal Complexes Derived from Boryl Anion -- 3.1 Boryl Complexes of Late Transition Metals (Groups 11-12) -- 3.2 Boryl Complexes of Early Transition Metals (Groups 3-5) -- 4 Chemistry of Boryl-Substituted Main Group Element Compounds Derived from Boryl Anions -- 4.1 Boryl-Substituted Group 13 Element Compounds -- 4.2 Boryl-Substituted Group 14 Element Compounds -- 4.3 Boryl-Substituted Group 15 Element Compounds -- 5 Summary and Outlook -- References -- Fundamental and Applied Properties of Borocations -- 1 Introduction -- 2 Fundamentals -- 2.1 Select Synthetic Considerations -- 2.2 Electrophilicity of Borocations -- 2.3 General Reactivity Pathways of Borocations with Nucleophiles -- 3 Borocations in Dehydroboration -- 3.1 Intramolecular Electrophilic Aromatic Borylation -- 3.2 Intramolecular Electrophilic Aliphatic Borylation -- 3.3 Intermolecular Electrophilic Aromatic Borylation -- 4 Borocations in Elemento-Boration -- 4.1 Hydroboration -- 4.2 Other Elemento-Boration Reactions -- 5 Borocations in Catalysis -- 6 Miscellaneous Applications of Borocations -- 6.1 Materials Applications -- 6.2 Borocations as Precursors to Borylenes and Boryl Radicals -- 6.3 Structural Rearrangement of Borocations -- 7 Conclusions and Future Outlook -- References -- Asymmetric Catalytic Borylation of α,beta-Unsaturated Acceptors -- 1 Introduction -- 2 Asymmetric beta-Borylation with Transition Metal Catalysts -- 2.1 Cu-Catalyzed beta-Borylation -- 2.1.1 beta-Monosubstituted Acyclic Substrates.
2.1.2 beta,beta-Disubstituted Acyclic Substrates: Formation of Organoboronates with a Quaternary Carbon -- 2.1.3 Cyclic Compounds -- 2.1.4 α,beta-Unsaturated C=N Compounds and N-Containing Compounds -- 2.1.5 Extended Michael Acceptors -- 2.2 Rh-Catalyzed beta-Borylation -- 2.3 Ni- and Pd-Catalyzed beta-Borylation -- 3 Asymmetric beta-Borylation with Organocatalysts -- 4 Asymmetric beta-Borylation in Water -- 5 Conclusions -- References -- Reactions of Alkynylboron Compounds -- 1 Introduction -- 2 Alkynylboronates (Esters of Alkynylboronic Acids) -- 2.1 Preparations -- 2.2 Insertion Reactions -- 2.3 Cycloaddition Reactions -- 2.4 Miscellaneous -- 3 Alkynylborates (Ate-Complexes) -- 3.1 Preparations -- 3.2 Uncatalyzed Reactions -- 3.3 Transition Metal-Catalyzed Reactions -- 3.4 Reactions Through Intermediacy of Alkynyl(Triorganyl)Borates -- 4 Conclusions -- References -- Improving Transformations Through Organotrifluoroborates -- 1 Introduction -- 2 Improvements Toward Organotrifluoroborate Synthesis -- 3 Recent Advances in C-C Bond Formation with Organotrifluoroborates -- 3.1 Cross-Coupling of Novel Organotrifluoroborates -- 3.2 Improved Incorporation of Important Scaffolds -- 3.3 C-H Functionalization with Organotrifluoroborates -- 3.4 Enantioselective C-C Bond Formation -- 3.5 Radical Reactions with Organotrifluoroborates -- 4 C-Y Bond Formation from Organotrifluoroborates -- 4.1 C-O Bond Formation -- 4.2 C-N Bond Formation -- 4.3 C-X Bond Formation -- 5 Using Organotrifluoroborates to Construct Novel Scaffolds -- 6 Conclusions and Outlook -- References -- The Catalytic Dehydrocoupling of Amine-Boranes and Phosphine-Boranes -- 1 Introduction -- 2 Transition-Metal-Catalysed Dehydrocoupling of Amine-Boranes -- 2.1 General Considerations -- 2.2 Aminoboranes: Observation and Trapping -- 2.3 Linear Diborazanes. 2.4 Early Examples of Metal-Catalysed Dehydrocoupling -- 2.5 Heterogeneous Catalysts for the Dehydrocoupling of Amine-Boranes -- 2.6 Transition-Metal-Catalysed Dehydrocoupling of H3BNH3 Promoted by Ionic Liquids -- 2.7 Homogeneous Dehydrocoupling of Amine-Boranes -- 2.7.1 Sigma Complexes of Amine-Boranes -- 2.8 Mechanistic Studies on Homogeneous Dehydrocoupling Systems -- 2.8.1 Early Transition Metals -- 2.8.2 Mid-Transition Metals -- 2.8.3 Late Transition Metals -- 2.8.4 Dehydrocoupling of Amine-Boranes Involving Ligand Cooperativity -- 2.8.5 The Role of Solvent in Dehydrocoupling Using Late Transition