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Functionalized inorganic fluorides [[electronic resource] ] : synthesis, characterization & properties of nanostructured solids / / edited by Alain Tressaud
Functionalized inorganic fluorides [[electronic resource] ] : synthesis, characterization & properties of nanostructured solids / / edited by Alain Tressaud
Pubbl/distr/stampa Hoboken, NJ, : Wiley, 2010
Descrizione fisica 1 online resource (617 p.)
Disciplina 546.731
546/.731
Altri autori (Persone) TressaudAlain
Soggetto topico Fluorides
Fluorine compounds
Soggetto genere / forma Electronic books.
ISBN 1-282-68579-1
9786612685798
0-470-66076-7
0-470-66075-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Functionalized Inorganic Fluorides; Contents; Preface; List of Contributors; 1 Sol-Gel Synthesis of Nano-Scaled Metal Fluorides - Mechanism and Properties; 1.1 Introduction; 1.1.1 Sol-Gel Syntheses of Oxides - An Intensively Studied and Widely Used Process; 1.1.2 Sol-Gel Syntheses of Metal Fluorides - Overview of Methods; 1.2 Fluorolytic Sol-Gel Synthesis; 1.2.1 Mechanism and Properties; 1.2.2 Insight into Mechanism by Analytical Methods; 1.2.3 Exploring Properties; 1.2.4 Possible Fields of Application; References; 2 Microwave-Assisted Route Towards Fluorinated Nanomaterials; 2.1 Introduction
2.2 Introduction to Microwave Synthesis2.2.1 A Brief History; 2.2.2 Mechanisms to Generate Heat; 2.2.3 Advantages of Microwave Synthesis; 2.2.4 Examples of Microwave Experiments; 2.3 Preparation of Nanosized Metal Fluorides; 2.3.1 Aluminium-based Fluoride Materials; 2.3.2 Microwave-assisted Synthesis of Transition Metal Oxy-Hydroxy-Fluorides; 2.4 Concluding Remarks; Acknowledgements; References; 3 High Surface Area Metal Fluorides as Catalysts; 3.1 Introduction; 3.2 High Surface Area Aluminium Fluoride as Catalyst; 3.3 Host-Guest Metal Fluoride Systems
3.4 Hydroxy(oxo)fluorides as Bi-acidic Catalysts3.5 Oxidation Catalysis; 3.6 Metal Fluoride Supported Noble Metal Catalysts; 3.6.1 Hydrodechlorination of Monochlorodifluoromethane; 3.6.2 Hydrodechlorination of Dichloroacetic Acid (DCA); 3.6.3 Suzuki Coupling; References; 4 Investigation of Surface Acidity using a Range of Probe Molecules; 4.1 Introduction; 4.1.1 Setting the Scene: Metal Fluorides versus Metal Oxides; 4.1.2 Some Examples of the Application of FTIR Spectroscopy to the Study of Surface Acidity in Metal Oxides; 4.1.3 A Preview
4.2 Characterization of Acidity on a Surface: Contrasts with Molecular Fluorides4.2.1 Molecular Brnsted and Molecular Lewis Acids; 4.2.2 A Possible Benchmark for Solid Metal Fluoride, Lewis Acids: Aluminium Chlorofluoride; 4.3 Experimental Methodology; 4.3.1 FTIR Spectroscopy; 4.3.2 Characteristic Reactions and the Detection of Adsorbed Species by a Radiotracer Method; 4.4 Experimental Studies of Surface Acidity; 4.4.1 Using FTIR Spectroscopy; 4.4.2 Using HCl as a Probe with Detection via [36Cl]-Labelling
4.4.3 Metal Fluoride Surfaces that Contain Surface Hydroxyl Groups: Aluminium Hydroxy Fluorides with the Hexagonal Tungsten Bronze Structure4.4.4 Possible Geometries for HCl Adsorbed at Metal Fluoride Surfaces: Relation to Oxide and Oxyfluoride Surfaces; 4.5 Conclusions; References; 5 Probing Short and Medium Range Order in Al-based Fluorides using High Resolution Solid State Nuclear Magnetic Resonance and Parameter Modelling; 5.1 Introduction; 5.2 High Resolution NMR Techniques; 5.2.1 Fast MAS and High Magnetic Field; 5.2.2 27Al NMR; 5.2.3 High Resolution Correlation NMR Techniques
5.3 Application to Functionalized Al-Based Fluorides with Catalytic Properties
Record Nr. UNINA-9910140558803321
Hoboken, NJ, : Wiley, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Functionalized inorganic fluorides [[electronic resource] ] : synthesis, characterization & properties of nanostructured solids / / edited by Alain Tressaud
Functionalized inorganic fluorides [[electronic resource] ] : synthesis, characterization & properties of nanostructured solids / / edited by Alain Tressaud
Pubbl/distr/stampa Hoboken, NJ, : Wiley, 2010
Descrizione fisica 1 online resource (617 p.)
Disciplina 546.731
546/.731
Altri autori (Persone) TressaudAlain
Soggetto topico Fluorides
Fluorine compounds
ISBN 1-282-68579-1
9786612685798
0-470-66076-7
0-470-66075-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Functionalized Inorganic Fluorides; Contents; Preface; List of Contributors; 1 Sol-Gel Synthesis of Nano-Scaled Metal Fluorides - Mechanism and Properties; 1.1 Introduction; 1.1.1 Sol-Gel Syntheses of Oxides - An Intensively Studied and Widely Used Process; 1.1.2 Sol-Gel Syntheses of Metal Fluorides - Overview of Methods; 1.2 Fluorolytic Sol-Gel Synthesis; 1.2.1 Mechanism and Properties; 1.2.2 Insight into Mechanism by Analytical Methods; 1.2.3 Exploring Properties; 1.2.4 Possible Fields of Application; References; 2 Microwave-Assisted Route Towards Fluorinated Nanomaterials; 2.1 Introduction
2.2 Introduction to Microwave Synthesis2.2.1 A Brief History; 2.2.2 Mechanisms to Generate Heat; 2.2.3 Advantages of Microwave Synthesis; 2.2.4 Examples of Microwave Experiments; 2.3 Preparation of Nanosized Metal Fluorides; 2.3.1 Aluminium-based Fluoride Materials; 2.3.2 Microwave-assisted Synthesis of Transition Metal Oxy-Hydroxy-Fluorides; 2.4 Concluding Remarks; Acknowledgements; References; 3 High Surface Area Metal Fluorides as Catalysts; 3.1 Introduction; 3.2 High Surface Area Aluminium Fluoride as Catalyst; 3.3 Host-Guest Metal Fluoride Systems
3.4 Hydroxy(oxo)fluorides as Bi-acidic Catalysts3.5 Oxidation Catalysis; 3.6 Metal Fluoride Supported Noble Metal Catalysts; 3.6.1 Hydrodechlorination of Monochlorodifluoromethane; 3.6.2 Hydrodechlorination of Dichloroacetic Acid (DCA); 3.6.3 Suzuki Coupling; References; 4 Investigation of Surface Acidity using a Range of Probe Molecules; 4.1 Introduction; 4.1.1 Setting the Scene: Metal Fluorides versus Metal Oxides; 4.1.2 Some Examples of the Application of FTIR Spectroscopy to the Study of Surface Acidity in Metal Oxides; 4.1.3 A Preview
4.2 Characterization of Acidity on a Surface: Contrasts with Molecular Fluorides4.2.1 Molecular Brnsted and Molecular Lewis Acids; 4.2.2 A Possible Benchmark for Solid Metal Fluoride, Lewis Acids: Aluminium Chlorofluoride; 4.3 Experimental Methodology; 4.3.1 FTIR Spectroscopy; 4.3.2 Characteristic Reactions and the Detection of Adsorbed Species by a Radiotracer Method; 4.4 Experimental Studies of Surface Acidity; 4.4.1 Using FTIR Spectroscopy; 4.4.2 Using HCl as a Probe with Detection via [36Cl]-Labelling
4.4.3 Metal Fluoride Surfaces that Contain Surface Hydroxyl Groups: Aluminium Hydroxy Fluorides with the Hexagonal Tungsten Bronze Structure4.4.4 Possible Geometries for HCl Adsorbed at Metal Fluoride Surfaces: Relation to Oxide and Oxyfluoride Surfaces; 4.5 Conclusions; References; 5 Probing Short and Medium Range Order in Al-based Fluorides using High Resolution Solid State Nuclear Magnetic Resonance and Parameter Modelling; 5.1 Introduction; 5.2 High Resolution NMR Techniques; 5.2.1 Fast MAS and High Magnetic Field; 5.2.2 27Al NMR; 5.2.3 High Resolution Correlation NMR Techniques
5.3 Application to Functionalized Al-Based Fluorides with Catalytic Properties
Record Nr. UNINA-9910830353303321
Hoboken, NJ, : Wiley, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Functionalized inorganic fluorides : synthesis, characterization & properties of nanostructured solids / / edited by Alain Tressaud
Functionalized inorganic fluorides : synthesis, characterization & properties of nanostructured solids / / edited by Alain Tressaud
Pubbl/distr/stampa Hoboken, NJ, : Wiley, 2010
Descrizione fisica 1 online resource (617 p.)
Disciplina 546/.731
Altri autori (Persone) TressaudAlain
Soggetto topico Fluorides
Fluorine compounds
ISBN 9786612685798
9781282685796
1282685791
9780470660768
0470660767
9780470660751
0470660759
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Functionalized Inorganic Fluorides; Contents; Preface; List of Contributors; 1 Sol-Gel Synthesis of Nano-Scaled Metal Fluorides - Mechanism and Properties; 1.1 Introduction; 1.1.1 Sol-Gel Syntheses of Oxides - An Intensively Studied and Widely Used Process; 1.1.2 Sol-Gel Syntheses of Metal Fluorides - Overview of Methods; 1.2 Fluorolytic Sol-Gel Synthesis; 1.2.1 Mechanism and Properties; 1.2.2 Insight into Mechanism by Analytical Methods; 1.2.3 Exploring Properties; 1.2.4 Possible Fields of Application; References; 2 Microwave-Assisted Route Towards Fluorinated Nanomaterials; 2.1 Introduction
2.2 Introduction to Microwave Synthesis2.2.1 A Brief History; 2.2.2 Mechanisms to Generate Heat; 2.2.3 Advantages of Microwave Synthesis; 2.2.4 Examples of Microwave Experiments; 2.3 Preparation of Nanosized Metal Fluorides; 2.3.1 Aluminium-based Fluoride Materials; 2.3.2 Microwave-assisted Synthesis of Transition Metal Oxy-Hydroxy-Fluorides; 2.4 Concluding Remarks; Acknowledgements; References; 3 High Surface Area Metal Fluorides as Catalysts; 3.1 Introduction; 3.2 High Surface Area Aluminium Fluoride as Catalyst; 3.3 Host-Guest Metal Fluoride Systems
3.4 Hydroxy(oxo)fluorides as Bi-acidic Catalysts3.5 Oxidation Catalysis; 3.6 Metal Fluoride Supported Noble Metal Catalysts; 3.6.1 Hydrodechlorination of Monochlorodifluoromethane; 3.6.2 Hydrodechlorination of Dichloroacetic Acid (DCA); 3.6.3 Suzuki Coupling; References; 4 Investigation of Surface Acidity using a Range of Probe Molecules; 4.1 Introduction; 4.1.1 Setting the Scene: Metal Fluorides versus Metal Oxides; 4.1.2 Some Examples of the Application of FTIR Spectroscopy to the Study of Surface Acidity in Metal Oxides; 4.1.3 A Preview
4.2 Characterization of Acidity on a Surface: Contrasts with Molecular Fluorides4.2.1 Molecular Brnsted and Molecular Lewis Acids; 4.2.2 A Possible Benchmark for Solid Metal Fluoride, Lewis Acids: Aluminium Chlorofluoride; 4.3 Experimental Methodology; 4.3.1 FTIR Spectroscopy; 4.3.2 Characteristic Reactions and the Detection of Adsorbed Species by a Radiotracer Method; 4.4 Experimental Studies of Surface Acidity; 4.4.1 Using FTIR Spectroscopy; 4.4.2 Using HCl as a Probe with Detection via [36Cl]-Labelling
4.4.3 Metal Fluoride Surfaces that Contain Surface Hydroxyl Groups: Aluminium Hydroxy Fluorides with the Hexagonal Tungsten Bronze Structure4.4.4 Possible Geometries for HCl Adsorbed at Metal Fluoride Surfaces: Relation to Oxide and Oxyfluoride Surfaces; 4.5 Conclusions; References; 5 Probing Short and Medium Range Order in Al-based Fluorides using High Resolution Solid State Nuclear Magnetic Resonance and Parameter Modelling; 5.1 Introduction; 5.2 High Resolution NMR Techniques; 5.2.1 Fast MAS and High Magnetic Field; 5.2.2 27Al NMR; 5.2.3 High Resolution Correlation NMR Techniques
5.3 Application to Functionalized Al-Based Fluorides with Catalytic Properties
Record Nr. UNINA-9911019493403321
Hoboken, NJ, : Wiley, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of fluorous chemistry [[electronic resource] /] / John A. Gladysz, Dennis P. Curran, István T. Horváth (Eds.)
Handbook of fluorous chemistry [[electronic resource] /] / John A. Gladysz, Dennis P. Curran, István T. Horváth (Eds.)
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2004
Descrizione fisica 1 online resource (627 p.)
Disciplina 546/.731
547.02
Altri autori (Persone) GladyszJohn A
CurranDennis P
HorváthIstván T
Soggetto topico Fluorine compounds
Fluorine
ISBN 1-280-51979-7
9786610519798
3-527-60390-5
3-527-60449-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Fluorous Chemistry; Contents; Preface; Contributors; 1 Fluorous Chemistry: Scope and Definition; 1.1 The Birth of a Term; 1.2 The Definition of Fluorous Today; 1.3 Other Definitions within the Fluorous Repertoire; 1.4 Present Scope of Fluorous Chemistry; References; 2 A Personal View of the History of Fluorous Chemistry; References; 3 Fluorous Solvents and Related Media; 3.1 Introductory Remarks; 3.2 Commercial Fluorous Solvents; 3.3 Related Solvents and Media; 3.3.1 Amphiphilic or Hybrid Solvents; 3.3.2 Fluorous Ionic Liquids; 3.3.3 ""Faux Fluorous"" Solvents
3.3.4 Fluorous Greases3.3.5 Bonded Fluorous Phases; 3.4 Polarities of Fluorous Solvents; 3.5 Solubilities of Solutes in Fluorous Solvents; 3.5.1 General Aspects; 3.5.2 Gas Solubilities; 3.6 Fluorous/Non-fluorous Solvent Miscibilities; 3.7 Special Reactivity Phenomena in Fluorous Solvents; References; 4 Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation; 4.1 Introduction; Basic Recycling Concepts; 4.2 Fluorous/Non-Fluorous Liquid/Liquid Biphase Catalysis; 4.3 Fluorous Catalysis in Amphiphilic or Hybrid Solvents
4.4 Fluorous Catalysis Without Non-Fluorous Solvents4.5 Fluorous Catalysis Without Fluorous Solvents; 4.5.1 Thermomorphic Catalysts; 4.5.2 Other Approaches; 4.6 Fluorous Catalysis Without Solvents; 4.7 Recovery of Fluorous Catalysts using Supports; 4.8 Criteria for Recoverability; 4.8.1 Yield as a Function of Cycle; 4.8.2 TOF as a Function of Cycle; 4.8.3 Catalyst Inventory; 4.9 Slanting Data: How to Make a Non-recoverable Catalyst Appear Recoverable; 4.10 Prospects; References; 5 Ponytails: Structural and Electronic Considerations; 5.1 Introduction; 5.2 Structural Aspects of Ponytails
5.3 NMR Characterization of Ponytails5.4 Electronic Effects: Introduction; 5.5 Electronic Effects: IR Data; 5.6 Electronic Effects: Gas Phase Ionization Data; 5.7 Electronic Effects: Calorimetry; 5.8 Electronic Effects: Solution Equilibria; 5.9 Electronic Effects: Computational Data; 5.10 Electronic Effects: Reactivity; 5.11 Electronic Effects: Additional Probes; 5.12 Electronic Effects: Conclusions; References; 6 Partition Coefficients Involving Fluorous Solvents; 6.1 Introduction; 6.2 Literature Data; 6.3 Trends with Respect to Functional Groups; 6.3.1 Non-Aromatic Hydrocarbons
6.3.2 Non-Aromatic Monofunctional Compounds6.3.3 Simple Monoarenes; 6.3.4 Triarylphosphines; 6.3.5 Pyridines; 6.3.6 Metal Complexes; 6.4 General Trends and Special Situations; 6.5 Quantitative Analysis and Prediction of Partition Coefficients; 6.6 Future Directions; 6.7 Sample Experimental Determinations; References; 7 Separations with Fluorous Silica Gel and Related Materials; 7.1 Introduction; 7.1.1 Fluorous Silica Gel; 7.1.2 Types and Sources of Fluorous Silica Gel Materials and Products; 7.2 Fluorous Solid Phase Extraction (FSPE)
7.2.1 Fluorous Solid Phase Extraction and its Relationship to Chromatography and Liquid/Liquid Extraction
Record Nr. UNINA-9910144297603321
Weinheim, : Wiley-VCH, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of fluorous chemistry [[electronic resource] /] / John A. Gladysz, Dennis P. Curran, István T. Horváth (Eds.)
Handbook of fluorous chemistry [[electronic resource] /] / John A. Gladysz, Dennis P. Curran, István T. Horváth (Eds.)
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2004
Descrizione fisica 1 online resource (627 p.)
Disciplina 546/.731
547.02
Altri autori (Persone) GladyszJohn A
CurranDennis P
HorváthIstván T
Soggetto topico Fluorine compounds
Fluorine
ISBN 1-280-51979-7
9786610519798
3-527-60390-5
3-527-60449-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Fluorous Chemistry; Contents; Preface; Contributors; 1 Fluorous Chemistry: Scope and Definition; 1.1 The Birth of a Term; 1.2 The Definition of Fluorous Today; 1.3 Other Definitions within the Fluorous Repertoire; 1.4 Present Scope of Fluorous Chemistry; References; 2 A Personal View of the History of Fluorous Chemistry; References; 3 Fluorous Solvents and Related Media; 3.1 Introductory Remarks; 3.2 Commercial Fluorous Solvents; 3.3 Related Solvents and Media; 3.3.1 Amphiphilic or Hybrid Solvents; 3.3.2 Fluorous Ionic Liquids; 3.3.3 ""Faux Fluorous"" Solvents
3.3.4 Fluorous Greases3.3.5 Bonded Fluorous Phases; 3.4 Polarities of Fluorous Solvents; 3.5 Solubilities of Solutes in Fluorous Solvents; 3.5.1 General Aspects; 3.5.2 Gas Solubilities; 3.6 Fluorous/Non-fluorous Solvent Miscibilities; 3.7 Special Reactivity Phenomena in Fluorous Solvents; References; 4 Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation; 4.1 Introduction; Basic Recycling Concepts; 4.2 Fluorous/Non-Fluorous Liquid/Liquid Biphase Catalysis; 4.3 Fluorous Catalysis in Amphiphilic or Hybrid Solvents
4.4 Fluorous Catalysis Without Non-Fluorous Solvents4.5 Fluorous Catalysis Without Fluorous Solvents; 4.5.1 Thermomorphic Catalysts; 4.5.2 Other Approaches; 4.6 Fluorous Catalysis Without Solvents; 4.7 Recovery of Fluorous Catalysts using Supports; 4.8 Criteria for Recoverability; 4.8.1 Yield as a Function of Cycle; 4.8.2 TOF as a Function of Cycle; 4.8.3 Catalyst Inventory; 4.9 Slanting Data: How to Make a Non-recoverable Catalyst Appear Recoverable; 4.10 Prospects; References; 5 Ponytails: Structural and Electronic Considerations; 5.1 Introduction; 5.2 Structural Aspects of Ponytails
5.3 NMR Characterization of Ponytails5.4 Electronic Effects: Introduction; 5.5 Electronic Effects: IR Data; 5.6 Electronic Effects: Gas Phase Ionization Data; 5.7 Electronic Effects: Calorimetry; 5.8 Electronic Effects: Solution Equilibria; 5.9 Electronic Effects: Computational Data; 5.10 Electronic Effects: Reactivity; 5.11 Electronic Effects: Additional Probes; 5.12 Electronic Effects: Conclusions; References; 6 Partition Coefficients Involving Fluorous Solvents; 6.1 Introduction; 6.2 Literature Data; 6.3 Trends with Respect to Functional Groups; 6.3.1 Non-Aromatic Hydrocarbons
6.3.2 Non-Aromatic Monofunctional Compounds6.3.3 Simple Monoarenes; 6.3.4 Triarylphosphines; 6.3.5 Pyridines; 6.3.6 Metal Complexes; 6.4 General Trends and Special Situations; 6.5 Quantitative Analysis and Prediction of Partition Coefficients; 6.6 Future Directions; 6.7 Sample Experimental Determinations; References; 7 Separations with Fluorous Silica Gel and Related Materials; 7.1 Introduction; 7.1.1 Fluorous Silica Gel; 7.1.2 Types and Sources of Fluorous Silica Gel Materials and Products; 7.2 Fluorous Solid Phase Extraction (FSPE)
7.2.1 Fluorous Solid Phase Extraction and its Relationship to Chromatography and Liquid/Liquid Extraction
Record Nr. UNINA-9910830242903321
Weinheim, : Wiley-VCH, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Handbook of fluorous chemistry / / John A. Gladysz, Dennis P. Curran, Istvan T. Horvath (Eds.)
Handbook of fluorous chemistry / / John A. Gladysz, Dennis P. Curran, Istvan T. Horvath (Eds.)
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2004
Descrizione fisica 1 online resource (627 p.)
Disciplina 546/.731
Altri autori (Persone) GladyszJohn A
CurranDennis P
HorváthIstván T
Soggetto topico Fluorine compounds
Fluorine
ISBN 9786610519798
9781280519796
1280519797
9783527603909
3527603905
9783527604494
3527604499
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Handbook of Fluorous Chemistry; Contents; Preface; Contributors; 1 Fluorous Chemistry: Scope and Definition; 1.1 The Birth of a Term; 1.2 The Definition of Fluorous Today; 1.3 Other Definitions within the Fluorous Repertoire; 1.4 Present Scope of Fluorous Chemistry; References; 2 A Personal View of the History of Fluorous Chemistry; References; 3 Fluorous Solvents and Related Media; 3.1 Introductory Remarks; 3.2 Commercial Fluorous Solvents; 3.3 Related Solvents and Media; 3.3.1 Amphiphilic or Hybrid Solvents; 3.3.2 Fluorous Ionic Liquids; 3.3.3 ""Faux Fluorous"" Solvents
3.3.4 Fluorous Greases3.3.5 Bonded Fluorous Phases; 3.4 Polarities of Fluorous Solvents; 3.5 Solubilities of Solutes in Fluorous Solvents; 3.5.1 General Aspects; 3.5.2 Gas Solubilities; 3.6 Fluorous/Non-fluorous Solvent Miscibilities; 3.7 Special Reactivity Phenomena in Fluorous Solvents; References; 4 Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation; 4.1 Introduction; Basic Recycling Concepts; 4.2 Fluorous/Non-Fluorous Liquid/Liquid Biphase Catalysis; 4.3 Fluorous Catalysis in Amphiphilic or Hybrid Solvents
4.4 Fluorous Catalysis Without Non-Fluorous Solvents4.5 Fluorous Catalysis Without Fluorous Solvents; 4.5.1 Thermomorphic Catalysts; 4.5.2 Other Approaches; 4.6 Fluorous Catalysis Without Solvents; 4.7 Recovery of Fluorous Catalysts using Supports; 4.8 Criteria for Recoverability; 4.8.1 Yield as a Function of Cycle; 4.8.2 TOF as a Function of Cycle; 4.8.3 Catalyst Inventory; 4.9 Slanting Data: How to Make a Non-recoverable Catalyst Appear Recoverable; 4.10 Prospects; References; 5 Ponytails: Structural and Electronic Considerations; 5.1 Introduction; 5.2 Structural Aspects of Ponytails
5.3 NMR Characterization of Ponytails5.4 Electronic Effects: Introduction; 5.5 Electronic Effects: IR Data; 5.6 Electronic Effects: Gas Phase Ionization Data; 5.7 Electronic Effects: Calorimetry; 5.8 Electronic Effects: Solution Equilibria; 5.9 Electronic Effects: Computational Data; 5.10 Electronic Effects: Reactivity; 5.11 Electronic Effects: Additional Probes; 5.12 Electronic Effects: Conclusions; References; 6 Partition Coefficients Involving Fluorous Solvents; 6.1 Introduction; 6.2 Literature Data; 6.3 Trends with Respect to Functional Groups; 6.3.1 Non-Aromatic Hydrocarbons
6.3.2 Non-Aromatic Monofunctional Compounds6.3.3 Simple Monoarenes; 6.3.4 Triarylphosphines; 6.3.5 Pyridines; 6.3.6 Metal Complexes; 6.4 General Trends and Special Situations; 6.5 Quantitative Analysis and Prediction of Partition Coefficients; 6.6 Future Directions; 6.7 Sample Experimental Determinations; References; 7 Separations with Fluorous Silica Gel and Related Materials; 7.1 Introduction; 7.1.1 Fluorous Silica Gel; 7.1.2 Types and Sources of Fluorous Silica Gel Materials and Products; 7.2 Fluorous Solid Phase Extraction (FSPE)
7.2.1 Fluorous Solid Phase Extraction and its Relationship to Chromatography and Liquid/Liquid Extraction
Record Nr. UNINA-9911019365203321
Weinheim, : Wiley-VCH, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Lifetimes of fluorinated compounds [[electronic resource] /] / Kazuaki Tokuhashi ... [et al.]
Lifetimes of fluorinated compounds [[electronic resource] /] / Kazuaki Tokuhashi ... [et al.]
Pubbl/distr/stampa New York, : Nova Science Publishers, c2008
Descrizione fisica 1 online resource (147 p.)
Disciplina 546/.731
Altri autori (Persone) TokuhashiKazuaki
Soggetto topico Fluorine compounds - Research
Fluorides
Soggetto genere / forma Electronic books.
ISBN 1-60876-251-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto ""LIFETIMES OF FLUORINATED COMPOUNDS""; ""NOTICE TO THE READER""; ""CONTENTS""; ""PREFACE""; ""INTRODUCTION""; ""EXPERIMENTAL APPARATUS AND METHODS""; ""2.1. KINETIC MEASUREMENTS""; ""2.2. APPARATUS AND PROCEDURE FOR THE ABSOLUTE RATE METHOD""; ""2.3. PURIFICATION AND ANALYSIS OF FLUORINATED COMPOUNDS""; ""RESULTS OF KINETIC MEASUREMENTS""; ""3.1. DATA ANALYSIS FOR THE ABSOLUTE RATE METHOD""; ""3.2. EFFECTS OF IMPURITIES""; ""3.3. RATE CONSTANTS FOR REACTIONS OF OH RADICALS WITH FLUORINATED COMPOUNDS""; ""CHF2Cl (HCFC-22)""; ""CHCl2CF3 (HCFC-123)""; ""CHFClCF2Cl (HCFC-123a)""
""CHFClCF3 (HCFC-124)""""CH2ClCF2Cl (HCFC-132b)""; ""CH2ClCF3 (HCFC-133a)""; ""CH2ClCHFCl (HCFC-141)""; ""CH3CFCl2 (HCFC-141b)""; ""CH3CF2Cl (HCFC-142b)""; ""CF3CHClCH2Cl (HCFC-243db)""; ""CF3CH2CH2Cl (HCFC-253fb)""; ""CH2F2 (HFC-32)""; ""CHF2CF3 (HFC-125)""; ""CH2FCF3 (HFC-134a)""; ""CH2FCHF2 (HFC-143)""; ""CH3CHF2 (HFC-152a)""; ""CF3CHFCHF2 (HFC-236ea)""; ""CH2FCF2CHF2 (HFC-245ca)""; ""CF3CHFCH2F (HFC-245eb)""; ""CHF2CH2CF3 (HFC-245fa)""; ""CF3CH2CH2F (HFC-254fb)""; ""CH3CF2CH3 (HFC-272ca)""; ""CF3CHFCHFCF2CF3 (HFC-43-10mee)""; ""3.4. TROPOSPHERIC LIFETIMES OF FLUORINATED COMPOUNDS""
""ESTIMATION OF RATE CONSTANTS BY THE NEURAL NETWORK METHOD""""4.1. EMPIRICAL METHODS FOR ESTIMATION OF RATE CONSTANTS OF REACTIONS WITH OH RADICALS""; ""4.2. TRENDS IN REACTIVITY OF FLUORINATED COMPOUNDS WITH OH RADICALS""; ""4.3. ESTIMATION OF RATE CONSTANTS FOR REACTION WITH OH RADICALS BY THE NEURAL NETWORK METHOD""; ""CONCLUSION""; ""REFERENCES""; ""INDEX""
Record Nr. UNINA-9910455374803321
New York, : Nova Science Publishers, c2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Lifetimes of fluorinated compounds [[electronic resource] /] / Kazuaki Tokuhashi ... [et al.]
Lifetimes of fluorinated compounds [[electronic resource] /] / Kazuaki Tokuhashi ... [et al.]
Pubbl/distr/stampa New York, : Nova Science Publishers, c2008
Descrizione fisica 1 online resource (147 p.)
Disciplina 546/.731
Altri autori (Persone) TokuhashiKazuaki
Soggetto topico Fluorine compounds - Research
Fluorides
ISBN 1-60876-251-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto ""LIFETIMES OF FLUORINATED COMPOUNDS""; ""NOTICE TO THE READER""; ""CONTENTS""; ""PREFACE""; ""INTRODUCTION""; ""EXPERIMENTAL APPARATUS AND METHODS""; ""2.1. KINETIC MEASUREMENTS""; ""2.2. APPARATUS AND PROCEDURE FOR THE ABSOLUTE RATE METHOD""; ""2.3. PURIFICATION AND ANALYSIS OF FLUORINATED COMPOUNDS""; ""RESULTS OF KINETIC MEASUREMENTS""; ""3.1. DATA ANALYSIS FOR THE ABSOLUTE RATE METHOD""; ""3.2. EFFECTS OF IMPURITIES""; ""3.3. RATE CONSTANTS FOR REACTIONS OF OH RADICALS WITH FLUORINATED COMPOUNDS""; ""CHF2Cl (HCFC-22)""; ""CHCl2CF3 (HCFC-123)""; ""CHFClCF2Cl (HCFC-123a)""
""CHFClCF3 (HCFC-124)""""CH2ClCF2Cl (HCFC-132b)""; ""CH2ClCF3 (HCFC-133a)""; ""CH2ClCHFCl (HCFC-141)""; ""CH3CFCl2 (HCFC-141b)""; ""CH3CF2Cl (HCFC-142b)""; ""CF3CHClCH2Cl (HCFC-243db)""; ""CF3CH2CH2Cl (HCFC-253fb)""; ""CH2F2 (HFC-32)""; ""CHF2CF3 (HFC-125)""; ""CH2FCF3 (HFC-134a)""; ""CH2FCHF2 (HFC-143)""; ""CH3CHF2 (HFC-152a)""; ""CF3CHFCHF2 (HFC-236ea)""; ""CH2FCF2CHF2 (HFC-245ca)""; ""CF3CHFCH2F (HFC-245eb)""; ""CHF2CH2CF3 (HFC-245fa)""; ""CF3CH2CH2F (HFC-254fb)""; ""CH3CF2CH3 (HFC-272ca)""; ""CF3CHFCHFCF2CF3 (HFC-43-10mee)""; ""3.4. TROPOSPHERIC LIFETIMES OF FLUORINATED COMPOUNDS""
""ESTIMATION OF RATE CONSTANTS BY THE NEURAL NETWORK METHOD""""4.1. EMPIRICAL METHODS FOR ESTIMATION OF RATE CONSTANTS OF REACTIONS WITH OH RADICALS""; ""4.2. TRENDS IN REACTIVITY OF FLUORINATED COMPOUNDS WITH OH RADICALS""; ""4.3. ESTIMATION OF RATE CONSTANTS FOR REACTION WITH OH RADICALS BY THE NEURAL NETWORK METHOD""; ""CONCLUSION""; ""REFERENCES""; ""INDEX""
Record Nr. UNINA-9910778008903321
New York, : Nova Science Publishers, c2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Lifetimes of fluorinated compounds / / Kazuaki Tokuhashi ... [et al.]
Lifetimes of fluorinated compounds / / Kazuaki Tokuhashi ... [et al.]
Edizione [1st ed.]
Pubbl/distr/stampa New York, : Nova Science Publishers, c2008
Descrizione fisica 1 online resource (147 p.)
Disciplina 546/.731
Altri autori (Persone) TokuhashiKazuaki
Soggetto topico Fluorine compounds - Research
Fluorides
ISBN 1-60876-251-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto ""LIFETIMES OF FLUORINATED COMPOUNDS""; ""NOTICE TO THE READER""; ""CONTENTS""; ""PREFACE""; ""INTRODUCTION""; ""EXPERIMENTAL APPARATUS AND METHODS""; ""2.1. KINETIC MEASUREMENTS""; ""2.2. APPARATUS AND PROCEDURE FOR THE ABSOLUTE RATE METHOD""; ""2.3. PURIFICATION AND ANALYSIS OF FLUORINATED COMPOUNDS""; ""RESULTS OF KINETIC MEASUREMENTS""; ""3.1. DATA ANALYSIS FOR THE ABSOLUTE RATE METHOD""; ""3.2. EFFECTS OF IMPURITIES""; ""3.3. RATE CONSTANTS FOR REACTIONS OF OH RADICALS WITH FLUORINATED COMPOUNDS""; ""CHF2Cl (HCFC-22)""; ""CHCl2CF3 (HCFC-123)""; ""CHFClCF2Cl (HCFC-123a)""
""CHFClCF3 (HCFC-124)""""CH2ClCF2Cl (HCFC-132b)""; ""CH2ClCF3 (HCFC-133a)""; ""CH2ClCHFCl (HCFC-141)""; ""CH3CFCl2 (HCFC-141b)""; ""CH3CF2Cl (HCFC-142b)""; ""CF3CHClCH2Cl (HCFC-243db)""; ""CF3CH2CH2Cl (HCFC-253fb)""; ""CH2F2 (HFC-32)""; ""CHF2CF3 (HFC-125)""; ""CH2FCF3 (HFC-134a)""; ""CH2FCHF2 (HFC-143)""; ""CH3CHF2 (HFC-152a)""; ""CF3CHFCHF2 (HFC-236ea)""; ""CH2FCF2CHF2 (HFC-245ca)""; ""CF3CHFCH2F (HFC-245eb)""; ""CHF2CH2CF3 (HFC-245fa)""; ""CF3CH2CH2F (HFC-254fb)""; ""CH3CF2CH3 (HFC-272ca)""; ""CF3CHFCHFCF2CF3 (HFC-43-10mee)""; ""3.4. TROPOSPHERIC LIFETIMES OF FLUORINATED COMPOUNDS""
""ESTIMATION OF RATE CONSTANTS BY THE NEURAL NETWORK METHOD""""4.1. EMPIRICAL METHODS FOR ESTIMATION OF RATE CONSTANTS OF REACTIONS WITH OH RADICALS""; ""4.2. TRENDS IN REACTIVITY OF FLUORINATED COMPOUNDS WITH OH RADICALS""; ""4.3. ESTIMATION OF RATE CONSTANTS FOR REACTION WITH OH RADICALS BY THE NEURAL NETWORK METHOD""; ""CONCLUSION""; ""REFERENCES""; ""INDEX""
Record Nr. UNINA-9910958400403321
New York, : Nova Science Publishers, c2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui