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Magnetic resonance in chemistry
| Magnetic resonance in chemistry |
| Pubbl/distr/stampa | Chichester, : Wiley Heyden |
| Disciplina | 543/.0877 |
| ISSN | 0749-1581 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Periodico |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-990009001310403321 |
| Chichester, : Wiley Heyden | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
NMR spectroscopy : processing strategies / / Peter Bigler
| NMR spectroscopy : processing strategies / / Peter Bigler |
| Autore | Bigler Peter |
| Edizione | [2nd updated ed.] |
| Pubbl/distr/stampa | Weinheim ; ; New York, : Wiley-VCH, c2000 |
| Descrizione fisica | 1 online resource (273 p.) |
| Disciplina | 543/.0877 |
| Collana | Spectroscopic techniques : an interactive course |
| Soggetto topico |
Nuclear magnetic resonance spectroscopy - Data processing
Chemistry |
| ISBN |
1-281-76414-0
9786611764142 3-527-61342-0 3-527-61343-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Spectroscopic Techniques: An Interactive Course; Table of Contents; 1 Introduction; 1.1 Scope and Audience; 1.2 Organisation; 1.3 Personal Qualifications; 1.4 Content; 1.5 Recommended Reading; 2 Your Personal "PC-NMR -Processing Station"; 2.1 Introduction; 2.2 Technical Requirements; 2.3 Software Tools; 2.3.1 General; 2.3.2 Installation of 1D WIN-NMR, 2D WIN-NMR and GETFILE; 2.3.3 Starting GETFILE, 1D WIN-NMR and 2D WIN-NMR; 2.4 Software- and Hardwareproblems; 2.5 NMR Data; 2.5.1 Samples; 2.5.2 Experiments; 2.5.3 Experimental Conditions; 2.5.4 Directory Structure
2.5.5 Copying the NMR Data from the CD to your Hard Disk2.5.6 Useful Options in the MS WINDOWS 95 Operating System; 2.6 Data Formats; 2.6.1 WINNMR Format; 2.6.2 UXNMR/XWINNMR Format; 2.6.3 DISNMR Format; 2.6.4 NMR Data Formats of other Manufacturers: Varian, JEOL, GE; 2.6.5 Other Formats: ASCII, JCAMP-DX; 2.7 Data Import and Export; 2.7.1 Network-Example; 2.7.2 Transfer and Conversion of NMR Data stored on Remote Computers; 2.7.2.1 UXNMR/XWINNMR-Format; 2.7.2.2 DISNMR-Format; 2.7.3 Decomposition of 2D Data Files; 2.8 References 3 Modern Homo- and Heteronuclear 1D and 2D NMR Experiments: A Short Overview3.1 Introduction; 3.2 The NMR Experiment; 3.3 1D Experiments; 3.3.1 1H Experiments; 3.3.1.1 1H One Pulse Experiment; 3.3.1.2 1H {1H} Selective Decoupling Experiment [3.1]; 3.3.1.3 1H {1H} Total Correlation Spectroscopy (TOCSY) Experiment [3.2]; 3.3.1.4 1H {1H} Nuclear Overhauser (NOE) Experiment [3.3]; 3.3.1.5 1H {1 H} Nuclear Overhauser Experiment in the Rotating Frame (ROE) [3.4]; 3.3.2 13C Experiments; 3.3.2.1 13C One-Pulse Experiment; 3.3.2.2 13C DEPT Experiment [3.5]; 3.3.2.3 13C JMOD (APT) Experiment [3.6,3.7] 3.3.2.4 13C T1 Inversion-Recovery Experiment [3.8,3.9]3.4 2D Experiments; 3.4.1 1H/1H Experiments [3.10,3.11]; 3.4.1.1 1H/1H COSY Experiment [3.10,3.11]; 3.4.1.2 1H/1H TOCSY Experiment [3.12,3.13]; 3.4.1.3 1H/1H NOESY and 1H/1H ROESY Experiments [3.14,3.15]; 3.4.1.4 1H/1H J -Resolved Spectroscopy Experiment [3.16]; 3.4.2 1H/13C Experiments; 3.4.2.1 1H/13C Shift Correlation Spectroscopy via 1JCH[3.17- 3.21]; 3.4.2.2 1H/13C Shift Correlation Spectroscopy via nJCH[3.22]; 3.4.2.3 1H/13C Shift Correlation Spectroscopy via 1JCH and 1H/1H TOCSY Transfer [3.23]; 3.5 Recommended Reading 4 How to Display and Plot 1D and 2D NMR Spectra4.1 Introduction; 4.2 Help Routines; 4.3 Application Windows for 1D WIN-NMR and 2D WIN-NMR; 4.4 File Handling; 4.5 Display of 1D Spectra with 1D WIN-NMR; 4.5.1 Buttons with 1D WIN-NMR [Spectrum]; 4.5.2 Additional Display Options with 1D WIN-NMR; 4.5.3 The Use of Scroll Bars, Keys and Function Keys with 1D WIN-NMR; 4.6 Basic Processing Steps with 1D Spectra; 4.6.1 Cali bration; 4.6.2 Peak Picking; 4.6.3 Integration; 4.6.4 Simple Spectral Analysis; 4.7 Plotting 1D Spectra; 4.7.1 Define Plot; 4.7.2 Page Layout 4.7.2.1 Page Layout Dialog Box in Normal 1D Display Mode |
| Record Nr. | UNINA-9910876687103321 |
Bigler Peter
|
||
| Weinheim ; ; New York, : Wiley-VCH, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
NMR spectroscopy : processing strategies
| NMR spectroscopy : processing strategies |
| Autore | Bigler Peter |
| Pubbl/distr/stampa | [Place of publication not identified], : VCH, 1997 |
| Disciplina | 543/.0877 |
| Collana | Spectroscopic techniques NMR spectroscopy |
| Soggetto topico |
Nuclear magnetic resonance spectroscopy - Data processing
Analytical Chemistry Chemistry Physical Sciences & Mathematics |
| ISBN | 3-527-61917-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNISA-996197426603316 |
|
Bigler Peter
|
||
| [Place of publication not identified], : VCH, 1997 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
On-line LC-NMR and related techniques [[electronic resource] /] / edited by Klaus Albert
| On-line LC-NMR and related techniques [[electronic resource] /] / edited by Klaus Albert |
| Pubbl/distr/stampa | New York, : J. Wiley & Sons, c2002 |
| Descrizione fisica | 1 online resource (308 p.) |
| Disciplina |
543.089
543/.0877 |
| Altri autori (Persone) | AlbertKlaus |
| Soggetto topico |
Nuclear magnetic resonance spectroscopy
Liquid chromatography |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-27011-X
9786610270118 0-470-31452-4 0-470-85481-2 0-470-85482-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
On-Line LC-NMR and Related Techniques; Contents; Contributors; Preface; 1 LC-NMR: Theory and Experiment; 1.1 Introduction; 1.2 NMR in a Flowing Liquid; 1.3 Design of Continuous-Flow NMR Probes; 1.4 Experimental Arrangement for HPLC-(1)H NMR Coupling; 1.5 Practical Considerations, Solvent Suppression Techniques, Gradient Elution and Purity of HPLC Solvents; 1.5.1 Solvent Signal Suppression; 1.5.2 Purity of HPLC-Grade Solvents; References; 2 LC-NMR: Automation; 2.1 Practical Use of LC-NMR and LC-NMR/MS; 2.2 Different Working Modes in LC-NMR; 2.2.1 On-Flow; 2.2.2 Direct Stop-Flow
2.2.3 Loop Storage/Loop Transfer2.2.4 Conclusions; 2.3 Use of Mass Spectrometry in the Set-Up; 2.4 Measurement Procedures; 2.4.1 Sample Preparation and Introduction ('Injection') into the Chromatography System; 2.4.2 Chromatographic Separation; 2.4.3 Peak Detection and Selection; 2.4.4 Mass Spectrometric Measurements; 2.4.5 Nuclear Magnetic Resonance Measurements; 2.4.6 Sample Recovery; 2.5 Conclusions; References; 3 Biomedical and Pharmaceutical Applications of HPLC-NMR and HPLC-NMR-MS; 3.1 Introduction; 3.2 Technical and Operational Overview; 3.3 Applications in Combinatorial Chemistry 3.4 Application to Chemical Impurities3.5 Application to Chiral Separations of Pharmaceutical Mixtures; 3.6 Application to Natural Products; 3.7 Application to Chemical Reactivity of Drug Glucuronides; 3.8 Application to Futile Deacetylation Reactions; 3.9 Application to Trapping of Reactive Intermediates; 3.10 Application to Uptake and Transformation of Xenobiotics by Plants; 3.11 Separation of Lipoproteins and their Characterisation using HPLC-NMR; 3.12 Superheated-Water HPLC-NMR and HPLC-NMR-MS Studies on Pharmaceuticals 3.13 Application of Hypernation to a Mixture of Non-Steroidal Anti-Inflammatory Drugs3.14 Concluding Remarks; References; 4 Application of On-Line LC-NMR and Related Techniques to Drug Metabolism Studies; 4.1 Introduction; 4.2 LC-NMR Techniques; 4.2.1 Continuous-Flow LC-NMR; 4.2.2 Time-Slice LC-NMR; 4.2.3 Stop-Flow LC-NMR; 4.2.4 Loop-Storage; 4.2.5 LC-NMR-MS; 4.3 Application of LC-NMR-MS to Drug Metabolism: The Structure Elucidation of Rat Urinary Metabolites of Efavirenz by LC-NMR-MS; 4.3.1 Experimental; 4.3.2 Results; 4.4 Conclusions; References; 5 LC-NMR for Natural Products Analysis 5.1 Application of LC-NMR and LC-NMR-MS Hyphenation to Natural Products Analysis5.1.1 Introduction; 5.1.1.1 General Aspects; 5.1.1.2 Applications; 5.1.2 Application of LC-NMR-MS to Glycosidic Natural Products of Marine Origin; 5.1.2.1 Introduction - Need for LC-NMR; 5.1.2.2 Methodology: On-Flow LC-NMR-MS Screening; 5.1.2.3 NMR - Structural Information; 5.1.2.4 Mass Spectrometry and D-H Back-Exchange Experiments; 5.1.2.5 Stop-Flow Experiments; 5.1.2.6 Complimentary Structural Information of NMR and MS; 5.1.2.7 Conclusions; 5.1.3 Acknowledgements; References 5.2 Hyphenation of Modern Extraction Techniques to LC-NMR for the Analysis of Geometrical Carotenoid Isomers in Functional Food and Biological Tissues |
| Record Nr. | UNINA-9910142493503321 |
| New York, : J. Wiley & Sons, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
On-line LC-NMR and related techniques [[electronic resource] /] / edited by Klaus Albert
| On-line LC-NMR and related techniques [[electronic resource] /] / edited by Klaus Albert |
| Pubbl/distr/stampa | New York, : J. Wiley & Sons, c2002 |
| Descrizione fisica | 1 online resource (308 p.) |
| Disciplina |
543.089
543/.0877 |
| Altri autori (Persone) | AlbertKlaus |
| Soggetto topico |
Nuclear magnetic resonance spectroscopy
Liquid chromatography |
| ISBN |
1-280-27011-X
9786610270118 0-470-31452-4 0-470-85481-2 0-470-85482-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
On-Line LC-NMR and Related Techniques; Contents; Contributors; Preface; 1 LC-NMR: Theory and Experiment; 1.1 Introduction; 1.2 NMR in a Flowing Liquid; 1.3 Design of Continuous-Flow NMR Probes; 1.4 Experimental Arrangement for HPLC-(1)H NMR Coupling; 1.5 Practical Considerations, Solvent Suppression Techniques, Gradient Elution and Purity of HPLC Solvents; 1.5.1 Solvent Signal Suppression; 1.5.2 Purity of HPLC-Grade Solvents; References; 2 LC-NMR: Automation; 2.1 Practical Use of LC-NMR and LC-NMR/MS; 2.2 Different Working Modes in LC-NMR; 2.2.1 On-Flow; 2.2.2 Direct Stop-Flow
2.2.3 Loop Storage/Loop Transfer2.2.4 Conclusions; 2.3 Use of Mass Spectrometry in the Set-Up; 2.4 Measurement Procedures; 2.4.1 Sample Preparation and Introduction ('Injection') into the Chromatography System; 2.4.2 Chromatographic Separation; 2.4.3 Peak Detection and Selection; 2.4.4 Mass Spectrometric Measurements; 2.4.5 Nuclear Magnetic Resonance Measurements; 2.4.6 Sample Recovery; 2.5 Conclusions; References; 3 Biomedical and Pharmaceutical Applications of HPLC-NMR and HPLC-NMR-MS; 3.1 Introduction; 3.2 Technical and Operational Overview; 3.3 Applications in Combinatorial Chemistry 3.4 Application to Chemical Impurities3.5 Application to Chiral Separations of Pharmaceutical Mixtures; 3.6 Application to Natural Products; 3.7 Application to Chemical Reactivity of Drug Glucuronides; 3.8 Application to Futile Deacetylation Reactions; 3.9 Application to Trapping of Reactive Intermediates; 3.10 Application to Uptake and Transformation of Xenobiotics by Plants; 3.11 Separation of Lipoproteins and their Characterisation using HPLC-NMR; 3.12 Superheated-Water HPLC-NMR and HPLC-NMR-MS Studies on Pharmaceuticals 3.13 Application of Hypernation to a Mixture of Non-Steroidal Anti-Inflammatory Drugs3.14 Concluding Remarks; References; 4 Application of On-Line LC-NMR and Related Techniques to Drug Metabolism Studies; 4.1 Introduction; 4.2 LC-NMR Techniques; 4.2.1 Continuous-Flow LC-NMR; 4.2.2 Time-Slice LC-NMR; 4.2.3 Stop-Flow LC-NMR; 4.2.4 Loop-Storage; 4.2.5 LC-NMR-MS; 4.3 Application of LC-NMR-MS to Drug Metabolism: The Structure Elucidation of Rat Urinary Metabolites of Efavirenz by LC-NMR-MS; 4.3.1 Experimental; 4.3.2 Results; 4.4 Conclusions; References; 5 LC-NMR for Natural Products Analysis 5.1 Application of LC-NMR and LC-NMR-MS Hyphenation to Natural Products Analysis5.1.1 Introduction; 5.1.1.1 General Aspects; 5.1.1.2 Applications; 5.1.2 Application of LC-NMR-MS to Glycosidic Natural Products of Marine Origin; 5.1.2.1 Introduction - Need for LC-NMR; 5.1.2.2 Methodology: On-Flow LC-NMR-MS Screening; 5.1.2.3 NMR - Structural Information; 5.1.2.4 Mass Spectrometry and D-H Back-Exchange Experiments; 5.1.2.5 Stop-Flow Experiments; 5.1.2.6 Complimentary Structural Information of NMR and MS; 5.1.2.7 Conclusions; 5.1.3 Acknowledgements; References 5.2 Hyphenation of Modern Extraction Techniques to LC-NMR for the Analysis of Geometrical Carotenoid Isomers in Functional Food and Biological Tissues |
| Record Nr. | UNINA-9910830799103321 |
| New York, : J. Wiley & Sons, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
On-line LC-NMR and related techniques / / edited by Klaus Albert
| On-line LC-NMR and related techniques / / edited by Klaus Albert |
| Pubbl/distr/stampa | New York, : J. Wiley & Sons, c2002 |
| Descrizione fisica | 1 online resource (308 p.) |
| Disciplina |
543.089
543/.0877 |
| Altri autori (Persone) | AlbertKlaus |
| Soggetto topico |
Nuclear magnetic resonance spectroscopy
Liquid chromatography |
| ISBN |
1-280-27011-X
9786610270118 0-470-31452-4 0-470-85481-2 0-470-85482-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
On-Line LC-NMR and Related Techniques; Contents; Contributors; Preface; 1 LC-NMR: Theory and Experiment; 1.1 Introduction; 1.2 NMR in a Flowing Liquid; 1.3 Design of Continuous-Flow NMR Probes; 1.4 Experimental Arrangement for HPLC-(1)H NMR Coupling; 1.5 Practical Considerations, Solvent Suppression Techniques, Gradient Elution and Purity of HPLC Solvents; 1.5.1 Solvent Signal Suppression; 1.5.2 Purity of HPLC-Grade Solvents; References; 2 LC-NMR: Automation; 2.1 Practical Use of LC-NMR and LC-NMR/MS; 2.2 Different Working Modes in LC-NMR; 2.2.1 On-Flow; 2.2.2 Direct Stop-Flow
2.2.3 Loop Storage/Loop Transfer2.2.4 Conclusions; 2.3 Use of Mass Spectrometry in the Set-Up; 2.4 Measurement Procedures; 2.4.1 Sample Preparation and Introduction ('Injection') into the Chromatography System; 2.4.2 Chromatographic Separation; 2.4.3 Peak Detection and Selection; 2.4.4 Mass Spectrometric Measurements; 2.4.5 Nuclear Magnetic Resonance Measurements; 2.4.6 Sample Recovery; 2.5 Conclusions; References; 3 Biomedical and Pharmaceutical Applications of HPLC-NMR and HPLC-NMR-MS; 3.1 Introduction; 3.2 Technical and Operational Overview; 3.3 Applications in Combinatorial Chemistry 3.4 Application to Chemical Impurities3.5 Application to Chiral Separations of Pharmaceutical Mixtures; 3.6 Application to Natural Products; 3.7 Application to Chemical Reactivity of Drug Glucuronides; 3.8 Application to Futile Deacetylation Reactions; 3.9 Application to Trapping of Reactive Intermediates; 3.10 Application to Uptake and Transformation of Xenobiotics by Plants; 3.11 Separation of Lipoproteins and their Characterisation using HPLC-NMR; 3.12 Superheated-Water HPLC-NMR and HPLC-NMR-MS Studies on Pharmaceuticals 3.13 Application of Hypernation to a Mixture of Non-Steroidal Anti-Inflammatory Drugs3.14 Concluding Remarks; References; 4 Application of On-Line LC-NMR and Related Techniques to Drug Metabolism Studies; 4.1 Introduction; 4.2 LC-NMR Techniques; 4.2.1 Continuous-Flow LC-NMR; 4.2.2 Time-Slice LC-NMR; 4.2.3 Stop-Flow LC-NMR; 4.2.4 Loop-Storage; 4.2.5 LC-NMR-MS; 4.3 Application of LC-NMR-MS to Drug Metabolism: The Structure Elucidation of Rat Urinary Metabolites of Efavirenz by LC-NMR-MS; 4.3.1 Experimental; 4.3.2 Results; 4.4 Conclusions; References; 5 LC-NMR for Natural Products Analysis 5.1 Application of LC-NMR and LC-NMR-MS Hyphenation to Natural Products Analysis5.1.1 Introduction; 5.1.1.1 General Aspects; 5.1.1.2 Applications; 5.1.2 Application of LC-NMR-MS to Glycosidic Natural Products of Marine Origin; 5.1.2.1 Introduction - Need for LC-NMR; 5.1.2.2 Methodology: On-Flow LC-NMR-MS Screening; 5.1.2.3 NMR - Structural Information; 5.1.2.4 Mass Spectrometry and D-H Back-Exchange Experiments; 5.1.2.5 Stop-Flow Experiments; 5.1.2.6 Complimentary Structural Information of NMR and MS; 5.1.2.7 Conclusions; 5.1.3 Acknowledgements; References 5.2 Hyphenation of Modern Extraction Techniques to LC-NMR for the Analysis of Geometrical Carotenoid Isomers in Functional Food and Biological Tissues |
| Record Nr. | UNINA-9910877424703321 |
| New York, : J. Wiley & Sons, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Solid-state NMR spectroscopy : principles and applications / / edited by Melinda J. Duer
| Solid-state NMR spectroscopy : principles and applications / / edited by Melinda J. Duer |
| Pubbl/distr/stampa | Oxford : , : Blackwell Science, , [2002] |
| Descrizione fisica | 1 online resource (562 pages) |
| Disciplina |
543.0877
543/.0877 |
| Altri autori (Persone) | DuerMelinda J |
| Soggetto topico |
Nuclear magnetic resonance spectroscopy
Solid state chemistry |
| ISBN |
1-281-31276-2
9786611312763 0-470-99939-X 0-470-99938-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Solid-State NMR Spectroscopy Principles and Applications; List of Contributors; Contents; Index; Preface; Acknowledgements; Part I The Theory of Solid-State NMR and its Experiments; 1 The Basics of Solid-State NMR; 1.1 The vector model of pulsed NMR; 1.1.1 Nuclei in a static, uniform magnetic field; 1.1.2 The effect of rf pulses; 1.2 The quantum mechanical picture: hamiltonians and the Schrödinger equation; Box 1.1 Quantum mechanics and NMR; 1.2.1 Nuclei in a static, uniform field; 1.2.2 The effect of rf pulses; Box 1.2 Exponential operators, rotation operators and rotations
1.3 The density matrix representation and coherences1.3.1 Coherences and populations; 1.3.2 The density operator at thermal equilibrium; 1.3.3 Time evolution of the density matrix; 1.4 Nuclear spin interactions; 1.4.1 The chemical shift and chemical shift anisotropy; 1.4.2 Dipole-dipole coupling; Box 1.3 Basis sets for multispin systems; 1.4.3 Quadrupolar coupling; 1.5 Calculating NMR powder patterns; 1.6 General features of NMR experiments; 1.6.1 Multidimensional NMR; 1.6.2 Phase cycling; 1.6.3 Quadrature detection; Box 1.4 The NMR spectrometer; References 2 Essential Techniques for Spin-1/2 Nuclei2.1 Introduction; 2.2 Magic-angle spinning (MAS); 2.2.1 Spinning sidebands; 2.2.2 Rotor or rotational echoes; 2.2.3 Removing spinning sidebands; 2.2.4 Magic-angle spinning for homonuclear dipolar couplings; 2.3 High-power decoupling; 2.4 Multiple pulse decoupling sequences; Box 2.1 Average hamiltonian theory and the toggling frame; 2.5 Cross-polarization; 2.5.1 Theory; 2.5.2 Experimental details; Box 2.2 Cross-polarization and magic-angle spinning; 2.6 Solid or quadrupole echo pulse sequence; References; 3 Dipolar Coupling: Its Measurement and Uses 3.1 IntroductionBox 3.1 The dipolar hamiltonian in terms of spherical tensor operators; 3.2 Techniques for measuring homonuclear dipolar couplings; 3.2.1 Recoupling pulse sequences; Box 3.2 Analysis of the DRAMA pulse sequence; 3.2.2 Double-quantum filtered experiments; 3.2.3 Rotational resonance; Box 3.3 Excitation of double-quantum coherence under magic-angle spinning; 3.3 Techniques for measuring heteronuclear dipolar couplings; Box 3.4 Analysis of the C7 pulse sequence for exciting double-quantum coherence in dipolar-coupled spin pairs; 3.3.1 Spin-echo double resonance Box 3.5 Theory of rotational resonance3.3.2 Rotational-echo double resonance; Box 3.6 Analysis of the REDOR experiment; 3.4 Techniques for dipolar-coupled quadrupolar (spin-1/2) pairs; 3.4.1 Transfer of population in double resonance; 3.4.2 Rotational echo, adiabatic passage, double resonance; 3.5 Techniques for measuring dipolar couplings between quadrupolar nuclei; 3.6 Correlation experiments; 3.6.1 Homonuclear correlation experiments for spin-systems; 3.6.2 Homonuclear correlation experiments for quadrupolar spin systems; 3.6.3 Heteronuclear correlation experiments for spin-1/2 3.7 Spin-counting experiments |
| Record Nr. | UNINA-9910145741203321 |
| Oxford : , : Blackwell Science, , [2002] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Solid-state NMR spectroscopy : principles and applications / / edited by Melinda J. Duer
| Solid-state NMR spectroscopy : principles and applications / / edited by Melinda J. Duer |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Oxford : , : Blackwell Science, , [2002] |
| Descrizione fisica | 1 online resource (562 pages) |
| Disciplina |
543.0877
543/.0877 |
| Altri autori (Persone) | DuerMelinda J |
| Soggetto topico |
Nuclear magnetic resonance spectroscopy
Solid state chemistry |
| ISBN |
1-281-31276-2
9786611312763 0-470-99939-X 0-470-99938-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Solid-State NMR Spectroscopy Principles and Applications; List of Contributors; Contents; Index; Preface; Acknowledgements; Part I The Theory of Solid-State NMR and its Experiments; 1 The Basics of Solid-State NMR; 1.1 The vector model of pulsed NMR; 1.1.1 Nuclei in a static, uniform magnetic field; 1.1.2 The effect of rf pulses; 1.2 The quantum mechanical picture: hamiltonians and the Schrödinger equation; Box 1.1 Quantum mechanics and NMR; 1.2.1 Nuclei in a static, uniform field; 1.2.2 The effect of rf pulses; Box 1.2 Exponential operators, rotation operators and rotations
1.3 The density matrix representation and coherences1.3.1 Coherences and populations; 1.3.2 The density operator at thermal equilibrium; 1.3.3 Time evolution of the density matrix; 1.4 Nuclear spin interactions; 1.4.1 The chemical shift and chemical shift anisotropy; 1.4.2 Dipole-dipole coupling; Box 1.3 Basis sets for multispin systems; 1.4.3 Quadrupolar coupling; 1.5 Calculating NMR powder patterns; 1.6 General features of NMR experiments; 1.6.1 Multidimensional NMR; 1.6.2 Phase cycling; 1.6.3 Quadrature detection; Box 1.4 The NMR spectrometer; References 2 Essential Techniques for Spin-1/2 Nuclei2.1 Introduction; 2.2 Magic-angle spinning (MAS); 2.2.1 Spinning sidebands; 2.2.2 Rotor or rotational echoes; 2.2.3 Removing spinning sidebands; 2.2.4 Magic-angle spinning for homonuclear dipolar couplings; 2.3 High-power decoupling; 2.4 Multiple pulse decoupling sequences; Box 2.1 Average hamiltonian theory and the toggling frame; 2.5 Cross-polarization; 2.5.1 Theory; 2.5.2 Experimental details; Box 2.2 Cross-polarization and magic-angle spinning; 2.6 Solid or quadrupole echo pulse sequence; References; 3 Dipolar Coupling: Its Measurement and Uses 3.1 IntroductionBox 3.1 The dipolar hamiltonian in terms of spherical tensor operators; 3.2 Techniques for measuring homonuclear dipolar couplings; 3.2.1 Recoupling pulse sequences; Box 3.2 Analysis of the DRAMA pulse sequence; 3.2.2 Double-quantum filtered experiments; 3.2.3 Rotational resonance; Box 3.3 Excitation of double-quantum coherence under magic-angle spinning; 3.3 Techniques for measuring heteronuclear dipolar couplings; Box 3.4 Analysis of the C7 pulse sequence for exciting double-quantum coherence in dipolar-coupled spin pairs; 3.3.1 Spin-echo double resonance Box 3.5 Theory of rotational resonance3.3.2 Rotational-echo double resonance; Box 3.6 Analysis of the REDOR experiment; 3.4 Techniques for dipolar-coupled quadrupolar (spin-1/2) pairs; 3.4.1 Transfer of population in double resonance; 3.4.2 Rotational echo, adiabatic passage, double resonance; 3.5 Techniques for measuring dipolar couplings between quadrupolar nuclei; 3.6 Correlation experiments; 3.6.1 Homonuclear correlation experiments for spin-systems; 3.6.2 Homonuclear correlation experiments for quadrupolar spin systems; 3.6.3 Heteronuclear correlation experiments for spin-1/2 3.7 Spin-counting experiments |
| Record Nr. | UNISA-996202095403316 |
| Oxford : , : Blackwell Science, , [2002] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Solid-state NMR spectroscopy : principles and applications / / edited by Melinda J. Duer
| Solid-state NMR spectroscopy : principles and applications / / edited by Melinda J. Duer |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Oxford ; ; Malden, MA, : Blackwell Science, 2002 |
| Descrizione fisica | 1 online resource (562 pages) |
| Disciplina |
543.0877
543/.0877 |
| Altri autori (Persone) | DuerMelinda J |
| Soggetto topico |
Nuclear magnetic resonance spectroscopy
Solid state chemistry |
| ISBN |
1-281-31276-2
9786611312763 0-470-99939-X 0-470-99938-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Solid-State NMR Spectroscopy Principles and Applications; List of Contributors; Contents; Index; Preface; Acknowledgements; Part I The Theory of Solid-State NMR and its Experiments; 1 The Basics of Solid-State NMR; 1.1 The vector model of pulsed NMR; 1.1.1 Nuclei in a static, uniform magnetic field; 1.1.2 The effect of rf pulses; 1.2 The quantum mechanical picture: hamiltonians and the Schrödinger equation; Box 1.1 Quantum mechanics and NMR; 1.2.1 Nuclei in a static, uniform field; 1.2.2 The effect of rf pulses; Box 1.2 Exponential operators, rotation operators and rotations
1.3 The density matrix representation and coherences1.3.1 Coherences and populations; 1.3.2 The density operator at thermal equilibrium; 1.3.3 Time evolution of the density matrix; 1.4 Nuclear spin interactions; 1.4.1 The chemical shift and chemical shift anisotropy; 1.4.2 Dipole-dipole coupling; Box 1.3 Basis sets for multispin systems; 1.4.3 Quadrupolar coupling; 1.5 Calculating NMR powder patterns; 1.6 General features of NMR experiments; 1.6.1 Multidimensional NMR; 1.6.2 Phase cycling; 1.6.3 Quadrature detection; Box 1.4 The NMR spectrometer; References 2 Essential Techniques for Spin-1/2 Nuclei2.1 Introduction; 2.2 Magic-angle spinning (MAS); 2.2.1 Spinning sidebands; 2.2.2 Rotor or rotational echoes; 2.2.3 Removing spinning sidebands; 2.2.4 Magic-angle spinning for homonuclear dipolar couplings; 2.3 High-power decoupling; 2.4 Multiple pulse decoupling sequences; Box 2.1 Average hamiltonian theory and the toggling frame; 2.5 Cross-polarization; 2.5.1 Theory; 2.5.2 Experimental details; Box 2.2 Cross-polarization and magic-angle spinning; 2.6 Solid or quadrupole echo pulse sequence; References; 3 Dipolar Coupling: Its Measurement and Uses 3.1 IntroductionBox 3.1 The dipolar hamiltonian in terms of spherical tensor operators; 3.2 Techniques for measuring homonuclear dipolar couplings; 3.2.1 Recoupling pulse sequences; Box 3.2 Analysis of the DRAMA pulse sequence; 3.2.2 Double-quantum filtered experiments; 3.2.3 Rotational resonance; Box 3.3 Excitation of double-quantum coherence under magic-angle spinning; 3.3 Techniques for measuring heteronuclear dipolar couplings; Box 3.4 Analysis of the C7 pulse sequence for exciting double-quantum coherence in dipolar-coupled spin pairs; 3.3.1 Spin-echo double resonance Box 3.5 Theory of rotational resonance3.3.2 Rotational-echo double resonance; Box 3.6 Analysis of the REDOR experiment; 3.4 Techniques for dipolar-coupled quadrupolar (spin-1/2) pairs; 3.4.1 Transfer of population in double resonance; 3.4.2 Rotational echo, adiabatic passage, double resonance; 3.5 Techniques for measuring dipolar couplings between quadrupolar nuclei; 3.6 Correlation experiments; 3.6.1 Homonuclear correlation experiments for spin-systems; 3.6.2 Homonuclear correlation experiments for quadrupolar spin systems; 3.6.3 Heteronuclear correlation experiments for spin-1/2 3.7 Spin-counting experiments |
| Record Nr. | UNINA-9910815642603321 |
| Oxford ; ; Malden, MA, : Blackwell Science, 2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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