Metals -- 2.9 Generic Mechanisms for Dehydrocoupling of H3BNMe2H Using Transition Metals -- 2.10 Main-Group Element-Catalysed Dehydrocoupling of Amine-Boranes -- 2.10.1 Main-Group Amidoboranes: Stoichiometric Studies -- 2.10.2 Group 2 Metal-Catalysed Dehydrocoupling of Amine-Boranes -- 2.10.3 Group 3 Metal-Catalysed Dehydrocoupling of Amine-Boranes -- 2.10.4 P-Block-Catalysed Dehydrocoupling of Amine-Boranes -- 2.10.5 Frustrated Lewis Pair Dehydrogenation of Amine-Boranes -- 3 Dehydrocoupling of Phosphine-Boranes -- 3.1 Transition-Metal-Catalysed Dehydrocoupling of Phosphine-Boranes -- 3.2 Determination of the Active Catalytic Species: Hetero- or Homogeneous -- 3.3 Sigma Complexes and B-Agostic Interactions of Phosphine-Boranes -- 3.4 Stabilised Phosphinoboranes -- 3.5 Group 8 Metal-Catalysed Dehydrocoupling of Phosphine-Boranes -- 3.6 Mechanistic Investigations into the Rhodium-Catalysed Dehydrocoupling of Secondary Phosphine-Boranes -- 3.7 Mechanistic Investigation into the Rhodium-Catalysed Dehydrocoupling of Primary Phosphine-Boranes -- 3.8 Lewis Acid-Catalysed Dehydrocoupling of Phosphine-Boranes -- 4 Future Prospects -- References -- At the Forefront of the Suzuki-Miyaura Reaction: Advances in Stereoselective Cross-Couplings -- 1 Introduction. 2 Applications to the Synthesis of Enantioenriched Atropisomers -- 3 Mechanistic Considerations in the Suzuki-Miyaura Cross-Coupling of sp3 Centres -- 3.1 Challenges Associated with the Coupling of Saturated Carbon Centres -- 3.2 Stereochemistry of Various Steps in the Suzuki-Miyaura Cross-Coupling Mechanism -- 4 Stereoselective C(sp3)-C(sp2) Suzuki-Miyaura Cross-Coupling Reactions -- 4.1 Stereoselective Couplings of Alkyl Boronates with Aryl or Alkenyl Halides -- 4.2 Stereoselective Couplings of Alkyl Halides and Pseudohalides with Aryl or Alkenyl Boronates -- 5 Stereoselective C(sp3)-C(sp3) Suzuki-Miyaura Cross-Coupling Reactions -- 5.1 Stereoselective Couplings of Alkyl Boranes with Alkyl Halides -- 6 Summary and Outlook -- References -- Boronic Acid-Catalyzed Reactions of Carboxylic Acids -- 1 Introduction -- 2 B(III)-Catalyzed Reactions of α,beta-Unsaturated Carboxylic Acids -- 3 B(III)-Catalyzed Dehydrative Condensation to Carboxamides -- 4 B(III)-Catalyzed Dehydrative Condensation to Carboxylic Acid Esters -- 5 B(III)-Catalyzed Dehydrative Condensation to Carboxylic Anhydrides -- 6 Other B(III)-Catalyzed Reactions -- 7 Conclusions -- References -- Reagent-Controlled Lithiation-Borylation -- 1 Introduction -- 2 Mechanism of Lithiation-Borylation Processes -- 3 α-Chloro-Stabilized Lithium Carbenoids -- 4 α-O-Stabilized Organolithiums -- 4.1 Primary Carbamates/Benzoates -- 4.2 Secondary Benzylic Carbamates -- 4.3 Secondary Allylic/Propargylic Carbamates -- 4.4 Secondary Benzoates -- 5 α-N-Stabilized Organolithiums -- 6 Conclusions and Outlook -- References -- Recent Advances in the Synthesis and Applications of Organoborane Polymers -- 1 Introduction -- 2 Synthesis of Organoborane Polymers -- 2.1 Polymer Modification Reactions on Polyolefins -- 2.2 Direct Polymerization of Borane Monomers by Chain Growth Methods. 2.3 Side-Chain Functionalization of Conjugated Polymers -- 2.4 Boron Incorporation into the Main Chain of Conjugated Polymers -- 3 Selected Examples of Polymers and Their Applications -- 3.1 Borane Polymers as Lewis Acids and Anion Sensors -- 3.2 Luminescent Polymers Based on Boron Chelate Complexes -- 3.2.1 Boron Quinolate-Functionalized Polymers -- 3.2.2 BODIPY-Functionalized Polymers -- 3.2.3 Boron Diketonate-Functionalized Polymers -- 3.3 Boronic and Borinic Acid-Functionalized Polymers for Biomedical Applications and as Smart Materials -- 3.4 Borate and Boronium-Functionalized Polymers as Polyelectrolytes and Polymeric Ligand -- 4 Conclusions -- References -- Index. |
| Record Nr. | UNINA-9910768440103321 |
| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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