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3D images of materials structures [[electronic resource] ] : processing and analysis / / Joachim Ohser and Katja Schladitz
3D images of materials structures [[electronic resource] ] : processing and analysis / / Joachim Ohser and Katja Schladitz
Autore Ohser Joachim
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2009
Descrizione fisica 1 online resource (343 p.)
Disciplina 541.22
620.1129902856693
Altri autori (Persone) SchladitzKatja
Soggetto topico Microstructure
Materials science
Three-dimensional imaging
Image processing - Digital techniques
Image analysis
ISBN 1-282-30254-X
9786612302541
3-527-62830-4
3-527-62831-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto 3D Images of Materials Structures; Foreword; Contents; Preface; Conventions and Notation; 1 Introduction; 2 Preliminaries; 2.1 General Notation; 2.1.1 Points and Sets in Euclidean Spaces; 2.1.2 Curvatures; 2.1.3 Measures and Measurable Spaces; 2.2 Characteristics of Sets; 2.2.1 The Euler Number and the Integral of Gaussian Curvature; 2.2.2 The Mean Width and the Integral of the Mean Curvature; 2.2.3 Intrinsic Volumes of Convex Bodies; 2.2.4 Additive Extensions on the Convex Ring; 2.2.5 The Principal Kinematic Formulae of Integral Geometry; 2.3 Random Sets; 2.3.1 Definition of Random Sets
2.3.2 Characteristics of Random Closed Sets2.3.3 Random Point Fields; 2.3.4 Random Tessellations; 2.4 Fourier Analysis; 2.4.1 Measurable Functions; 2.4.2 Fourier Transform; 2.4.3 Bochner's Theorem; 3 Lattices, Adjacency of Lattice Points, and Images; 3.1 Introduction; 3.2 Point Lattices, Digitizations and Pixel Configurations; 3.2.1 Homogeneous Lattices; 3.2.2 Digitization; 3.2.3 Pixel Configurations; 3.3 Adjacency and Euler Number; 3.3.1 Adjacency Systems; 3.3.2 Discretization of Sets with Respect to Adjacency; 3.3.3 Euler Number; 3.3.4 Complementarity; 3.3.5 Multi-grid Convergence
3.4 The Euler Number of Microstructure Constituents3.4.1 Counting Nodes in Open Foams; 3.4.2 Connectivity of the Fibres in Non-woven Materials; 3.5 Image Data; 3.5.1 The Inverse Lattice; 3.5.2 The Nyquist--Shannon Sampling Theorem; 3.6 Rendering; 3.6.1 Volume Rendering; 3.6.2 Surface Rendering; 4 Image Processing; 4.1 Fourier Transform of an Image; 4.1.1 The Discrete Fourier Transform of a Discrete One-Dimensional Signal; 4.1.2 Fast Fourier Transform; 4.1.3 Extensions to Higher Dimensions; 4.2 Filtering; 4.2.1 Morphological Transforms of Sets; 4.2.2 Linear Filters; 4.2.3 Morphological Filters
4.2.4 Rank Value Filters4.2.5 Diffusion Filters; 4.2.6 Geodesic Morphological Transforms; 4.2.7 Distance Transforms; 4.2.8 Skeletonization; 4.3 Segmentation; 4.3.1 Binarization; 4.3.2 Connectedness, Connected Components and Labelling; 4.3.3 Watershed Transform; 4.3.4 Further Segmentation Methods; 5 Measurement of Intrinsic Volumes and Related Quantities; 5.1 Introduction; 5.2 Intrinsic Volumes; 5.2.1 Section Lattices and Translation Lattices; 5.2.2 Measurement of Intrinsic Volumes; 5.2.3 Discretization of the Translative Integral; 5.2.4 Discretization of the Integral over all Subspaces
5.2.5 Shape Factors5.2.6 Edge Correction; 5.3 Intrinsic Volume Densities; 5.3.1 Estimation of Intrinsic Volume Densities for Macroscopically Homogeneous Random Sets; 5.3.2 Characterization of Anisotropy; 5.3.3 Mean Chord Length; 5.3.4 Structure Model Index; 5.3.5 Estimation of the Intrinsic Volume Densities for Macroscopically Homogeneous and Isotropic Random Sets; 5.3.6 Intrinsic Volume Densities of the Solid Matter of Two Natural Porous Structures; 5.4 Directional Analysis; 5.4.1 Inverse Cosine Transform; 5.4.2 Use of Pixel Configurations Carrying Directional Information
5.4.3 Gradient and Hessian Matrix
Record Nr. UNINA-9910139486503321
Ohser Joachim  
Weinheim, : Wiley-VCH, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
3D images of materials structures [[electronic resource] ] : processing and analysis / / Joachim Ohser and Katja Schladitz
3D images of materials structures [[electronic resource] ] : processing and analysis / / Joachim Ohser and Katja Schladitz
Autore Ohser Joachim
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2009
Descrizione fisica 1 online resource (343 p.)
Disciplina 541.22
620.1129902856693
Altri autori (Persone) SchladitzKatja
Soggetto topico Microstructure
Materials science
Three-dimensional imaging
Image processing - Digital techniques
Image analysis
ISBN 1-282-30254-X
9786612302541
3-527-62830-4
3-527-62831-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto 3D Images of Materials Structures; Foreword; Contents; Preface; Conventions and Notation; 1 Introduction; 2 Preliminaries; 2.1 General Notation; 2.1.1 Points and Sets in Euclidean Spaces; 2.1.2 Curvatures; 2.1.3 Measures and Measurable Spaces; 2.2 Characteristics of Sets; 2.2.1 The Euler Number and the Integral of Gaussian Curvature; 2.2.2 The Mean Width and the Integral of the Mean Curvature; 2.2.3 Intrinsic Volumes of Convex Bodies; 2.2.4 Additive Extensions on the Convex Ring; 2.2.5 The Principal Kinematic Formulae of Integral Geometry; 2.3 Random Sets; 2.3.1 Definition of Random Sets
2.3.2 Characteristics of Random Closed Sets2.3.3 Random Point Fields; 2.3.4 Random Tessellations; 2.4 Fourier Analysis; 2.4.1 Measurable Functions; 2.4.2 Fourier Transform; 2.4.3 Bochner's Theorem; 3 Lattices, Adjacency of Lattice Points, and Images; 3.1 Introduction; 3.2 Point Lattices, Digitizations and Pixel Configurations; 3.2.1 Homogeneous Lattices; 3.2.2 Digitization; 3.2.3 Pixel Configurations; 3.3 Adjacency and Euler Number; 3.3.1 Adjacency Systems; 3.3.2 Discretization of Sets with Respect to Adjacency; 3.3.3 Euler Number; 3.3.4 Complementarity; 3.3.5 Multi-grid Convergence
3.4 The Euler Number of Microstructure Constituents3.4.1 Counting Nodes in Open Foams; 3.4.2 Connectivity of the Fibres in Non-woven Materials; 3.5 Image Data; 3.5.1 The Inverse Lattice; 3.5.2 The Nyquist--Shannon Sampling Theorem; 3.6 Rendering; 3.6.1 Volume Rendering; 3.6.2 Surface Rendering; 4 Image Processing; 4.1 Fourier Transform of an Image; 4.1.1 The Discrete Fourier Transform of a Discrete One-Dimensional Signal; 4.1.2 Fast Fourier Transform; 4.1.3 Extensions to Higher Dimensions; 4.2 Filtering; 4.2.1 Morphological Transforms of Sets; 4.2.2 Linear Filters; 4.2.3 Morphological Filters
4.2.4 Rank Value Filters4.2.5 Diffusion Filters; 4.2.6 Geodesic Morphological Transforms; 4.2.7 Distance Transforms; 4.2.8 Skeletonization; 4.3 Segmentation; 4.3.1 Binarization; 4.3.2 Connectedness, Connected Components and Labelling; 4.3.3 Watershed Transform; 4.3.4 Further Segmentation Methods; 5 Measurement of Intrinsic Volumes and Related Quantities; 5.1 Introduction; 5.2 Intrinsic Volumes; 5.2.1 Section Lattices and Translation Lattices; 5.2.2 Measurement of Intrinsic Volumes; 5.2.3 Discretization of the Translative Integral; 5.2.4 Discretization of the Integral over all Subspaces
5.2.5 Shape Factors5.2.6 Edge Correction; 5.3 Intrinsic Volume Densities; 5.3.1 Estimation of Intrinsic Volume Densities for Macroscopically Homogeneous Random Sets; 5.3.2 Characterization of Anisotropy; 5.3.3 Mean Chord Length; 5.3.4 Structure Model Index; 5.3.5 Estimation of the Intrinsic Volume Densities for Macroscopically Homogeneous and Isotropic Random Sets; 5.3.6 Intrinsic Volume Densities of the Solid Matter of Two Natural Porous Structures; 5.4 Directional Analysis; 5.4.1 Inverse Cosine Transform; 5.4.2 Use of Pixel Configurations Carrying Directional Information
5.4.3 Gradient and Hessian Matrix
Record Nr. UNINA-9910830690203321
Ohser Joachim  
Weinheim, : Wiley-VCH, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
3D images of materials structures : processing and analysis / / Joachim Ohser and Katja Schladitz
3D images of materials structures : processing and analysis / / Joachim Ohser and Katja Schladitz
Autore Ohser Joachim
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2009
Descrizione fisica 1 online resource (343 p.)
