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3D images of materials structures [[electronic resource] ] : processing and analysis / / Joachim Ohser and Katja Schladitz
| 3D images of materials structures [[electronic resource] ] : processing and analysis / / Joachim Ohser and Katja Schladitz |
| Autore | Ohser Joachim |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (343 p.) |
| Disciplina |
541.22
620.1129902856693 |
| Altri autori (Persone) | SchladitzKatja |
| Soggetto topico |
Microstructure
Materials science Three-dimensional imaging Image processing - Digital techniques Image analysis |
| ISBN |
1-282-30254-X
9786612302541 3-527-62830-4 3-527-62831-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
3D Images of Materials Structures; Foreword; Contents; Preface; Conventions and Notation; 1 Introduction; 2 Preliminaries; 2.1 General Notation; 2.1.1 Points and Sets in Euclidean Spaces; 2.1.2 Curvatures; 2.1.3 Measures and Measurable Spaces; 2.2 Characteristics of Sets; 2.2.1 The Euler Number and the Integral of Gaussian Curvature; 2.2.2 The Mean Width and the Integral of the Mean Curvature; 2.2.3 Intrinsic Volumes of Convex Bodies; 2.2.4 Additive Extensions on the Convex Ring; 2.2.5 The Principal Kinematic Formulae of Integral Geometry; 2.3 Random Sets; 2.3.1 Definition of Random Sets
2.3.2 Characteristics of Random Closed Sets2.3.3 Random Point Fields; 2.3.4 Random Tessellations; 2.4 Fourier Analysis; 2.4.1 Measurable Functions; 2.4.2 Fourier Transform; 2.4.3 Bochner's Theorem; 3 Lattices, Adjacency of Lattice Points, and Images; 3.1 Introduction; 3.2 Point Lattices, Digitizations and Pixel Configurations; 3.2.1 Homogeneous Lattices; 3.2.2 Digitization; 3.2.3 Pixel Configurations; 3.3 Adjacency and Euler Number; 3.3.1 Adjacency Systems; 3.3.2 Discretization of Sets with Respect to Adjacency; 3.3.3 Euler Number; 3.3.4 Complementarity; 3.3.5 Multi-grid Convergence 3.4 The Euler Number of Microstructure Constituents3.4.1 Counting Nodes in Open Foams; 3.4.2 Connectivity of the Fibres in Non-woven Materials; 3.5 Image Data; 3.5.1 The Inverse Lattice; 3.5.2 The Nyquist--Shannon Sampling Theorem; 3.6 Rendering; 3.6.1 Volume Rendering; 3.6.2 Surface Rendering; 4 Image Processing; 4.1 Fourier Transform of an Image; 4.1.1 The Discrete Fourier Transform of a Discrete One-Dimensional Signal; 4.1.2 Fast Fourier Transform; 4.1.3 Extensions to Higher Dimensions; 4.2 Filtering; 4.2.1 Morphological Transforms of Sets; 4.2.2 Linear Filters; 4.2.3 Morphological Filters 4.2.4 Rank Value Filters4.2.5 Diffusion Filters; 4.2.6 Geodesic Morphological Transforms; 4.2.7 Distance Transforms; 4.2.8 Skeletonization; 4.3 Segmentation; 4.3.1 Binarization; 4.3.2 Connectedness, Connected Components and Labelling; 4.3.3 Watershed Transform; 4.3.4 Further Segmentation Methods; 5 Measurement of Intrinsic Volumes and Related Quantities; 5.1 Introduction; 5.2 Intrinsic Volumes; 5.2.1 Section Lattices and Translation Lattices; 5.2.2 Measurement of Intrinsic Volumes; 5.2.3 Discretization of the Translative Integral; 5.2.4 Discretization of the Integral over all Subspaces 5.2.5 Shape Factors5.2.6 Edge Correction; 5.3 Intrinsic Volume Densities; 5.3.1 Estimation of Intrinsic Volume Densities for Macroscopically Homogeneous Random Sets; 5.3.2 Characterization of Anisotropy; 5.3.3 Mean Chord Length; 5.3.4 Structure Model Index; 5.3.5 Estimation of the Intrinsic Volume Densities for Macroscopically Homogeneous and Isotropic Random Sets; 5.3.6 Intrinsic Volume Densities of the Solid Matter of Two Natural Porous Structures; 5.4 Directional Analysis; 5.4.1 Inverse Cosine Transform; 5.4.2 Use of Pixel Configurations Carrying Directional Information 5.4.3 Gradient and Hessian Matrix |
| Record Nr. | UNINA-9910139486503321 |
Ohser Joachim
|
||
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
3D images of materials structures [[electronic resource] ] : processing and analysis / / Joachim Ohser and Katja Schladitz
| 3D images of materials structures [[electronic resource] ] : processing and analysis / / Joachim Ohser and Katja Schladitz |
