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Modern organonickel chemistry [[electronic resource] /] / edited by Yoshinao Tamaru
| Modern organonickel chemistry [[electronic resource] /] / edited by Yoshinao Tamaru |
| Pubbl/distr/stampa | Weinheim [Germany], : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (349 p.) |
| Disciplina | 547.05625 |
| Altri autori (Persone) | TamaruYoshinao <1945-> |
| Soggetto topico |
Organonickel compounds
Chemistry, Organic |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-51963-0
9786610519637 3-527-60484-7 3-527-60423-5 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Organonickel Chemistry; Contents; Preface; List of Contributors; Abbreviations; 1 Introductory Guide to Organonickel Chemistry; 1.1 The Crystal Field; 1.2 Nickel has Wings: The Mond Method; 1.3 The Ligand Field; 1.4 The Formal Oxidation Number; 1.5 The 16- and 18-Electron Rule; 1.6 The Structure, Reactivity, and Electronic Configuration of Nickel-Complexes; 1.7 The Elementary Reactions; 1.7.1 Oxidative Addition; 1.7.2 Insertion; 1.7.3 Transmetallation; 1.7.4 Reductive Elimination; 1.7.5 β-Hydrogen Elimination; 1.7.6 α- and β-Carbon Elimination (C-C Bond Cleavage)
1.8 Catalytic ReactionsReferences; 2 Nickel-catalyzed Cross-coupling Reactions; 2.1 Cross-coupling of Alkyl Electrophiles with Organometallic Compounds; 2.2 Cross-coupling of Alkenyl Electrophiles with Organometallic Compounds; 2.3 Cross-coupling of Allyl Electrophiles with Organometallic Compounds; 2.4 Cross-coupling of Aryl Electrophiles with Organometallic Compounds; 2.5 Asymmetric Cross-coupling Reactions; References; 3 Reaction of Alkenes and Allyl Alcohol Derivatives; 3.1 Hydrovinylation of Olefins; 3.2 Hydrocyanation of Olefins; 3.3 Heck-type Cyclization; 3.4 Olefin Insertion 3.5 Nickel-catalyzed Hydrozincation of Olefins3.6 Ni-catalyzed Addition of Organometallics to Electron-deficient Olefins; 3.6.1 The Reaction with Organometallics; 3.6.2 The Reaction with Organic Halides as Nucleophiles; 3.7 Polymerization of Ethylene and α-Olefins using Ni(II)-based Catalysts; 3.8 The Nucleophilic Reactions of π-Allylnickel Complexes; 3.9 π-Allylnickel Complexes from Enones; 3.10 Carbonylative Cycloaddition of Allylic Halides and Acetylenes; 3.11 Nucleophilic Allylation Toward π-Allylnickel Complexes; 3.11.1 Allylation with Grignard Reagents 3.11.2 Allylation with Soft Nucleophiles3.11.3 Regiochemical Control Based on Internal Chelation; 3.11.4 Organometallics other than Grignard Reagents for Allylation; 3.11.4.1 Ni-catalyzed Allylation with Lithium Borates Derived from Trimethyl Borate; 3.11.4.2 Allylation with Lithium Borates Derived from Acetylene; 3.11.4.3 Allylation with Borates Derived from Cyclic Boronate Esters; 3.11.5 The Design of Functionalized Reagents for Allylation; 3.11.6 Nickel-catalyzed Reactions of Cyclopentenyl Acetate and Borates 3.11.7 Synthetic Application of Nickel-catalyzed Reactions of Cyclopentenyl Acetate and Borates3.11.8 Extension of the Lithium Borate/Nickel Catalyst for Coupling with Alkenyl and Aryl Substrates; 3.12 Nickel Enolates; 3.12.1 Reactions of Ni(II) Complexes with Lithium or Potassium Enolates; 3.12.2 The Reformatsky-type Reaction; 3.12.3 Other Reactions through Nickel Enolates; References; 4 Reaction of Alkynes; 4.1 Hydrogenation; 4.2 Hydrometallation and Related Reactions; 4.2.1 Hydrosilylation and Hydrostannylation; 4.2.2 Hydroboration; 4.2.3 Hydroalumination 4.2.4 Miscellaneous: the Addition of H-P and H-S Groups |
| Record Nr. | UNINA-9910144327903321 |
| Weinheim [Germany], : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern organonickel chemistry [[electronic resource] /] / edited by Yoshinao Tamaru
| Modern organonickel chemistry [[electronic resource] /] / edited by Yoshinao Tamaru |
| Pubbl/distr/stampa | Weinheim [Germany], : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (349 p.) |
| Disciplina | 547.05625 |
| Altri autori (Persone) | TamaruYoshinao <1945-> |
| Soggetto topico |
Organonickel compounds
Chemistry, Organic |
| ISBN |
1-280-51963-0
9786610519637 3-527-60484-7 3-527-60423-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Organonickel Chemistry; Contents; Preface; List of Contributors; Abbreviations; 1 Introductory Guide to Organonickel Chemistry; 1.1 The Crystal Field; 1.2 Nickel has Wings: The Mond Method; 1.3 The Ligand Field; 1.4 The Formal Oxidation Number; 1.5 The 16- and 18-Electron Rule; 1.6 The Structure, Reactivity, and Electronic Configuration of Nickel-Complexes; 1.7 The Elementary Reactions; 1.7.1 Oxidative Addition; 1.7.2 Insertion; 1.7.3 Transmetallation; 1.7.4 Reductive Elimination; 1.7.5 β-Hydrogen Elimination; 1.7.6 α- and β-Carbon Elimination (C-C Bond Cleavage)
1.8 Catalytic ReactionsReferences; 2 Nickel-catalyzed Cross-coupling Reactions; 2.1 Cross-coupling of Alkyl Electrophiles with Organometallic Compounds; 2.2 Cross-coupling of Alkenyl Electrophiles with Organometallic Compounds; 2.3 Cross-coupling of Allyl Electrophiles with Organometallic Compounds; 2.4 Cross-coupling of Aryl Electrophiles with Organometallic Compounds; 2.5 Asymmetric Cross-coupling Reactions; References; 3 Reaction of Alkenes and Allyl Alcohol Derivatives; 3.1 Hydrovinylation of Olefins; 3.2 Hydrocyanation of Olefins; 3.3 Heck-type Cyclization; 3.4 Olefin Insertion 3.5 Nickel-catalyzed Hydrozincation of Olefins3.6 Ni-catalyzed Addition of Organometallics to Electron-deficient Olefins; 3.6.1 The Reaction with Organometallics; 3.6.2 The Reaction with Organic Halides as Nucleophiles; 3.7 Polymerization of Ethylene and α-Olefins using Ni(II)-based Catalysts; 3.8 The Nucleophilic Reactions of π-Allylnickel Complexes; 3.9 π-Allylnickel Complexes from Enones; 3.10 Carbonylative Cycloaddition of Allylic Halides and Acetylenes; 3.11 Nucleophilic Allylation Toward π-Allylnickel Complexes; 3.11.1 Allylation with Grignard Reagents 3.11.2 Allylation with Soft Nucleophiles3.11.3 Regiochemical Control Based on Internal Chelation; 3.11.4 Organometallics other than Grignard Reagents for Allylation; 3.11.4.1 Ni-catalyzed Allylation with Lithium Borates Derived from Trimethyl Borate; 3.11.4.2 Allylation with Lithium Borates Derived from Acetylene; 3.11.4.3 Allylation with Borates Derived from Cyclic Boronate Esters; 3.11.5 The Design of Functionalized Reagents for Allylation; 3.11.6 Nickel-catalyzed Reactions of Cyclopentenyl Acetate and Borates 3.11.7 Synthetic Application of Nickel-catalyzed Reactions of Cyclopentenyl Acetate and Borates3.11.8 Extension of the Lithium Borate/Nickel Catalyst for Coupling with Alkenyl and Aryl Substrates; 3.12 Nickel Enolates; 3.12.1 Reactions of Ni(II) Complexes with Lithium or Potassium Enolates; 3.12.2 The Reformatsky-type Reaction; 3.12.3 Other Reactions through Nickel Enolates; References; 4 Reaction of Alkynes; 4.1 Hydrogenation; 4.2 Hydrometallation and Related Reactions; 4.2.1 Hydrosilylation and Hydrostannylation; 4.2.2 Hydroboration; 4.2.3 Hydroalumination 4.2.4 Miscellaneous: the Addition of H-P and H-S Groups |
| Record Nr. | UNINA-9910830153903321 |
| Weinheim [Germany], : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern organonickel chemistry / / edited by Yoshinao Tamaru
| Modern organonickel chemistry / / edited by Yoshinao Tamaru |
| Pubbl/distr/stampa | Weinheim [Germany], : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (349 p.) |
| Disciplina | 547.05625 |
| Altri autori (Persone) | TamaruYoshinao <1945-> |
| Soggetto topico |
Organonickel compounds
Chemistry, Organic |
| ISBN |
1-280-51963-0
9786610519637 3-527-60484-7 3-527-60423-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Organonickel Chemistry; Contents; Preface; List of Contributors; Abbreviations; 1 Introductory Guide to Organonickel Chemistry; 1.1 The Crystal Field; 1.2 Nickel has Wings: The Mond Method; 1.3 The Ligand Field; 1.4 The Formal Oxidation Number; 1.5 The 16- and 18-Electron Rule; 1.6 The Structure, Reactivity, and Electronic Configuration of Nickel-Complexes; 1.7 The Elementary Reactions; 1.7.1 Oxidative Addition; 1.7.2 Insertion; 1.7.3 Transmetallation; 1.7.4 Reductive Elimination; 1.7.5 β-Hydrogen Elimination; 1.7.6 α- and β-Carbon Elimination (C-C Bond Cleavage)
1.8 Catalytic ReactionsReferences; 2 Nickel-catalyzed Cross-coupling Reactions; 2.1 Cross-coupling of Alkyl Electrophiles with Organometallic Compounds; 2.2 Cross-coupling of Alkenyl Electrophiles with Organometallic Compounds; 2.3 Cross-coupling of Allyl Electrophiles with Organometallic Compounds; 2.4 Cross-coupling of Aryl Electrophiles with Organometallic Compounds; 2.5 Asymmetric Cross-coupling Reactions; References; 3 Reaction of Alkenes and Allyl Alcohol Derivatives; 3.1 Hydrovinylation of Olefins; 3.2 Hydrocyanation of Olefins; 3.3 Heck-type Cyclization; 3.4 Olefin Insertion 3.5 Nickel-catalyzed Hydrozincation of Olefins3.6 Ni-catalyzed Addition of Organometallics to Electron-deficient Olefins; 3.6.1 The Reaction with Organometallics; 3.6.2 The Reaction with Organic Halides as Nucleophiles; 3.7 Polymerization of Ethylene and α-Olefins using Ni(II)-based Catalysts; 3.8 The Nucleophilic Reactions of π-Allylnickel Complexes; 3.9 π-Allylnickel Complexes from Enones; 3.10 Carbonylative Cycloaddition of Allylic Halides and Acetylenes; 3.11 Nucleophilic Allylation Toward π-Allylnickel Complexes; 3.11.1 Allylation with Grignard Reagents 3.11.2 Allylation with Soft Nucleophiles3.11.3 Regiochemical Control Based on Internal Chelation; 3.11.4 Organometallics other than Grignard Reagents for Allylation; 3.11.4.1 Ni-catalyzed Allylation with Lithium Borates Derived from Trimethyl Borate; 3.11.4.2 Allylation with Lithium Borates Derived from Acetylene; 3.11.4.3 Allylation with Borates Derived from Cyclic Boronate Esters; 3.11.5 The Design of Functionalized Reagents for Allylation; 3.11.6 Nickel-catalyzed Reactions of Cyclopentenyl Acetate and Borates 3.11.7 Synthetic Application of Nickel-catalyzed Reactions of Cyclopentenyl Acetate and Borates3.11.8 Extension of the Lithium Borate/Nickel Catalyst for Coupling with Alkenyl and Aryl Substrates; 3.12 Nickel Enolates; 3.12.1 Reactions of Ni(II) Complexes with Lithium or Potassium Enolates; 3.12.2 The Reformatsky-type Reaction; 3.12.3 Other Reactions through Nickel Enolates; References; 4 Reaction of Alkynes; 4.1 Hydrogenation; 4.2 Hydrometallation and Related Reactions; 4.2.1 Hydrosilylation and Hydrostannylation; 4.2.2 Hydroboration; 4.2.3 Hydroalumination 4.2.4 Miscellaneous: the Addition of H-P and H-S Groups |
| Record Nr. | UNINA-9910876850103321 |
| Weinheim [Germany], : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||