Ruthenium in organic synthesis [[electronic resource] /] / Shun-Ichi Murahashi (Ed.)
| Ruthenium in organic synthesis [[electronic resource] /] / Shun-Ichi Murahashi (Ed.) |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (401 p.) |
| Disciplina | 547.05632 |
| Altri autori (Persone) | MurahashiShunʼichi <1937-> |
| Soggetto topico |
Organometallic chemistry
Organoruthenium compounds Ruthenium |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-52073-6
9786610520732 3-527-60383-2 3-527-60579-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ruthenium in Organic Synthesis; Contents; Preface; List of Contributors; 1 Introduction; 2 Hydrogenation and Transfer Hydrogenation; 2.1 Introduction; 2.2 Hydrogenation; 2.2.1 Unfunctionalized Olefins; 2.2.2 Functionalized Olefins; 2.2.3 Unfunctionalized Ketones and Aldehydes; 2.2.4 Functionalized Ketones; 2.2.5 Imines; 2.2.6 Others; 2.3 Transfer Hydrogenation; 2.3.1 Olefins; 2.3.2 Ketones and Aldehydes; 2.3.3 Imines; 2.3.4 Others; 2.4 Concluding Remarks; 3 Oxidation Reactions; 3.1 Introduction; 3.2 Dehydrogenative Oxidation; 3.2.1 Oxidation of Alcohols; 3.2.2 Oxidative Amination of Alcohols
3.2.3 Oxidation of Secondary and Primary Amines3.3 Oxidation with RuO(4); 3.4 Oxidation with Ruthenium Complex Catalysts and Oxidants; 3.4.1 Oxidation of Alcohols; 3.4.2 Oxidation of Alkenes; 3.4.3 Oxidation of Amines; 3.4.4 Oxidation of Amides and β-Lactams; 3.4.5 Oxidation of Phenols; 3.4.6 Oxidation of Hydrocarbons; 3.5 Conclusions; 4 Carbon-Carbon Bond Formations via Ruthenacycle Intermediates; 4.1 Introduction; 4.2 C-C Bond Formations Involving Ruthenacyclopentadiene/Ruthenacyclopentatriene; 4.2.1 Alkyne Cyclotrimerizations 4.2.2 Cyclocotrimerizations of Alkynes with Other Unsaturated Molecules and Related Reactions4.2.3 Miscellaneous Reactions; 4.3 C-C Bond Formations Involving Ruthenacyclopentene; 4.3.1 Coupling Reactions Between Alkynes and Alkenes; 4.3.2 Three-Component Couplings of Alkynes, Alkenes, and Other Unsaturated Molecules; 4.3.3 Intramolecular Coupling of Alkynes with Enones and Vinylcyclopropanes; 4.4 C-C Bond Formations Involving Ruthenacyclopentane; 4.5 C-C Bond Formations Involving Ruthenacyclopentenedione and Ruthenacyclobutenone; 4.6 Conclusion 5 Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates5.1 Introduction; 5.2 Synthesis, Structure, and Reactivity of π-Allylruthenium Complexes; 5.2.1 π-Allylruthenium(II) Complexes; 5.2.2 π-Allylruthenium(IV) Complexes; 5.2.3 π-Allylruthenium Clusters; 5.2.4 Reactivity and Catalytic Activity of (π-C(3)H(5))Ru(CO)(3)X (X = Cl or Br); 5.3 Catalytic Reactions via π-Allylruthenium Intermediates; 5.3.1 C-C Bond Formation via π-Allylruthenium Intermediates; 5.3.2 Miscellaneous Reactions via π-Allylruthenium Intermediates; 6 Ruthenium-Catalyzed Olefin Metathesis; 6.1 Introduction 6.2 Ruthenium Olefin Metathesis Catalysts6.2.1 Mechanistic Considerations; 6.2.2 Case Study: Developing a Ruthenium-Carbene Catalyst for Acrylonitrile Metathesis; 6.3 Applications of Ruthenium-Catalyzed Olefin Metathesis in Organic Synthesis; 6.3.1 Ring-Closing Metathesis; 6.3.2 Cross Metathesis; 6.3.3 Combination Metathesis Processes; 6.4 Summary; 7 Ruthenium-Catalyzed Cyclopropanation; 7.1 Introduction; 7.2 Asymmetric Catalytic Cyclopropanation; 7.2.1 Styrene; 7.2.2 Other Olefins; 7.3 Non-Asymmetric Catalytic Cyclopropanation; 7.4 Carbene-Complexes and Mechanisms; 7.5 Conclusions 8 Nucleophilic Additions to Alkynes and Reactions via Vinylidene Intermediates |
| Record Nr. | UNINA-9910144298003321 |
| Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ruthenium in organic synthesis [[electronic resource] /] / Shun-Ichi Murahashi (Ed.)
| Ruthenium in organic synthesis [[electronic resource] /] / Shun-Ichi Murahashi (Ed.) |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (401 p.) |
| Disciplina | 547.05632 |
| Altri autori (Persone) | MurahashiShunʼichi <1937-> |
| Soggetto topico |
Organometallic chemistry
Organoruthenium compounds Ruthenium |
| ISBN |
1-280-52073-6
9786610520732 3-527-60383-2 3-527-60579-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ruthenium in Organic Synthesis; Contents; Preface; List of Contributors; 1 Introduction; 2 Hydrogenation and Transfer Hydrogenation; 2.1 Introduction; 2.2 Hydrogenation; 2.2.1 Unfunctionalized Olefins; 2.2.2 Functionalized Olefins; 2.2.3 Unfunctionalized Ketones and Aldehydes; 2.2.4 Functionalized Ketones; 2.2.5 Imines; 2.2.6 Others; 2.3 Transfer Hydrogenation; 2.3.1 Olefins; 2.3.2 Ketones and Aldehydes; 2.3.3 Imines; 2.3.4 Others; 2.4 Concluding Remarks; 3 Oxidation Reactions; 3.1 Introduction; 3.2 Dehydrogenative Oxidation; 3.2.1 Oxidation of Alcohols; 3.2.2 Oxidative Amination of Alcohols
3.2.3 Oxidation of Secondary and Primary Amines3.3 Oxidation with RuO(4); 3.4 Oxidation with Ruthenium Complex Catalysts and Oxidants; 3.4.1 Oxidation of Alcohols; 3.4.2 Oxidation of Alkenes; 3.4.3 Oxidation of Amines; 3.4.4 Oxidation of Amides and β-Lactams; 3.4.5 Oxidation of Phenols; 3.4.6 Oxidation of Hydrocarbons; 3.5 Conclusions; 4 Carbon-Carbon Bond Formations via Ruthenacycle Intermediates; 4.1 Introduction; 4.2 C-C Bond Formations Involving Ruthenacyclopentadiene/Ruthenacyclopentatriene; 4.2.1 Alkyne Cyclotrimerizations 4.2.2 Cyclocotrimerizations of Alkynes with Other Unsaturated Molecules and Related Reactions4.2.3 Miscellaneous Reactions; 4.3 C-C Bond Formations Involving Ruthenacyclopentene; 4.3.1 Coupling Reactions Between Alkynes and Alkenes; 4.3.2 Three-Component Couplings of Alkynes, Alkenes, and Other Unsaturated Molecules; 4.3.3 Intramolecular Coupling of Alkynes with Enones and Vinylcyclopropanes; 4.4 C-C Bond Formations Involving Ruthenacyclopentane; 4.5 C-C Bond Formations Involving Ruthenacyclopentenedione and Ruthenacyclobutenone; 4.6 Conclusion 5 Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates5.1 Introduction; 5.2 Synthesis, Structure, and Reactivity of π-Allylruthenium Complexes; 5.2.1 π-Allylruthenium(II) Complexes; 5.2.2 π-Allylruthenium(IV) Complexes; 5.2.3 π-Allylruthenium Clusters; 5.2.4 Reactivity and Catalytic Activity of (π-C(3)H(5))Ru(CO)(3)X (X = Cl or Br); 5.3 Catalytic Reactions via π-Allylruthenium Intermediates; 5.3.1 C-C Bond Formation via π-Allylruthenium Intermediates; 5.3.2 Miscellaneous Reactions via π-Allylruthenium Intermediates; 6 Ruthenium-Catalyzed Olefin Metathesis; 6.1 Introduction 6.2 Ruthenium Olefin Metathesis Catalysts6.2.1 Mechanistic Considerations; 6.2.2 Case Study: Developing a Ruthenium-Carbene Catalyst for Acrylonitrile Metathesis; 6.3 Applications of Ruthenium-Catalyzed Olefin Metathesis in Organic Synthesis; 6.3.1 Ring-Closing Metathesis; 6.3.2 Cross Metathesis; 6.3.3 Combination Metathesis Processes; 6.4 Summary; 7 Ruthenium-Catalyzed Cyclopropanation; 7.1 Introduction; 7.2 Asymmetric Catalytic Cyclopropanation; 7.2.1 Styrene; 7.2.2 Other Olefins; 7.3 Non-Asymmetric Catalytic Cyclopropanation; 7.4 Carbene-Complexes and Mechanisms; 7.5 Conclusions 8 Nucleophilic Additions to Alkynes and Reactions via Vinylidene Intermediates |
| Record Nr. | UNINA-9910830356103321 |
| Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ruthenium in organic synthesis / / Shun-Ichi Murahashi (Ed.)
| Ruthenium in organic synthesis / / Shun-Ichi Murahashi (Ed.) |
| Pubbl/distr/stampa | Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (401 p.) |
| Disciplina | 547.05632 |
| Altri autori (Persone) | MurahashiShunichi <1937-> |
| Soggetto topico |
Organometallic chemistry
Organoruthenium compounds Ruthenium |
| ISBN |
1-280-52073-6
9786610520732 3-527-60383-2 3-527-60579-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ruthenium in Organic Synthesis; Contents; Preface; List of Contributors; 1 Introduction; 2 Hydrogenation and Transfer Hydrogenation; 2.1 Introduction; 2.2 Hydrogenation; 2.2.1 Unfunctionalized Olefins; 2.2.2 Functionalized Olefins; 2.2.3 Unfunctionalized Ketones and Aldehydes; 2.2.4 Functionalized Ketones; 2.2.5 Imines; 2.2.6 Others; 2.3 Transfer Hydrogenation; 2.3.1 Olefins; 2.3.2 Ketones and Aldehydes; 2.3.3 Imines; 2.3.4 Others; 2.4 Concluding Remarks; 3 Oxidation Reactions; 3.1 Introduction; 3.2 Dehydrogenative Oxidation; 3.2.1 Oxidation of Alcohols; 3.2.2 Oxidative Amination of Alcohols
3.2.3 Oxidation of Secondary and Primary Amines3.3 Oxidation with RuO(4); 3.4 Oxidation with Ruthenium Complex Catalysts and Oxidants; 3.4.1 Oxidation of Alcohols; 3.4.2 Oxidation of Alkenes; 3.4.3 Oxidation of Amines; 3.4.4 Oxidation of Amides and β-Lactams; 3.4.5 Oxidation of Phenols; 3.4.6 Oxidation of Hydrocarbons; 3.5 Conclusions; 4 Carbon-Carbon Bond Formations via Ruthenacycle Intermediates; 4.1 Introduction; 4.2 C-C Bond Formations Involving Ruthenacyclopentadiene/Ruthenacyclopentatriene; 4.2.1 Alkyne Cyclotrimerizations 4.2.2 Cyclocotrimerizations of Alkynes with Other Unsaturated Molecules and Related Reactions4.2.3 Miscellaneous Reactions; 4.3 C-C Bond Formations Involving Ruthenacyclopentene; 4.3.1 Coupling Reactions Between Alkynes and Alkenes; 4.3.2 Three-Component Couplings of Alkynes, Alkenes, and Other Unsaturated Molecules; 4.3.3 Intramolecular Coupling of Alkynes with Enones and Vinylcyclopropanes; 4.4 C-C Bond Formations Involving Ruthenacyclopentane; 4.5 C-C Bond Formations Involving Ruthenacyclopentenedione and Ruthenacyclobutenone; 4.6 Conclusion 5 Carbon-Carbon Bond Formation via π-Allylruthenium Intermediates5.1 Introduction; 5.2 Synthesis, Structure, and Reactivity of π-Allylruthenium Complexes; 5.2.1 π-Allylruthenium(II) Complexes; 5.2.2 π-Allylruthenium(IV) Complexes; 5.2.3 π-Allylruthenium Clusters; 5.2.4 Reactivity and Catalytic Activity of (π-C(3)H(5))Ru(CO)(3)X (X = Cl or Br); 5.3 Catalytic Reactions via π-Allylruthenium Intermediates; 5.3.1 C-C Bond Formation via π-Allylruthenium Intermediates; 5.3.2 Miscellaneous Reactions via π-Allylruthenium Intermediates; 6 Ruthenium-Catalyzed Olefin Metathesis; 6.1 Introduction 6.2 Ruthenium Olefin Metathesis Catalysts6.2.1 Mechanistic Considerations; 6.2.2 Case Study: Developing a Ruthenium-Carbene Catalyst for Acrylonitrile Metathesis; 6.3 Applications of Ruthenium-Catalyzed Olefin Metathesis in Organic Synthesis; 6.3.1 Ring-Closing Metathesis; 6.3.2 Cross Metathesis; 6.3.3 Combination Metathesis Processes; 6.4 Summary; 7 Ruthenium-Catalyzed Cyclopropanation; 7.1 Introduction; 7.2 Asymmetric Catalytic Cyclopropanation; 7.2.1 Styrene; 7.2.2 Other Olefins; 7.3 Non-Asymmetric Catalytic Cyclopropanation; 7.4 Carbene-Complexes and Mechanisms; 7.5 Conclusions 8 Nucleophilic Additions to Alkynes and Reactions via Vinylidene Intermediates |
| Record Nr. | UNINA-9911019484103321 |
| Weinheim ; ; [Great Britain], : Wiley-VCH, c2004 | ||
| Lo trovi qui: Univ. Federico II | ||
| ||