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Chiral ferrocenes in asymmetric catalysis
| Chiral ferrocenes in asymmetric catalysis |
| Autore | Dai Li-xin |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2010 |
| Disciplina | 547.05621 |
| Soggetto topico |
Ferrocene
Chirality Catalysis Asymmetry (Chemistry) Chemistry Physical Sciences & Mathematics Organic Chemistry |
| ISBN | 3-527-62884-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910140166403321 |
Dai Li-xin
|
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| [Place of publication not identified], : Wiley VCH, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chiral ferrocenes in asymmetric catalysis
| Chiral ferrocenes in asymmetric catalysis |
| Autore | Dai Li-xin |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2010 |
| Disciplina | 547.05621 |
| Soggetto topico |
Ferrocene
Chirality Catalysis Asymmetry (Chemistry) Chemistry Physical Sciences & Mathematics Organic Chemistry |
| ISBN | 3-527-62884-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910830974903321 |
|
Dai Li-xin
|
||
| [Place of publication not identified], : Wiley VCH, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Chiral ferrocenes in asymmetric catalysis
| Chiral ferrocenes in asymmetric catalysis |
| Autore | Dai Li-xin |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley VCH, 2010 |
| Disciplina | 547.05621 |
| Soggetto topico |
Ferrocene
Chirality Catalysis Asymmetry (Chemistry) Chemistry Physical Sciences & Mathematics Organic Chemistry |
| ISBN | 3-527-62884-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9911020237903321 |
|
Dai Li-xin
|
||
| [Place of publication not identified], : Wiley VCH, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes [[electronic resource] ] : ligands, materials and biomolecules / / editor, Petr Štěpnička
| Ferrocenes [[electronic resource] ] : ligands, materials and biomolecules / / editor, Petr Štěpnička |
| Pubbl/distr/stampa | Chichester, England ; ; Hoboken, NJ, : J.Wiley, c2008 |
| Descrizione fisica | 1 online resource (669 p.) |
| Disciplina |
547
547.05621 547/.05621 |
| Altri autori (Persone) | ŠtěpničkaPetr |
| Soggetto topico |
Ferrocene
Ligands Biomolecules |
| ISBN |
1-281-31984-8
9786611319847 0-470-98566-6 0-470-98565-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Contents; Preface; Contributors; PART I FERROCENE LIGANDS; 1 Monodentate Ferrocene Donor Ligands; 2 The Coordination and Homogeneous Catalytic Chemistry of 1,1 -Bis(diphenylphosphino)ferrocene and its Chalcogenide Derivatives; 3 Synthesis, Coordination Chemistry and Catalytic Use of dppf Analogs; 4 Other Symmetric 1,1 -Bidentate Ferrocene Ligands; 5 1 -Functionalised Ferrocene Phosphines: Synthesis, Coordination Chemistry and Catalytic Applications; 6 Chiral 1,2-Disubstituted Ferrocene Diphosphines for Asymmetric Catalysis
7 Synthesis and Catalytic Use of Planar Chiral and Polydentate Ferrocene DonorsPART II MATERIALS, MOLECULAR DEVICES AND BIOMOLECULES; 8 Ferrocene Sensors; 9 Ferrocene-Based Electro-Optical Materials; 10 Ferrocene-Containing Polymers and Dendrimers; 11 Ferrocene-Containing Thermotropic Liquid Crystals; 12 Crystal Engineering with Ferrocene Compounds; 13 The Bioorganometallic Chemistry of Ferrocene; Index |
| Record Nr. | UNINA-9910145421803321 |
| Chichester, England ; ; Hoboken, NJ, : J.Wiley, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes : ligands, materials and biomolecules / / editor, Petr Stepnicka
| Ferrocenes : ligands, materials and biomolecules / / editor, Petr Stepnicka |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Chichester, England ; ; Hoboken, NJ, : J.Wiley, c2008 |
| Descrizione fisica | 1 online resource (669 p.) |
| Disciplina |
547
547.05621 547/.05621 |
| Altri autori (Persone) | ŠtěpničkaPetr |
| Soggetto topico |
Ferrocene
Ligands Biomolecules |
| ISBN |
9786611319847
9781281319845 1281319848 9780470985663 0470985666 9780470985656 0470985658 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Contents; Preface; Contributors; PART I FERROCENE LIGANDS; 1 Monodentate Ferrocene Donor Ligands; 2 The Coordination and Homogeneous Catalytic Chemistry of 1,1 -Bis(diphenylphosphino)ferrocene and its Chalcogenide Derivatives; 3 Synthesis, Coordination Chemistry and Catalytic Use of dppf Analogs; 4 Other Symmetric 1,1 -Bidentate Ferrocene Ligands; 5 1 -Functionalised Ferrocene Phosphines: Synthesis, Coordination Chemistry and Catalytic Applications; 6 Chiral 1,2-Disubstituted Ferrocene Diphosphines for Asymmetric Catalysis
7 Synthesis and Catalytic Use of Planar Chiral and Polydentate Ferrocene DonorsPART II MATERIALS, MOLECULAR DEVICES AND BIOMOLECULES; 8 Ferrocene Sensors; 9 Ferrocene-Based Electro-Optical Materials; 10 Ferrocene-Containing Polymers and Dendrimers; 11 Ferrocene-Containing Thermotropic Liquid Crystals; 12 Crystal Engineering with Ferrocene Compounds; 13 The Bioorganometallic Chemistry of Ferrocene; Index |
| Record Nr. | UNINA-9910821787503321 |
| Chichester, England ; ; Hoboken, NJ, : J.Wiley, c2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi
| Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH Publishers, c1995 |
| Descrizione fisica | 1 online resource (562 p.) |
| Disciplina | 547.05621 |
| Altri autori (Persone) |
TogniAntonio
HayashiTamio |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-75871-X
9786611758714 3-527-61559-8 3-527-61558-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mössbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling
1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction 2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via π-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of α-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols 3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes 3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic α-Thio- and α-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis 4.3.1.3 From the Chiral Pool |
| Record Nr. | UNINA-9910144280003321 |
| Weinheim ; ; New York, : VCH Publishers, c1995 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi
| Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH Publishers, c1995 |
| Descrizione fisica | 1 online resource (562 p.) |
| Disciplina | 547.05621 |
| Altri autori (Persone) |
TogniAntonio
HayashiTamio |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| ISBN |
1-281-75871-X
9786611758714 3-527-61559-8 3-527-61558-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mössbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling
1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction 2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via π-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of α-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols 3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes 3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic α-Thio- and α-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis 4.3.1.3 From the Chiral Pool |
| Record Nr. | UNISA-996202136003316 |
| Weinheim ; ; New York, : VCH Publishers, c1995 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi
| Ferrocenes [[electronic resource] ] : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH Publishers, c1995 |
| Descrizione fisica | 1 online resource (562 p.) |
| Disciplina | 547.05621 |
| Altri autori (Persone) |
TogniAntonio
HayashiTamio |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| ISBN |
1-281-75871-X
9786611758714 3-527-61559-8 3-527-61558-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mössbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling
1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction 2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via π-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of α-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols 3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes 3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic α-Thio- and α-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis 4.3.1.3 From the Chiral Pool |
| Record Nr. | UNINA-9910830440803321 |
| Weinheim ; ; New York, : VCH Publishers, c1995 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ferrocenes : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi
| Ferrocenes : homogeneous catalysis, organic synthesis, materials science / / edited by Antonio Togni and Tamio Hayashi |
| Pubbl/distr/stampa | Weinheim ; ; New York, : VCH Publishers, c1995 |
| Descrizione fisica | 1 online resource (562 p.) |
| Disciplina | 547.05621 |
| Altri autori (Persone) |
TogniAntonio
HayashiTamio |
| Soggetto topico |
Ferrocene
Organoiron compounds |
| ISBN |
9786611758714
9781281758712 128175871X 9783527615599 3527615598 9783527615582 352761558X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Ferrocenes; Preface; Contents; List of Contributors; List of Abbreviations; Part 1. Homogeneous Catalysis; 1 1,1'-Bis (dipheny1phosphino)ferrocene - Coordination Chemistry, Organic Syntheses, and Catalysis; 1.1 Introduction; 1.2 Preparation and Complexation; 1.3 Structural Properties; 1.3.1 Modes of Coordination; 1.3.2 Geometrical Distortions; 1.4 Spectroscopic Characteristics; 1.4.1 Techniques; 1.4.1.1 31P NMR Spectroscopy; 1.4.1.2 1H NMR Spectroscopy; 1.4.1.3 Mössbauer Spectroscopy; 1.4.2 NMR Fluxionality; 1.5 Catalysis; 1.5.1 Cross Coupling
1.5.1.1 Organic Electrophile and Organometallic Coupling1.5.1.2 Arylation and Vinylation of Alkenes; 1.5.1.3 Carbonylation and Carbonylative Coupling; 1.5.1.4 Nucleophilic Substitution; 1.5.1.5 Polycondensation and Polymerization; 1.5.2 Olefin Functionalization; 1.5.2.1 Hydroformylation; 1.5.2.2 Hydrogenation and Reduction; 1.5.2.3 Hydroboration and Hydrosilylation; 1.5.2.4 Isomerization; 1.6 Cluster Complexes; 1.7 Electrochemistry; 1.8 Biomedical Applications; 1.9 Summary; References; 2 Asymmetric Catalysis with Chiral Ferrocenylphosphine Ligands; 2.1 Introduction 2.2 Preparation of Chiral Ferrocenylphosphines2.3 Structure of Chiral Ferrocenylphosphines and their Transition-Metal Complexes; 2.4 Catalytic Asymmetric Reactions with Chiral Ferrocenylphosphine Ligands; 2.4.1 Cross-Coupling of Organometallics with Halides; 2.4.2 Allylic Substitution Reactions via π-Ally1 Complexes; 2.4.3 Hydrogenation of Olefins and Ketones; 2.4.4 Hydrosilylation of Olefins and Ketones; 2.4.5 Aldol Reaction of α-Isocyanocarboxylates; 2.4.6 Others; References; 3 Enantioselective Addition of Dialkylzinc to Aldehydes Catalyzed by Chiral Ferrocenyl Aminoalcohols 3.1 Introduction3.2 Chiral Ferrocenylzincs Bearing an Aminoethanol Auxiliary [12]; 3.2.1 Synthesis of the Catalysts; 3.2.2 Addition of Diethylzinc to Benzaldehyde; 3.3 N- (1-Ferrocenylalky1)-N-alk ylnorephedrines [13]; 3.3.1 Synthesis of the Catalysts; 3.3.2 Addition of Diethylzinc to Aldehydes; 3.4 Chiral Polymers Bearing N-Ferrocenylmethylephedrine [14]; 3.4.1 Synthesis of the Catalysts; 3.4.2 Addition of Diethylzinc to Benzaldehyde; 3.5 Chiral 1,2-Disubstituted Ferrocenyl Aminoalcohols [15]; 3.5.1 Synthesis of the Catalysts; 3.5.2 Addition of Dialkylzinc to Aldehydes 3.5.3 Addition of Dialkylzincs to o-Phthalaldehyde: A Facile Synthesis of Optically Active 3-Alkylphthalides [16]3.5.4 Enantio- and Diastereoselective Addition of Diethylzinc to Racemic α-Thio- and α-Selenoaldehydes [17]; 3.6 Summary; References; Part 2. Organic Synthesis - Selected Aspects; 4 Chiral Ferrocene Derivatives. An Introduction; 4.1 Central and Planar Chirality in Metallocenes; 4.2 a-Ferrocenylalkyl Carbocations; 4.2.1 Structure and Stability; 4.2.2 Stereochemistry; 4.3 Central Chiral Ferrocene Derivatives; 4.3.1 Syntheses; 4.3.1.1 By Resolution; 4.3.1.2 By Asymmetric Synthesis 4.3.1.3 From the Chiral Pool |
| Record Nr. | UNINA-9911019665203321 |
| Weinheim ; ; New York, : VCH Publishers, c1995 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Iron catalysis in organic chemistry : reactions and applications / / edited by Bernd Plietker
| Iron catalysis in organic chemistry : reactions and applications / / edited by Bernd Plietker |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (297 p.) |
| Disciplina | 547.05621 |
| Soggetto topico |
Iron catalysts
Catalysis |
| ISBN |
1-281-94719-9
9786611947194 3-527-62327-2 3-527-62328-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Iron Catalysis in Organic Chemistry; Contents; Preface; List of Contributors; 1 Iron Complexes in Organic Chemistry; 1.1 Introduction; 1.2 General Aspects of Iron Complex Chemistry; 1.2.1 Electronic Configuration, Oxidation States, Structures; 1.2.2 Fundamental Reactions; 1.3 Organoiron Complexes and Their Applications; 1.3.1 Binary Carbonyl-Iron Complexes; 1.3.2 Alkene-Iron Complexes; 1.3.3 Allyl- and Trimethylenemethane-Iron Complexes; 1.3.4 Acyl- and Carbene-Iron Complexes; 1.3.5 Diene-Iron Complexes; 1.3.6 Ferrocenes; 1.3.7 Arene-Iron Complexes; 1.4 Catalysis Using Iron Complexes
1.4.1 Iron Complexes as Substrates and/or Products in Catalytic Reactions1.4.2 Iron Complexes as Ligands for Other Transition Metal Catalysts; 1.4.3 Iron Complexes as Catalytically Active Species; References; 2 Iron Catalysis in Biological and Biomimetic Reactions; 2.1 Non-heme Iron Catalysts in Biological and Biomimetic Transformations; 2.1.1 Introduction: Iron in Biological Processes; 2.1.2 Non-heme Iron Proteins; 2.1.2.1 Mononuclear Iron Sites; 2.1.2.2 Dinuclear Iron Sites; 2.1.3 Summary; References; 2.2 Organic Reactions Catalyzed by Heme Proteins 2.2.1 Classification and General Reactivity Schemes of Heme Proteins Used in Organic Synthesis2.2.2 Organic Reactions Catalyzed by Cytochromes P450; 2.2.3 Organic Reactions Catalyzed by Heme Peroxidases; 2.2.3.1 Dehydrogenations (""Peroxidase Reactivity""); 2.2.3.2 Sulfoxidations (""Peroxygenase Reactivity""); 2.2.3.3 Peroxide Disproportionation (""Catalase Reactivity""); 2.2.3.4 Halogenation (""Haloperoxidase Reactivity""); 2.2.3.5 Epoxidations (""Monoxygenase Activity""); References; 3 Iron-catalyzed Oxidation Reactions; 3.1 Oxidations of C-H and C=C Bonds; 3.1.1 Gif Chemistry 3.1.2 Alkene Epoxidation3.1.3 Alkene Dihydroxylation; 3.1.4 The Kharasch Reaction and Related Reactions; 3.1.5 Aziridination and Diamination; References; 3.2 Oxidative Allylic Oxygenation and Amination; 3.2.1 Introduction; 3.2.2 Iron-catalyzed Allylic Oxidations; 3.2.2.1 Simple Iron Salts; 3.2.2.2 Fe(III) Complexes with Bidentate Ligands; 3.2.2.3 Fe(3+)/Fe(2+) Porphyrin and Phthalocyanine Complexes; 3.2.2.4 Iron(III) Salen Complexes; 3.2.2.5 Non-heme Iron Complexes with Tetra- and Pentadentate Ligands; 3.2.3 Oxidative Allylic Aminations; 3.2.4 Conclusion; References 3.3 Oxidation of Heteroatoms (N and S)3.3.1 Oxidation of Nitrogen Compounds; 3.3.1.1 Oxidation of Hydroxylamines to Nitroso Compounds; 3.3.1.2 Oxidation of Arylamines; 3.3.1.3 Other N-Oxidations; 3.3.2 Oxidation of Sulfur Compounds; 3.3.2.1 Oxidation of Thiols to Disulfides; 3.3.2.2 Oxidation of Sulfides; 3.3.2.3 Oxidative Imination of Sulfur Compounds; References; 4 Reduction of Unsaturated Compounds with Homogeneous Iron Catalysts; 4.1 Introduction; 4.2 Hydrogenation of Carbonyl Compounds; 4.3 Hydrogenation of Carbon-Carbon Double Bonds; 4.4 Hydrogenation of Imines and Similar Compounds 4.5 Catalytic Hydrosilylations |
| Record Nr. | UNINA-9910144120103321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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