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Anion coordination chemistry [[electronic resource] /] / edited by Kristin Bowman-James, Antonio Bianchi, Enrique García-Espana
Anion coordination chemistry [[electronic resource] /] / edited by Kristin Bowman-James, Antonio Bianchi, Enrique García-Espana
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2012
Descrizione fisica 1 online resource (575 p.)
Disciplina 541.3722
Altri autori (Persone) BianchiAntonio <1956->
Bowman-JamesKristin <1946->
García-EspañaEnrique
Soggetto topico Anions
Supramolecular chemistry
ISBN 3-527-63951-9
1-283-86971-3
3-527-63952-7
3-527-63950-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Anion Coordination Chemistry; Contents; Preface; List of Contributors; 1 Aspects of Anion Coordination from Historical Perspectives; 1.1 Introduction; 1.2 Halide and Pseudohalide Anions; 1.3 Oxoanions; 1.4 Phosphate and Polyphosphate Anions; 1.5 Carboxylate Anions and Amino Acids; 1.6 Anionic Complexes: Supercomplex Formation; 1.7 Nucleotides; 1.8 Final Notes; References; 2 Thermodynamic Aspects of Anion Coordination; 2.1 Introduction; 2.2 Parameters Determining the Stability of Anion Complexes; 2.2.1 Type of Binding Group: Noncovalent Forces in Anion Coordination
2.2.2 Charge of Anions and Receptors2.2.3 Number of Binding Groups; 2.2.3.1 Additivity of Noncovalent Forces; 2.2.4 Preorganization; 2.2.4.1 Macrocyclic Effect; 2.2.5 Solvent Effects; 2.3 Molecular Recognition and Selectivity; 2.4 Enthalpic and Entropic Contributions in Anion Coordination; References; 3 Structural Aspects of Anion Coordination Chemistry; 3.1 Introduction; 3.2 Basic Concepts of Anion Coordination Chemistry; 3.3 Classes of Anion Hosts; 3.4 Acycles; 3.4.1 Bidentate; 3.4.2 Tridentate; 3.4.3 Tetradentate; 3.4.4 Pentadentate; 3.4.5 Hexadentate; 3.5 Monocycles; 3.5.1 Bidentate
3.5.2 Tridentate3.5.3 Tetradentate; 3.5.4 Pentadentate; 3.5.5 Hexadentate; 3.5.6 Octadentate; 3.5.7 Dodecadentate; 3.6 Cryptands; 3.6.1 Bidentate; 3.6.2 Tridentate; 3.6.3 Tetradentate; 3.6.4 Pentadentate; 3.6.5 Hexadentate; 3.6.6 Septadentate; 3.6.7 Octadentate; 3.6.8 Nonadentate; 3.6.9 Decadentate; 3.6.10 Dodecadentate; 3.7 Transition-Metal-Assisted Ligands; 3.7.1 Bidentate; 3.7.2 Tridentate; 3.7.3 Tetradentate; 3.7.4 Hexadentate; 3.7.5 Septadentate; 3.7.6 Dodecadentate; 3.8 Lewis Acid Ligands; 3.8.1 Transition Metal Cascade Complexes; 3.8.2 Other Lewis Acid Donor Ligands
3.8.2.1 Boron-Based Ligands3.8.2.2 Tin-Based Ligands; 3.8.2.3 Hg-Based Ligands; 3.9 Conclusion; Acknowledgments; References; 4 Synthetic Strategies; 4.1 Introduction; 4.2 Design and Synthesis of Polyamine-Based Receptors for Anions; 4.2.1 Acyclic Polyamine Receptors; 4.2.2 Tripodal Polyamine Receptors; 4.2.3 Macrocyclic Polyamine Receptors with Aliphatic Skeletons; 4.2.4 Macrocyclic Receptors Incorporating a Single Aromatic Unit; 4.2.5 Macrocyclic Receptors Incorporating Two Aromatic Units; 4.2.6 Anion Receptors Containing Separated Macrocyclic Binding Units; 4.2.7 Cryptands
4.3 Design and Synthesis of Amide Receptors4.3.1 Acid Halides as Starting Materials; 4.3.1.1 Acyclic Amide Receptors; 4.3.1.2 Macrocyclic Amide Receptors; 4.3.2 Esters as Starting Materials; 4.3.3 Using Coupling Reagents; References; 5 Template Synthesis; 5.1 Introductory Remarks; 5.2 Macrocyclic Systems; 5.3 Bowl-Shaped Systems; 5.4 Capsule, Cage, and Tube-Shaped Systems; 5.5 Circular Helicates and meso-Helicates; 5.6 Mechanically Linked Systems; 5.7 Concluding Remarks; References; 6 Anion-ð Interactions in Molecular Recognition; 6.1 Introduction; 6.2 Physical Nature of the Interaction
6.3 Energetic and Geometric Features of the Interaction Depending on the Host (Aromatic Moieties) and the Guest (Anions)
Record Nr. UNINA-9910141252003321
Weinheim, : Wiley-VCH, c2012
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Anion coordination chemistry / / edited by Kristin Bowman-James, Antonio Bianchi, Enrique García-Espana
Anion coordination chemistry / / edited by Kristin Bowman-James, Antonio Bianchi, Enrique García-Espana
Edizione [1st ed.]
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2012
Descrizione fisica 1 online resource (575 p.)
Disciplina 541.3722
Altri autori (Persone) BianchiAntonio <1956->
Bowman-JamesKristin <1946->
García-EspañaEnrique
Soggetto topico Anions
Supramolecular chemistry
ISBN 9783527639519
3527639519
9781283869713
1283869713
9783527639526
3527639527
9783527639502
3527639500
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Anion Coordination Chemistry; Contents; Preface; List of Contributors; 1 Aspects of Anion Coordination from Historical Perspectives; 1.1 Introduction; 1.2 Halide and Pseudohalide Anions; 1.3 Oxoanions; 1.4 Phosphate and Polyphosphate Anions; 1.5 Carboxylate Anions and Amino Acids; 1.6 Anionic Complexes: Supercomplex Formation; 1.7 Nucleotides; 1.8 Final Notes; References; 2 Thermodynamic Aspects of Anion Coordination; 2.1 Introduction; 2.2 Parameters Determining the Stability of Anion Complexes; 2.2.1 Type of Binding Group: Noncovalent Forces in Anion Coordination
2.2.2 Charge of Anions and Receptors2.2.3 Number of Binding Groups; 2.2.3.1 Additivity of Noncovalent Forces; 2.2.4 Preorganization; 2.2.4.1 Macrocyclic Effect; 2.2.5 Solvent Effects; 2.3 Molecular Recognition and Selectivity; 2.4 Enthalpic and Entropic Contributions in Anion Coordination; References; 3 Structural Aspects of Anion Coordination Chemistry; 3.1 Introduction; 3.2 Basic Concepts of Anion Coordination Chemistry; 3.3 Classes of Anion Hosts; 3.4 Acycles; 3.4.1 Bidentate; 3.4.2 Tridentate; 3.4.3 Tetradentate; 3.4.4 Pentadentate; 3.4.5 Hexadentate; 3.5 Monocycles; 3.5.1 Bidentate
3.5.2 Tridentate3.5.3 Tetradentate; 3.5.4 Pentadentate; 3.5.5 Hexadentate; 3.5.6 Octadentate; 3.5.7 Dodecadentate; 3.6 Cryptands; 3.6.1 Bidentate; 3.6.2 Tridentate; 3.6.3 Tetradentate; 3.6.4 Pentadentate; 3.6.5 Hexadentate; 3.6.6 Septadentate; 3.6.7 Octadentate; 3.6.8 Nonadentate; 3.6.9 Decadentate; 3.6.10 Dodecadentate; 3.7 Transition-Metal-Assisted Ligands; 3.7.1 Bidentate; 3.7.2 Tridentate; 3.7.3 Tetradentate; 3.7.4 Hexadentate; 3.7.5 Septadentate; 3.7.6 Dodecadentate; 3.8 Lewis Acid Ligands; 3.8.1 Transition Metal Cascade Complexes; 3.8.2 Other Lewis Acid Donor Ligands
3.8.2.1 Boron-Based Ligands3.8.2.2 Tin-Based Ligands; 3.8.2.3 Hg-Based Ligands; 3.9 Conclusion; Acknowledgments; References; 4 Synthetic Strategies; 4.1 Introduction; 4.2 Design and Synthesis of Polyamine-Based Receptors for Anions; 4.2.1 Acyclic Polyamine Receptors; 4.2.2 Tripodal Polyamine Receptors; 4.2.3 Macrocyclic Polyamine Receptors with Aliphatic Skeletons; 4.2.4 Macrocyclic Receptors Incorporating a Single Aromatic Unit; 4.2.5 Macrocyclic Receptors Incorporating Two Aromatic Units; 4.2.6 Anion Receptors Containing Separated Macrocyclic Binding Units; 4.2.7 Cryptands
4.3 Design and Synthesis of Amide Receptors4.3.1 Acid Halides as Starting Materials; 4.3.1.1 Acyclic Amide Receptors; 4.3.1.2 Macrocyclic Amide Receptors; 4.3.2 Esters as Starting Materials; 4.3.3 Using Coupling Reagents; References; 5 Template Synthesis; 5.1 Introductory Remarks; 5.2 Macrocyclic Systems; 5.3 Bowl-Shaped Systems; 5.4 Capsule, Cage, and Tube-Shaped Systems; 5.5 Circular Helicates and meso-Helicates; 5.6 Mechanically Linked Systems; 5.7 Concluding Remarks; References; 6 Anion-ð Interactions in Molecular Recognition; 6.1 Introduction; 6.2 Physical Nature of the Interaction
6.3 Energetic and Geometric Features of the Interaction Depending on the Host (Aromatic Moieties) and the Guest (Anions)
Record Nr. UNINA-9910816078203321
Weinheim, : Wiley-VCH, c2012
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui