Autore	Billing, Gert D.
Pubbl/distr/stampa	New York : Wiley, c1997
Descrizione fisica	xiii, 288 p. : ill. ; 25 cm
Disciplina	541.3/9
Altri autori (Persone)	Mikkelsen, Kurt V.
Soggetto topico	Chemical kinetics Molecular dynamics
ISBN	9780471127406
Classificazione	LC QD461
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Record Nr.	UNISALENTO-991003802279707536

Autore	Atkins, Peter William
Pubbl/distr/stampa	New York : Scientific American Library : Distritubed by W.H. Freeman, c1991
Descrizione fisica	ix, 242 p. : ill. (some col.) ; 24 cm
Disciplina	541.3/9
Soggetto topico	Chemical reactions Atomic theory
ISBN	0716750287
Classificazione	LC QD461
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Record Nr.	UNISALENTO-991003803889707536

Autore	Adams Dave J
Pubbl/distr/stampa	Chichester, West Sussex, England ; ; Hoboken, NJ, : J. Wiley, c2004
Descrizione fisica	1 online resource (269 p.)
Disciplina	541.3/9
Altri autori (Persone)	DysonPaul J TavenerStewart J
Soggetto topico	Solvents Solvation Chemical reactions Chemical kinetics
ISBN	9786610238927 9780470869666 0470869666 9780470491232 047049123X 9780471498483 0471498483 9781280238925 1280238925
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Chemistry In Alternative Reaction Media; CONTENTS; Preface; Abbreviations and Acronyms; 1 Chemistry in Alternative Reaction Media; 1.1 Economic and Political Considerations; 1.2 Why Do Things Dissolve?; 1.3 Solvent Properties and Solvent Classification; 1.3.1 Density; 1.3.2 Mass Transport; 1.3.3 Boiling Point, Melting Point and Volatility; 1.3.4 Solvents as Heat-Transfer Media; 1.3.5 Cohesive Pressure, Internal Pressure, and Solubility Parameter; 1.4 Solvent Polarity; 1.4.1 Dipole Moment and Dispersive Forces; 1.4.2 Dielectric Constant; 1.4.3 Electron Pair Donor and Acceptor Numbers 1.4.4 Empirical Polarity Scales1.4.5 E(N)(T) and E(T)(30) Parameters; 1.4.6 Kamlet-Taft Parameters; 1.4.7 Hydrogen Bond Donor (HBD) and Hydrogen Bond Acceptor (HBA) Solvents; 1.5 The Effect of Solvent Polarity on Chemical Systems; 1.5.1 The Effect of Solvent Polarity on Chemical Reactions; 1.5.2 The Effect of Solvent Polarity on Equilibria; 1.6 What is Required from Alternative Solvent Strategies?; References; 2 Multiphasic Solvent Systems; 2.1 An Introduction to Multiphasic Chemistry; 2.1.1 The Traditional Biphasic Approach; 2.1.2 Temperature Dependent Solvent Systems 2.1.3 Single- to Two-Phase Systems2.1.4 Multiphasic Systems; 2.2 Solvent Combinations; 2.2.1 Water; 2.2.2 Fluorous Solvents; 2.2.3 Ionic Liquids; 2.2.4 Supercritical Fluids and Other Solvent Combinations; 2.3 Benefits and Problems Associated with Multiphasic Systems; 2.3.1 Partially Miscible Liquids; 2.4 Kinetics of Homogeneous Reactions; 2.4.1 Rate is Independent of Stoichiometry; 2.4.2 Rate is Determined by the Probability of Reactants Meeting; 2.4.3 Rate is Measured by the Concentration of the Reagents; 2.4.4 Catalysed Systems; 2.5 Kinetics of Biphasic Reactions 2.5.1 The Concentration of Reactants in Each Phase is Affected by Diffusion2.5.2 The Concentration of the Reactants and Products in the Reacting Phase is Determined by Their Partition Coefficients; 2.5.3 The Partition Coefficients of the Reactants and Products May Alter the Position of the Equilibrium; 2.5.4 Effect of Diffusion on Rate; 2.5.5 Determining the Rate of a Reaction in a Biphasic System; 2.6 Conclusions; References; 3 Reactions in Fluorous Media; 3.1 Introduction; 3.2 Properties of Perfluorinated Solvents; 3.3 Designing Molecules for Fluorous Compatibility 3.4 Probing the Effect of Perfluoroalkylation on Ligand Properties3.5 Partition Coefficients; 3.6 Liquid-Liquid Extractions; 3.7 Solid Separations; 3.8 Conclusions; References; 4 Ionic Liquids; 4.1 Introduction; 4.1.1 The Cations and Anions; 4.1.2 Synthesis of Ionic Liquids; 4.2 Physical Properties of Ionic Liquids; 4.3 Benefits and Problems Associated with Using Ionic Liquids in Synthesis; 4.4 Catalyst Design; 4.5 Conclusions; References; 5 Reactions in Water; 5.1 The Structure and Properties of Water; 5.1.1 The Structure of Water; 5.1.2 Near-Critical Water; 5.1.3 The Hydrophobic Effect 5.1.4 The Salt Effect
Record Nr.	UNINA-9911019095303321

Pubbl/distr/stampa	[Deerfield Beach, FL], : VCH, c1986
Descrizione fisica	1 online resource (426 p.)
Disciplina	541.3/9 541.39
Altri autori (Persone)	ZuckermanJ. J <1936-1987.> (Jerold J.)
Collana	Inorganic reactions and methods
Soggetto topico	Photochemistry Charge transfer
Soggetto genere / forma	Electronic books.
ISBN	1-282-30827-0 9786612308277 0-470-14530-7 0-470-14551-X
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Inorganic Reactions and Methods; Contents; How to Use this Book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 15; Electron-Transfer and Electrochemical Reactions; Introduction; Electron Transfer; Introduction; Classification of Electron-Transfer Reactions; Outer-Sphere Reactions; Examples of Outer-Sphere Reactions; Outer-Sphere Transition States; Inner-Sphere Reactions; Inner-Sphere Reactions: Scheme I; Inner-Sphere Reactions: Scheme II; Inner-Sphere Reactions: Scheme Ill; Double-Ligand Bridging; Other Reaction Classes Mixed Outer- and Innersphere ReactionsIntramolecular Electron Transfer; Two-Electron Transfers; Theory of Electron-Transfer Reactions; The Stability of the Precursor Complex; Potential-Energy Surfaces; of Zero Order.; of First Order.; The Electronic Factor; Electron-Exchange Reactions; The Reorganization Energy; Nuclear Tunneling in Electron Exchange; Quantum-Mechanical Treatment; Comparison of Observed and Calculated Parameters for Electron Exchange; Electron Transfer Accompanied by a Net Chemical Change; Semiclassical Treatment; Cross Reactions and Electron-Exchange Rates Quantum-Mechanical TreatmentConclusions; General Reactivity Patterns in Electron Transfer; The Inner-Shell Reorganization Energy: Exchange Rates of Aquo Ions; Variations with Ligand: The Outer-Shell Reorganization Energy; Electronic Factors: Nonadiabaticity; Free-Energy Relations; Inner-Sphere Versus Outer-Sphere Electron Transfer; Rate Saturation in Electron Transfer; Specific Reactivity Patterns in Electron-Transfer Reactions; Variation with the Reductant; One-Electron Reductants; Two-Electron Reductants; Variation with the Oxidant; One-Electron Oxidants; Multiple-Electron Oxidants Oxidation and Reduction of Coordinated LigandsCatalysis in Electron-Transfer Reactions; Catalyzed Electron Transfer; Catalyzed Ligand Substitution; Induced Electron-Transfer Reactions; Photoinduced Electron-Transfer Reactions; Electrochemical Reactions; Introduction; The Electrode Process; Reversibility; Electrochemical Reversibility; Chemical Reversibility; Complex Electrode Mechanisms; Diagnostic Electrochemical Measurements; Voltammetric Methods; Direct-Current Polarography; Pulse-Polarographic Methods; Alternating-Current Polarography; Cyclic Voltammetry; Evaluation of Formal Potentials Involving Stable Reactants and Products.Involving Unstable Electrode Products.; Involving Reactants Undergoing Multiple- Electrode Reactions.; Chemical Reactions Accompanying Electrode Reactions; Reactions Preceding Electron Transfer (CE); Slow-Reaction (1 >a) Limit; Intermediate-Reaction Kinetics; Reactions Following Electron Transfer (EC); Giving Electroinactive Products.; Giving Electroactive Products (ECE).; Other Coupled Chemical Reactions; Electrochemical Synthesis; by Controlled-Potential Electrolysis.; Involving Bulk Preparations.; Conclusions Thermodynamics of Simple Electrochemical Reactions
Record Nr.	UNINA-9910144319203321

Pubbl/distr/stampa	New York, N.Y., : VCH Publishers, 1991
Descrizione fisica	1 online resource (633 p.)
Disciplina	541.3/9 541.39
Altri autori (Persone)	ZuckermanJ. J <1936-1987.> (Jerold J.) HagenA. P
Collana	Inorganic reactions and methods
Soggetto topico	Chemical kinetics - Effect of temperature on Inorganic compounds - Synthesis
Soggetto genere / forma	Electronic books.
ISBN	1-282-30813-0 9786612308130 0-470-14523-4 0-470-14544-7
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Inorganic Reactions and Methods; Contents; How to use this book; Preface to the Series; Editorial Consultants to the Series; Contributors to Volume 9; Formation of the Bonds to the Group-IVB (C, Si, Ge, Sn, Pb) Elements; Introduction; Formation of the Group-IVB (C, Si, Ge, Sn, Pb)-Group-IVB (C, Si, Ge, Sn, Pb) Element Bond; Introduction; Formation of the Carbon-Carbon Bond; Formation of the Si-Si Bond; in Elemental Silicon; from Oxides.; by Other Methods.; Formation of High-Purity Silicon; Electrochemical Formation of Compounds with Si-Si Bonds (Including Elemental Silicon) from Metal Silicidesby Solvolysis in Aqueous or Liquid Ammonia Solutions.; Formation of Oligosilanes; Formation of Polymeric Compounds; from Silicon Hydrides and Organosilicon Hydrides; by the Action of a Silent Electric Discharge.; by Direct Photolysis.; by Sensitized Photolysis.; by Catalyzed Reactions.; by Reaction with Silylmetallic Compounds.; from Silicon Halides and Organosilicon Halides; by Electrochemical Reduction.; by Halide Elimination with Active Metals.; by Reaction with Silylmetallics.; by Catalyzed Disproportionation.; by Reaction with Organomagnesium Halide Reagents. by the Action of Silent Electric Discharge.by Mercury-Photosensitized Photolyses.; from Bissilylmercury Compounds; by Thermolysis.; by Photolysis.; from Organosilanes and Silicon Halides by Hydrogenolysis.; from Silylenes; by Oligomerization.; by Insertions into Bonds of Silicon to Hydrogen, Oxygen and Silicon.; by Addition to Si = C.; in the Direct Reaction of Methyl Chloride with Silicon-Copper.; Formation of the Germanium-Germanium Bond; in Elemental Germanium; from Oxides.; from Sulfides.; by Other Syntheses.; Formation of High-Purity Germanium.; from Organogermanium Hydrides by Reaction with Diorganomercury Compounds in the Presence of UV Radiation.by Hydrogermolysis Reaction.; by Germanium Hydride Decomposition.; from Ge(lV) Halides and Organogermanium(IV) Halides; by the Action of a Microwave Discharge of Ge(lV) Halides.; by Electrochemical Reduction.; by Halide Elimination with Active Metals.; by Reaction with Germyl-Metal Reagents.; by Reaction with Organometallic Reagents.; from Germanium(lI) Halides; by Reactions with Germyl-Metal Reagents.; by Reaction with Organometallic Reagents.; from Germyl Compounds of Cadmium, Mercury, Thallium, Antimony and Bismuth by Thermolysis or Photolysis.from Germylenes; by Oligomerization of Germylenes.; by Insertions into Bonds of Germanium to Hydrogen, Halogen, Carbon, Oxygen, Sulfur, Nitrogen, Phosphorus and Germanium.; The Formation of the Tin-Tin Bond; in Elemental Tin; from Oxides.; from Sulfides.; by Other Syntheses.; Allotropy of Tin; from Organotin Hydrides; by Catalytic Hydrogen Elimination.; by Reaction with Organotin Halogen, Pseudohalogen, Chalcogen and Pnictogen Compounds.; by Reaction with Organometallic Compounds.; by Reaction with Reducible Organic Compounds.; from Organotin Halides by Electrochemical Reduction.
Record Nr.	UNINA-9910144322603321