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Models for Polymeric and Anisotropic Liquids / / by Martin Kröger
| Models for Polymeric and Anisotropic Liquids / / by Martin Kröger |
| Autore | Kröger Martin |
| Edizione | [1st ed. 2005.] |
| Pubbl/distr/stampa | Berlin, Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2005 |
| Descrizione fisica | 1 online resource (XIV, 234 p. 77 illus.) |
| Disciplina | 547/.70454 |
| Collana | Lecture Notes in Physics |
| Soggetto topico |
Soft condensed matter
Polymers Physics Mathematical physics Mechanics, Applied Solids Soft and Granular Matter Classical and Continuum Physics Theoretical, Mathematical and Computational Physics Solid Mechanics |
| ISBN |
9783540315193
3540315195 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Simpler Models for Polymeric Liquids Far from Equilibrium -- Dumbbell Model for Dilute and Semi-Dilute Solutions -- Chain Model for Dilute Solutions -- Chain Model for Concentrated Solutions and Melts -- Chain Models for Transient and Semiflexible Structures -- Primitive Path Models -- Elongated Particle Models. |
| Record Nr. | UNINA-9910144605503321 |
Kröger Martin
|
||
| Berlin, Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Models for Polymeric and Anisotropic Liquids [[electronic resource] /] / by Martin Kröger
| Models for Polymeric and Anisotropic Liquids [[electronic resource] /] / by Martin Kröger |
| Autore | Kröger Martin |
| Edizione | [1st ed. 2005.] |
| Pubbl/distr/stampa | Berlin, Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2005 |
| Descrizione fisica | 1 online resource (XIV, 234 p. 77 illus.) |
| Disciplina | 547/.70454 |
| Collana | Lecture Notes in Physics |
| Soggetto topico |
Amorphous substances
Complex fluids Polymers Continuum physics Physics Mechanics Mechanics, Applied Soft and Granular Matter, Complex Fluids and Microfluidics Polymer Sciences Classical and Continuum Physics Numerical and Computational Physics, Simulation Solid Mechanics |
| ISBN | 3-540-31519-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Simpler Models for Polymeric Liquids Far from Equilibrium -- Dumbbell Model for Dilute and Semi-Dilute Solutions -- Chain Model for Dilute Solutions -- Chain Model for Concentrated Solutions and Melts -- Chain Models for Transient and Semiflexible Structures -- Primitive Path Models -- Elongated Particle Models. |
| Record Nr. | UNISA-996466792903316 |
|
Kröger Martin
|
||
| Berlin, Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Polymer phase behavior [[electronic resource] /] / Timothy P. Ehlers and James K. Wilhelm, editors
| Polymer phase behavior [[electronic resource] /] / Timothy P. Ehlers and James K. Wilhelm, editors |
| Pubbl/distr/stampa | Hauppauge, N.Y., : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (328 p.) |
| Disciplina | 547/.70454 |
| Altri autori (Persone) |
EhlersTimothy P
WilhelmJames K |
| Collana | Materials science and technologies |
| Soggetto topico |
Polymers - Solubility
Polymers - Mixing Polymers - Separation Phase rule and equilibrium |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-62808-476-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910465721603321 |
| Hauppauge, N.Y., : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polymer phase behavior [[electronic resource] /] / Timothy P. Ehlers and James K. Wilhelm, editors
| Polymer phase behavior [[electronic resource] /] / Timothy P. Ehlers and James K. Wilhelm, editors |
| Pubbl/distr/stampa | Hauppauge, N.Y., : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (328 p.) |
| Disciplina | 547/.70454 |
| Altri autori (Persone) |
EhlersTimothy P
WilhelmJames K |
| Collana | Materials science and technologies |
| Soggetto topico |
Polymers - Solubility
Polymers - Mixing Polymers - Separation Phase rule and equilibrium |
| ISBN | 1-62808-476-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910792298403321 |
| Hauppauge, N.Y., : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polymer phase behavior / / Timothy P. Ehlers and James K. Wilhelm, editors
| Polymer phase behavior / / Timothy P. Ehlers and James K. Wilhelm, editors |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hauppauge, N.Y., : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (328 p.) |
| Disciplina | 547/.70454 |
| Altri autori (Persone) |
EhlersTimothy P
WilhelmJames K |
| Collana | Materials science and technologies |
| Soggetto topico |
Polymers - Solubility
Polymers - Mixing Polymers - Separation Phase rule and equilibrium |
| ISBN | 1-62808-476-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- POLYMER PHASE BEHAVIOR -- POLYMER PHASE BEHAVIOR -- Library of Congress Cataloging-in-Publication Data -- Contents -- Preface -- Chapter 1: Application of Lattice Cluster Theory to the Calculation of Miscibility and Interfacial Behavior of Hyperbranched Polymer Containing Systems -- Abstract -- Introduction -- Properties and Applications of Hyperbranched Polymers -- Application in Medicine -- Application in Chemistry -- Application in Energy Technique -- Thermodynamics of Hyperbranched Polymers -- Role of Branching -- Thermodynamic Model - Lattice Cluster Theory -- Thermodynamic Model - Wertheim Theory -- Phase Equilibria Calculation - Examples -- Hyperbranched Polymer + Solvent -- Polymer Blends -- Thermodynamics of Interfacial Properties -- Interfacial Properties - Calculation Examples -- Conclusion -- Acknowledgments -- Reference -- Chapter 2: Raman Study of the Pressure and Temperature Induced Transformations in Crystalline Polymers of C60 -- Abstract -- 1. Introduction -- 2. Research Method and Experimental Technique -- 3. Raman Spectra of the 2D-T Polymer and Pressure Induced Phase Transitions -- 4. Raman Spectra of the 2D-R Polymer and Pressure Induced Phase Transitions -- 5. Photo- and Pressure-Induced Transformations in the Linear Orthorhombic Polymer of C60 -- 5.1. Photo-Induced Transformation -- 5.2. Pressure-Induced Transformations -- 6. Photoluminescence of the C60 Polymers at High Pressure -- 7. Thermal Stability and Decomposition Kinetics of the 2D-R Polymer of C60 -- Conclusion -- Acknowledgments -- References -- Chapter 3: Polymer Phase Behavior in Nanocomposites -- Abstract -- Introduction -- Features of Nanocomposites Semicrystalline Matrix Crystallization -- The Influence of Polymer Phase Molecular Characteristics Change on Nanocomposites Mechanical Properties.
The Influence of Polymer Phase Molecular Characteristics on Interfacial Regions Formation in Polymer Nanocomposites -- Conclusions -- References -- Chapter 4: Phase Inverting Polymer Systems in Drug Delivery and Medicine -- Abstract -- 1. Introduction -- 2. Techniques for Evaluating the Phase Inversion Process -- 2.1. Dark Ground Optics -- 2.2. Electron Paramagnetic Resonance Spectroscopy -- 2.3. Diagnostic Ultrasound Imaging -- 3. Factors Affecting In Vitro Release and Phase Inversion -- 3.1. Fast Phase-Inverting Systems -- 3.2. Slow Phase-Inverting Systems -- 3.3. Effects of Cosolvent Composition -- 3.4. Polymer Type -- 3.5. Polymer Formulation Additives -- 4. The Role of Injection Site on In Vivo Implant Behavior -- 4.1. In Vivo Release -- 4.2. Comparison of In Vitro and In Vivo Release and Phase Inversion -- 4.3. Effects of Injection Site on Release -- Conclusion -- Summary -- Characterization Techniques -- In Vitro Phase Inversion and Drug Release -- In Vivo Phase Inversion and Drug Release -- References -- Chapter 5: Eco-Friendly (co) Polyesters Containing 1,4-Cyclohexylene Units: Correlations between Stereochemistry and Phase Behavior -- Abstract -- 1. Introduction -- 2. Experimental Part -- 2.1. Materials -- 2.2. Sample Preparation -- 2.2.1. Synthesis of Poly(Butylene 1,4-Cyclohexanedicarboxylate) (PBCHD) -- 2.2.2. Synthesis of (4-6)-co-PBCHD90-50/50 Copolyester -- 2.3. Characterization -- 3. Results and Discussion -- 3.1. Preparation and Characterization of Homopolymers -- 3.1.1. Synthesis -- 3.1.2. Effect of the Molecular Structure on Thermal Properties -- 3.1.3. Analysis of the Phase Behaviour for PBCHD and PCCD Homopolymers -- 3.1.4. Relationship between Molecular Structure and Phase Behavior -- 3.1.4.1. PBCHD -- 3.1.4.2. PCCD -- 3.2. Preparation and Characterization of Copolymers -- 3.2.1. Molecular Characterization. 3.2.2. Analysis of the Phase Behaviour of Copolymers -- Conclusions -- References -- Chapter 6: The Features of Partitioning Behavior of Recombinant Amino Acid Dehydrogenases in Aqueous Two-phase Systems -- Abstract -- 1. Introduction -- 2. Expeimntal Procedures -- 2.1. Materials -- 2.2. Production of Recombinant AADHs -- 2.2.1. Production of Recombinant Bacillus badius PheDH -- 2.2.2. Production of Recombinant Pseudomonas putida POS-F84 ProDH -- 2.2.3. Production of Recombinant Bacillus cereus LeuDH -- 2.3. Partitioning Studies of Model Recombinant AADHs in Polymer-Salt ATPS -- 2.3.1. Phase Diagram Determination for PEG-4000/K2HPO4-KH2PO4 -- 2.3.2. Partition Experiment -- 2.3.3. Parameters Affecting Partition Behavior of Recombinant Enzymes -- 2.4. Activity Assay of AADHs -- 2.4.1. Determination of PheDH Activity -- 2.4.2. Determination of ProDH Activity -- 2.4.3. Determination of LeuDH Activity -- 2.5. Protein Assay -- 2.6. Purity Analysis of the Separated Enzymes from ATPS -- 3. Results and Discussion -- 3.1. Phase Behaviors of the PEG-4000/Salt ATPS -- 3.1.1. Phase Diagrams -- 3.1.2. Effect of Concentrations of Phase-Forming Components on Partitioning Behavior -- 3.1.3. Effect of Phase-Forming Polymer Molecular Weight on Partition Behavior -- 3.1.4. Effect of Salt Type -- 3.1.5. Effect of System pH on Partition Behavior -- 3.1.6. Effect of Added Salts on Partition Behavior -- 3.1.7. Effect of TIL on Partition Behavior -- 3.1.8. Effect of System Temperature on Partition Behavior -- 3.1.9. Effect of Cell Extract Loading and Phase Volume Ratio -- 3.2. Purity Analysis of Model Enzymes -- Conclusion -- Acknowledgments -- References -- Chapter 7: Phase Separation, Phase Dissolution and Crystallization in Poly(e-Caprolactone)/ Poly(Styrene-Co-Acrylonitrile) Blends -- Abstract -- Introduction -- Experimental -- Results and Discussion. Crystallization Kinetics by Optical Microscopy -- Crystallization by Hv Light Scattering -- TEM Analysis -- Conclusion -- Review -- Acknowledgment -- References -- Chapter 8: Thermo- and pH-Sensitivity of Poly(N-Vinylpyrrolidone) in Water Media -- Abstract -- Introduction -- Thermosensitivity of PVP Solutions, Containing Salts -- Phase Separation of PVP Solutions in the Presence of Organic Compounds Capable to form Complexes with the Polymer -- Phase Separation in Water Solutions of PVP Copolymers and Derivatives -- Stimuli-Responsive Hydrogels on the Base of PVP Copolymers -- References -- Index. |
| Record Nr. | UNINA-9910960563103321 |
| Hauppauge, N.Y., : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polymer solutions [[electronic resource] ] : an introduction to physical properties / / Iwao Teraoka
| Polymer solutions [[electronic resource] ] : an introduction to physical properties / / Iwao Teraoka |
| Autore | Teraoka Iwao |
| Pubbl/distr/stampa | New York, : Wiley-Interscience, c2002 |
| Descrizione fisica | 1 online resource (355 p.) |
| Disciplina |
547.7
547/.70454 |
| Soggetto topico |
Polymer solutions
Polymers |
| ISBN |
1-5231-4395-9
1-280-54175-X 9786610541751 0-471-46076-1 0-471-22451-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Contents; Preface; 1 Models of Polymer Chains; 1.1 Introduction; 1.1.1 Chain Architecture; 1.1.2 Models of a Linear Polymer Chain; 1.1.3 Real Chains and Ideal Chains; 1.2 Ideal Chains; 1.2.1 Random Walk in One Dimension; 1.2.2 Random Walks in Two and Three Dimensions; 1.2.3 Dimensions of Random-Walk Chains; 1.2.4 Problems; 1.3 Gaussian Chain; 1.3.1 What is a Gaussian Chain?; 1.3.2 Dimension of a Gaussian Chain; 1.3.3 Entropy Elasticity; 1.3.4 Problems; 1.4 Real Chains; 1.4.1 Excluded Volume; 1.4.2 Dimension of a Real Chain; 1.4.3 Self-Avoiding Walk; 1.4.4 Problems; 1.5 Semirigid Chains
1.5.1 Examples of Semirigid Chains1.5.2 Wormlike Chain; 1.5.3 Problems; 1.6 Branched Chains; 1.6.1 Architecture of Branched Chains; 1.6.2 Dimension of Branched Chains; 1.6.3 Problems; 1.7 Molecular Weight Distribution; 1.7.1 Average Molecular Weights; 1.7.2 Typical Distributions; 1.7.3 Problems; 1.8 Concentration Regimes; 1.8.1 Concentration Regimes for Linear Flexible Polymers; 1.8.2 Concentration Regimes for Rodlike Molecules; 1.8.3 Problems; 2 Thermodynamics of Dilute Polymer Solutions; 2.1 Polymer Solutions and Thermodynamics; 2.2 Flory-Huggins Mean-Field Theory; 2.2.1 Model 2.2.2 Free Energy, Chemical Potentials, and Osmotic Pressure2.2.3 Dilute Solutions; 2.2.4 Coexistence Curve and Stability; 2.2.5 Polydisperse Polymer; 2.2.6 Problems; 2.3 Phase Diagram and Theta Solutions; 2.3.1 Phase Diagram; 2.3.2 Theta Solutions; 2.3.3 Coil-Globule Transition; 2.3.4 Solubility Parameter; 2.3.5 Problems; 2.4 Static Light Scattering; 2.4.1 Sample Geometry in Light-Scattering Measurements; 2.4.2 Scattering by a Small Particle; 2.4.3 Scattering by a Polymer Chain; 2.4.4 Scattering by Many Polymer Chains; 2.4.5 Correlation Function and Structure Factor 2.4.6 Structure Factor of a Polymer Chain2.4.7 Light Scattering of a Polymer Solution; 2.4.8 Other Scattering Techniques; 2.4.9 Problems; 2.5 Size Exclusion Chromatography and Confinement; 2.5.1 Separation System; 2.5.2 Plate Theory; 2.5.3 Partitioning of Polymer with a Pore; 2.5.4 Calibration of SEC; 2.5.5 SEC With an On-Line Light-Scattering Detector; 2.5.6 Problems; APPENDICES; 2.A: Review of Thermodynamics for Colligative Properties in Nonideal Solutions; 2.B: Another Approach to Thermodynamics of Polymer Solutions; 2.C: Correlation Function of a Gaussian Chain 3 Dynamics of Dilute Polymer Solutions3.1 Dynamics of Polymer Solutions; 3.2 Dynamic Light Scattering and Diffusion of Polymers; 3.2.1 Measurement System and Autocorrelation Function; 3.2.2 Autocorrelation Function; 3.2.3 Dynamic Structure Factor of Suspended Particles; 3.2.4 Diffusion of Particles; 3.2.5 Diffusion and DLS; 3.2.6 Dynamic Structure Factor of a Polymer Solution; 3.2.7 Hydrodynamic Radius; 3.2.8 Particle Sizing; 3.2.9 Diffusion From Equation of Motion; 3.2.10 Diffusion as Kinetics; 3.2.11 Concentration Effect on Diffusion; 3.2.12 Diffusion in a Nonuniform System; 3.2.13 Problems 3.3 Viscosity |
| Record Nr. | UNINA-9910143180003321 |
|
Teraoka Iwao
|
||
| New York, : Wiley-Interscience, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polymer solutions [[electronic resource] ] : an introduction to physical properties / / Iwao Teraoka
| Polymer solutions [[electronic resource] ] : an introduction to physical properties / / Iwao Teraoka |
| Autore | Teraoka Iwao |
| Pubbl/distr/stampa | New York, : Wiley-Interscience, c2002 |
| Descrizione fisica | 1 online resource (355 p.) |
| Disciplina |
547.7
547/.70454 |
| Soggetto topico |
Polymer solutions
Polymers |
| ISBN |
1-5231-4395-9
1-280-54175-X 9786610541751 0-471-46076-1 0-471-22451-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Contents; Preface; 1 Models of Polymer Chains; 1.1 Introduction; 1.1.1 Chain Architecture; 1.1.2 Models of a Linear Polymer Chain; 1.1.3 Real Chains and Ideal Chains; 1.2 Ideal Chains; 1.2.1 Random Walk in One Dimension; 1.2.2 Random Walks in Two and Three Dimensions; 1.2.3 Dimensions of Random-Walk Chains; 1.2.4 Problems; 1.3 Gaussian Chain; 1.3.1 What is a Gaussian Chain?; 1.3.2 Dimension of a Gaussian Chain; 1.3.3 Entropy Elasticity; 1.3.4 Problems; 1.4 Real Chains; 1.4.1 Excluded Volume; 1.4.2 Dimension of a Real Chain; 1.4.3 Self-Avoiding Walk; 1.4.4 Problems; 1.5 Semirigid Chains
1.5.1 Examples of Semirigid Chains1.5.2 Wormlike Chain; 1.5.3 Problems; 1.6 Branched Chains; 1.6.1 Architecture of Branched Chains; 1.6.2 Dimension of Branched Chains; 1.6.3 Problems; 1.7 Molecular Weight Distribution; 1.7.1 Average Molecular Weights; 1.7.2 Typical Distributions; 1.7.3 Problems; 1.8 Concentration Regimes; 1.8.1 Concentration Regimes for Linear Flexible Polymers; 1.8.2 Concentration Regimes for Rodlike Molecules; 1.8.3 Problems; 2 Thermodynamics of Dilute Polymer Solutions; 2.1 Polymer Solutions and Thermodynamics; 2.2 Flory-Huggins Mean-Field Theory; 2.2.1 Model 2.2.2 Free Energy, Chemical Potentials, and Osmotic Pressure2.2.3 Dilute Solutions; 2.2.4 Coexistence Curve and Stability; 2.2.5 Polydisperse Polymer; 2.2.6 Problems; 2.3 Phase Diagram and Theta Solutions; 2.3.1 Phase Diagram; 2.3.2 Theta Solutions; 2.3.3 Coil-Globule Transition; 2.3.4 Solubility Parameter; 2.3.5 Problems; 2.4 Static Light Scattering; 2.4.1 Sample Geometry in Light-Scattering Measurements; 2.4.2 Scattering by a Small Particle; 2.4.3 Scattering by a Polymer Chain; 2.4.4 Scattering by Many Polymer Chains; 2.4.5 Correlation Function and Structure Factor 2.4.6 Structure Factor of a Polymer Chain2.4.7 Light Scattering of a Polymer Solution; 2.4.8 Other Scattering Techniques; 2.4.9 Problems; 2.5 Size Exclusion Chromatography and Confinement; 2.5.1 Separation System; 2.5.2 Plate Theory; 2.5.3 Partitioning of Polymer with a Pore; 2.5.4 Calibration of SEC; 2.5.5 SEC With an On-Line Light-Scattering Detector; 2.5.6 Problems; APPENDICES; 2.A: Review of Thermodynamics for Colligative Properties in Nonideal Solutions; 2.B: Another Approach to Thermodynamics of Polymer Solutions; 2.C: Correlation Function of a Gaussian Chain 3 Dynamics of Dilute Polymer Solutions3.1 Dynamics of Polymer Solutions; 3.2 Dynamic Light Scattering and Diffusion of Polymers; 3.2.1 Measurement System and Autocorrelation Function; 3.2.2 Autocorrelation Function; 3.2.3 Dynamic Structure Factor of Suspended Particles; 3.2.4 Diffusion of Particles; 3.2.5 Diffusion and DLS; 3.2.6 Dynamic Structure Factor of a Polymer Solution; 3.2.7 Hydrodynamic Radius; 3.2.8 Particle Sizing; 3.2.9 Diffusion From Equation of Motion; 3.2.10 Diffusion as Kinetics; 3.2.11 Concentration Effect on Diffusion; 3.2.12 Diffusion in a Nonuniform System; 3.2.13 Problems 3.3 Viscosity |
| Record Nr. | UNINA-9910830829503321 |
|
Teraoka Iwao
|
||
| New York, : Wiley-Interscience, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polymer solutions : an introduction to physical properties / / Iwao Teraoka
| Polymer solutions : an introduction to physical properties / / Iwao Teraoka |
| Autore | Teraoka Iwao |
| Pubbl/distr/stampa | New York, : Wiley-Interscience, c2002 |
| Descrizione fisica | 1 online resource (355 p.) |
| Disciplina |
547.7
547/.70454 |
| Soggetto topico |
Polymer solutions
Polymers |
| ISBN |
9786610541751
9781523143955 1523143959 9781280541759 128054175X 9780471460763 0471460761 9780471224518 0471224510 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Contents; Preface; 1 Models of Polymer Chains; 1.1 Introduction; 1.1.1 Chain Architecture; 1.1.2 Models of a Linear Polymer Chain; 1.1.3 Real Chains and Ideal Chains; 1.2 Ideal Chains; 1.2.1 Random Walk in One Dimension; 1.2.2 Random Walks in Two and Three Dimensions; 1.2.3 Dimensions of Random-Walk Chains; 1.2.4 Problems; 1.3 Gaussian Chain; 1.3.1 What is a Gaussian Chain?; 1.3.2 Dimension of a Gaussian Chain; 1.3.3 Entropy Elasticity; 1.3.4 Problems; 1.4 Real Chains; 1.4.1 Excluded Volume; 1.4.2 Dimension of a Real Chain; 1.4.3 Self-Avoiding Walk; 1.4.4 Problems; 1.5 Semirigid Chains
1.5.1 Examples of Semirigid Chains1.5.2 Wormlike Chain; 1.5.3 Problems; 1.6 Branched Chains; 1.6.1 Architecture of Branched Chains; 1.6.2 Dimension of Branched Chains; 1.6.3 Problems; 1.7 Molecular Weight Distribution; 1.7.1 Average Molecular Weights; 1.7.2 Typical Distributions; 1.7.3 Problems; 1.8 Concentration Regimes; 1.8.1 Concentration Regimes for Linear Flexible Polymers; 1.8.2 Concentration Regimes for Rodlike Molecules; 1.8.3 Problems; 2 Thermodynamics of Dilute Polymer Solutions; 2.1 Polymer Solutions and Thermodynamics; 2.2 Flory-Huggins Mean-Field Theory; 2.2.1 Model 2.2.2 Free Energy, Chemical Potentials, and Osmotic Pressure2.2.3 Dilute Solutions; 2.2.4 Coexistence Curve and Stability; 2.2.5 Polydisperse Polymer; 2.2.6 Problems; 2.3 Phase Diagram and Theta Solutions; 2.3.1 Phase Diagram; 2.3.2 Theta Solutions; 2.3.3 Coil-Globule Transition; 2.3.4 Solubility Parameter; 2.3.5 Problems; 2.4 Static Light Scattering; 2.4.1 Sample Geometry in Light-Scattering Measurements; 2.4.2 Scattering by a Small Particle; 2.4.3 Scattering by a Polymer Chain; 2.4.4 Scattering by Many Polymer Chains; 2.4.5 Correlation Function and Structure Factor 2.4.6 Structure Factor of a Polymer Chain2.4.7 Light Scattering of a Polymer Solution; 2.4.8 Other Scattering Techniques; 2.4.9 Problems; 2.5 Size Exclusion Chromatography and Confinement; 2.5.1 Separation System; 2.5.2 Plate Theory; 2.5.3 Partitioning of Polymer with a Pore; 2.5.4 Calibration of SEC; 2.5.5 SEC With an On-Line Light-Scattering Detector; 2.5.6 Problems; APPENDICES; 2.A: Review of Thermodynamics for Colligative Properties in Nonideal Solutions; 2.B: Another Approach to Thermodynamics of Polymer Solutions; 2.C: Correlation Function of a Gaussian Chain 3 Dynamics of Dilute Polymer Solutions3.1 Dynamics of Polymer Solutions; 3.2 Dynamic Light Scattering and Diffusion of Polymers; 3.2.1 Measurement System and Autocorrelation Function; 3.2.2 Autocorrelation Function; 3.2.3 Dynamic Structure Factor of Suspended Particles; 3.2.4 Diffusion of Particles; 3.2.5 Diffusion and DLS; 3.2.6 Dynamic Structure Factor of a Polymer Solution; 3.2.7 Hydrodynamic Radius; 3.2.8 Particle Sizing; 3.2.9 Diffusion From Equation of Motion; 3.2.10 Diffusion as Kinetics; 3.2.11 Concentration Effect on Diffusion; 3.2.12 Diffusion in a Nonuniform System; 3.2.13 Problems 3.3 Viscosity |
| Record Nr. | UNINA-9910877832303321 |
|
Teraoka Iwao
|
||
| New York, : Wiley-Interscience, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||