Disciplina 541.22
620.1129902856693
Altri autori (Persone) SchladitzKatja
Soggetto topico Microstructure
Materials science
Three-dimensional imaging
Image processing - Digital techniques
Image analysis
ISBN 9786612302541
9781282302549
128230254X
9783527628308
3527628304
9783527628315
3527628312
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto 3D Images of Materials Structures; Foreword; Contents; Preface; Conventions and Notation; 1 Introduction; 2 Preliminaries; 2.1 General Notation; 2.1.1 Points and Sets in Euclidean Spaces; 2.1.2 Curvatures; 2.1.3 Measures and Measurable Spaces; 2.2 Characteristics of Sets; 2.2.1 The Euler Number and the Integral of Gaussian Curvature; 2.2.2 The Mean Width and the Integral of the Mean Curvature; 2.2.3 Intrinsic Volumes of Convex Bodies; 2.2.4 Additive Extensions on the Convex Ring; 2.2.5 The Principal Kinematic Formulae of Integral Geometry; 2.3 Random Sets; 2.3.1 Definition of Random Sets
2.3.2 Characteristics of Random Closed Sets2.3.3 Random Point Fields; 2.3.4 Random Tessellations; 2.4 Fourier Analysis; 2.4.1 Measurable Functions; 2.4.2 Fourier Transform; 2.4.3 Bochner's Theorem; 3 Lattices, Adjacency of Lattice Points, and Images; 3.1 Introduction; 3.2 Point Lattices, Digitizations and Pixel Configurations; 3.2.1 Homogeneous Lattices; 3.2.2 Digitization; 3.2.3 Pixel Configurations; 3.3 Adjacency and Euler Number; 3.3.1 Adjacency Systems; 3.3.2 Discretization of Sets with Respect to Adjacency; 3.3.3 Euler Number; 3.3.4 Complementarity; 3.3.5 Multi-grid Convergence
3.4 The Euler Number of Microstructure Constituents3.4.1 Counting Nodes in Open Foams; 3.4.2 Connectivity of the Fibres in Non-woven Materials; 3.5 Image Data; 3.5.1 The Inverse Lattice; 3.5.2 The Nyquist--Shannon Sampling Theorem; 3.6 Rendering; 3.6.1 Volume Rendering; 3.6.2 Surface Rendering; 4 Image Processing; 4.1 Fourier Transform of an Image; 4.1.1 The Discrete Fourier Transform of a Discrete One-Dimensional Signal; 4.1.2 Fast Fourier Transform; 4.1.3 Extensions to Higher Dimensions; 4.2 Filtering; 4.2.1 Morphological Transforms of Sets; 4.2.2 Linear Filters; 4.2.3 Morphological Filters
4.2.4 Rank Value Filters4.2.5 Diffusion Filters; 4.2.6 Geodesic Morphological Transforms; 4.2.7 Distance Transforms; 4.2.8 Skeletonization; 4.3 Segmentation; 4.3.1 Binarization; 4.3.2 Connectedness, Connected Components and Labelling; 4.3.3 Watershed Transform; 4.3.4 Further Segmentation Methods; 5 Measurement of Intrinsic Volumes and Related Quantities; 5.1 Introduction; 5.2 Intrinsic Volumes; 5.2.1 Section Lattices and Translation Lattices; 5.2.2 Measurement of Intrinsic Volumes; 5.2.3 Discretization of the Translative Integral; 5.2.4 Discretization of the Integral over all Subspaces
5.2.5 Shape Factors5.2.6 Edge Correction; 5.3 Intrinsic Volume Densities; 5.3.1 Estimation of Intrinsic Volume Densities for Macroscopically Homogeneous Random Sets; 5.3.2 Characterization of Anisotropy; 5.3.3 Mean Chord Length; 5.3.4 Structure Model Index; 5.3.5 Estimation of the Intrinsic Volume Densities for Macroscopically Homogeneous and Isotropic Random Sets; 5.3.6 Intrinsic Volume Densities of the Solid Matter of Two Natural Porous Structures; 5.4 Directional Analysis; 5.4.1 Inverse Cosine Transform; 5.4.2 Use of Pixel Configurations Carrying Directional Information
5.4.3 Gradient and Hessian Matrix
Record Nr. UNINA-9911019715903321
Ohser Joachim  
Weinheim, : Wiley-VCH, c2009
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
A Structural and Vibrational Investigation into Chromylazide, Acetate, Perchlorate, and Thiocyanate Compounds / Silvia A. Brandán
A Structural and Vibrational Investigation into Chromylazide, Acetate, Perchlorate, and Thiocyanate Compounds / Silvia A. Brandán
Autore Brandán, Silvia A.
Pubbl/distr/stampa Dordrecht, : Springer, 2013
Descrizione fisica VI, 87 p. : ill. ; 24 cm
Disciplina 547(Chimica organica)
541.22(Chimica teorica. Struttura molecolare)
546(Chimica inorganica)
541(Chimica fisica)
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNICAMPANIA-VAN00256999
Brandán, Silvia A.  
Dordrecht, : Springer, 2013
Materiale a stampa
Lo trovi qui: Univ. Vanvitelli
Opac: Controlla la disponibilità qui
Accurate Structure Determination of Free Molecules / / by Jean Demaison, Natalja Vogt
Accurate Structure Determination of Free Molecules / / by Jean Demaison, Natalja Vogt
Autore Demaison J (Jean)
Edizione [1st ed. 2020.]
Pubbl/distr/stampa Cham : , : Springer International Publishing : , : Imprint : Springer, , 2020
Descrizione fisica 1 online resource (XVIII, 277 p. 42 illus., 24 illus. in color.)
Disciplina 541.22
Collana Lecture Notes in Chemistry
Soggetto topico Spectrum analysis
Atomic structure 
Molecular structure
Crystallography
Spectroscopy
Atomic and Molecular Structure and Properties
Crystallography and Scattering Methods
ISBN 3-030-60492-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Introduction -- Computational methods -- Diatomic molecules -- Rotation of the polyatomic molecule -- The vibrations of polyatomic molecule -- Equilibrium structures from spectroscopy -- Molecular structures from gas-phase electron diffraction -- Models of chemical bonding and "empirical" methods -- Least-squares method -- Databases with information on molecular structure.
Record Nr. UNINA-9910431353103321
Demaison J (Jean)  
Cham : , : Springer International Publishing : , : Imprint : Springer, , 2020
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman
Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2006
Descrizione fisica 1 online resource (383 p.)
Disciplina 541.22
Altri autori (Persone) TolmanWilliam B
Soggetto topico Molecules
Ions
Inorganic compounds
Inorganic compounds - Synthesis
Soggetto genere / forma Electronic books.
ISBN 1-280-72285-1
9786610722853
3-527-60935-0
3-527-60937-7
Classificazione 35.60
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts
1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References
2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO
2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer
2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle"
3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten
Record Nr. UNINA-9910144319803321
Weinheim, : Wiley-VCH, c2006
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman
Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2006
Descrizione fisica 1 online resource (383 p.)
Disciplina 541.22
Altri autori (Persone) TolmanWilliam B
Soggetto topico Molecules
Ions
Inorganic compounds
Inorganic compounds - Synthesis
ISBN 1-280-72285-1
9786610722853
3-527-60935-0
3-527-60937-7
Classificazione 35.60
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts
1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References
2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO
2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer
2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle"
3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten
Record Nr. UNINA-9910830157403321
Weinheim, : Wiley-VCH, c2006
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Activation of small molecules : organometallic and bioinorganic perspectives / / edited by William B. Tolman
Activation of small molecules : organometallic and bioinorganic perspectives / / edited by William B. Tolman
Pubbl/distr/stampa Weinheim, : Wiley-VCH, c2006
Descrizione fisica 1 online resource (383 p.)
Disciplina 541.22
Altri autori (Persone) TolmanWilliam B
Soggetto topico Molecules
Ions
Inorganic compounds
Inorganic compounds - Synthesis
ISBN 9786610722853
9781280722851
1280722851
9783527609352
3527609350
9783527609376
3527609377
Classificazione 35.60
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts
1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References
2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO
2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer
2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle"
3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten
Record Nr. UNINA-9911019451403321
Weinheim, : Wiley-VCH, c2006
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Advanced structural chemistry . Volume 1 : tailoring properties of inorganic materials and their applications / / edited by Rong Cao
Advanced structural chemistry . Volume 1 : tailoring properties of inorganic materials and their applications / / edited by Rong Cao
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH, , [2021]
Descrizione fisica 1 online resource (1,066 pages)
Disciplina 541.22
Soggetto topico Inorganic compounds - Structure
Soggetto genere / forma Electronic books.
ISBN 3-527-83174-6
3-527-83173-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910554874003321
Weinheim, Germany : , : Wiley-VCH, , [2021]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Advanced structural chemistry . Volume 1 : tailoring properties of inorganic materials and their applications / / edited by Rong Cao
Advanced structural chemistry . Volume 1 : tailoring properties of inorganic materials and their applications / / edited by Rong Cao
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH, , [2021]
Descrizione fisica 1 online resource (1,066 pages)
Disciplina 541.22
Soggetto topico Inorganic compounds - Structure
ISBN 3-527-83174-6
3-527-83173-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Record Nr. UNINA-9910831068303321
Weinheim, Germany : , : Wiley-VCH, , [2021]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui