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Liquid phase oxidation via heterogeneous catalysis [[electronic resource] ] : organic synthesis and industrial applications / / edited by Mario G. Clerici, Oxana A. Kholdeeva
Liquid phase oxidation via heterogeneous catalysis [[electronic resource] ] : organic synthesis and industrial applications / / edited by Mario G. Clerici, Oxana A. Kholdeeva
Pubbl/distr/stampa Hoboken, N.J., : Wiley, 2013
Descrizione fisica 1 online resource (548 p.)
Disciplina 541/.393
Altri autori (Persone) ClericiMario G
KholdeevaOxana A
Soggetto topico Oxidation
Oxidation - Industrial applications
Heterogeneous catalysis
Heterogeneous catalysis - Industrial applications
ISBN 1-118-35675-6
1-118-35676-4
1-118-35674-8
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Liquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis And Industrial Applications; Contents; Preface; Contributors; Abbreviations; 1 Environmentally Benign Oxidants; 1.1 Introduction; 1.2 Oxygen (Air); 1.3 Alkylhydroperoxides; 1.4 Hydrogen Peroxide; 1.5 Conclusions; References; 2 Oxidation Reactions Catalyzed by Transition-Metal-Substituted Zeolites; 2.1 Introduction; 2.2 Synthesis and Characterization of Zeolites; 2.2.1 Isomorphous Metal Substitution; 2.2.2 Synthesis of Titanium Silicalite-1 (TS-1); 2.2.3 Characterization of Titanium Silicalite-1 (TS-1)
2.2.4 Ti-Beta, Synthesis and Characterization2.2.5 Other Ti Zeolites; 2.2.6 Other Metal Zeolites; 2.3 Catalytic Properties; 2.3.1 Hydroxylation of Alkanes; 2.3.2 Hydroxylation of Aromatic Compounds; 2.3.3 Oxidation of Olefinic Compounds; 2.3.4 Oxidation of Alcohol and Ether Compounds; 2.3.5 Reactions of Carbonyl Compounds; 2.3.6 Oxidation of N-Compounds; 2.3.7 Oxidation of S-Compounds; 2.4 Mechanistic Aspects; 2.4.1 The Nature of Active Species; 2.4.2 Hydroxylation; 2.4.3 Epoxidation; 2.4.4 Oxidation of Alcohols; 2.4.5 Ammoximation; 2.4.6 Decomposition of Hydrogen Peroxide
2.4.7 Active Species, Adsorption and Catalytic Activity2.5 Stability of Metal-Substituted Zeolites to Reaction Conditions; 2.6 Conclusions; References; 3 Selective Catalytic Oxidation over Ordered Nanoporous Metallo-Aluminophosphates; 3.1 Introduction; 3.2 Synthesis; 3.2.1 Microporous Aluminophosphates; 3.2.2 Mesoporous Aluminophosphates; 3.3 Characterization; 3.4 Catalytic Properties; 3.4.1 Oxidation of Hydrocarbons; 3.4.2 Oxidation of Olefins; 3.4.3 Oxidation of Alcohols; 3.4.4 Oxidation of Phenols; 3.4.5 Ammoximation and Ammoxidation; 3.4.6 Baeyer-Villiger Oxidation
3.4.7 Oxidation of Heterocycles3.5 Mechanistic Aspects; 3.6 Catalysts Stability; 3.7 Conclusion; References; 4 Selective Oxidations Catalyzed by Mesoporous Metal Silicates; 4.1 Introduction; 4.2 Synthesis and Characterization; 4.2.1 General Synthetic Approaches; 4.2.2 Characterization Techniques; 4.2.3 Sol-Gel Synthesis of Amorphous Mixed Oxides; 4.2.4 Thermolytic Molecular Precursor Method; 4.2.5 Templated Synthesis of Ordered Metal Silicates; 4.2.6 Postsynthesis Modifications; 4.2.7 Organic-Inorganic Hybrid Materials; 4.3 Catalytic Properties; 4.3.1 Oxidation of Alkanes
4.3.2 Oxidation of Aromatic Compounds4.3.3 Oxidation of Olefins; 4.3.4 Oxidation of Alcohols; 4.3.5 Oxidation of Ketones and Aldehydes; 4.3.6 Oxidation of S-compounds; 4.3.7 Oxidation of Amines; 4.4 Mechanistic Aspects; 4.5 Stability; 4.5.1 Mechanisms of Deactivation; 4.5.2 Solving Problem of Hydrothermal Stability; 4.5.3 Hydrothermally Stable Catalysts: Scope and Limitations; 4.6 Conclusions and Outlook; References; 5 Liquid Phase Oxidation of Organic Compounds by Supported Metal-Based Catalysts with a Focus on Gold; 5.1 Introduction; 5.2 Catalyst Preparation and Characterization
5.3 Catalytic Properties
Record Nr. UNINA-9910141612203321
Hoboken, N.J., : Wiley, 2013
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Liquid phase oxidation via heterogeneous catalysis : organic synthesis and industrial applications / / edited by Mario G. Clerici, Oxana A. Kholdeeva
Liquid phase oxidation via heterogeneous catalysis : organic synthesis and industrial applications / / edited by Mario G. Clerici, Oxana A. Kholdeeva
Edizione [1st ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley, 2013
Descrizione fisica 1 online resource (548 p.)
Disciplina 541/.393
Altri autori (Persone) ClericiMario G
KholdeevaOxana A
Soggetto topico Oxidation
Oxidation - Industrial applications
Heterogeneous catalysis
Heterogeneous catalysis - Industrial applications
ISBN 9781118356753
1118356756
9781118356760
1118356764
9781118356746
1118356748
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Liquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis And Industrial Applications; Contents; Preface; Contributors; Abbreviations; 1 Environmentally Benign Oxidants; 1.1 Introduction; 1.2 Oxygen (Air); 1.3 Alkylhydroperoxides; 1.4 Hydrogen Peroxide; 1.5 Conclusions; References; 2 Oxidation Reactions Catalyzed by Transition-Metal-Substituted Zeolites; 2.1 Introduction; 2.2 Synthesis and Characterization of Zeolites; 2.2.1 Isomorphous Metal Substitution; 2.2.2 Synthesis of Titanium Silicalite-1 (TS-1); 2.2.3 Characterization of Titanium Silicalite-1 (TS-1)
2.2.4 Ti-Beta, Synthesis and Characterization2.2.5 Other Ti Zeolites; 2.2.6 Other Metal Zeolites; 2.3 Catalytic Properties; 2.3.1 Hydroxylation of Alkanes; 2.3.2 Hydroxylation of Aromatic Compounds; 2.3.3 Oxidation of Olefinic Compounds; 2.3.4 Oxidation of Alcohol and Ether Compounds; 2.3.5 Reactions of Carbonyl Compounds; 2.3.6 Oxidation of N-Compounds; 2.3.7 Oxidation of S-Compounds; 2.4 Mechanistic Aspects; 2.4.1 The Nature of Active Species; 2.4.2 Hydroxylation; 2.4.3 Epoxidation; 2.4.4 Oxidation of Alcohols; 2.4.5 Ammoximation; 2.4.6 Decomposition of Hydrogen Peroxide
2.4.7 Active Species, Adsorption and Catalytic Activity2.5 Stability of Metal-Substituted Zeolites to Reaction Conditions; 2.6 Conclusions; References; 3 Selective Catalytic Oxidation over Ordered Nanoporous Metallo-Aluminophosphates; 3.1 Introduction; 3.2 Synthesis; 3.2.1 Microporous Aluminophosphates; 3.2.2 Mesoporous Aluminophosphates; 3.3 Characterization; 3.4 Catalytic Properties; 3.4.1 Oxidation of Hydrocarbons; 3.4.2 Oxidation of Olefins; 3.4.3 Oxidation of Alcohols; 3.4.4 Oxidation of Phenols; 3.4.5 Ammoximation and Ammoxidation; 3.4.6 Baeyer-Villiger Oxidation
3.4.7 Oxidation of Heterocycles3.5 Mechanistic Aspects; 3.6 Catalysts Stability; 3.7 Conclusion; References; 4 Selective Oxidations Catalyzed by Mesoporous Metal Silicates; 4.1 Introduction; 4.2 Synthesis and Characterization; 4.2.1 General Synthetic Approaches; 4.2.2 Characterization Techniques; 4.2.3 Sol-Gel Synthesis of Amorphous Mixed Oxides; 4.2.4 Thermolytic Molecular Precursor Method; 4.2.5 Templated Synthesis of Ordered Metal Silicates; 4.2.6 Postsynthesis Modifications; 4.2.7 Organic-Inorganic Hybrid Materials; 4.3 Catalytic Properties; 4.3.1 Oxidation of Alkanes
4.3.2 Oxidation of Aromatic Compounds4.3.3 Oxidation of Olefins; 4.3.4 Oxidation of Alcohols; 4.3.5 Oxidation of Ketones and Aldehydes; 4.3.6 Oxidation of S-compounds; 4.3.7 Oxidation of Amines; 4.4 Mechanistic Aspects; 4.5 Stability; 4.5.1 Mechanisms of Deactivation; 4.5.2 Solving Problem of Hydrothermal Stability; 4.5.3 Hydrothermally Stable Catalysts: Scope and Limitations; 4.6 Conclusions and Outlook; References; 5 Liquid Phase Oxidation of Organic Compounds by Supported Metal-Based Catalysts with a Focus on Gold; 5.1 Introduction; 5.2 Catalyst Preparation and Characterization
5.3 Catalytic Properties
Record Nr. UNINA-9910822251303321
Hoboken, N.J., : Wiley, 2013
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Modern oxidation methods / / edited by Jan-Erling Backvall
Modern oxidation methods / / edited by Jan-Erling Backvall
Edizione [2nd, completely rev. and enlarged ed.]
Pubbl/distr/stampa Weinheim, Germany, : Wiley-VCH, c2010
Descrizione fisica 1 online resource (483 p.)
Disciplina 541/.393
Altri autori (Persone) BackvallJan-Erling
Soggetto topico Oxidation - Methodology
Chemistry
ISBN 9786612849541
9783527632275
3527632271
9781282849549
1282849549
9783527632039
3527632034
9783527632046
3527632042
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Modern Oxidation Methods; Contents; Preface; List of Contributors; 1 Recent Developments in Metal-catalyzed Dihydroxylation of Alkenes; 2 Transition Metal-Catalyzed Epoxidation of Alkenes; 3 Organocatalytic Oxidation. Ketone-Catalyzed Asymmetric Epoxidation of Alkenes and Synthetic Applications; 4 Catalytic Oxidations with Hydrogen Peroxide in Fluorinated Alcohol Solvents; 5 Modern Oxidation of Alcohols using Environmentally Benign Oxidants; 6 Aerobic Oxidations and Related Reactions Catalyzed by N-Hydroxyphthalimide; 7 Ruthenium-Catalyzed Oxidation for Organic Synthesis
8 Selective Oxidation of Amines and Sulfides9 Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates; 10 Oxidation of Carbonyl Compounds; 11 Manganese-Catalyzed Oxidation with Hydrogen Peroxide; 12 Biooxidation with Cytochrome P450 Monooxygenases; Index
Record Nr. UNINA-9911019886203321
Weinheim, Germany, : Wiley-VCH, c2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Redox biochemistry [[electronic resource] /] / edited by Ruma Banerjee ; associate editors, Donald Becker ... [et al.]
Redox biochemistry [[electronic resource] /] / edited by Ruma Banerjee ; associate editors, Donald Becker ... [et al.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley-Interscience, c2008
Descrizione fisica 1 online resource (339 p.)
Disciplina 541/.393
Altri autori (Persone) BanerjeeRuma
Soggetto topico Oxidation-reduction reaction - Physiological effect
ISBN 1-281-22150-3
9786611221508
0-470-17733-0
0-470-17732-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto REDOX BIOCHEMISTRY; CONTENTS; Contributors; List of Abbreviations; Preface; 1. Redox Metabolism and Life; 1.1. Redox Biochemistry and the Evolution of Life; 1.2. Global Redox Cycles; 1.3. Major Bioenergetic Cycles; 1.3.A. Photosynthesis; 1.3.B. Aerobic Respiration; 2. Antioxidant Molecules and Redox Cofactors; 2.1. Glutathione; 2.1.A. Biological Functions; 2.1.B. Biosynthesis; 2.1.C. Degradation; 2.1.D. Other Thiol-Based Redox Buffers; 2.2. Ascorbate; 2.2.A. Ascorbate Chemistry; 2.2.B. Ascorbate Biosynthesis; 2.2.C. Ascorbate Recycling; 2.2.D. Ascorbate Transport
2.2.E. Importance of Ascorbate in Stress and Disease2.3. Other Antioxidants; 2.3.A. Lipid-Soluble Antioxidants; 2.3.B. Water-Soluble Antioxidants; 2.3.C. Antioxidants and Human Health; 2.4. Redox Coenzymes; 2.4.A. Flavin; 2.4.B. NAD; 2.4.C. Quinones; 2.4.D. Pterins and Molybdopterins; 2.4.E. Folic Acid; 3. Antioxidant Enzymes; 3.1. ROS-Dependent Enzymes; 3.1.A. Catalase; 3.1.B. Superoxide Dismutase; 3.1.C. Peroxiredoxins; 3.1.D. Alkyl Hydroperoxide Reductases; 3.2. The Thioredoxin System; 3.2.A. Thioredoxin; 3.2.B. Thioredoxin Reductase; 3.3. The Glutathione System
3.3.A. Glutathione Reductase3.3.B. Glutaredoxin (Thioltransferase); 3.4. Repair Enzymes; 3.4.A. Methionine Sulfoxide Reductases; 3.4.B. DNA Repair Enzymes; 3.4.C. Sulfiredoxins; 3.5. Detoxification Enzymes; 3.5.A. Cytochrome P450 Enzymes: Structure, Function, and Mechanism; 3.5.B. GSH Transferases; 3.6. Oxidative Folding; 3.6.A. Disulfide Bond Formation in Bacteria; 3.6.B. Disulfide Bond Formation in Eukaryotes; 3.7. Other Antioxidant Enzymes; 3.7.A. Selenoproteins; 3.7.B. Heme Oxygenase; 4. Redox Regulation of Physiological Processes
4.1. Reactive Oxygen, Nitrogen, and Thiol-Based Signal Transduction4.1.A. Nitric Oxide Signaling; 4.1.B. Carbon Monoxide Signaling; 4.1.C. Superoxide and Hydrogen Peroxide; 4.1.D. Other Novel Redox Molecules; 4.2. Role of Nitric Oxide Synthases in Redox Signaling; 4.2.A. Characterization of the Nitric Oxide Synthases; 4.2.B. Regulation of Nitric Oxide Synthases by Intrinsic Elements; 4.2.C. Extrinsic Regulation of Nitric Oxide Synthases; 4.2.D. Interactions of NO with Other Proteins and Enzymes; 4.3. Redox Regulation of Genes; 4.3.A. MAP Kinase/Cell Cycle
4.3.B. Redox Control of Gene Expression4.3.C. Peptide Editing and Thiol-Mediated Redox Regulation; 4.4. Redox Regulation of Apoptosis; 4.4.A. Apoptotic Pathways; 4.4.B. Reactive Oxygen Species and Apoptosis; 4.5. Metal Homeostasis; 4.5.A. Physiological Significance of Metal Metabolism; 4.5.B. Metal Uptake from the Extracellular Environment; 4.5.C. Intracellular Metal Distribution by Target-Specific Chaperones; 4.5.D. Subcellular Membrane Metal Transporters; 4.5.E. Heme and Iron-Sulfur Cluster Synthesis; 4.5.F. Cellular Storage; 4.5.G. Metal Export; 4.5.H. Regulation of Metal Metabolism
4.5.I. Genetic Disorders in Metal Metabolism
Record Nr. UNINA-9910144011103321
Hoboken, N.J., : Wiley-Interscience, c2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Redox biochemistry / / edited by Ruma Banerjee ; associate editors, Donald Becker ... [et al.]
Redox biochemistry / / edited by Ruma Banerjee ; associate editors, Donald Becker ... [et al.]
Edizione [1st ed.]
Pubbl/distr/stampa Hoboken, N.J., : Wiley-Interscience, c2008
Descrizione fisica 1 online resource (339 p.)
