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Ligand design in metal chemistry : reactivity and catalysis / / edited by Mark Stradiotto, Rylan J. Lundgren
| Ligand design in metal chemistry : reactivity and catalysis / / edited by Mark Stradiotto, Rylan J. Lundgren |
| Pubbl/distr/stampa | Chichester, England : , : Wiley, , 2016 |
| Descrizione fisica | 1 online resource (456 p.) |
| Disciplina | 546/.3 |
| Soggetto topico |
Ligands
Organometallic compounds - Reactivity Homogeneous catalysis |
| ISBN |
1-118-83981-1
1-118-83977-3 1-118-83962-5 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
4.2.6 Ir-catalyzed hydrogenation of ketones 4.2.7 Ru-catalyzed hydrogenation of racemic 2-substituted aldehydes via dynamic kinetic resolution ; 4.2.8 Ru-catalyzed hydrogenation of racemic 2-substituted ketones via DKR ; 4.2.9 Ir-catalyzed hydrogenation of imines ; 4.3 Carbon-carbon bond-forming reactions ; 4.3.1 Ni-catalyzed hydrovinylation of olefins ; 4.3.2 Rh-catalyzed hydroacylation ; 4.3.3 Rh-catalyzed arylation of carbonyl compounds and imines ; 4.3.4 Pd-catalyzed umpolung allylation reactions of aldehydes, ketones, and imines ; 4.3.5 Ni-catalyzed three-component coupling reaction
4.3.6 Au-catalyzed Mannich reactions of azlactones |
| Record Nr. | UNINA-9910134876203321 |
| Chichester, England : , : Wiley, , 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Ligand design in metal chemistry : reactivity and catalysis / / edited by Mark Stradiotto, Rylan J. Lundgren
| Ligand design in metal chemistry : reactivity and catalysis / / edited by Mark Stradiotto, Rylan J. Lundgren |
| Pubbl/distr/stampa | Chichester, England : , : Wiley, , 2016 |
| Descrizione fisica | 1 online resource (456 p.) |
| Disciplina | 546/.3 |
| Soggetto topico |
Ligands
Organometallic compounds - Reactivity Homogeneous catalysis |
| ISBN |
1-118-83981-1
1-118-83977-3 1-118-83962-5 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
4.2.6 Ir-catalyzed hydrogenation of ketones 4.2.7 Ru-catalyzed hydrogenation of racemic 2-substituted aldehydes via dynamic kinetic resolution ; 4.2.8 Ru-catalyzed hydrogenation of racemic 2-substituted ketones via DKR ; 4.2.9 Ir-catalyzed hydrogenation of imines ; 4.3 Carbon-carbon bond-forming reactions ; 4.3.1 Ni-catalyzed hydrovinylation of olefins ; 4.3.2 Rh-catalyzed hydroacylation ; 4.3.3 Rh-catalyzed arylation of carbonyl compounds and imines ; 4.3.4 Pd-catalyzed umpolung allylation reactions of aldehydes, ketones, and imines ; 4.3.5 Ni-catalyzed three-component coupling reaction
4.3.6 Au-catalyzed Mannich reactions of azlactones |
| Record Nr. | UNINA-9910830519803321 |
| Chichester, England : , : Wiley, , 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Metal clusters / edited by Walter Ekardt
| Metal clusters / edited by Walter Ekardt |
| Pubbl/distr/stampa | Chichester ; New York : Wiley, c1999 |
| Descrizione fisica | xii, 286 p. : ill. ; 26 cm |
| Disciplina | 546/.3 |
| Altri autori (Persone) | Ekardt, Walter |
| Collana | Wiley series in theoretical chemistry |
| Soggetto topico | Metal clusters |
| ISBN | 0471987832 (hardback : alk. paper) |
| Classificazione |
LC QD921
53.4.16 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISALENTO-991003522909707536 |
| Chichester ; New York : Wiley, c1999 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. del Salento | ||
| ||
Polyoxometalate chemistry [[electronic resource] ] : some recent trends / / editor, Francis Secheresse
| Polyoxometalate chemistry [[electronic resource] ] : some recent trends / / editor, Francis Secheresse |
| Pubbl/distr/stampa | Hackensack [NJ], : World Scientific, c2013 |
| Descrizione fisica | 1 online resource (360 p.) |
| Disciplina | 546/.3 |
| Altri autori (Persone) | SecheresseFrancis |
| Collana | World Scientific series in nanoscience and nanotechnology |
| Soggetto topico |
Polyoxometalates
Coordination compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN | 981-4458-98-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COLOR PLATE 36 Chapter 1 Polyoxometalate-Protected Metal Nanoparticles: Synthesis, Structure and Catalysis Yifeng Wang and Ira A. Weinstock; 1. Introduction; 2. Synthesis of Polyoxometalate Stabilized Metal(0) Nanoparticles; 2.1. Control over shape and size; 2.2. Ir and Ru nanoparticles by H2 reduction; 2.3. Reactions of metal salts with reduced polyoxometalate anions; 2.3.1. Synthesis of nanoparticles; 2.3.2 Synthesis of complex nanostructures; 2.4. Ligand-exchange reactions; 3. Structures of Inorganic Cluster Anions Stabilized Nanoparticles
3.1. Evidence for the stabilization of metal(0) nanoparticles by polyoxometalates 3.2. Direct imaging of POM-ligand monolayers by cryo-TEM; 3.3. Electric double layer of a polyoxometalate-stabilized nanoparticle; 4. Application of POM-stabilized Au NPs in Catalysis; 4.1. Hydrogenation reactions using POM-stabilized metal NPs; 4.2. Molecular oxygen activation reactions for organic synthesis; 4.3. Other organic reactions catalyzed by polyoxometalate-stabilized metal nanoparticles; 4.4. Electrocatalysis; 5. Closing Comments; References Chapter 2 When Giants Meet Dwarves in the Same Pond - Unique Solution Physical Chemistry Opportunities Offered by Polyoxometalate Macroions Dong Li, Panchao Yin and Tianbo Liu 1. Introduction and Retrospection; 1.1. Derivation of the Debye-Hückel's limiting theory5; 1.2. General features of the DLVO theory; 1.2.1. DLVO potential and the primary and secondary minima; 1.2.2. Limitations of the DLVO theory; 2. Characterization of Macroion Solution Behaviors; 2.1. Polyoxometalates (POMs) type macroanions; 2.1.1. Characterization of the self-assembly of POM macroanions in dilute solutions 2.1.2. The driving forces that responsible for the unexpected self-assembly of macroanions 2.1.2.1. Van der Waals attractions; 2.1.2.2. Hydrogen bonding; 2.1.2.3. Counterions mediated attractions; a) Interactions between discrete macroions and counterions; b) Effect of surface charge density; c) Effect of counterion valence state and counterion hydrated size; d) Effect of ionic strength; 2.1.2.4. Solvent effect; 2.1.3. Kinetics of the blackberry formation; 2.1.3.1. Long equilibrium time; 2.1.3.2. High activation energy; 2.1.3.3. Slow nucleation and fast aggregation 2.2. Self-assembly of macrocations |
| Record Nr. | UNINA-9910452294103321 |
| Hackensack [NJ], : World Scientific, c2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse, Universite de Versailles-St. Quentin, France
| Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse, Universite de Versailles-St. Quentin, France |
| Pubbl/distr/stampa | Hackensack [NJ], : World Scientific, c2013 |
| Descrizione fisica | 1 online resource (xiii, 309 pages) : illustrations (some color) |
| Disciplina | 546/.3 |
| Collana | World Scientific series in nanoscience and nanotechnology |
| Soggetto topico | Polyoxometalates |
| ISBN | 981-4458-98-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COLOR PLATE 36 Chapter 1 Polyoxometalate-Protected Metal Nanoparticles: Synthesis, Structure and Catalysis Yifeng Wang and Ira A. Weinstock; 1. Introduction; 2. Synthesis of Polyoxometalate Stabilized Metal(0) Nanoparticles; 2.1. Control over shape and size; 2.2. Ir and Ru nanoparticles by H2 reduction; 2.3. Reactions of metal salts with reduced polyoxometalate anions; 2.3.1. Synthesis of nanoparticles; 2.3.2 Synthesis of complex nanostructures; 2.4. Ligand-exchange reactions; 3. Structures of Inorganic Cluster Anions Stabilized Nanoparticles
3.1. Evidence for the stabilization of metal(0) nanoparticles by polyoxometalates 3.2. Direct imaging of POM-ligand monolayers by cryo-TEM; 3.3. Electric double layer of a polyoxometalate-stabilized nanoparticle; 4. Application of POM-stabilized Au NPs in Catalysis; 4.1. Hydrogenation reactions using POM-stabilized metal NPs; 4.2. Molecular oxygen activation reactions for organic synthesis; 4.3. Other organic reactions catalyzed by polyoxometalate-stabilized metal nanoparticles; 4.4. Electrocatalysis; 5. Closing Comments; References Chapter 2 When Giants Meet Dwarves in the Same Pond - Unique Solution Physical Chemistry Opportunities Offered by Polyoxometalate Macroions Dong Li, Panchao Yin and Tianbo Liu 1. Introduction and Retrospection; 1.1. Derivation of the Debye-Hückel's limiting theory5; 1.2. General features of the DLVO theory; 1.2.1. DLVO potential and the primary and secondary minima; 1.2.2. Limitations of the DLVO theory; 2. Characterization of Macroion Solution Behaviors; 2.1. Polyoxometalates (POMs) type macroanions; 2.1.1. Characterization of the self-assembly of POM macroanions in dilute solutions 2.1.2. The driving forces that responsible for the unexpected self-assembly of macroanions 2.1.2.1. Van der Waals attractions; 2.1.2.2. Hydrogen bonding; 2.1.2.3. Counterions mediated attractions; a) Interactions between discrete macroions and counterions; b) Effect of surface charge density; c) Effect of counterion valence state and counterion hydrated size; d) Effect of ionic strength; 2.1.2.4. Solvent effect; 2.1.3. Kinetics of the blackberry formation; 2.1.3.1. Long equilibrium time; 2.1.3.2. High activation energy; 2.1.3.3. Slow nucleation and fast aggregation 2.2. Self-assembly of macrocations |
| Record Nr. | UNINA-9910779882803321 |
| Hackensack [NJ], : World Scientific, c2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse, Universite de Versailles-St. Quentin, France
| Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse, Universite de Versailles-St. Quentin, France |
| Pubbl/distr/stampa | Hackensack [NJ], : World Scientific, c2013 |
| Descrizione fisica | 1 online resource (xiii, 309 pages) : illustrations (some color) |
| Disciplina | 546/.3 |
| Collana | World Scientific series in nanoscience and nanotechnology |
| Soggetto topico | Polyoxometalates |
| ISBN | 981-4458-98-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
COLOR PLATE 36 Chapter 1 Polyoxometalate-Protected Metal Nanoparticles: Synthesis, Structure and Catalysis Yifeng Wang and Ira A. Weinstock; 1. Introduction; 2. Synthesis of Polyoxometalate Stabilized Metal(0) Nanoparticles; 2.1. Control over shape and size; 2.2. Ir and Ru nanoparticles by H2 reduction; 2.3. Reactions of metal salts with reduced polyoxometalate anions; 2.3.1. Synthesis of nanoparticles; 2.3.2 Synthesis of complex nanostructures; 2.4. Ligand-exchange reactions; 3. Structures of Inorganic Cluster Anions Stabilized Nanoparticles
3.1. Evidence for the stabilization of metal(0) nanoparticles by polyoxometalates 3.2. Direct imaging of POM-ligand monolayers by cryo-TEM; 3.3. Electric double layer of a polyoxometalate-stabilized nanoparticle; 4. Application of POM-stabilized Au NPs in Catalysis; 4.1. Hydrogenation reactions using POM-stabilized metal NPs; 4.2. Molecular oxygen activation reactions for organic synthesis; 4.3. Other organic reactions catalyzed by polyoxometalate-stabilized metal nanoparticles; 4.4. Electrocatalysis; 5. Closing Comments; References Chapter 2 When Giants Meet Dwarves in the Same Pond - Unique Solution Physical Chemistry Opportunities Offered by Polyoxometalate Macroions Dong Li, Panchao Yin and Tianbo Liu 1. Introduction and Retrospection; 1.1. Derivation of the Debye-Hückel's limiting theory5; 1.2. General features of the DLVO theory; 1.2.1. DLVO potential and the primary and secondary minima; 1.2.2. Limitations of the DLVO theory; 2. Characterization of Macroion Solution Behaviors; 2.1. Polyoxometalates (POMs) type macroanions; 2.1.1. Characterization of the self-assembly of POM macroanions in dilute solutions 2.1.2. The driving forces that responsible for the unexpected self-assembly of macroanions 2.1.2.1. Van der Waals attractions; 2.1.2.2. Hydrogen bonding; 2.1.2.3. Counterions mediated attractions; a) Interactions between discrete macroions and counterions; b) Effect of surface charge density; c) Effect of counterion valence state and counterion hydrated size; d) Effect of ionic strength; 2.1.2.4. Solvent effect; 2.1.3. Kinetics of the blackberry formation; 2.1.3.1. Long equilibrium time; 2.1.3.2. High activation energy; 2.1.3.3. Slow nucleation and fast aggregation 2.2. Self-assembly of macrocations |
| Record Nr. | UNINA-9910824591503321 |
| Hackensack [NJ], : World Scientific, c2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse
| Polyoxometalate chemistry : some recent trends / / editor, Francis Secheresse |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hackensack [NJ], : World Scientific, c2013 |
| Descrizione fisica | 1 online resource (360 pages) |
| Disciplina | 546/.3 |
| Altri autori (Persone) | SecheresseFrancis |
| Collana | World Scientific series in nanoscience and nanotechnology |
| Soggetto topico |
Polyoxometalates
Coordination compounds |
| ISBN |
9789814458986
9814458988 9789814458979 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- CONTENTS -- Preface -- List of Color Plates -- COLOR PLATE 1 -- COLOR PLATE 2 -- COLOR PLATE 3 -- COLOR PLATE 4 -- COLOR PLATE 5 -- COLOR PLATE 6 -- COLOR PLATE 7 -- COLOR PLATE 8 -- COLOR PLATE 9 -- COLOR PLATE 10 -- COLOR PLATE 11 -- COLOR PLATE 12 -- COLOR PLATE 13 -- COLOR PLATE 14 -- COLOR PLATE 15 -- COLOR PLATE 16 -- COLOR PLATE 17 -- COLOR PLATE 18 -- COLOR PLATE 19 -- COLOR PLATE 20 -- COLOR PLATE 21 -- COLOR PLATE 22 -- COLOR PLATE 23 -- COLOR PLATE 24 -- COLOR PLATE 25 -- COLOR PLATE 26 -- COLOR PLATE 27 -- COLOR PLATE 28 -- COLOR PLATE 29 -- COLOR PLATE 30 -- COLOR PLATE 31 -- COLOR PLATE 32 -- COLOR PLATE 33 -- COLOR PLATE 34 -- COLOR PLATE 35 -- COLOR PLATE 36 -- Chapter 1 Polyoxometalate-Protected Metal Nanoparticles: Synthesis, Structure and Catalysis Yifeng Wang and Ira A. Weinstock -- 1. Introduction -- 2. Synthesis of Polyoxometalate Stabilized Metal(0) Nanoparticles -- 2.1. Control over shape and size -- 2.2. Ir and Ru nanoparticles by H2 reduction -- 2.3. Reactions of metal salts with reduced polyoxometalate anions -- 2.3.1. Synthesis of nanoparticles -- 2.3.2 Synthesis of complex nanostructures -- 2.4. Ligand-exchange reactions -- 3. Structures of Inorganic Cluster Anions Stabilized Nanoparticles -- 3.1. Evidence for the stabilization of metal(0) nanoparticles by polyoxometalates -- 3.2. Direct imaging of POM-ligand monolayers by cryo-TEM -- 3.3. Electric double layer of a polyoxometalate-stabilized nanoparticle -- 4. Application of POM-stabilized Au NPs in Catalysis -- 4.1. Hydrogenation reactions using POM-stabilized metal NPs -- 4.2. Molecular oxygen activation reactions for organic synthesis -- 4.3. Other organic reactions catalyzed by polyoxometalate-stabilized metal nanoparticles -- 4.4. Electrocatalysis -- 5. Closing Comments -- References.
Chapter 2 When Giants Meet Dwarves in the Same Pond - Unique Solution Physical Chemistry Opportunities Offered by Polyoxometalate Macroions Dong Li, Panchao Yin and Tianbo Liu -- 1. Introduction and Retrospection -- 1.1. Derivation of the Debye-Hückel's limiting theory5 -- 1.2. General features of the DLVO theory -- 1.2.1. DLVO potential and the primary and secondary minima -- 1.2.2. Limitations of the DLVO theory -- 2. Characterization of Macroion Solution Behaviors -- 2.1. Polyoxometalates (POMs) type macroanions -- 2.1.1. Characterization of the self-assembly of POM macroanions in dilute solutions -- 2.1.2. The driving forces that responsible for the unexpected self-assembly of macroanions -- 2.1.2.1. Van der Waals attractions -- 2.1.2.2. Hydrogen bonding -- 2.1.2.3. Counterions mediated attractions -- a) Interactions between discrete macroions and counterions -- b) Effect of surface charge density -- c) Effect of counterion valence state and counterion hydrated size -- d) Effect of ionic strength -- 2.1.2.4. Solvent effect -- 2.1.3. Kinetics of the blackberry formation -- 2.1.3.1. Long equilibrium time -- 2.1.3.2. High activation energy -- 2.1.3.3. Slow nucleation and fast aggregation -- 2.2. Self-assembly of macrocations -- 3. Connection to Virus Capsid Formation -- 3.1. Trans-membrane transport of counterions over blackberry surface -- 4. Inorganic-Organic Hybrid POMs -- 4.1. The motivation of synthesizing new hybrid POMs -- 4.2. POMs based amphiphilic surfactants and their assemblies -- 4.2.1. Diblock hybrid surfactants -- 4.2.2. Triblock hybrid surfactants -- 4.2.2.1. Organic-inorganic-organic type hybrid surfactants -- 4.2.2.2. Inorganic-organic-inorganic type hybrid surfactants -- 4.2.3. Comparison with blackberries -- 5. Conclusions -- Acknowledgement -- References. Chapter 3 Directed Assembly of Polyoxometalates Across Length Scales: From Macro-Molecules to Microsystems and iChells Antoine G. Boulay, Geoffrey J. T. Cooper and Leroy Cronin -- 1. Building Blocks to Cation Control -- 1.1. Background -- 1.2. Isopolyoxometalates and their derivatives -- 2. Host-Guest Chemistry to Networks -- 2.1. Cage compounds and switchable POMs -- 2.2. POM based architectures and framework materials -- 2.3. Organic-inorganic hybrids POMs -- 3. Extended Architectures Based on Transition Metal Salts/Oxides: Tubes, iChells and Blackberries -- 3.1. Tubular systems: Mechanism of formation -- 3.2. Particular tubes/minimal systems -- 3.3. Growth control -- 3.4. Formation of inorganic-chemical cells: iCHELLs -- 3.5. iCHELL chemistry -- 4. Conclusions -- Acknowledgements -- References -- Chapter 4 Magnetic Polyoxometalates Juan M. Clemente-Juan, Eugenio Coronado and Alejandro Gaita-Ariño -- 1. Introduction -- 2. Spin Clusters -- 3. Single-molecule Magnets -- 4. Mixed-valence Clusters -- 5. Conclusions -- Acknowledgements -- References -- Chapter 5 Magnetism of Keplerates Paul Kögerler -- 1. Introduction -- 2. From Pentagonal Building Blocks to Keplerates -- 3. The {Mo72Fe30} System: From Classical to Quantum Spin Models -- 4. The Quantum-spin Keplerates {Mo72V30} and {Mo72Cr30} -- References -- Chapter 6 Polyoxometalates as Ligands for Functional Lanthanoid Complexes Chris Ritchie and Colette Boskovic -- 1. Introduction -- 2. Synthesis and Structures -- 2.1. Ln-POMs and Ln-org-POMs synthesized in the presence of acetate -- 2.2. Ln-org-POMs synthesized in the presence of glycine -- 2.3. Ln-org-POMs synthesized in the presence of 2-picolinate -- 3. Magnetic Properties -- 4. Luminescence Properties -- 5. Concluding Remarks -- Acknowledgements -- References -- Chapter 7 Polyoxothiometalates POTM Francis Sécheresse and Emmanuel Cadot. 1. Introduction -- 1.1. Thiometalates -- 2. Polyoxothiometalates POTM -- 2.1. The choice of a precursor -- 2.1.1. [Mo2O2S2]2+ a promising precursor -- 2.1.2. [Mo3S4] 4+ a possible building block for the coordination to vacant POMs -- 2.2. Self-condensation of the {Mo2O2S2}2+ precursor -- 2.3. Condensations via inorganic assembling groups -- 2.3.1. Halides as templates -- 2.3.2. Examples of other weak bases acting as templating groups -- 2.3.2.1. Dynamics associated to phosphate template effect -- 2.3.2.2. Rings based on phosphate anions -- 2.4. POTM derived from organic templates -- 2.4.1. Ring design with carboxylate and dicarboxylates -- 2.4.2. Adaptability and stability of host-guest rings -- 2.4.2.1. Example of C6, C7, and C8 based rings -- 2.4.2.2. Intrinsic stability -- 2.4.3. Example of dynamic associated to dicarboxylate templating -- 2.4.4. DOSY NMR methods applied to host-guest rings -- 3. Polyoxothiometalates Derived from the Archetypal Keggin Structure -- 3.1. Functionalization of polyvacant polyoxometalates -- 3.1.1. Example of [γ-SiW10O36]8- -- 3.1.2. Examples of the monovacant Keggin α-[PW11O39]7- and Dawson [P2W17O61]10- -- 3.1.3 Trivacant polyoxometalates as ligands -- 3.1.3.1. Reaction of {M2O2S2} with [A-α-PW9O34]9- -- 3.1.3.2. Reaction of {M2O2S2} with [B-P2W15O56]12- -- 3.1.3.3. Reaction of {M2O2S2} with [A-α-AsW9O33]9- -- 3.1.4. Tetravacant-trivacant POMs conversion induced by {Mo2O2S2} coordination -- 4. [Mo2O2S2(OH2)2}2+ a Building Block Involved in Mo- and W-giant Capsules -- 4.1. Sulfurated Kleperates -- 4.1.1. Sulfates as stabilizing ligands -- 4.1.2. Acetates as stabilizing ligands -- 5. Functionalization of vacant POMS by [Mo3S4(H2O)9]4- -- 5.1. Saturation of a monovacant Dawson POM -- 5.2. Mo3S4 as supramolecular linker -- Conclusion -- References -- Index. |
| Record Nr. | UNINA-9910993973703321 |
| Hackensack [NJ], : World Scientific, c2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Superalloys [[electronic resource] ] : production, properties and applications / / Jeremy E. Watson, editor
| Superalloys [[electronic resource] ] : production, properties and applications / / Jeremy E. Watson, editor |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (178 p.) |
| Disciplina | 546/.3 |
| Altri autori (Persone) | WatsonJeremy E |
| Collana | Materials science and technologies |
| Soggetto topico | Heat resistant alloys |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-62257-035-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910453818503321 |
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Superalloys [[electronic resource] ] : production, properties and applications / / Jeremy E. Watson, editor
| Superalloys [[electronic resource] ] : production, properties and applications / / Jeremy E. Watson, editor |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (178 p.) |
| Disciplina | 546/.3 |
| Altri autori (Persone) | WatsonJeremy E |
| Collana | Materials science and technologies |
| Soggetto topico | Heat resistant alloys |
| ISBN | 1-62257-035-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910779788103321 |
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Superalloys : production, properties and applications / / Jeremy E. Watson, editor
| Superalloys : production, properties and applications / / Jeremy E. Watson, editor |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | New York, : Nova Science Publishers, c2011 |
| Descrizione fisica | 1 online resource (178 p.) |
| Disciplina | 546/.3 |
| Altri autori (Persone) | WatsonJeremy E |
| Collana | Materials science and technologies |
| Soggetto topico | Heat resistant alloys |
| ISBN | 1-62257-035-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- SUPERALLOYS: PRODUCTION, PROPERTIES AND APPLICATIONS -- SUPERALLOYS: PRODUCTION, PROPERTIES AND APPLICATIONS -- CONTENTS -- PREFACE -- EFFECT OF RESIDUAL STRESSES ON CRACK SHAPE OF CORNER CRACKS AT HOLES IN NICKEL BASE SUPERALLOYS -- ABSTRACT -- 1. INTRODUCTION -- 2. NUMERICAL AND EXPERIMENTAL PROCEDURES -- 2.1. Numerical -- 2.2. Experimental Procedure -- 3. PRESENTATION AND ANALYSIS OF RESULTS -- 3.1. Stable Crack Shapes -- 3.2. Crack Propagation Stages -- 3.3. Effect of Residual Stress -- CONCLUSIONS -- ACKNOWLEDGMENT -- REFERENCES -- WROUGHT SUPERALLOYS - SCIENCE, TECHNOLOGY AND APPLICATIONS -- ABSTRACT -- 1. INTRODUCTION -- 2. IRON-BASE SUPERALLOYS -- 3. NICKEL-BASE AND NICKEL-IRON-BASE SUPERALLOYS -- 3.1. Precipitation Strengthening Phases in Ni-Base and Ni-Fe-Base Superalloys -- 3.1.1.Gamma Prime -- 3.1.2.Gamma Double Prime -- 4. COBALT-BASE SUPERALLOYS -- 5. MELTING AND CONSOLIDATION OF WROUGHT SUPERALLOYS -- 5.1. Vacuum Induction Melting -- 5.2. Remelting -- 5.2.1. Electroslag Remelting -- 5.2.2. Vacuum Arc Remelting -- 5.3. Triple Melting -- 5.4. Maximum Ingot Size -- 5.5. Micro Segregation in Ingots -- 5.6. Macro Scale Segregation Defects in Ingots -- 5.7. Homogenisation of Ingots -- 6. HOT WORKING -- 6.1. Hot Working Processes and Equipment -- 6.2. Hot Working Range -- 6.3. Rotary Forging -- 6.4. Isothermal Forging -- 7. HEAT TREATMENT OF WROUGHT SUPERALLOYS -- 8. METALLURGICAL STABILITY OF SUPERALLOYS -- 9. ROLE OF TRACE ELEMENTS -- 10. APPLICATIONS OF WROUGHT SUPERALLOYS -- 10.1. Aerospace Sector -- 10.2. Electric Power Generation -- 10.3. Chemical Process Industries -- CONCLUSION -- ACKNOWLEDGMENT -- REFERENCES -- HIGH-TEMPERATURE OXIDATION BEHAVIOR OF THE NICKEL-BASE SINGLE CRYSTAL SUPERALLOY AND ITS ALUMINIDE DIFFUSION COATING -- ABSTRACT -- 1. INTRODUCTION -- 2. SUPERALLOY DD32 AND ITS COATING PRIOR TO OXIDATION.
3. HIGH-TEMPERATURE OXIDATION BEHAVIOR OF SUPERALLOY DD32 AND ITS COATING -- 3.1. Oxidation Kinetics -- 3.2. Phase Analysis -- 3.3. Surface Morphology after Oxidation -- 3.4. Microstructure after Oxidation -- 3.5. Oxidation Mechanism -- REFERENCES -- LOW CYCLE FATIGUE CHARACTERIZATION OF NICKEL-BASE AERONAUTICAL SUPERALLOYS -- ABSTRACT -- INTRODUCTION -- MATERIALS -- Inconel 718 -- Udimet 720Li -- EXPERIMENTAL PROCEDURE -- INCONEL 718Plus -- Experimental Results -- Structural Analysis -- UDIMET 720 Li -- Experimental Results -- Miscrostructural Analysis -- CONCLUSION -- REFERENCES -- MECHANICAL PROPERTY AND CHARACTERIZATION OF A NICOCRALY TYPE METALLIC BOND COAT USED IN TURBINE BLADE MADE OF AE-437A NI BASE SUPERALLOY -- ABSTRACT -- 1. INTRODUCTION -- 2. EXPERIMENTAL -- 2.1. Generation of TBCs -- 2.2. Metallography -- 2.3. Measurement of Residual Stress -- 2.4. Hardness Measurement on Bond Coat -- 2.5. Tensile Test -- 2.6. Shear Test -- 3. FINITE ELEMENT ANALYSIS -- 4. RESULTS AND DISCUSSION -- CONCLUSION -- ACKNOWLEDGMENT -- REFERENCES -- CONTROL OF MICROSTRUCTURES BY HEAT TREATMENTS AND HIGH-TEMPERATURE PROPERTIES IN HIGH-TUNGSTEN COBALT-BASE SUPERALLOYS* -- ABSTRACT -- INTRODUCTION -- EXPERIMENTAL PROCEDURE -- RESULTS AND DISCUSSION -- Effects of Tungsten Content on Creep-rupture Properties at 1089 K -- Effects of Tungsten Content on Creep-rupture Properties at 1311 K -- CONCLUSIONS -- ACKNOWLEDGMENTS -- REFERENCES -- DEVELOPMENT, PROPERTIES, APPLICATIONS AND MACHINABILITY OF SUPERALLOY INCONEL# -- ABSTRACT -- 1. INTRODUCTION -- 2. DEVELOPMENT AND PROPERTIES OF NI-BASED ALLOYS -- 2.1. Wrought Ni-Based Alloys -- 2.2. Cast Ni-Based Alloys -- 2.3. Alloying Elements and Microstructures of Ni-Based Alloys -- 2.3.1. Effect of Alloying Elements on Ni-Based Alloys -- 2.3.2. Microstructures of Nickel-Based Alloys. 2.4. Strengthening and Heat Treatment of Nickel-Based Alloys -- 2.4.1. Strengthening of Ni-Based Alloys -- 2.4.2. Heat Treatment of Ni-Based Alloys -- 3. APPLICATIONS OF NI-BASED ALLOYS -- 4. MACHINABILITY STUDY OF NI-BASED HIGH TEMPERATURE ALLOYS -- 4.1. Conventional Turning of Ni-Based Htas -- 4.2. Conventional Milling of Ni-Based HTAs -- 4.3. High Speed Machining of Ni-Based Htas -- 4.3.1. High Speed Turning of Ni-Based Htas -- 4.3.2. High Speed Milling of Ni-Based Htas -- 4.4. Hybrid Machining of Ni-Based HTAs -- 4.5. Ultrasonic Vibration Cutting Ni-Based HTAs -- 4.5.1. Cutting Principle -- 4.5.2. Experimental Findings with the CUVC Method -- 4.5.2.1. Tool Wear vs. Cutting Time -- 4.5.2.2. Curface Roughness vs. Cutting Speed -- CONCLUSIONS -- ACKNOWLEDGMENTS -- REFERENCES -- INDEX. |
| Record Nr. | UNINA-9910962138303321 |
| New York, : Nova Science Publishers, c2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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