| Autore | Ohser Joachim |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (343 p.) |
| Disciplina |
541.22
620.1129902856693 |
| Altri autori (Persone) | SchladitzKatja |
| Soggetto topico |
Microstructure
Materials science Three-dimensional imaging Image processing - Digital techniques Image analysis |
| ISBN |
1-282-30254-X
9786612302541 3-527-62830-4 3-527-62831-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
3D Images of Materials Structures; Foreword; Contents; Preface; Conventions and Notation; 1 Introduction; 2 Preliminaries; 2.1 General Notation; 2.1.1 Points and Sets in Euclidean Spaces; 2.1.2 Curvatures; 2.1.3 Measures and Measurable Spaces; 2.2 Characteristics of Sets; 2.2.1 The Euler Number and the Integral of Gaussian Curvature; 2.2.2 The Mean Width and the Integral of the Mean Curvature; 2.2.3 Intrinsic Volumes of Convex Bodies; 2.2.4 Additive Extensions on the Convex Ring; 2.2.5 The Principal Kinematic Formulae of Integral Geometry; 2.3 Random Sets; 2.3.1 Definition of Random Sets
2.3.2 Characteristics of Random Closed Sets2.3.3 Random Point Fields; 2.3.4 Random Tessellations; 2.4 Fourier Analysis; 2.4.1 Measurable Functions; 2.4.2 Fourier Transform; 2.4.3 Bochner's Theorem; 3 Lattices, Adjacency of Lattice Points, and Images; 3.1 Introduction; 3.2 Point Lattices, Digitizations and Pixel Configurations; 3.2.1 Homogeneous Lattices; 3.2.2 Digitization; 3.2.3 Pixel Configurations; 3.3 Adjacency and Euler Number; 3.3.1 Adjacency Systems; 3.3.2 Discretization of Sets with Respect to Adjacency; 3.3.3 Euler Number; 3.3.4 Complementarity; 3.3.5 Multi-grid Convergence 3.4 The Euler Number of Microstructure Constituents3.4.1 Counting Nodes in Open Foams; 3.4.2 Connectivity of the Fibres in Non-woven Materials; 3.5 Image Data; 3.5.1 The Inverse Lattice; 3.5.2 The Nyquist--Shannon Sampling Theorem; 3.6 Rendering; 3.6.1 Volume Rendering; 3.6.2 Surface Rendering; 4 Image Processing; 4.1 Fourier Transform of an Image; 4.1.1 The Discrete Fourier Transform of a Discrete One-Dimensional Signal; 4.1.2 Fast Fourier Transform; 4.1.3 Extensions to Higher Dimensions; 4.2 Filtering; 4.2.1 Morphological Transforms of Sets; 4.2.2 Linear Filters; 4.2.3 Morphological Filters 4.2.4 Rank Value Filters4.2.5 Diffusion Filters; 4.2.6 Geodesic Morphological Transforms; 4.2.7 Distance Transforms; 4.2.8 Skeletonization; 4.3 Segmentation; 4.3.1 Binarization; 4.3.2 Connectedness, Connected Components and Labelling; 4.3.3 Watershed Transform; 4.3.4 Further Segmentation Methods; 5 Measurement of Intrinsic Volumes and Related Quantities; 5.1 Introduction; 5.2 Intrinsic Volumes; 5.2.1 Section Lattices and Translation Lattices; 5.2.2 Measurement of Intrinsic Volumes; 5.2.3 Discretization of the Translative Integral; 5.2.4 Discretization of the Integral over all Subspaces 5.2.5 Shape Factors5.2.6 Edge Correction; 5.3 Intrinsic Volume Densities; 5.3.1 Estimation of Intrinsic Volume Densities for Macroscopically Homogeneous Random Sets; 5.3.2 Characterization of Anisotropy; 5.3.3 Mean Chord Length; 5.3.4 Structure Model Index; 5.3.5 Estimation of the Intrinsic Volume Densities for Macroscopically Homogeneous and Isotropic Random Sets; 5.3.6 Intrinsic Volume Densities of the Solid Matter of Two Natural Porous Structures; 5.4 Directional Analysis; 5.4.1 Inverse Cosine Transform; 5.4.2 Use of Pixel Configurations Carrying Directional Information 5.4.3 Gradient and Hessian Matrix |
| Record Nr. | UNINA-9910830690203321 |
|
Ohser Joachim
|
||
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
3D images of materials structures : processing and analysis / / Joachim Ohser and Katja Schladitz
| 3D images of materials structures : processing and analysis / / Joachim Ohser and Katja Schladitz |
| Autore | Ohser Joachim |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2009 |
| Descrizione fisica | 1 online resource (343 p.) |
| Disciplina |
541.22
620.1129902856693 |
| Altri autori (Persone) | SchladitzKatja |
| Soggetto topico |
Microstructure
Materials science Three-dimensional imaging Image processing - Digital techniques Image analysis |
| ISBN |
1-282-30254-X
9786612302541 3-527-62830-4 3-527-62831-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
3D Images of Materials Structures; Foreword; Contents; Preface; Conventions and Notation; 1 Introduction; 2 Preliminaries; 2.1 General Notation; 2.1.1 Points and Sets in Euclidean Spaces; 2.1.2 Curvatures; 2.1.3 Measures and Measurable Spaces; 2.2 Characteristics of Sets; 2.2.1 The Euler Number and the Integral of Gaussian Curvature; 2.2.2 The Mean Width and the Integral of the Mean Curvature; 2.2.3 Intrinsic Volumes of Convex Bodies; 2.2.4 Additive Extensions on the Convex Ring; 2.2.5 The Principal Kinematic Formulae of Integral Geometry; 2.3 Random Sets; 2.3.1 Definition of Random Sets
2.3.2 Characteristics of Random Closed Sets2.3.3 Random Point Fields; 2.3.4 Random Tessellations; 2.4 Fourier Analysis; 2.4.1 Measurable Functions; 2.4.2 Fourier Transform; 2.4.3 Bochner's Theorem; 3 Lattices, Adjacency of Lattice Points, and Images; 3.1 Introduction; 3.2 Point Lattices, Digitizations and Pixel Configurations; 3.2.1 Homogeneous Lattices; 3.2.2 Digitization; 3.2.3 Pixel Configurations; 3.3 Adjacency and Euler Number; 3.3.1 Adjacency Systems; 3.3.2 Discretization of Sets with Respect to Adjacency; 3.3.3 Euler Number; 3.3.4 Complementarity; 3.3.5 Multi-grid Convergence 3.4 The Euler Number of Microstructure Constituents3.4.1 Counting Nodes in Open Foams; 3.4.2 Connectivity of the Fibres in Non-woven Materials; 3.5 Image Data; 3.5.1 The Inverse Lattice; 3.5.2 The Nyquist--Shannon Sampling Theorem; 3.6 Rendering; 3.6.1 Volume Rendering; 3.6.2 Surface Rendering; 4 Image Processing; 4.1 Fourier Transform of an Image; 4.1.1 The Discrete Fourier Transform of a Discrete One-Dimensional Signal; 4.1.2 Fast Fourier Transform; 4.1.3 Extensions to Higher Dimensions; 4.2 Filtering; 4.2.1 Morphological Transforms of Sets; 4.2.2 Linear Filters; 4.2.3 Morphological Filters 4.2.4 Rank Value Filters4.2.5 Diffusion Filters; 4.2.6 Geodesic Morphological Transforms; 4.2.7 Distance Transforms; 4.2.8 Skeletonization; 4.3 Segmentation; 4.3.1 Binarization; 4.3.2 Connectedness, Connected Components and Labelling; 4.3.3 Watershed Transform; 4.3.4 Further Segmentation Methods; 5 Measurement of Intrinsic Volumes and Related Quantities; 5.1 Introduction; 5.2 Intrinsic Volumes; 5.2.1 Section Lattices and Translation Lattices; 5.2.2 Measurement of Intrinsic Volumes; 5.2.3 Discretization of the Translative Integral; 5.2.4 Discretization of the Integral over all Subspaces 5.2.5 Shape Factors5.2.6 Edge Correction; 5.3 Intrinsic Volume Densities; 5.3.1 Estimation of Intrinsic Volume Densities for Macroscopically Homogeneous Random Sets; 5.3.2 Characterization of Anisotropy; 5.3.3 Mean Chord Length; 5.3.4 Structure Model Index; 5.3.5 Estimation of the Intrinsic Volume Densities for Macroscopically Homogeneous and Isotropic Random Sets; 5.3.6 Intrinsic Volume Densities of the Solid Matter of Two Natural Porous Structures; 5.4 Directional Analysis; 5.4.1 Inverse Cosine Transform; 5.4.2 Use of Pixel Configurations Carrying Directional Information 5.4.3 Gradient and Hessian Matrix |
| Record Nr. | UNINA-9910877340703321 |
|
Ohser Joachim
|
||
| Weinheim, : Wiley-VCH, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Accurate structure determination of free molecules / / Jean Demaison, Natalja Vogt
| Accurate structure determination of free molecules / / Jean Demaison, Natalja Vogt |
| Autore | Demaison J (Jean) |
| Edizione | [1st ed. 2020.] |
| Pubbl/distr/stampa | Cham, Switzerland : , : Springer, , [2020] |
| Descrizione fisica | 1 online resource (XVIII, 277 p. 42 illus., 24 illus. in color.) |
| Disciplina | 541.22 |
| Collana | Lecture notes in chemistry |
| Soggetto topico |
Molecular structure
Free molecules Spectrum analysis |
| ISBN | 3-030-60492-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Introduction -- Computational methods -- Diatomic molecules -- Rotation of the polyatomic molecule -- The vibrations of polyatomic molecule -- Equilibrium structures from spectroscopy -- Molecular structures from gas-phase electron diffraction -- Models of chemical bonding and "empirical" methods -- Least-squares method -- Databases with information on molecular structure. |
| Record Nr. | UNINA-9910431353103321 |
|
Demaison J (Jean)
|
||
| Cham, Switzerland : , : Springer, , [2020] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman
| Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (383 p.) |
| Disciplina | 541.22 |
| Altri autori (Persone) | TolmanWilliam B |
| Soggetto topico |
Molecules
Ions Inorganic compounds Inorganic compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-72285-1
9786610722853 3-527-60935-0 3-527-60937-7 |
| Classificazione | 35.60 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts
1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References 2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO 2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer 2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle" 3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten |
| Record Nr. | UNINA-9910144319803321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman
| Activation of small molecules [[electronic resource] ] : organometallic and bioinorganic perspectives / / edited by William B. Tolman |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (383 p.) |
| Disciplina | 541.22 |
| Altri autori (Persone) | TolmanWilliam B |
| Soggetto topico |
Molecules
Ions Inorganic compounds Inorganic compounds - Synthesis |
| ISBN |
1-280-72285-1
9786610722853 3-527-60935-0 3-527-60937-7 |
| Classificazione | 35.60 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts
1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References 2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO 2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer 2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle" 3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten |
| Record Nr. | UNINA-9910830157403321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Activation of small molecules : organometallic and bioinorganic perspectives / / edited by William B. Tolman
| Activation of small molecules : organometallic and bioinorganic perspectives / / edited by William B. Tolman |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2006 |
| Descrizione fisica | 1 online resource (383 p.) |
| Disciplina | 541.22 |
| Altri autori (Persone) | TolmanWilliam B |
| Soggetto topico |
Molecules
Ions Inorganic compounds Inorganic compounds - Synthesis |
| ISBN |
1-280-72285-1
9786610722853 3-527-60935-0 3-527-60937-7 |
| Classificazione | 35.60 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Activation of Small Molecules; Contents; Preface; List of Contributors; 1 Carbon Dioxide Reduction and Uses as a Chemical Feedstock; 1.1 Introduction; 1.2 Properties of the CO(2) Molecule; 1.2.1 Molecular Geometry; 1.2.2 Spectroscopic Properties; 1.2.2.1 Vibrational; 1.2.2.2 UV-Vis; 1.2.2.3 (13)C-Nuclear Magnetic Resonance (NMR); 1.2.3 Energy Data and Reaction Kinetics Relevant to CO(2) Conversion; 1.3 CO(2) Coordination to Metal Centers and Reactivity of Coordinated CO(2); 1.3.1 Modes of Coordination; 1.3.2 Interaction of CO(2) with Metal Atoms at Low Temperature: Stability of the Adducts
1.3.3 Reactivity of CO(2) Coordinated to Transition Metal Systems1.4 CO(2) Conversion; 1.4.1 Carboxylation Reactions; 1.4.1.1 C-C Bond Formation; 1.4.1.1.1 Natural Processes; 1.4.1.1.2 Artificial Processes; 1.4.1.2 N-C Bond Formation; 1.4.1.3 O-C Bond Formation; 1.4.1.3.1 Cyclic Carbonates; 1.4.1.3.2 Linear Carbonates; 1.4.1.4 Use of Urea as an Active-CO(2) Form; 1.4.1.5 Transesterification Reactions; 1.4.2 Reduction Reactions; 1.4.2.1 Energetics of the Reactions; 1.4.2.1.1 Natural Processes; 1.4.2.1.2 Artificial Processes; 1.4.2.1.3 Photoelectrochemical Reduction; 1.5 Conclusions; References 2 Nitrogen Monoxide and Nitrous Oxide Binding and Reduction2.1 Introduction; 2.2 NO; 2.2.1 Bonding and Structures of Metal Nitrosyls; 2.2.1.1 Heme Proteins: Guanylate Cyclase - NO Binding and Trans-bond Labilization; 2.2.1.2 Bridging (η(1)-μ(2)-) Complexes; 2.2.1.3 η(1)-μ(3)-NO Bridging Complexes; 2.2.1.4 η(2)-NO Bridging Complexes; 2.2.1.5 Isonitrosyl and Side-on η(2)-NO Complexes; 2.2.1.6 Side-on η(2)-NO Copper Protein Structures; 2.2.1.7 Spectroscopic Features of Nitrosyl Metal Complexes; 2.2.2 Chemical Reduction of NO and Related Chemistry; 2.2.2.1 Chemical Reduction of Metal-bound NO 2.2.2.1.1 Metal-NO Reduction Accompanied by N-O Cleavage2.2.2.2 Electrophilic Attack on Metal-bound NO:HNO (Nitroxyl) Complexes; 2.2.2.3 Electrocatalytic Reduction of NO; 2.2.2.4 Biological NO Reduction: NORs; 2.2.2.4.1 Bacterial NORs of the Heme Copper Oxidase (HCO) Type [54, 147]; 2.2.2.4.2 Models for NORs; 2.2.2.4.3 Fungal P450-type NORs; 2.2.2.4.4 Flavorubredoxins as Scavenging (S)-NORs; 2.2.2.5 Metal Complex-mediated NO Disproportionation; 2.3 N(2)O; 2.3.1 Structure and Bonding; 2.3.2 Metal-mediated N(2)O Reduction; 2.3.2.1 Oxo Transfer Reactions; 2.3.2.2 Catalytic Oxo Transfer 2.3.2.3 N(2)O N-N Bond Cleavage2.3.2.4 Electrocatalytic Reduction of N(2)O to N(2); 2.3.2.5 Biological N(2)O Reduction; 2.4 Summary and Conclusions; References; 3 Bio-organometallic Approaches to Nitrogen Fixation Chemistry; 3.1 Introduction - The N(2) Fixation Challenge; 3.2 Biological N(2) Reduction; 3.2.1 General Comments; 3.2.2 Structural Data; 3.2.3 Assigning the FeMoco Oxidation States; 3.3 Biomimetic Systems that Model Structure and Function; 3.3.1 General Comments; 3.3.2 Mononuclear Molybdenum Systems of Biomimetic Interest; 3.3.2.1 The Originally Proposed "Chatt Cycle" 3.3.2.2 An Electrocatalytic Reduction Cycle using Low-valent Tungsten |
| Record Nr. | UNINA-9910876731103321 |
| Weinheim, : Wiley-VCH, c2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Advanced structural chemistry . Volume 1 : tailoring properties of inorganic materials and their applications / / edited by Rong Cao
| Advanced structural chemistry . Volume 1 : tailoring properties of inorganic materials and their applications / / edited by Rong Cao |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2021] |
| Descrizione fisica | 1 online resource (1,066 pages) |
| Disciplina | 541.22 |
| Soggetto topico | Inorganic compounds - Structure |
| Soggetto genere / forma | Electronic books. |
| ISBN |
3-527-83174-6
3-527-83173-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910554874003321 |
| Weinheim, Germany : , : Wiley-VCH, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Advanced structural chemistry . Volume 1 : tailoring properties of inorganic materials and their applications / / edited by Rong Cao
| Advanced structural chemistry . Volume 1 : tailoring properties of inorganic materials and their applications / / edited by Rong Cao |
| Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2021] |
| Descrizione fisica | 1 online resource (1,066 pages) |
| Disciplina | 541.22 |
| Soggetto topico | Inorganic compounds - Structure |
| ISBN |
3-527-83174-6
3-527-83173-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910831068303321 |
| Weinheim, Germany : , : Wiley-VCH, , [2021] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Aquaphotomics : Exploring Water Molecular Systems in Nature / / Roumiana Tsenkova, Jelena Muncan
| Aquaphotomics : Exploring Water Molecular Systems in Nature / / Roumiana Tsenkova, Jelena Muncan |
| Autore | Tsenkova Roumiana |
| Pubbl/distr/stampa | Basel : , : MDPI, , 2023 |
| Descrizione fisica | 1 online resource |
| Disciplina | 541.22 |
| Soggetto topico | Molecular theory |
| ISBN | 3-0365-7119-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910683368203321 |
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Tsenkova Roumiana
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| Basel : , : MDPI, , 2023 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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