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Advanced organic chemistry [[electronic resource] ] : reaction mechanisms / / Reinhard Bruckner
| Advanced organic chemistry [[electronic resource] ] : reaction mechanisms / / Reinhard Bruckner |
| Autore | Bruckner Reinhard <1955-> |
| Pubbl/distr/stampa | San Diego, : Harcourt/Academic Press, c2002 |
| Descrizione fisica | 1 online resource (661 p.) |
| Disciplina | 547/.139 |
| Collana | Advanced organic chemistry series |
| Soggetto topico | Organic reaction mechanisms |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-46679-4
9786611466794 0-08-049880-9 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Advanced Organic Chemistry; Copyright Page; Contents; Foreword; Preface to the English Edition; Preface to the German Edition; Acknowledgments; Chapter 1. Radical Substitution Reactions at the Saturated C Atom; 1.1 Bonding and Preferred Geometries in C Radicals, Carbenium Ions and Carbanions; 1.2 Stability of Radicals; 1.3 Relative Rates of Analogous Radical Reactions; 1.4 Radical Substitution Reactions: Chain Reactions; 1.5 Radical Initiators; 1.6 Radical Chemistry of Alkylmercury(II) Hydrides; 1.7 Radical Halogenation of Hydrocarbons; 1.8 Autoxidations
1.9 Defunctionalizations via Radical Substitution ReactionsReferences; Chapter 2. Nucleophilic Substitution Reactions at the Saturated C Atom; 2.1 Nucleophiles and Electrophiles; Leaving Groups; 2.2 Good and Poor Nucleophiles; 2.3 Leaving Groups and the Quality of Leaving Groups; 2.4 SN2 Reactions: Kinetic and Stereochemical Analysis-Substituent Effects on Reactivity; 2.5 SN1 Reactions: Kinetic and Stereochemical Analysis; Substituent Effects on Reactivity 2.6 When Do SN Reactions at Saturated C Atoms Take Place According to the SN1 Mechanism and When Do They Take Place According to the SN2 Mechanism?2.7 Unimolecular SN Reactions That Do Not Take Place via Simple Carbenium Ion Intermediates: Neighboring Group Participation; 2.8 Preparatively Useful SN2 Reactions: Alkylations; References; Chapter 3. Additions to the Olefinic C=C Double Bond; 3.1 The Concept of cis and trans Addition; 3.2 Vocabulary of Stereochemistry and Stereoselective Synthesis I; 3.3 Additions That Take Place Diastereoselectivity as cis Additions 3.4 Enantioselective cis Additions to C=C Double Bonds3.5 Additions That Take Place Diastereoselectively as trans Additions (Additions via Onium Intermediates); 3.6 Additions That Take Place or Can Take Place without Stereocontrol Depending on the Mechanism; References; Chapter 4. ß-Eliminations; 4.1 Concepts of Elimination Reactions; 4.2 b-Eliminations of H/Het via Cyclic Transition States; 4.3 b-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives; 4.4 E2 Eliminations of H/Het and the E2/SN2 Competition 4.5 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition4.6 E1cb Eliminations; 4.7 ß-Eliminations of Het1/Het2; References; Chapter 5. Substitution Reactions on Aromatic Compounds; 5.1 Electrophilic Aromatic Substitutions via Wheland Complexes (""Ar-SE Reactions""); 5.2 Ar-SE Reactions via Wheland Complexes: Individual Reactions; 5.3 Electrophilic Substitution Reactions on Metallated Aromatic Compounds; 5.4 Nucleophilic Substitution Reactions in Aryldiazonium Salts; 5.5 Nucleophilic Substitution Reactions via Meisenheimer Complexes 5.6 Nucleophilic Aromatic Substitution via Arynes, cine Substitution |
| Record Nr. | UNINA-9910458258703321 |
Bruckner Reinhard <1955->
|
||
| San Diego, : Harcourt/Academic Press, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner [[electronic resource]]
| Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner [[electronic resource]] |
| Autore | Bruckner Reinhard <1955-> |
| Pubbl/distr/stampa | San Diego, : Harcourt/Academic Press, c2002 |
| Descrizione fisica | 1 online resource (661 p.) |
| Disciplina | 547/.139 |
| Collana | Advanced organic chemistry series |
| Soggetto topico | Organic reaction mechanisms |
| ISBN |
1-281-46679-4
9786611466794 0-08-049880-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Advanced Organic Chemistry; Copyright Page; Contents; Foreword; Preface to the English Edition; Preface to the German Edition; Acknowledgments; Chapter 1. Radical Substitution Reactions at the Saturated C Atom; 1.1 Bonding and Preferred Geometries in C Radicals, Carbenium Ions and Carbanions; 1.2 Stability of Radicals; 1.3 Relative Rates of Analogous Radical Reactions; 1.4 Radical Substitution Reactions: Chain Reactions; 1.5 Radical Initiators; 1.6 Radical Chemistry of Alkylmercury(II) Hydrides; 1.7 Radical Halogenation of Hydrocarbons; 1.8 Autoxidations
1.9 Defunctionalizations via Radical Substitution ReactionsReferences; Chapter 2. Nucleophilic Substitution Reactions at the Saturated C Atom; 2.1 Nucleophiles and Electrophiles; Leaving Groups; 2.2 Good and Poor Nucleophiles; 2.3 Leaving Groups and the Quality of Leaving Groups; 2.4 SN2 Reactions: Kinetic and Stereochemical Analysis-Substituent Effects on Reactivity; 2.5 SN1 Reactions: Kinetic and Stereochemical Analysis; Substituent Effects on Reactivity 2.6 When Do SN Reactions at Saturated C Atoms Take Place According to the SN1 Mechanism and When Do They Take Place According to the SN2 Mechanism?2.7 Unimolecular SN Reactions That Do Not Take Place via Simple Carbenium Ion Intermediates: Neighboring Group Participation; 2.8 Preparatively Useful SN2 Reactions: Alkylations; References; Chapter 3. Additions to the Olefinic C=C Double Bond; 3.1 The Concept of cis and trans Addition; 3.2 Vocabulary of Stereochemistry and Stereoselective Synthesis I; 3.3 Additions That Take Place Diastereoselectivity as cis Additions 3.4 Enantioselective cis Additions to C=C Double Bonds3.5 Additions That Take Place Diastereoselectively as trans Additions (Additions via Onium Intermediates); 3.6 Additions That Take Place or Can Take Place without Stereocontrol Depending on the Mechanism; References; Chapter 4. ß-Eliminations; 4.1 Concepts of Elimination Reactions; 4.2 b-Eliminations of H/Het via Cyclic Transition States; 4.3 b-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives; 4.4 E2 Eliminations of H/Het and the E2/SN2 Competition 4.5 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition4.6 E1cb Eliminations; 4.7 ß-Eliminations of Het1/Het2; References; Chapter 5. Substitution Reactions on Aromatic Compounds; 5.1 Electrophilic Aromatic Substitutions via Wheland Complexes (""Ar-SE Reactions""); 5.2 Ar-SE Reactions via Wheland Complexes: Individual Reactions; 5.3 Electrophilic Substitution Reactions on Metallated Aromatic Compounds; 5.4 Nucleophilic Substitution Reactions in Aryldiazonium Salts; 5.5 Nucleophilic Substitution Reactions via Meisenheimer Complexes 5.6 Nucleophilic Aromatic Substitution via Arynes, cine Substitution |
| Record Nr. | UNINA-9910784534903321 |
|
Bruckner Reinhard <1955->
|
||
| San Diego, : Harcourt/Academic Press, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner
| Advanced organic chemistry : reaction mechanisms / / Reinhard Bruckner |
| Autore | Bruckner Reinhard <1955-> |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | San Diego, : Harcourt/Academic Press, c2002 |
| Descrizione fisica | 1 online resource (661 p.) |
| Disciplina | 547/.139 |
| Collana | Advanced organic chemistry series |
| Soggetto topico | Organic reaction mechanisms |
| ISBN |
1-281-46679-4
9786611466794 0-08-049880-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Advanced Organic Chemistry; Copyright Page; Contents; Foreword; Preface to the English Edition; Preface to the German Edition; Acknowledgments; Chapter 1. Radical Substitution Reactions at the Saturated C Atom; 1.1 Bonding and Preferred Geometries in C Radicals, Carbenium Ions and Carbanions; 1.2 Stability of Radicals; 1.3 Relative Rates of Analogous Radical Reactions; 1.4 Radical Substitution Reactions: Chain Reactions; 1.5 Radical Initiators; 1.6 Radical Chemistry of Alkylmercury(II) Hydrides; 1.7 Radical Halogenation of Hydrocarbons; 1.8 Autoxidations
1.9 Defunctionalizations via Radical Substitution ReactionsReferences; Chapter 2. Nucleophilic Substitution Reactions at the Saturated C Atom; 2.1 Nucleophiles and Electrophiles; Leaving Groups; 2.2 Good and Poor Nucleophiles; 2.3 Leaving Groups and the Quality of Leaving Groups; 2.4 SN2 Reactions: Kinetic and Stereochemical Analysis-Substituent Effects on Reactivity; 2.5 SN1 Reactions: Kinetic and Stereochemical Analysis; Substituent Effects on Reactivity 2.6 When Do SN Reactions at Saturated C Atoms Take Place According to the SN1 Mechanism and When Do They Take Place According to the SN2 Mechanism?2.7 Unimolecular SN Reactions That Do Not Take Place via Simple Carbenium Ion Intermediates: Neighboring Group Participation; 2.8 Preparatively Useful SN2 Reactions: Alkylations; References; Chapter 3. Additions to the Olefinic C=C Double Bond; 3.1 The Concept of cis and trans Addition; 3.2 Vocabulary of Stereochemistry and Stereoselective Synthesis I; 3.3 Additions That Take Place Diastereoselectivity as cis Additions 3.4 Enantioselective cis Additions to C=C Double Bonds3.5 Additions That Take Place Diastereoselectively as trans Additions (Additions via Onium Intermediates); 3.6 Additions That Take Place or Can Take Place without Stereocontrol Depending on the Mechanism; References; Chapter 4. ß-Eliminations; 4.1 Concepts of Elimination Reactions; 4.2 b-Eliminations of H/Het via Cyclic Transition States; 4.3 b-Eliminations of H/Het via Acyclic Transition States: The Mechanistic Alternatives; 4.4 E2 Eliminations of H/Het and the E2/SN2 Competition 4.5 E1 Elimination of H/Het from Rtert-X and the E1/SN1 Competition4.6 E1cb Eliminations; 4.7 ß-Eliminations of Het1/Het2; References; Chapter 5. Substitution Reactions on Aromatic Compounds; 5.1 Electrophilic Aromatic Substitutions via Wheland Complexes (""Ar-SE Reactions""); 5.2 Ar-SE Reactions via Wheland Complexes: Individual Reactions; 5.3 Electrophilic Substitution Reactions on Metallated Aromatic Compounds; 5.4 Nucleophilic Substitution Reactions in Aryldiazonium Salts; 5.5 Nucleophilic Substitution Reactions via Meisenheimer Complexes 5.6 Nucleophilic Aromatic Substitution via Arynes, cine Substitution |
| Record Nr. | UNINA-9910811682803321 |
|
Bruckner Reinhard <1955->
|
||
| San Diego, : Harcourt/Academic Press, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern tools for the synthesis of complex bioactive molecules [[electronic resource] /] / edited by Stellios Arseniyadis, Janine Cossy
| Modern tools for the synthesis of complex bioactive molecules [[electronic resource] /] / edited by Stellios Arseniyadis, Janine Cossy |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2012 |
| Descrizione fisica | 1 online resource (600 p.) |
| Disciplina | 547/.139 |
| Altri autori (Persone) |
ArseniyadisS (Stellios)
CossyJanine |
| Soggetto topico |
Biomolecules - Synthesis
Biochemistry |
| ISBN |
1-283-59891-4
9786613911360 1-118-34287-9 1-118-34288-7 1-118-34285-2 |
| Classificazione | SCI007000 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
MODERN TOOLS FOR THE SYNTHESIS OF COMPLEX BIOACTIVE MOLECULES; CONTENTS; FOREWORD; PREFACE; CONTRIBUTORS; CHAPTER 1: C-H FUNCTIONALIZATION: A NEW STRATEGY FOR THE SYNTHESIS OF BIOLOGICALLY ACTIVE NATURAL PRODUCTS; 1.1. INTRODUCTION; 1.2. PALLADIUM(0)-CATALYZED INTRAMOLECULAR DIRECT ARYLATION; 1.3. PALLADIUM(0)-CATALYZED INTRAMOLECULAR ALKENYLATION OF sp2 C-H BONDS; 1.4. PALLADIUM(0)-CATALYZED INTRAMOLECULAR ARYLATION OF sp3 C-H BONDS; 1.5. PALLADIUM(II)-MEDIATED INTRAMOLECULAR OXIDATIVE ALKENYLATION OF sp2 C-H BONDS
1.6. DIRECTING GROUP-ASSISTED PALLADIUM(II)- ENABLED CARBON-CARBON BOND FORMATION AT sp3 C-H BONDS1.7. PLATINUM(II)-MEDIATED ALKANE DEHYDROGENATION; 1.8. PALLADIUM(II)-ENABLED CARBON-OXYGEN BOND FORMATION AT sp3 C-H BONDS; 1.9. IRIDIUM-CATALYZED BORYLATION OF sp2 C-H BONDS; 1.10. RHODIUM(I)-CATALYZED INTRAMOLECULAR DIRECTED ALKYLATION OF sp2 C-H BONDS; 1.11. RHODIUM(III)-CATALYZED SYNTHESIS OF NITROGEN-CONTAINING HETEROCYCLES; 1.12. CONCLUSION; REFERENCES; CHAPTER 2: THE NEGISHI CROSS-COUPLING IN THE SYNTHESIS OF NATURAL PRODUCTS AND BIOACTIVE MOLECULES; 2.1. INTRODUCTION 2.2. SYNTHESIS OF NATURAL PRODUCTS 2.2.1. Synthesis of Polyenes; 2.2.2. Synthesis of Amino Acids and Macrocyclic Peptides; 2.2.3. Synthesis of Macrocycles; 2.2.4. Synthesis of Small Heterocycles; 2.3. LARGE-SCALE SYNTHESIS OF BIOLOGICALLY ACTIVE MOLECULES; 2.3.1. Nonsteroidal Ligand A-224817.0 1A; 2.3.2. Phosphodiesterase Inhibitor PDE472; 2.3.3. Reverse Transcriptase Inhibitor MIV-150; 2.3.4. B-Raf Kinase Inhibitors; 2.3.5. mGluR1 Antagonist; 2.4. CONCLUSION; REFERENCES; CHAPTER 3: METAL-CATALYZED C-HETEROATOM CROSS-COUPLING REACTIONS; 3.1. GENERAL INTRODUCTION 3.2. BUCHWALD-HARTWIG-TYPE REACTIONS 3.2.1. Introduction; 3.2.2. Mechanism; 3.2.3. Scope and Limitations; 3.2.4. Applications in the Synthesis of Complex Bioactive Molecules; 3.2.5. C-N Bond Formation; 3.2.6. C-S and C-O Bond Formation; 3.3. ULLMANN-TYPE REACTIONS; 3.3.1. Introduction; 3.3.2. Mechanism; 3.3.3. Scope and Limitations; 3.3.4. Applications in the Synthesis of Complex Bioactive Molecules; 3.3.5. C-N Bond Formation; 3.3.6. C-O Bond Formation; 3.4. MISCELLANEOUS; 3.4.1. Chan-Lam-Evans; 3.4.2. Iron/Copper-Mediated Methodologies; 3.4.3. Other Metals; 3.5. CONCLUSION; REFERENCES CHAPTER 4: GOLDEN OPPORTUNITIES IN THE SYNTHESIS OF NATURAL PRODUCTS AND BIOLOGICALLY ACTIVE COMPOUNDS 4.1. INTRODUCTION; 4.2. GOLD-CATALYZED FORMATION OF OXYGEN-CONTAINING HETEROCYCLES; 4.2.1. Cyclizations Leading to Furan and Pyran Derivatives; 4.2.2. Spiroketalizations; 4.2.3. Other Transformations; 4.3. GOLD-CATALYZED FORMATION OF NITROGEN-CONTAINING HETEROCYCLES; 4.3.1. Cyclizations Involving the Formation of a New C-N Bond; 4.3.2. Cyclizations Involving the Formation of a New C-C Bond; 4.4. GOLD-CATALYZED FORMATION OF CARBOCYCLES 4.4.1. Cyclizations Involving the Formation of a Single New C-C Bond |
| Record Nr. | UNINA-9910137616703321 |
| Hoboken, N.J., : Wiley, c2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern tools for the synthesis of complex bioactive molecules [[electronic resource] /] / edited by Stellios Arseniyadis, Janine Cossy
| Modern tools for the synthesis of complex bioactive molecules [[electronic resource] /] / edited by Stellios Arseniyadis, Janine Cossy |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2012 |
| Descrizione fisica | 1 online resource (600 p.) |
| Disciplina | 547/.139 |
| Altri autori (Persone) |
ArseniyadisS (Stellios)
CossyJanine |
| Soggetto topico |
Biomolecules - Synthesis
Biochemistry |
| ISBN |
1-283-59891-4
9786613911360 1-118-34287-9 1-118-34288-7 1-118-34285-2 |
| Classificazione | SCI007000 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
MODERN TOOLS FOR THE SYNTHESIS OF COMPLEX BIOACTIVE MOLECULES; CONTENTS; FOREWORD; PREFACE; CONTRIBUTORS; CHAPTER 1: C-H FUNCTIONALIZATION: A NEW STRATEGY FOR THE SYNTHESIS OF BIOLOGICALLY ACTIVE NATURAL PRODUCTS; 1.1. INTRODUCTION; 1.2. PALLADIUM(0)-CATALYZED INTRAMOLECULAR DIRECT ARYLATION; 1.3. PALLADIUM(0)-CATALYZED INTRAMOLECULAR ALKENYLATION OF sp2 C-H BONDS; 1.4. PALLADIUM(0)-CATALYZED INTRAMOLECULAR ARYLATION OF sp3 C-H BONDS; 1.5. PALLADIUM(II)-MEDIATED INTRAMOLECULAR OXIDATIVE ALKENYLATION OF sp2 C-H BONDS
1.6. DIRECTING GROUP-ASSISTED PALLADIUM(II)- ENABLED CARBON-CARBON BOND FORMATION AT sp3 C-H BONDS1.7. PLATINUM(II)-MEDIATED ALKANE DEHYDROGENATION; 1.8. PALLADIUM(II)-ENABLED CARBON-OXYGEN BOND FORMATION AT sp3 C-H BONDS; 1.9. IRIDIUM-CATALYZED BORYLATION OF sp2 C-H BONDS; 1.10. RHODIUM(I)-CATALYZED INTRAMOLECULAR DIRECTED ALKYLATION OF sp2 C-H BONDS; 1.11. RHODIUM(III)-CATALYZED SYNTHESIS OF NITROGEN-CONTAINING HETEROCYCLES; 1.12. CONCLUSION; REFERENCES; CHAPTER 2: THE NEGISHI CROSS-COUPLING IN THE SYNTHESIS OF NATURAL PRODUCTS AND BIOACTIVE MOLECULES; 2.1. INTRODUCTION 2.2. SYNTHESIS OF NATURAL PRODUCTS 2.2.1. Synthesis of Polyenes; 2.2.2. Synthesis of Amino Acids and Macrocyclic Peptides; 2.2.3. Synthesis of Macrocycles; 2.2.4. Synthesis of Small Heterocycles; 2.3. LARGE-SCALE SYNTHESIS OF BIOLOGICALLY ACTIVE MOLECULES; 2.3.1. Nonsteroidal Ligand A-224817.0 1A; 2.3.2. Phosphodiesterase Inhibitor PDE472; 2.3.3. Reverse Transcriptase Inhibitor MIV-150; 2.3.4. B-Raf Kinase Inhibitors; 2.3.5. mGluR1 Antagonist; 2.4. CONCLUSION; REFERENCES; CHAPTER 3: METAL-CATALYZED C-HETEROATOM CROSS-COUPLING REACTIONS; 3.1. GENERAL INTRODUCTION 3.2. BUCHWALD-HARTWIG-TYPE REACTIONS 3.2.1. Introduction; 3.2.2. Mechanism; 3.2.3. Scope and Limitations; 3.2.4. Applications in the Synthesis of Complex Bioactive Molecules; 3.2.5. C-N Bond Formation; 3.2.6. C-S and C-O Bond Formation; 3.3. ULLMANN-TYPE REACTIONS; 3.3.1. Introduction; 3.3.2. Mechanism; 3.3.3. Scope and Limitations; 3.3.4. Applications in the Synthesis of Complex Bioactive Molecules; 3.3.5. C-N Bond Formation; 3.3.6. C-O Bond Formation; 3.4. MISCELLANEOUS; 3.4.1. Chan-Lam-Evans; 3.4.2. Iron/Copper-Mediated Methodologies; 3.4.3. Other Metals; 3.5. CONCLUSION; REFERENCES CHAPTER 4: GOLDEN OPPORTUNITIES IN THE SYNTHESIS OF NATURAL PRODUCTS AND BIOLOGICALLY ACTIVE COMPOUNDS 4.1. INTRODUCTION; 4.2. GOLD-CATALYZED FORMATION OF OXYGEN-CONTAINING HETEROCYCLES; 4.2.1. Cyclizations Leading to Furan and Pyran Derivatives; 4.2.2. Spiroketalizations; 4.2.3. Other Transformations; 4.3. GOLD-CATALYZED FORMATION OF NITROGEN-CONTAINING HETEROCYCLES; 4.3.1. Cyclizations Involving the Formation of a New C-N Bond; 4.3.2. Cyclizations Involving the Formation of a New C-C Bond; 4.4. GOLD-CATALYZED FORMATION OF CARBOCYCLES 4.4.1. Cyclizations Involving the Formation of a Single New C-C Bond |
| Record Nr. | UNINA-9910819593103321 |
| Hoboken, N.J., : Wiley, c2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Writing reaction mechanisms in organic chemistry / / Audrey Miller, Philippa H. Solomon
| Writing reaction mechanisms in organic chemistry / / Audrey Miller, Philippa H. Solomon |
| Autore | Miller Audrey |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | San Diego, California : , : Academic Press, , 2000 |
| Descrizione fisica | 1 online resource (487 p.) |
| Disciplina | 547/.139 |
| Collana | Advanced Organic Chemistry Series |
| Soggetto topico | Organic reaction mechanisms |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-03728-1
9786611037284 0-08-052133-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Writing Reaction Mechanisms in Organic Chemistry; Copyright Page; Contents; Preface to the Second Edition; Preface to First Edition; Chapter 1. Introduction-Molecular Structure and Reactivity; 1. How to Write Lewis Structures and Calculate Formal Charges; 2. Representations of Organic Compounds; 3. Geometry and Hybridization; 4. Electronegativities and Dipoles; 5. Resonance Structures; 6. Aromaticity and Antiaromaticity; 7. Tautomers and Equilibrium; 8. Acidity and Basicity; 9. Nucleophiles and Electrophiles; Chapter 2. General Principles for Writing Reaction Mechanisms
1. Balancing Equations2. Using Arrows to Show Moving Electrons; 3. Mechanisms in Acidic and Basic Media; 4. Electron-Rich Species: Bases or Nucleophiles?; 5. Trimolecular Steps; 6. Stability of Intermediates; 7. Driving Forces for Reactions; 8. Structural Relationships between Starting Materials and Products; 9. Solvent Effects; 10. A Last Word; Chapter 3. Reactions of Nucleophiles and Bases; 1. Nucleophilic Substitution; 2. Eliminations at Saturated Carbon; 3. Nucleophilic Addition to Carbonyl Compounds; 4. Base-Promoted Rearrangements; 5. Additional Mechanisms in Basic Media Chapter 4. Reactions Involving Acids and Other Electrophiles1. Stability of Carbocations; 2. Formation of Carbocations; 3. The Fate of Carbocations; 4. Rearrangement of Carbocations; 5. Electrophilic Addition; 6. Acid-Catalyzed Reactions of Carbonyl Compounds; 7. Electrophilic Aromatic Substitution; 8. Carbenes; 9. Electrophilic Heteroatoms; Chapter 5. Radicals and Radical Anions; 1. Introduction; 2. Formation of Radicals; 3. Radical Chain Processes; 4. Radical Inhibitors; 5. Determining the Thermodynamic Feasibility of Radical Reactions; 6. Addition of Radicals; 7. Fragmentation Reactions 8. Rearrangement of Radicals9. The Srnl Reaction; 10. The Birch Reduction; 11. A Radical Mechanism for the Rearrangement of Some Anions; Chapter 6. Pericyclic Reactions; 1. Introduction; 2. Electrocyclic Reactions; 3. Cycloadditions; 4. Sigmatropic Rearrangements; 5. The Ene Reaction; 6. A Molecular Orbital View of Pericyclic Processes; Chapter 7. Additional Problems; Appendix A: Lewis Structures of Common Functional Groups; Appendix B: Symbols and Abbreviations Used in Chemical Notation; Appendix C: Relative Acidities of Common Organic and Inorganic Substances; Index |
| Record Nr. | UNINA-9910458081803321 |
|
Miller Audrey
|
||
| San Diego, California : , : Academic Press, , 2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Writing reaction mechanisms in organic chemistry / / Audrey Miller, Philippa H. Solomon
| Writing reaction mechanisms in organic chemistry / / Audrey Miller, Philippa H. Solomon |
| Autore | Miller Audrey |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | San Diego, California : , : Academic Press, , 2000 |
| Descrizione fisica | 1 online resource (487 p.) |
| Disciplina | 547/.139 |
| Collana | Advanced Organic Chemistry Series |
| Soggetto topico | Organic reaction mechanisms |
| ISBN |
1-281-03728-1
9786611037284 0-08-052133-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Writing Reaction Mechanisms in Organic Chemistry; Copyright Page; Contents; Preface to the Second Edition; Preface to First Edition; Chapter 1. Introduction-Molecular Structure and Reactivity; 1. How to Write Lewis Structures and Calculate Formal Charges; 2. Representations of Organic Compounds; 3. Geometry and Hybridization; 4. Electronegativities and Dipoles; 5. Resonance Structures; 6. Aromaticity and Antiaromaticity; 7. Tautomers and Equilibrium; 8. Acidity and Basicity; 9. Nucleophiles and Electrophiles; Chapter 2. General Principles for Writing Reaction Mechanisms
1. Balancing Equations2. Using Arrows to Show Moving Electrons; 3. Mechanisms in Acidic and Basic Media; 4. Electron-Rich Species: Bases or Nucleophiles?; 5. Trimolecular Steps; 6. Stability of Intermediates; 7. Driving Forces for Reactions; 8. Structural Relationships between Starting Materials and Products; 9. Solvent Effects; 10. A Last Word; Chapter 3. Reactions of Nucleophiles and Bases; 1. Nucleophilic Substitution; 2. Eliminations at Saturated Carbon; 3. Nucleophilic Addition to Carbonyl Compounds; 4. Base-Promoted Rearrangements; 5. Additional Mechanisms in Basic Media Chapter 4. Reactions Involving Acids and Other Electrophiles1. Stability of Carbocations; 2. Formation of Carbocations; 3. The Fate of Carbocations; 4. Rearrangement of Carbocations; 5. Electrophilic Addition; 6. Acid-Catalyzed Reactions of Carbonyl Compounds; 7. Electrophilic Aromatic Substitution; 8. Carbenes; 9. Electrophilic Heteroatoms; Chapter 5. Radicals and Radical Anions; 1. Introduction; 2. Formation of Radicals; 3. Radical Chain Processes; 4. Radical Inhibitors; 5. Determining the Thermodynamic Feasibility of Radical Reactions; 6. Addition of Radicals; 7. Fragmentation Reactions 8. Rearrangement of Radicals9. The Srnl Reaction; 10. The Birch Reduction; 11. A Radical Mechanism for the Rearrangement of Some Anions; Chapter 6. Pericyclic Reactions; 1. Introduction; 2. Electrocyclic Reactions; 3. Cycloadditions; 4. Sigmatropic Rearrangements; 5. The Ene Reaction; 6. A Molecular Orbital View of Pericyclic Processes; Chapter 7. Additional Problems; Appendix A: Lewis Structures of Common Functional Groups; Appendix B: Symbols and Abbreviations Used in Chemical Notation; Appendix C: Relative Acidities of Common Organic and Inorganic Substances; Index |
| Record Nr. | UNINA-9910784566903321 |
|
Miller Audrey
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| San Diego, California : , : Academic Press, , 2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Writing reaction mechanisms in organic chemistry / / Audrey Miller, Philippa H. Solomon
| Writing reaction mechanisms in organic chemistry / / Audrey Miller, Philippa H. Solomon |
| Autore | Miller Audrey |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | San Diego, California : , : Academic Press, , 2000 |
| Descrizione fisica | 1 online resource (487 p.) |
| Disciplina | 547/.139 |
| Collana | Advanced Organic Chemistry Series |
| Soggetto topico | Organic reaction mechanisms |
| ISBN |
1-281-03728-1
9786611037284 0-08-052133-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Writing Reaction Mechanisms in Organic Chemistry; Copyright Page; Contents; Preface to the Second Edition; Preface to First Edition; Chapter 1. Introduction-Molecular Structure and Reactivity; 1. How to Write Lewis Structures and Calculate Formal Charges; 2. Representations of Organic Compounds; 3. Geometry and Hybridization; 4. Electronegativities and Dipoles; 5. Resonance Structures; 6. Aromaticity and Antiaromaticity; 7. Tautomers and Equilibrium; 8. Acidity and Basicity; 9. Nucleophiles and Electrophiles; Chapter 2. General Principles for Writing Reaction Mechanisms
1. Balancing Equations2. Using Arrows to Show Moving Electrons; 3. Mechanisms in Acidic and Basic Media; 4. Electron-Rich Species: Bases or Nucleophiles?; 5. Trimolecular Steps; 6. Stability of Intermediates; 7. Driving Forces for Reactions; 8. Structural Relationships between Starting Materials and Products; 9. Solvent Effects; 10. A Last Word; Chapter 3. Reactions of Nucleophiles and Bases; 1. Nucleophilic Substitution; 2. Eliminations at Saturated Carbon; 3. Nucleophilic Addition to Carbonyl Compounds; 4. Base-Promoted Rearrangements; 5. Additional Mechanisms in Basic Media Chapter 4. Reactions Involving Acids and Other Electrophiles1. Stability of Carbocations; 2. Formation of Carbocations; 3. The Fate of Carbocations; 4. Rearrangement of Carbocations; 5. Electrophilic Addition; 6. Acid-Catalyzed Reactions of Carbonyl Compounds; 7. Electrophilic Aromatic Substitution; 8. Carbenes; 9. Electrophilic Heteroatoms; Chapter 5. Radicals and Radical Anions; 1. Introduction; 2. Formation of Radicals; 3. Radical Chain Processes; 4. Radical Inhibitors; 5. Determining the Thermodynamic Feasibility of Radical Reactions; 6. Addition of Radicals; 7. Fragmentation Reactions 8. Rearrangement of Radicals9. The Srnl Reaction; 10. The Birch Reduction; 11. A Radical Mechanism for the Rearrangement of Some Anions; Chapter 6. Pericyclic Reactions; 1. Introduction; 2. Electrocyclic Reactions; 3. Cycloadditions; 4. Sigmatropic Rearrangements; 5. The Ene Reaction; 6. A Molecular Orbital View of Pericyclic Processes; Chapter 7. Additional Problems; Appendix A: Lewis Structures of Common Functional Groups; Appendix B: Symbols and Abbreviations Used in Chemical Notation; Appendix C: Relative Acidities of Common Organic and Inorganic Substances; Index |
| Record Nr. | UNINA-9910826597503321 |
|
Miller Audrey
|
||
| San Diego, California : , : Academic Press, , 2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||