Disciplina 541/.393
Altri autori (Persone) BanerjeeRuma
Soggetto topico Oxidation-reduction reaction - Physiological effect
ISBN 9786611221508
9781281221506
1281221503
9780470177334
0470177330
9780470177327
0470177322
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto REDOX BIOCHEMISTRY; CONTENTS; Contributors; List of Abbreviations; Preface; 1. Redox Metabolism and Life; 1.1. Redox Biochemistry and the Evolution of Life; 1.2. Global Redox Cycles; 1.3. Major Bioenergetic Cycles; 1.3.A. Photosynthesis; 1.3.B. Aerobic Respiration; 2. Antioxidant Molecules and Redox Cofactors; 2.1. Glutathione; 2.1.A. Biological Functions; 2.1.B. Biosynthesis; 2.1.C. Degradation; 2.1.D. Other Thiol-Based Redox Buffers; 2.2. Ascorbate; 2.2.A. Ascorbate Chemistry; 2.2.B. Ascorbate Biosynthesis; 2.2.C. Ascorbate Recycling; 2.2.D. Ascorbate Transport
2.2.E. Importance of Ascorbate in Stress and Disease2.3. Other Antioxidants; 2.3.A. Lipid-Soluble Antioxidants; 2.3.B. Water-Soluble Antioxidants; 2.3.C. Antioxidants and Human Health; 2.4. Redox Coenzymes; 2.4.A. Flavin; 2.4.B. NAD; 2.4.C. Quinones; 2.4.D. Pterins and Molybdopterins; 2.4.E. Folic Acid; 3. Antioxidant Enzymes; 3.1. ROS-Dependent Enzymes; 3.1.A. Catalase; 3.1.B. Superoxide Dismutase; 3.1.C. Peroxiredoxins; 3.1.D. Alkyl Hydroperoxide Reductases; 3.2. The Thioredoxin System; 3.2.A. Thioredoxin; 3.2.B. Thioredoxin Reductase; 3.3. The Glutathione System
3.3.A. Glutathione Reductase3.3.B. Glutaredoxin (Thioltransferase); 3.4. Repair Enzymes; 3.4.A. Methionine Sulfoxide Reductases; 3.4.B. DNA Repair Enzymes; 3.4.C. Sulfiredoxins; 3.5. Detoxification Enzymes; 3.5.A. Cytochrome P450 Enzymes: Structure, Function, and Mechanism; 3.5.B. GSH Transferases; 3.6. Oxidative Folding; 3.6.A. Disulfide Bond Formation in Bacteria; 3.6.B. Disulfide Bond Formation in Eukaryotes; 3.7. Other Antioxidant Enzymes; 3.7.A. Selenoproteins; 3.7.B. Heme Oxygenase; 4. Redox Regulation of Physiological Processes
4.1. Reactive Oxygen, Nitrogen, and Thiol-Based Signal Transduction4.1.A. Nitric Oxide Signaling; 4.1.B. Carbon Monoxide Signaling; 4.1.C. Superoxide and Hydrogen Peroxide; 4.1.D. Other Novel Redox Molecules; 4.2. Role of Nitric Oxide Synthases in Redox Signaling; 4.2.A. Characterization of the Nitric Oxide Synthases; 4.2.B. Regulation of Nitric Oxide Synthases by Intrinsic Elements; 4.2.C. Extrinsic Regulation of Nitric Oxide Synthases; 4.2.D. Interactions of NO with Other Proteins and Enzymes; 4.3. Redox Regulation of Genes; 4.3.A. MAP Kinase/Cell Cycle
4.3.B. Redox Control of Gene Expression4.3.C. Peptide Editing and Thiol-Mediated Redox Regulation; 4.4. Redox Regulation of Apoptosis; 4.4.A. Apoptotic Pathways; 4.4.B. Reactive Oxygen Species and Apoptosis; 4.5. Metal Homeostasis; 4.5.A. Physiological Significance of Metal Metabolism; 4.5.B. Metal Uptake from the Extracellular Environment; 4.5.C. Intracellular Metal Distribution by Target-Specific Chaperones; 4.5.D. Subcellular Membrane Metal Transporters; 4.5.E. Heme and Iron-Sulfur Cluster Synthesis; 4.5.F. Cellular Storage; 4.5.G. Metal Export; 4.5.H. Regulation of Metal Metabolism
4.5.I. Genetic Disorders in Metal Metabolism
Record Nr. UNINA-9910829111303321
Hoboken, N.J., : Wiley-Interscience, c2008
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui