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Ruthenium in organic synthesis [[electronic resource] /] / Shun-Ichi Murahashi (Ed.)
Ruthenium in organic synthesis [[electronic resource] /] / Shun-Ichi Murahashi (Ed.)
Pubbl/distr/stampa Weinheim ; ; [Great Britain], : Wiley-VCH, c2004
Descrizione fisica 1 online resource (401 p.)
Disciplina 547.05632
Altri autori (Persone) MurahashiShunʼichi <1937->
Soggetto topico Organometallic chemistry
Organoruthenium compounds
Ruthenium
Soggetto genere / forma Electronic books.
ISBN 1-280-52073-6
9786610520732
3-527-60383-2
3-527-60579-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ruthenium in Organic Synthesis; Contents; Preface; List of Contributors; 1 Introduction; 2 Hydrogenation and Transfer Hydrogenation; 2.1 Introduction; 2.2 Hydrogenation; 2.2.1 Unfunctionalized Olefins; 2.2.2 Functionalized Olefins; 2.2.3 Unfunctionalized Ketones and Aldehydes; 2.2.4 Functionalized Ketones; 2.2.5 Imines; 2.2.6 Others; 2.3 Transfer Hydrogenation; 2.3.1 Olefins; 2.3.2 Ketones and Aldehydes; 2.3.3 Imines; 2.3.4 Others; 2.4 Concluding Remarks; 3 Oxidation Reactions; 3.1 Introduction; 3.2 Dehydrogenative Oxidation; 3.2.1 Oxidation of Alcohols; 3.2.2 Oxidative Amination of Alcohols
3.2.3 Oxidation of Secondary and Primary Amines3.3 Oxidation with RuO(4); 3.4 Oxidation with Ruthenium Complex Catalysts and Oxidants; 3.4.1 Oxidation of Alcohols; 3.4.2 Oxidation of Alkenes; 3.4.3 Oxidation of Amines; 3.4.4 Oxidation of Amides and β-Lactams; 3.4.5 Oxidation of Phenols; 3.4.6 Oxidation of Hydrocarbons; 3.5 Conclusions; 4 Carbon-Carbon Bond Formations via Ruthenacycle Intermediates; 4.1 Introduction; 4.2 C-C Bond Formations Involving Ruthenacyclopentadiene/Ruthenacyclopentatriene; 4.2.1 Alkyne Cyclotrimerizations
4.2.2 Cyclocotrimerizations of Alkynes with Other Unsaturated Molecules and Related Reactions4.2.3 Miscellaneous Reactions; 4.3 C-C Bond Formations Involving Ruthenacyclopentene; 4.3.1 Coupling Reactions Between Alkynes and Alkenes; 4.3.2 Three-Component Couplings of Alkynes, Alkenes, and Other Unsaturated Molecules; 4.3.3 Intramolecular Coupling of Alkynes with Enones and Vinylcyclopropanes; 4.4 C-C Bond Formations Involving Ruthenacyclopentane; 4.5 C-C Bond Formations Involving Ruthenacyclopentenedione and Ruthenacyclobutenone; 4.6 Conclusion
5 Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates5.1 Introduction; 5.2 Synthesis, Structure, and Reactivity of π-Allylruthenium Complexes; 5.2.1 π-Allylruthenium(II) Complexes; 5.2.2 π-Allylruthenium(IV) Complexes; 5.2.3 π-Allylruthenium Clusters; 5.2.4 Reactivity and Catalytic Activity of (π-C(3)H(5))Ru(CO)(3)X (X = Cl or Br); 5.3 Catalytic Reactions via π-Allylruthenium Intermediates; 5.3.1 C-C Bond Formation via π-Allylruthenium Intermediates; 5.3.2 Miscellaneous Reactions via π-Allylruthenium Intermediates; 6 Ruthenium-Catalyzed Olefin Metathesis; 6.1 Introduction
6.2 Ruthenium Olefin Metathesis Catalysts6.2.1 Mechanistic Considerations; 6.2.2 Case Study: Developing a Ruthenium-Carbene Catalyst for Acrylonitrile Metathesis; 6.3 Applications of Ruthenium-Catalyzed Olefin Metathesis in Organic Synthesis; 6.3.1 Ring-Closing Metathesis; 6.3.2 Cross Metathesis; 6.3.3 Combination Metathesis Processes; 6.4 Summary; 7 Ruthenium-Catalyzed Cyclopropanation; 7.1 Introduction; 7.2 Asymmetric Catalytic Cyclopropanation; 7.2.1 Styrene; 7.2.2 Other Olefins; 7.3 Non-Asymmetric Catalytic Cyclopropanation; 7.4 Carbene-Complexes and Mechanisms; 7.5 Conclusions
8 Nucleophilic Additions to Alkynes and Reactions via Vinylidene Intermediates
Record Nr. UNINA-9910144298003321
Weinheim ; ; [Great Britain], : Wiley-VCH, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ruthenium in organic synthesis [[electronic resource] /] / Shun-Ichi Murahashi (Ed.)
Ruthenium in organic synthesis [[electronic resource] /] / Shun-Ichi Murahashi (Ed.)
Pubbl/distr/stampa Weinheim ; ; [Great Britain], : Wiley-VCH, c2004
Descrizione fisica 1 online resource (401 p.)
Disciplina 547.05632
Altri autori (Persone) MurahashiShunʼichi <1937->
Soggetto topico Organometallic chemistry
Organoruthenium compounds
Ruthenium
ISBN 1-280-52073-6
9786610520732
3-527-60383-2
3-527-60579-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ruthenium in Organic Synthesis; Contents; Preface; List of Contributors; 1 Introduction; 2 Hydrogenation and Transfer Hydrogenation; 2.1 Introduction; 2.2 Hydrogenation; 2.2.1 Unfunctionalized Olefins; 2.2.2 Functionalized Olefins; 2.2.3 Unfunctionalized Ketones and Aldehydes; 2.2.4 Functionalized Ketones; 2.2.5 Imines; 2.2.6 Others; 2.3 Transfer Hydrogenation; 2.3.1 Olefins; 2.3.2 Ketones and Aldehydes; 2.3.3 Imines; 2.3.4 Others; 2.4 Concluding Remarks; 3 Oxidation Reactions; 3.1 Introduction; 3.2 Dehydrogenative Oxidation; 3.2.1 Oxidation of Alcohols; 3.2.2 Oxidative Amination of Alcohols
3.2.3 Oxidation of Secondary and Primary Amines3.3 Oxidation with RuO(4); 3.4 Oxidation with Ruthenium Complex Catalysts and Oxidants; 3.4.1 Oxidation of Alcohols; 3.4.2 Oxidation of Alkenes; 3.4.3 Oxidation of Amines; 3.4.4 Oxidation of Amides and β-Lactams; 3.4.5 Oxidation of Phenols; 3.4.6 Oxidation of Hydrocarbons; 3.5 Conclusions; 4 Carbon-Carbon Bond Formations via Ruthenacycle Intermediates; 4.1 Introduction; 4.2 C-C Bond Formations Involving Ruthenacyclopentadiene/Ruthenacyclopentatriene; 4.2.1 Alkyne Cyclotrimerizations
4.2.2 Cyclocotrimerizations of Alkynes with Other Unsaturated Molecules and Related Reactions4.2.3 Miscellaneous Reactions; 4.3 C-C Bond Formations Involving Ruthenacyclopentene; 4.3.1 Coupling Reactions Between Alkynes and Alkenes; 4.3.2 Three-Component Couplings of Alkynes, Alkenes, and Other Unsaturated Molecules; 4.3.3 Intramolecular Coupling of Alkynes with Enones and Vinylcyclopropanes; 4.4 C-C Bond Formations Involving Ruthenacyclopentane; 4.5 C-C Bond Formations Involving Ruthenacyclopentenedione and Ruthenacyclobutenone; 4.6 Conclusion
5 Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates5.1 Introduction; 5.2 Synthesis, Structure, and Reactivity of π-Allylruthenium Complexes; 5.2.1 π-Allylruthenium(II) Complexes; 5.2.2 π-Allylruthenium(IV) Complexes; 5.2.3 π-Allylruthenium Clusters; 5.2.4 Reactivity and Catalytic Activity of (π-C(3)H(5))Ru(CO)(3)X (X = Cl or Br); 5.3 Catalytic Reactions via π-Allylruthenium Intermediates; 5.3.1 C-C Bond Formation via π-Allylruthenium Intermediates; 5.3.2 Miscellaneous Reactions via π-Allylruthenium Intermediates; 6 Ruthenium-Catalyzed Olefin Metathesis; 6.1 Introduction
6.2 Ruthenium Olefin Metathesis Catalysts6.2.1 Mechanistic Considerations; 6.2.2 Case Study: Developing a Ruthenium-Carbene Catalyst for Acrylonitrile Metathesis; 6.3 Applications of Ruthenium-Catalyzed Olefin Metathesis in Organic Synthesis; 6.3.1 Ring-Closing Metathesis; 6.3.2 Cross Metathesis; 6.3.3 Combination Metathesis Processes; 6.4 Summary; 7 Ruthenium-Catalyzed Cyclopropanation; 7.1 Introduction; 7.2 Asymmetric Catalytic Cyclopropanation; 7.2.1 Styrene; 7.2.2 Other Olefins; 7.3 Non-Asymmetric Catalytic Cyclopropanation; 7.4 Carbene-Complexes and Mechanisms; 7.5 Conclusions
8 Nucleophilic Additions to Alkynes and Reactions via Vinylidene Intermediates
Record Nr. UNINA-9910830356103321
Weinheim ; ; [Great Britain], : Wiley-VCH, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ruthenium in organic synthesis / / Shun-Ichi Murahashi (Ed.)
Ruthenium in organic synthesis / / Shun-Ichi Murahashi (Ed.)
Pubbl/distr/stampa Weinheim ; ; [Great Britain], : Wiley-VCH, c2004
Descrizione fisica 1 online resource (401 p.)
Disciplina 547.05632
Altri autori (Persone) MurahashiShunichi <1937->
Soggetto topico Organometallic chemistry
Organoruthenium compounds
Ruthenium
ISBN 1-280-52073-6
9786610520732
3-527-60383-2
3-527-60579-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ruthenium in Organic Synthesis; Contents; Preface; List of Contributors; 1 Introduction; 2 Hydrogenation and Transfer Hydrogenation; 2.1 Introduction; 2.2 Hydrogenation; 2.2.1 Unfunctionalized Olefins; 2.2.2 Functionalized Olefins; 2.2.3 Unfunctionalized Ketones and Aldehydes; 2.2.4 Functionalized Ketones; 2.2.5 Imines; 2.2.6 Others; 2.3 Transfer Hydrogenation; 2.3.1 Olefins; 2.3.2 Ketones and Aldehydes; 2.3.3 Imines; 2.3.4 Others; 2.4 Concluding Remarks; 3 Oxidation Reactions; 3.1 Introduction; 3.2 Dehydrogenative Oxidation; 3.2.1 Oxidation of Alcohols; 3.2.2 Oxidative Amination of Alcohols
3.2.3 Oxidation of Secondary and Primary Amines3.3 Oxidation with RuO(4); 3.4 Oxidation with Ruthenium Complex Catalysts and Oxidants; 3.4.1 Oxidation of Alcohols; 3.4.2 Oxidation of Alkenes; 3.4.3 Oxidation of Amines; 3.4.4 Oxidation of Amides and β-Lactams; 3.4.5 Oxidation of Phenols; 3.4.6 Oxidation of Hydrocarbons; 3.5 Conclusions; 4 Carbon-Carbon Bond Formations via Ruthenacycle Intermediates; 4.1 Introduction; 4.2 C-C Bond Formations Involving Ruthenacyclopentadiene/Ruthenacyclopentatriene; 4.2.1 Alkyne Cyclotrimerizations
4.2.2 Cyclocotrimerizations of Alkynes with Other Unsaturated Molecules and Related Reactions4.2.3 Miscellaneous Reactions; 4.3 C-C Bond Formations Involving Ruthenacyclopentene; 4.3.1 Coupling Reactions Between Alkynes and Alkenes; 4.3.2 Three-Component Couplings of Alkynes, Alkenes, and Other Unsaturated Molecules; 4.3.3 Intramolecular Coupling of Alkynes with Enones and Vinylcyclopropanes; 4.4 C-C Bond Formations Involving Ruthenacyclopentane; 4.5 C-C Bond Formations Involving Ruthenacyclopentenedione and Ruthenacyclobutenone; 4.6 Conclusion
5 Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates5.1 Introduction; 5.2 Synthesis, Structure, and Reactivity of π-Allylruthenium Complexes; 5.2.1 π-Allylruthenium(II) Complexes; 5.2.2 π-Allylruthenium(IV) Complexes; 5.2.3 π-Allylruthenium Clusters; 5.2.4 Reactivity and Catalytic Activity of (π-C(3)H(5))Ru(CO)(3)X (X = Cl or Br); 5.3 Catalytic Reactions via π-Allylruthenium Intermediates; 5.3.1 C-C Bond Formation via π-Allylruthenium Intermediates; 5.3.2 Miscellaneous Reactions via π-Allylruthenium Intermediates; 6 Ruthenium-Catalyzed Olefin Metathesis; 6.1 Introduction
6.2 Ruthenium Olefin Metathesis Catalysts6.2.1 Mechanistic Considerations; 6.2.2 Case Study: Developing a Ruthenium-Carbene Catalyst for Acrylonitrile Metathesis; 6.3 Applications of Ruthenium-Catalyzed Olefin Metathesis in Organic Synthesis; 6.3.1 Ring-Closing Metathesis; 6.3.2 Cross Metathesis; 6.3.3 Combination Metathesis Processes; 6.4 Summary; 7 Ruthenium-Catalyzed Cyclopropanation; 7.1 Introduction; 7.2 Asymmetric Catalytic Cyclopropanation; 7.2.1 Styrene; 7.2.2 Other Olefins; 7.3 Non-Asymmetric Catalytic Cyclopropanation; 7.4 Carbene-Complexes and Mechanisms; 7.5 Conclusions
8 Nucleophilic Additions to Alkynes and Reactions via Vinylidene Intermediates
Record Nr. UNINA-9911019484103321
Weinheim ; ; [Great Britain], : Wiley-VCH, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui