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Catalytic oxidations with hydrogen peroxide as oxidant / edited by Giorgio Strukul
Catalytic oxidations with hydrogen peroxide as oxidant / edited by Giorgio Strukul
Pubbl/distr/stampa Boston ; Dordrecht ; London : Kluwer Academic, c1992
Descrizione fisica IX, 283 p. : ill. ; 24 cm
Disciplina 541.393
Collana Catalysis by metal complexes
ISBN 0-7923-1771-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-990000368330403321
Boston ; Dordrecht ; London : Kluwer Academic, c1992
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Electron transfer in chemistry and biology : an introduction to the theory / Alexander M. Kuznetsov, Jens Ulstrup
Electron transfer in chemistry and biology : an introduction to the theory / Alexander M. Kuznetsov, Jens Ulstrup
Autore Kuznetsov, Alexander M.
Pubbl/distr/stampa Chichester [etc.] : Wiley, c1999
Descrizione fisica XVI, 357 p. : ill. ; 26 cm
Disciplina 541.393
Altri autori (Persone) Ulstrup, Jensauthor
Collana Wiley series in theoretical chemistry
Soggetto topico Reazioni chimiche
ISBN 0471967491
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNISALENTO-991002350949707536
Kuznetsov, Alexander M.  
Chichester [etc.] : Wiley, c1999
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Functional Molecular Silicon Compounds I : Regular Oxidation States / / edited by David Scheschkewitz
Functional Molecular Silicon Compounds I : Regular Oxidation States / / edited by David Scheschkewitz
Edizione [1st ed. 2014.]
Pubbl/distr/stampa Cham : , : Springer International Publishing : , : Imprint : Springer, , 2014
Descrizione fisica 1 online resource (IX, 233 p.)
Disciplina 541.393
Collana Structure and Bonding
Soggetto topico Inorganic chemistry
Organic chemistry
Pharmaceutical technology
Inorganic Chemistry
Organic Chemistry
Pharmaceutical Sciences/Technology
ISBN 3-319-03620-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Silsesquioxanes -- Penta- and Hexacoordinate Molecular Silanes -- Molecular Silicon Clusters -- Multiple bonds with Silicon -- Silylenes -- Silylenium Cations -- Silyl Anions -- Oligosilanes -- Silicon Pharmaceuticals -- NHC-stabilized low valent silicon compounds.
Record Nr. UNINA-9910298636803321
Cham : , : Springer International Publishing : , : Imprint : Springer, , 2014
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Functional Molecular Silicon Compounds II : Low Oxidation States / / edited by David Scheschkewitz
Functional Molecular Silicon Compounds II : Low Oxidation States / / edited by David Scheschkewitz
Edizione [1st ed. 2014.]
Pubbl/distr/stampa Cham : , : Springer International Publishing : , : Imprint : Springer, , 2014
Descrizione fisica 1 online resource (IX, 232 p. 100 illus., 1 illus. in color.)
Disciplina 541.393
Collana Structure and Bonding
Soggetto topico Inorganic chemistry
Organic chemistry
Pharmaceutical technology
Inorganic Chemistry
Organic Chemistry
Pharmaceutical Sciences/Technology
ISBN 3-319-03734-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Silyl Anions -- Molecular Silicon Clusters -- Silylenes -- Multiple bonds with Silicon -- NHC-stabilized low valent silicon compounds.
Record Nr. UNINA-9910298636103321
Cham : , : Springer International Publishing : , : Imprint : Springer, , 2014
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Heterogeneous reaction dynamics / Steven L. Bernasek
Heterogeneous reaction dynamics / Steven L. Bernasek
Autore BERNASEK, Steven L.
Pubbl/distr/stampa New York : VCH, c.1995
Descrizione fisica XII, 158 p. : ill. ; 24 cm
Disciplina 541.393
Soggetto topico Reazioni chimiche
Sistemi gas-solidi
ISBN 0-89573-742-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNISA-990000439480203316
BERNASEK, Steven L.  
New York : VCH, c.1995
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Hydrogen sulfide in redox biology : Part B / edited by Enrique Cadenas, Lester Packer
Hydrogen sulfide in redox biology : Part B / edited by Enrique Cadenas, Lester Packer
Pubbl/distr/stampa Amsterdam...[etc.], : Elsevier, copyr. 2015
Descrizione fisica XV, 356 p., [5] c. di tav. : ill. ; 24 cm
Disciplina 541.393
Collana Methods in enzymology
Soggetto topico Ossidoriduzione - Patogenesi - Ruolo [dell'] Acido solforico
ISBN 978-0-12-801511-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNISA-990006052140203316
Amsterdam...[etc.], : Elsevier, copyr. 2015
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Hydrogen sulfide in redox biology : Part A / edited by Enrique Cadenas, Lester Packer
Hydrogen sulfide in redox biology : Part A / edited by Enrique Cadenas, Lester Packer
Pubbl/distr/stampa Amsterdam...[etc.], : Elsevier, copyr. 2015
Descrizione fisica XV, 327 p., [4] c. di tav. : ill. ; 24 cm
Disciplina 541.393
Collana Methods in enzymology
Soggetto topico Ossidoriduzione - Patogenesi - Ruolo [dell'] Acido solforico
ISBN 978-0-12-801512-4
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNISA-990006052120203316
Amsterdam...[etc.], : Elsevier, copyr. 2015
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Kinetic and thermodynamic lumping of multicomponent mixtures : proceedings of an ACS symposium onkinetic and thermodynamic lumping of multicomponent mixtures : Atlanta, GA, April 15, 1991 / edyted by Gianni Astarita
Kinetic and thermodynamic lumping of multicomponent mixtures : proceedings of an ACS symposium onkinetic and thermodynamic lumping of multicomponent mixtures : Atlanta, GA, April 15, 1991 / edyted by Gianni Astarita
Autore ACS symposium on kinetic and thermodynamic lumping of multicomponent mixtures : 1991
Pubbl/distr/stampa Amsterdam : Elsevier, 1991
Disciplina 541.393
Soggetto non controllato reazioni chimiche congressi 1991
termodinamica congressi 1991
ISBN 0-444-89032-7
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNISA-990000159460203316
ACS symposium on kinetic and thermodynamic lumping of multicomponent mixtures : 1991  
Amsterdam : Elsevier, 1991
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Liquid phase aerobic oxidation catalysis : industrial applications and academic perspectives / / edited by Shannon S. Stahl and Paul L. Alsters
Liquid phase aerobic oxidation catalysis : industrial applications and academic perspectives / / edited by Shannon S. Stahl and Paul L. Alsters
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH, , 2016
Descrizione fisica 1 online resource (511 p.)
Disciplina 541.393
Soggetto topico Oxidation - Methodology
ISBN 3-527-69015-8
3-527-69014-X
3-527-69012-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Title Page; Copyright; Table of Contents; Preface; List of Contributors; Part I: Radical Chain Aerobic Oxidation; Chapter 1: Overview of Radical Chain Oxidation Chemistry; 1.1 Introduction; 1.2 Chain Initiation; 1.3 Chain Propagation; 1.4 Formation of Ring-Opened By-Products in the Case of Cyclohexane Oxidation; 1.5 Complications in the Case of Olefin Autoxidation; 1.6 Summary and Conclusions; References; Chapter 2: Noncatalyzed Radical Chain Oxidation: Cumene Hydroperoxide; 2.1 Introduction; 2.2 Chemistry and Catalysis; 2.3 Process Technology; 2.4 New Developments; References
Chapter 3: Cyclohexane Oxidation: History of Transition from Catalyzed to Noncatalyzed3.1 Introduction; 3.2 Chemistry and Catalysis; 3.3 Process Technology; 3.4 New Developments; Epilogue; References; Chapter 4: Chemistry and Mechanism of Oxidation of para-Xylene to Terephthalic Acid Using Co-Mn-Br Catalyst; 4.1 Introduction; 4.2 Chemistry and Catalysis; 4.3 Process Technology; 4.4 New Developments; 4.5 Conclusions; References; Part II: Cu-Catalyzed Aerobic Oxidation; Chapter 5: Cu-Catalyzed Aerobic Oxidation: Overview and New Developments; 5.1 Introduction; 5.2 Chemistry and Catalysis
5.3 Process Technology5.4 New Developments: Pharmaceutical Applications of Cu-Catalyzed Aerobic Oxidation Reactions; References; Chapter 6: Copper-Catalyzed Aerobic Alcohol Oxidation; 6.1 Introduction; 6.2 Chemistry and Catalysis; 6.3 Prospects for Scale-Up; 6.4 Conclusions; References; Chapter 7: Phenol Oxidations; 7.1 Polyphenylene Oxides by Oxidative Polymerization of Phenols; 7.2 2,3,5-Trimethylhydroquinone as a Vitamin E Intermediate via Oxidation of Methyl-Substituted Phenols; References; Part III: Pd-Catalyzed Aerobic Oxidation
Chapter 8: Pd-Catalyzed Aerobic Oxidation Reactions: Industrial Applications and New Developments8.1 Introduction; 8.2 Chemistry and Catalysis: Industrial Applications; 8.3 Chemistry and Catalysis: Applications of Potential Industrial Interest; 8.4 Chemistry and Catalysis: New Developments and Opportunities; 8.5 Conclusion; References; Chapter 9: Acetaldehyde from Ethylene and Related Wacker-Type Reactions; 9.1 Introduction; 9.2 Chemistry and Catalysis; 9.3 Process Technology (Wacker Process); 9.4 Other Developments; References; Further Reading; Chapter 10: 1,4-Butanediol from 1,3-Butadiene
10.1 Introduction10.2 Chemistry and Catalysis; 10.3 Process Technology; 10.4 New Developments; 10.5 Summary and Conclusions; References; Chapter 11: Mitsubishi Chemicals Liquid Phase Palladium-Catalyzed Oxidation Technology: Oxidation of Cyclohexene, Acrolein, and Methyl Acrylate to Useful Industrial Chemicals; 11.1 Introduction; 11.2 Chemistry and Catalysis; 11.3 Prospects for Scale-Up; 11.4 Conclusion; References; Chapter 12: Oxidative Carbonylation: Diphenyl Carbonate; 12.1 Introduction; 12.2 Chemistry and Catalysis; 12.3 Prospects for Scale-Up; 12.4 Conclusions and Outlook
Acknowledgments
Record Nr. UNINA-9910134855103321
Weinheim, Germany : , : Wiley-VCH, , 2016
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Magma redox geochemistry / / Roberto Moretti, Daniel R. Neuville, editors
Magma redox geochemistry / / Roberto Moretti, Daniel R. Neuville, editors
Pubbl/distr/stampa Hoboken, New Jersey : , : American Geophysical Union : , : Wiley, , [2022]
Descrizione fisica 1 online resource (429 pages)
Disciplina 541.393
Collana Geophysical monograph series
Soggetto topico Oxidation-reduction reaction
Soggetto genere / forma Electronic books.
ISBN 1-119-47324-1
1-119-47320-9
1-119-47329-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover -- Title Page -- Copyright Page -- Contents -- List of Contributors -- Preface -- Chapter 1 Redox Equilibria: From Basic Concepts to the Magmatic Realm -- 1.1 General Aspects and Rationale -- 1.2 Oxygen Fugacity: The Centrality of an Elusive Parameter -- 1.3 Concluding Remarks and Perspectives -- Acknowledgments -- References -- Part I Redox from the Earth's Accretion to Global Geodynamics -- Chapter 2 Redox Processes Before, During, and After Earth´s Accretion Affecting the Deep Carbon Cycle -- 2.1 The Redox State of Planetary Interiors and the Speciation of Carbon in the Earth -- 2.2 Oxidation State of Earth´s Building Blocks and Early Differentiation -- 2.3 Mantle Oxidation State Over Time and Its Effect on the C-O-H Volatile Speciation -- 2.4 The Mantle Great Oxidation Event: Fact or Artefact? -- Acknowledgments -- References -- Chapter 3 Oxygen Fugacity Across Tectonic Settings -- 3.1 Introduction -- 3.2 Sample Selection, Methodology, and Design of this Study -- 3.3 Results -- 3.4 Discussion -- 3.5 Conclusions and Future Directions -- Acknowledgments -- Oxygen Fugacity Calculations -- References -- Chapter 4 Redox Variables and Mechanisms in Subduction Magmatism and Volcanism -- 4.1 Introduction -- 4.2 Redox Variables -- 4.3 Mechanisms -- 4.4 Discussion -- Acknowledgments -- References -- Chapter 5 Redox Melting in the Mantle -- 5.1 Introduction -- 5.2 Mantle Melting with Volatile Components -- 5.3 Redox Melting -- 5.4 Compositions of Melts Formed by Redox Melting -- 5.5 The Oxidation State in the Mantle Lithosphere, Asthenosphere, and Subduction Zones -- 5.6 Discussion -- 5.7 Closing Comments -- Acknowledgments -- References -- Part II Redox at Work: From Magma Sources to Volcanic Phenomena -- Chapter 6 Ionic Syntax and Equilibrium Approach to Redox Exchanges in Melts: Basic Concepts and the Case of Iron and Sulfur in Degassing Magmas.
6.1 Introduction -- 6.2 Ionic Syntax, Speciation State and the Melt/Glass Network: State of the Art and Conceptual Framework -- 6.3 Redox Evolution and Magmatic Degassing -- 6.4 Discussion -- 6.5 Conclusions -- Acknowledgments -- References -- Chapter 7 The Petrological Consequences of the Estimated Oxidation State of Primitive MORB Glass -- 7.1 Introduction -- 7.2 Modeling Methods and Sample Selection -- 7.3 Results -- 7.4 Summary and Prospects -- Acknowledgments -- References -- Chapter 8 Oxygen Content, Oxygen Fugacity, the Oxidation State of Iron, and Mid-Ocean Ridge Basalts -- 8.1 Oxygen Content, Oxygen Fugacity, and the Oxidation State of Iron -- 8.2 Mid-Ocean Ridge Basalts -- Acknowledgments -- References -- Chapter 9 Chromium Redox Systematics in Basaltic Liquids and Olivine -- 9.1 Introduction -- 9.2 Measuring Cr Valence in Geologic Materials with Cr-K edge XANES Spectroscopy -- 9.3 Cr-Redox Systematics in Silicate Liquids: What We Know and Don´t Know -- 9.4 Cr-Valence Systematics in Equilibrium Liquid-Olivine Pairs -- 9.5 Concluding Remarks -- Acknowledgments -- References -- Chapter 10 The Thermodynamic Controls on Sulfide Saturation in Silicate Melts with Application to Ocean Floor Basalts -- 10.1 Introduction -- 10.2 Sulfide Capacity -- 10.3 The Thermodynamic Meaning of the Sulfide Capacity -- 10.4 A New Parameterization of Sulfide Capacity for Basaltic Melts -- 10.5 Sulfide Content at Sulfide Saturation (SCSS) -- 10.6 Application to Mid-Ocean Ridge and Similar Basalts -- 10.7 The Sulfur Fugacity (fS2) of Ocean Floor Basalts -- 10.8 Conclusions -- Acknowledgments -- References -- Chapter 11 Redox State of Volatiles and Their Relationships with Iron in Silicate Melts -- 11.1 Introduction -- 11.2 Water Concentration in Melt and its Effect on Redox -- 11.3 The Sulfur Species and the Redox (Fe3+/SigmaFe Ratio) of Silicate Melts.
11.4 Natural Systems: Magma Degassing and Redox -- 11.5 Concluding Remarks -- Acknowledgments -- References -- Chapter 12 Iron in Silicate Glasses and Melts -- 12.1 Introduction -- 12.2 Iron Distribution in the Different Terrestrial Envelopes -- 12.3 Redox Equilibrium in Melts -- 12.4 Physical Properties: Highlights on Density and Viscosity -- 12.5 Influences on Crystallization and Degassing in Magmatic Systems -- 12.6 Concluding Remarks -- Acknowledgments -- References -- Part III Tools and Techniques to Characterize the Redox and its Effect on Isotope Partitioning -- Chapter 13 How to Measure the Oxidation State of Multivalent Elements in Minerals, Glasses, and Melts? -- 13.1 Introduction -- 13.2 Wet-Chemical Analyses -- 13.3 Electronic Microprobe -- 13.4 Mössbauer Spectroscopy -- 13.5 Optical Absorption Spectroscopy -- 13.6 X-ray Absorption Spectroscopy -- 13.7 Raman Spectroscopy -- 13.8 In situ Redox Determination at High Temperature or at High Pressure -- 13.9 Conclusion -- Acknowledgments -- References -- Chapter 14 Oxidation State, Coordination, and Covalency Controls on Iron Isotopic Fractionation in Earth´s Mantle and Crust -- 14.1 Introduction -- 14.2 Theory: Equilibrium Isotopic Fractionation from Vibrational Properties -- 14.3 Calculation of Vibrational Properties -- 14.4 Iron Isotope Studies Based on NRIXS or DFT -- 14.5 Comparison of Equilibrium Fractionation Factors Derived from Various Techniques -- 14.6 Parameters Controlling Equilibrium Fractionation Factors -- 14.7 Selected Applications to the Interpretation of Iron Isotopic Variations in Igneous Rocks -- 14.8 Conclusions and Perspectives -- Acknowledgments -- References -- Chapter 15 The Role of Redox Processes in Determining the Iron Isotope Compositions of Minerals, Melts, and Fluids -- 15.1 Introduction -- 15.2 Principles and Nomenclature.
15.3 Methods for the Calibration of Iron Isotope Fractionation Factors -- 15.4 Fundamental Controls on Isotopic Fractionation Between Minerals, Melts, and Fluids -- 15.5 Effect of Redox Processes in Influencing Iron Isotope Fractionation in Natural Systems -- 15.6 Conclusion -- Acknowledgments -- References -- Chapter 16 Zinc and Copper Isotopes as Tracers of Redox Processes -- 16.1 Introduction -- 16.2 The Determination of Cu and Zn Isotope Ratios -- 16.3 Theoretical and Experimental Constraints on Cu and Zn Isotope Behavior in Relation to Redox Processes -- 16.4 Application of Cu and Zn to Trace Redox Processes in Natural Systems -- 16.5 Summary and Conclusions -- Acknowledgments -- References -- Chapter 17 Mineral-Melt Partitioning of Redox-Sensitive Elements -- 17.1 Introduction -- 17.2 Theoretical Background -- 17.3 Transition Metals (Fe, Cr, Ti, V) -- 17.4 Rare Earths (Ce, Eu) -- 17.5 Uranium (U) -- 17.6 Siderophile Elements (MO, W, Re, Pt GROUP ELEMENTS) -- 17.7 Concluding Remarks -- Acknowledgments -- References -- Chapter 18 Titanomagnetite - Silicate Melt Oxybarometry -- 18.1 Introduction -- 18.2 Oxybarometers Related to Titanomagnetite -- 18.3 Oxybarometers Based on Mineral Equilibria Involving Titanomagnetite -- 18.4 Oxybarometers Based on Element Partitioning Between Titanomagnetite and Silicate Melt -- 18.5 Application of Titanomagnetite-Based Oxybarometers to Natural Silicic Rocks -- 18.6 Conclusions -- Acknowledgments -- References -- Supplementary references -- Chapter 19 The Redox Behavior of Rare Earth Elements -- 19.1 Introduction -- 19.2 Geochemistry of Rare Earth Elements -- 19.3 Multivalent Rare Earth Elements -- 19.4 Conclusions and Perspectives -- Acknowledgments -- References -- Index -- EULA.
Record Nr. UNINA-9910555059803321
Hoboken, New Jersey : , : American Geophysical Union : , : Wiley, , [2022]
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