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Ligand design in metal chemistry : reactivity and catalysis / / edited by Mark Stradiotto, Rylan J. Lundgren
| Ligand design in metal chemistry : reactivity and catalysis / / edited by Mark Stradiotto, Rylan J. Lundgren |
| Pubbl/distr/stampa | Chichester, England : , : Wiley, , 2016 |
| Descrizione fisica | 1 online resource (456 p.) |
| Disciplina | 546/.3 |
| Soggetto topico |
Ligands
Organometallic compounds - Reactivity Homogeneous catalysis |
| ISBN |
1-118-83981-1
1-118-83977-3 1-118-83962-5 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
4.2.6 Ir-catalyzed hydrogenation of ketones 4.2.7 Ru-catalyzed hydrogenation of racemic 2-substituted aldehydes via dynamic kinetic resolution ; 4.2.8 Ru-catalyzed hydrogenation of racemic 2-substituted ketones via DKR ; 4.2.9 Ir-catalyzed hydrogenation of imines ; 4.3 Carbon-carbon bond-forming reactions ; 4.3.1 Ni-catalyzed hydrovinylation of olefins ; 4.3.2 Rh-catalyzed hydroacylation ; 4.3.3 Rh-catalyzed arylation of carbonyl compounds and imines ; 4.3.4 Pd-catalyzed umpolung allylation reactions of aldehydes, ketones, and imines ; 4.3.5 Ni-catalyzed three-component coupling reaction
4.3.6 Au-catalyzed Mannich reactions of azlactones |
| Record Nr. | UNINA-9910134876203321 |
| Chichester, England : , : Wiley, , 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ligand design in metal chemistry : reactivity and catalysis / / edited by Mark Stradiotto, Rylan J. Lundgren
| Ligand design in metal chemistry : reactivity and catalysis / / edited by Mark Stradiotto, Rylan J. Lundgren |
| Pubbl/distr/stampa | Chichester, England : , : Wiley, , 2016 |
| Descrizione fisica | 1 online resource (456 p.) |
| Disciplina | 546/.3 |
| Soggetto topico |
Ligands
Organometallic compounds - Reactivity Homogeneous catalysis |
| ISBN |
1-118-83981-1
1-118-83977-3 1-118-83962-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
4.2.6 Ir-catalyzed hydrogenation of ketones 4.2.7 Ru-catalyzed hydrogenation of racemic 2-substituted aldehydes via dynamic kinetic resolution ; 4.2.8 Ru-catalyzed hydrogenation of racemic 2-substituted ketones via DKR ; 4.2.9 Ir-catalyzed hydrogenation of imines ; 4.3 Carbon-carbon bond-forming reactions ; 4.3.1 Ni-catalyzed hydrovinylation of olefins ; 4.3.2 Rh-catalyzed hydroacylation ; 4.3.3 Rh-catalyzed arylation of carbonyl compounds and imines ; 4.3.4 Pd-catalyzed umpolung allylation reactions of aldehydes, ketones, and imines ; 4.3.5 Ni-catalyzed three-component coupling reaction
4.3.6 Au-catalyzed Mannich reactions of azlactones |
| Record Nr. | UNINA-9910830519803321 |
| Chichester, England : , : Wiley, , 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Metal clusters / edited by Walter Ekardt
| Metal clusters / edited by Walter Ekardt |
| Pubbl/distr/stampa | Chichester ; New York : Wiley, c1999 |
| Descrizione fisica | xii, 286 p. : ill. ; 26 cm |
| Disciplina | 546/.3 |
| Altri autori (Persone) | Ekardt, Walter |
| Collana | Wiley series in theoretical chemistry |
| Soggetto topico | Metal clusters |
| ISBN | 0471987832 (hardback : alk. paper) |
| Classificazione |
LC QD921
53.4.16 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991003522909707536 |
| Chichester ; New York : Wiley, c1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Polyoxometalate chemistry [[electronic resource] ] : some recent trends / / editor, Francis Secheresse
| Polyoxometalate chemistry [[electronic resource] ] : some recent trends / / editor, Francis Secheresse |
| Pubbl/distr/stampa | Hackensack [NJ], : World Scientific, c2013 |
| Descrizione fisica | 1 online resource (360 p.) |
| Disciplina | 546/.3 |
| Altri autori (Persone) | SecheresseFrancis |
| Collana | World Scientific series in nanoscience and nanotechnology |
| Soggetto topico |
Polyoxometalates
Coordination compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN | 981-4458-98-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COLOR PLATE 36 Chapter 1 Polyoxometalate-Protected Metal Nanoparticles: Synthesis, Structure and Catalysis Yifeng Wang and Ira A. Weinstock; 1. Introduction; 2. Synthesis of Polyoxometalate Stabilized Metal(0) Nanoparticles; 2.1. Control over shape and size; 2.2. Ir and Ru nanoparticles by H2 reduction; 2.3. Reactions of metal salts with reduced polyoxometalate anions; 2.3.1. Synthesis of nanoparticles; 2.3.2 Synthesis of complex nanostructures; 2.4. Ligand-exchange reactions; 3. Structures of Inorganic Cluster Anions Stabilized Nanoparticles
3.1. Evidence for the stabilization of metal(0) nanoparticles by polyoxometalates 3.2. Direct imaging of POM-ligand monolayers by cryo-TEM; 3.3. Electric double layer of a polyoxometalate-stabilized nanoparticle; 4. Application of POM-stabilized Au NPs in Catalysis; 4.1. Hydrogenation reactions using POM-stabilized metal NPs; 4.2. Molecular oxygen activation reactions for organic synthesis; 4.3. Other organic reactions catalyzed by polyoxometalate-stabilized metal nanoparticles; 4.4. Electrocatalysis; 5. Closing Comments; References Chapter 2 When Giants Meet Dwarves in the Same Pond - Unique Solution Physical Chemistry Opportunities Offered by Polyoxometalate Macroions Dong Li, Panchao Yin and Tianbo Liu 1. Introduction and Retrospection; 1.1. Derivation of the Debye-Hückel's limiting theory5; 1.2. General features of the DLVO theory; 1.2.1. DLVO potential and the primary and secondary minima; 1.2.2. Limitations of the DLVO theory; 2. Characterization of Macroion Solution Behaviors; 2.1. Polyoxometalates (POMs) type macroanions; 2.1.1. Characterization of the self-assembly of POM macroanions in dilute solutions 2.1.2. The driving forces that responsible for the unexpected self-assembly of macroanions 2.1.2.1. Van der Waals attractions; 2.1.2.2. Hydrogen bonding; 2.1.2.3. Counterions mediated attractions; a) Interactions between discrete macroions and counterions; b) Effect of surface charge density; c) Effect of counterion valence state and counterion hydrated size; d) Effect of ionic strength; 2.1.2.4. Solvent effect; 2.1.3. Kinetics of the blackberry formation; 2.1.3.1. Long equilibrium time; 2.1.3.2. High activation energy; 2.1.3.3. Slow nucleation and fast aggregation 2.2. Self-assembly of macrocations |
| Record Nr. | UNINA-9910452294103321 |
| Hackensack [NJ], : World Scientific, c2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse, Universite de Versailles-St. Quentin, France
| Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse, Universite de Versailles-St. Quentin, France |
| Pubbl/distr/stampa | Hackensack [NJ], : World Scientific, c2013 |
| Descrizione fisica | 1 online resource (xiii, 309 pages) : illustrations (some color) |
| Disciplina | 546/.3 |
| Collana | World Scientific series in nanoscience and nanotechnology |
| Soggetto topico | Polyoxometalates |
| ISBN | 981-4458-98-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COLOR PLATE 36 Chapter 1 Polyoxometalate-Protected Metal Nanoparticles: Synthesis, Structure and Catalysis Yifeng Wang and Ira A. Weinstock; 1. Introduction; 2. Synthesis of Polyoxometalate Stabilized Metal(0) Nanoparticles; 2.1. Control over shape and size; 2.2. Ir and Ru nanoparticles by H2 reduction; 2.3. Reactions of metal salts with reduced polyoxometalate anions; 2.3.1. Synthesis of nanoparticles; 2.3.2 Synthesis of complex nanostructures; 2.4. Ligand-exchange reactions; 3. Structures of Inorganic Cluster Anions Stabilized Nanoparticles
3.1. Evidence for the stabilization of metal(0) nanoparticles by polyoxometalates 3.2. Direct imaging of POM-ligand monolayers by cryo-TEM; 3.3. Electric double layer of a polyoxometalate-stabilized nanoparticle; 4. Application of POM-stabilized Au NPs in Catalysis; 4.1. Hydrogenation reactions using POM-stabilized metal NPs; 4.2. Molecular oxygen activation reactions for organic synthesis; 4.3. Other organic reactions catalyzed by polyoxometalate-stabilized metal nanoparticles; 4.4. Electrocatalysis; 5. Closing Comments; References Chapter 2 When Giants Meet Dwarves in the Same Pond - Unique Solution Physical Chemistry Opportunities Offered by Polyoxometalate Macroions Dong Li, Panchao Yin and Tianbo Liu 1. Introduction and Retrospection; 1.1. Derivation of the Debye-Hückel's limiting theory5; 1.2. General features of the DLVO theory; 1.2.1. DLVO potential and the primary and secondary minima; 1.2.2. Limitations of the DLVO theory; 2. Characterization of Macroion Solution Behaviors; 2.1. Polyoxometalates (POMs) type macroanions; 2.1.1. Characterization of the self-assembly of POM macroanions in dilute solutions 2.1.2. The driving forces that responsible for the unexpected self-assembly of macroanions 2.1.2.1. Van der Waals attractions; 2.1.2.2. Hydrogen bonding; 2.1.2.3. Counterions mediated attractions; a) Interactions between discrete macroions and counterions; b) Effect of surface charge density; c) Effect of counterion valence state and counterion hydrated size; d) Effect of ionic strength; 2.1.2.4. Solvent effect; 2.1.3. Kinetics of the blackberry formation; 2.1.3.1. Long equilibrium time; 2.1.3.2. High activation energy; 2.1.3.3. Slow nucleation and fast aggregation 2.2. Self-assembly of macrocations |
| Record Nr. | UNINA-9910779882803321 |
| Hackensack [NJ], : World Scientific, c2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse, Universite de Versailles-St. Quentin, France
| Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse, Universite de Versailles-St. Quentin, France |
| Pubbl/distr/stampa | Hackensack [NJ], : World Scientific, c2013 |
| Descrizione fisica | 1 online resource (xiii, 309 pages) : illustrations (some color) |
| Disciplina | 546/.3 |
| Collana | World Scientific series in nanoscience and nanotechnology |
| Soggetto topico | Polyoxometalates |
| ISBN | 981-4458-98-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COLOR PLATE 36 Chapter 1 Polyoxometalate-Protected Metal Nanoparticles: Synthesis, Structure and Catalysis Yifeng Wang and Ira A. Weinstock; 1. Introduction; 2. Synthesis of Polyoxometalate Stabilized Metal(0) Nanoparticles; 2.1. Control over shape and size; 2.2. Ir and Ru nanoparticles by H2 reduction; 2.3. Reactions of metal salts with reduced polyoxometalate anions; 2.3.1. Synthesis of nanoparticles; 2.3.2 Synthesis of complex nanostructures; 2.4. Ligand-exchange reactions; 3. Structures of Inorganic Cluster Anions Stabilized Nanoparticles
3.1. Evidence for the stabilization of metal(0) nanoparticles by polyoxometalates 3.2. Direct imaging of POM-ligand monolayers by cryo-TEM; 3.3. Electric double layer of a polyoxometalate-stabilized nanoparticle; 4. Application of POM-stabilized Au NPs in Catalysis; 4.1. Hydrogenation reactions using POM-stabilized metal NPs; 4.2. Molecular oxygen activation reactions for organic synthesis; 4.3. Other organic reactions catalyzed by polyoxometalate-stabilized metal nanoparticles; 4.4. Electrocatalysis; 5. Closing Comments; References Chapter 2 When Giants Meet Dwarves in the Same Pond - Unique Solution Physical Chemistry Opportunities Offered by Polyoxometalate Macroions Dong Li, Panchao Yin and Tianbo Liu 1. Introduction and Retrospection; 1.1. Derivation of the Debye-Hückel's limiting theory5; 1.2. General features of the DLVO theory; 1.2.1. DLVO potential and the primary and secondary minima; 1.2.2. Limitations of the DLVO theory; 2. Characterization of Macroion Solution Behaviors; 2.1. Polyoxometalates (POMs) type macroanions; 2.1.1. Characterization of the self-assembly of POM macroanions in dilute solutions 2.1.2. The driving forces that responsible for the unexpected self-assembly of macroanions 2.1.2.1. Van der Waals attractions; 2.1.2.2. Hydrogen bonding; 2.1.2.3. Counterions mediated attractions; a) Interactions between discrete macroions and counterions; b) Effect of surface charge density; c) Effect of counterion valence state and counterion hydrated size; d) Effect of ionic strength; 2.1.2.4. Solvent effect; 2.1.3. Kinetics of the blackberry formation; 2.1.3.1. Long equilibrium time; 2.1.3.2. High activation energy; 2.1.3.3. Slow nucleation and fast aggregation 2.2. Self-assembly of macrocations |
| Record Nr. | UNINA-9910824591503321 |
| Hackensack [NJ], : World Scientific, c2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Superalloys [[electronic resource] ] : production, properties and applications / / Jeremy E. Watson, editor
| Superalloys [[electronic resource] ] : production, properties and applications / / Jeremy E. Watson, editor |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (178 p.) |
| Disciplina | 546/.3 |
| Altri autori (Persone) | WatsonJeremy E |
| Collana | Materials science and technologies |
| Soggetto topico | Heat resistant alloys |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-62257-035-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910453818503321 |
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Superalloys [[electronic resource] ] : production, properties and applications / / Jeremy E. Watson, editor
| Superalloys [[electronic resource] ] : production, properties and applications / / Jeremy E. Watson, editor |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (178 p.) |
| Disciplina | 546/.3 |
| Altri autori (Persone) | WatsonJeremy E |
| Collana | Materials science and technologies |
| Soggetto topico | Heat resistant alloys |
| ISBN | 1-62257-035-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910779788103321 |
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||