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Chemical thermodynamics : advanced applications / / J. Bevan Ott and Juliana Boerio-Goates
| Chemical thermodynamics : advanced applications / / J. Bevan Ott and Juliana Boerio-Goates |
| Autore | Ott J. Bevan <1934-> |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | London, UK ; ; San Diego, : Academic Press, c2000 |
| Descrizione fisica | 1 online resource (689 p.) |
| Disciplina | 541/.369 |
| Altri autori (Persone) | Boerio-GoatesJuliana |
| Soggetto topico |
Thermodynamics
Chemistry, Physical and theoretical |
| ISBN |
9786611038465
9781281038463 1281038466 9780080500980 0080500986 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Chemical Thermodynamics: Principles and Applications; Copyright Page; Contents; Preface to the Two-Volume Series; Preface to the First Volume; Chapter 1. Introduction; 1.1 Thermodynamics - A Pre-eminent Example of an Exact Science; 1.2 The Language of Thermodynamics; 1.3 Thermodynamic Variables; 1.4 The Mathematics of Thermodynamics; 1.5 Derivation of Thermodynamic Equations using the Properties of the Exact Differential; 1.6 Calculation of Changes in the Thermodynamic Variable; 1.7 Use of Units; References; Chapter 2. The First and Second Laws of Thermodynamics
2.1 The First Law of Thermodynamics2.2 The Second Law of Thermodynamics; 2.3 Implications of the Laws; References; Chapter 3. Thermodynamic Relationships and Applications; 3.1 The Gibbs Equations; 3.2 Partial Differential Relationships; 3.3 Applications of the Differential Relationships; 3.4 Relationship Between Free Energy and Work; References; Chapter 4. The Third Law and Absolute Entropy Measurements; 4.1 Verification of the Third Law; 4.2 Exceptions to the Third Law; 4.3 Implications and Applications of the Third Law; 4.4 Production of Low Temperatures and the Inaccessibility of Absolute 4.5 Thermodynamic Functions References; Chapter 5. The Chemical Potential and Equilibrium; 5.1 Composition as a Variable; 5.2 The Chemical Potential; 5.3 Partial Molar Properties; 5.4 The Gibbs-Duhem Equation; 5.5 Determination of Partial Molar Properties; 5.6 Criteria for Equilibrium; References; Chapter 6. Fugacity, Activity, and Standard States; 6.1 Fugacity; 6.2 The Activity; 6.3 Standard States; 6.4 Activities of Electrolyte Solutions; 6.5 Determination of Activity; References; Chapter 7. The Thermodynamic Properties of Solutions 7.1 Change in the Thermodynamic Properties of Nonelectrolyte Solutions due to the Mixing Process7.2 Calculation of the Thermodynamic Properties of Strong Electrolyte Solutes: The Debye - Hückel Theory; 7.3 Relative Partial Molar and Apparent Relative Partial Molar Thermal Properties; 7.4 The Osmotic Pressure; References; Chapter 8. The Equilibrium Condition Applied to Phase Equilibria; 8.1 Phase Equilibria for Pure Substances; 8.2 Phase Equilibria for Mixtures; References; Chapter 9. The Equilibrium Condition Applied to Chemical Processes; 9.1 The Equilibrium Constant 9.2 Enthalpies and Gibbs Free Energies of Formation9.3 Examples of Chemical Equilibrium Calculations; 9.4 Electrochemical Cells; References; Chapter 10. Statistical Thermodynamics; 10.1 Energy Levels of an Ideal Gas Molecule; 10.2 Distribution of Energy Among Energy Levels; 10.3 The Boltzmann Distribution Law; 10.4 The Partition Function; 10.5 Relationship Between the Partition Function and the Thermodynamic Properties; 10.6 Evaluation of the Partition Function for the Ideal Gas; 10.7 Calculation of the Thermodynamic Properties of the Ideal Gas 10.8 Calculation of the Thermodynamic Properties of Solids |
| Record Nr. | UNINA-9910958763503321 |
Ott J. Bevan <1934->
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| London, UK ; ; San Diego, : Academic Press, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Chemical thermodynamics of materials : macroscopic and microscopic aspects / / Svein Stolen, Tor Grande ; with a chapter on thermodynamics and materials modelling by Neil L. Allan
| Chemical thermodynamics of materials : macroscopic and microscopic aspects / / Svein Stolen, Tor Grande ; with a chapter on thermodynamics and materials modelling by Neil L. Allan |
| Autore | Stlen Svein |
| Pubbl/distr/stampa | Hoboken, NJ, : J. Wiley, c2004 |
| Descrizione fisica | 1 online resource (410 p.) |
| Disciplina | 541/.369 |
| Altri autori (Persone) | GrandeTor |
| Soggetto topico | Thermodynamics |
| ISBN |
9786610269341
9781280269349 1280269340 9780470092675 047009267X 9780470092682 0470092688 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Chemical Thermodynamics of Materials; Contents; Preface; 1 Thermodynamic foundations; 1.1 Basic concepts; Thermodynamic systems; Thermodynamic variables; Thermodynamic processes and equilibrium; 1.2 The first law of thermodynamics; Conservation of energy; Heat capacity and definition of enthalpy; Reference and standard states; Enthalpy of physical transformations and chemical reactions; 1.3 The second and third laws of thermodynamics; The second law and the definition of entropy; Reversible and non-reversible processes
Conditions for equilibrium and the definition of Helmholtz and Gibbs energiesMaximum work and maximum non-expansion work; The variation of entropy with temperature; The third law of thermodynamics; The Maxwell relations; Properties of the Gibbs energy; 1.4 Open systems; Definition of the chemical potential; Conditions for equilibrium in a heterogeneous system; Partial molar properties; The Gibbs-Duhem equation; References; Further reading; 2 Single-component systems; 2.1 Phases, phase transitions and phase diagrams; Phases and phase transitions; Slopes of the phase boundaries Phase diagrams and Gibbs phase ruleField-induced phase transitions; 2.2 The gas phase; Ideal gases; Real gases and the definition of fugacity; Equations of state of real gases; 2.3 Condensed phases; Variation of the standard chemical potential with temperature; Representation of transitions; Equations of state; References; Further reading; 3 Solution thermodynamics; 3.1 Fundamental definitions; Measures of composition; Mixtures of gases; Solid and liquid solutions - the definition of chemical activity; 3.2 Thermodynamics of solutions; Definition of mixing properties; Ideal solutions Excess functions and deviation from ideality3.3 Standard states; Henry's and Raoult's laws; Raoultian and Henrian standard states; 3.4 Analytical solution models; Dilute solutions; Solution models; Derivation of partial molar properties; 3.5 Integration of the Gibbs-Duhem equation; References; Further reading; 4 Phase diagrams; 4.1 Binary phase diagrams from thermodynamics; Gibbs phase rule; Conditions for equilibrium; Ideal and nearly ideal binary systems; Simple eutectic systems; Regular solution modelling; Invariant phase equilibria; Formation of intermediate phases Melting temperature: depression or elevation?Minimization of Gibbs energy and heterogeneous phase equilibria; 4.2 Multi-component systems; Ternary phase diagrams; Quaternary systems; Ternary reciprocal systems; 4.3 Predominance diagrams; References; Further reading; 5 Phase stability; 5.1 Supercooling of liquids - superheating of crystals; 5.2 Fluctuations and instability; The driving force for chemical reactions: definition of affinity; Stability with regard to infinitesimal fluctuations; Compositional fluctuations and instability; The van der Waals theory of liquid-gas transitions Pressure-induced amorphization and mechanical instability |
| Record Nr. | UNINA-9911019633803321 |
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Stlen Svein
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| Hoboken, NJ, : J. Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Thermodynamics and introductory statistical mechanics [[electronic resource] /] / Bruno Linder
| Thermodynamics and introductory statistical mechanics [[electronic resource] /] / Bruno Linder |
| Autore | Linder Bruno |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2004 |
| Descrizione fisica | 1 online resource (227 p.) |
| Disciplina |
541
541.369 541/.369 |
| Soggetto topico |
Thermodynamics
Statistical mechanics |
| ISBN |
1-280-26505-1
9786610265053 0-470-35315-5 0-471-68174-1 0-471-68175-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THERMODYNAMICS AND INTRODUCTORY STATISTICAL MECHANICS; CONTENTS; PREFACE; 1 INTRODUCTORY REMARKS; 1.1 Scope and Objectives; 1.2 Level of Course; 1.3 Course Outline; 1.4 Books; PART I THERMODYNAMICS; 2 BASIC CONCEPTS AND DEFINITIONS; 2.1 Systems and Surroundings; 2.2 State Variables and Thermodynamic Properties; 2.3 Intensive and Extensive Variables; 2.4 Homogeneous and Heterogeneous Systems, Phases; 2.5 Work; 2.6 Reversible and Quasi-Static Processes; 2.6.1 Quasi-Static Process; 2.6.2 Reversible Process; 2.7 Adiabatic and Diathermal Walls; 2.8 Thermal Contact and Thermal Equilibrium
3 THE LAWS OF THERMODYNAMICS I3.1 The Zeroth Law-Temperature; 3.2 The First Law-Traditional Approach; 3.3 Mathematical Interlude I: Exact and Inexact Differentials; 3.4 The First Law-Axiomatic Approach; 3.5 Some Applications of the First Law; 3.5.1 Heat Capacity; 3.5.2 Heat and Internal Energy; 3.5.3 Heat and Enthalpy; 3.6 Mathematical Interlude II: Partial Derivatives; 3.6.1 Relations Between Partials of Dependent Variables; 3.6.2 Relations Between Partials with Different Subscripts; 3.7 Other Applications of the First Law; 3.7.1 C(P) - C(V); 3.7.2 Isothermal Change, Ideal Gas 3.7.3 Adiabatic Change, Ideal Gas3.7.4 The Joule and the Joule-Thomson Coefficients; 4 THE LAWS OF THERMODYNAMICS II; 4.1 The Second Law-Traditional Approach; 4.2 Engine Efficiency: Absolute Temperature; 4.2.1 Ideal Gas; 4.2.2 Coupled Cycles; 4.3 Generalization: Arbitrary Cycle; 4.4 The Clausius Inequality; 4.5 The Second Law-Axiomatic Approach (Carathéodory); 4.6 Mathematical Interlude III: Pfaffian Differential Forms; 4.7 Pfaffian Expressions in Two Variables; 4.8 Pfaffian Expressions in More Than Two Dimensions; 4.9 Carathéodory's Theorem; 4.10 Entropy-Axiomatic Approach 4.11 Entropy Changes for Nonisolated Systems4.12 Summary; 4.13 Some Applications of the Second Law; 4.13.1 Reversible Processes (PV Work Only); 4.13.2 Irreversible Processes; 5 USEFUL FUNCTIONS: THE FREE ENERGY FUNCTIONS; 5.1 Mathematical Interlude IV: Legendre Transformations; 5.1.1 Application of the Legendre Transformation; 5.2 Maxwell Relations; 5.3 The Gibbs-Helmholtz Equations; 5.4 Relation of DA and DG to Work: Criteria for Spontaneity; 5.4.1 Expansion and Other Types of Work; 5.4.2 Comments; 5.5 Generalization to Open Systems and Systems of Variable Composition 5.5.1 Single Component System5.5.2 Multicomponent Systems; 5.6 The Chemical Potential; 5.7 Mathematical Interlude V: Euler's Theorem; 5.8 Thermodynamic Potentials; 6 THE THIRD LAW OF THERMODYNAMICS; 6.1 Statements of the Third Law; 6.2 Additional Comments and Conclusions; 7 GENERAL CONDITIONS FOR EQUILIBRIUM AND STABILITY; 7.1 Virtual Variations; 7.2 Thermodynamic Potentials-Inequalities; 7.3 Equilibrium Condition From Energy; 7.3.1 Boundary Fully Heat Conducting, Deformable, Permeable (Normal System); 7.3.2 Special Cases: Boundary Semi-Heat Conducting, Semi-Deformable, or Semi-Permeable 7.4 Equilibrium Conditions From Other Potentials |
| Record Nr. | UNINA-9910146054503321 |
|
Linder Bruno
|
||
| Hoboken, N.J., : Wiley-Interscience, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Thermodynamics and introductory statistical mechanics [[electronic resource] /] / Bruno Linder
| Thermodynamics and introductory statistical mechanics [[electronic resource] /] / Bruno Linder |
| Autore | Linder Bruno |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2004 |
| Descrizione fisica | 1 online resource (227 p.) |
| Disciplina |
541
541.369 541/.369 |
| Soggetto topico |
Thermodynamics
Statistical mechanics |
| ISBN |
1-280-26505-1
9786610265053 0-470-35315-5 0-471-68174-1 0-471-68175-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THERMODYNAMICS AND INTRODUCTORY STATISTICAL MECHANICS; CONTENTS; PREFACE; 1 INTRODUCTORY REMARKS; 1.1 Scope and Objectives; 1.2 Level of Course; 1.3 Course Outline; 1.4 Books; PART I THERMODYNAMICS; 2 BASIC CONCEPTS AND DEFINITIONS; 2.1 Systems and Surroundings; 2.2 State Variables and Thermodynamic Properties; 2.3 Intensive and Extensive Variables; 2.4 Homogeneous and Heterogeneous Systems, Phases; 2.5 Work; 2.6 Reversible and Quasi-Static Processes; 2.6.1 Quasi-Static Process; 2.6.2 Reversible Process; 2.7 Adiabatic and Diathermal Walls; 2.8 Thermal Contact and Thermal Equilibrium
3 THE LAWS OF THERMODYNAMICS I3.1 The Zeroth Law-Temperature; 3.2 The First Law-Traditional Approach; 3.3 Mathematical Interlude I: Exact and Inexact Differentials; 3.4 The First Law-Axiomatic Approach; 3.5 Some Applications of the First Law; 3.5.1 Heat Capacity; 3.5.2 Heat and Internal Energy; 3.5.3 Heat and Enthalpy; 3.6 Mathematical Interlude II: Partial Derivatives; 3.6.1 Relations Between Partials of Dependent Variables; 3.6.2 Relations Between Partials with Different Subscripts; 3.7 Other Applications of the First Law; 3.7.1 C(P) - C(V); 3.7.2 Isothermal Change, Ideal Gas 3.7.3 Adiabatic Change, Ideal Gas3.7.4 The Joule and the Joule-Thomson Coefficients; 4 THE LAWS OF THERMODYNAMICS II; 4.1 The Second Law-Traditional Approach; 4.2 Engine Efficiency: Absolute Temperature; 4.2.1 Ideal Gas; 4.2.2 Coupled Cycles; 4.3 Generalization: Arbitrary Cycle; 4.4 The Clausius Inequality; 4.5 The Second Law-Axiomatic Approach (Carathéodory); 4.6 Mathematical Interlude III: Pfaffian Differential Forms; 4.7 Pfaffian Expressions in Two Variables; 4.8 Pfaffian Expressions in More Than Two Dimensions; 4.9 Carathéodory's Theorem; 4.10 Entropy-Axiomatic Approach 4.11 Entropy Changes for Nonisolated Systems4.12 Summary; 4.13 Some Applications of the Second Law; 4.13.1 Reversible Processes (PV Work Only); 4.13.2 Irreversible Processes; 5 USEFUL FUNCTIONS: THE FREE ENERGY FUNCTIONS; 5.1 Mathematical Interlude IV: Legendre Transformations; 5.1.1 Application of the Legendre Transformation; 5.2 Maxwell Relations; 5.3 The Gibbs-Helmholtz Equations; 5.4 Relation of DA and DG to Work: Criteria for Spontaneity; 5.4.1 Expansion and Other Types of Work; 5.4.2 Comments; 5.5 Generalization to Open Systems and Systems of Variable Composition 5.5.1 Single Component System5.5.2 Multicomponent Systems; 5.6 The Chemical Potential; 5.7 Mathematical Interlude V: Euler's Theorem; 5.8 Thermodynamic Potentials; 6 THE THIRD LAW OF THERMODYNAMICS; 6.1 Statements of the Third Law; 6.2 Additional Comments and Conclusions; 7 GENERAL CONDITIONS FOR EQUILIBRIUM AND STABILITY; 7.1 Virtual Variations; 7.2 Thermodynamic Potentials-Inequalities; 7.3 Equilibrium Condition From Energy; 7.3.1 Boundary Fully Heat Conducting, Deformable, Permeable (Normal System); 7.3.2 Special Cases: Boundary Semi-Heat Conducting, Semi-Deformable, or Semi-Permeable 7.4 Equilibrium Conditions From Other Potentials |
| Record Nr. | UNINA-9910830616603321 |
|
Linder Bruno
|
||
| Hoboken, N.J., : Wiley-Interscience, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Thermodynamics and introductory statistical mechanics / / Bruno Linder
| Thermodynamics and introductory statistical mechanics / / Bruno Linder |
| Autore | Linder Bruno |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley-Interscience, c2004 |
| Descrizione fisica | 1 online resource (227 p.) |
| Disciplina | 541/.369 |
| Soggetto topico |
Thermodynamics
Statistical mechanics |
| ISBN |
9786610265053
9781280265051 1280265051 9780470353158 0470353155 9780471681748 0471681741 9780471681755 047168175X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
THERMODYNAMICS AND INTRODUCTORY STATISTICAL MECHANICS; CONTENTS; PREFACE; 1 INTRODUCTORY REMARKS; 1.1 Scope and Objectives; 1.2 Level of Course; 1.3 Course Outline; 1.4 Books; PART I THERMODYNAMICS; 2 BASIC CONCEPTS AND DEFINITIONS; 2.1 Systems and Surroundings; 2.2 State Variables and Thermodynamic Properties; 2.3 Intensive and Extensive Variables; 2.4 Homogeneous and Heterogeneous Systems, Phases; 2.5 Work; 2.6 Reversible and Quasi-Static Processes; 2.6.1 Quasi-Static Process; 2.6.2 Reversible Process; 2.7 Adiabatic and Diathermal Walls; 2.8 Thermal Contact and Thermal Equilibrium
3 THE LAWS OF THERMODYNAMICS I3.1 The Zeroth Law-Temperature; 3.2 The First Law-Traditional Approach; 3.3 Mathematical Interlude I: Exact and Inexact Differentials; 3.4 The First Law-Axiomatic Approach; 3.5 Some Applications of the First Law; 3.5.1 Heat Capacity; 3.5.2 Heat and Internal Energy; 3.5.3 Heat and Enthalpy; 3.6 Mathematical Interlude II: Partial Derivatives; 3.6.1 Relations Between Partials of Dependent Variables; 3.6.2 Relations Between Partials with Different Subscripts; 3.7 Other Applications of the First Law; 3.7.1 C(P) - C(V); 3.7.2 Isothermal Change, Ideal Gas 3.7.3 Adiabatic Change, Ideal Gas3.7.4 The Joule and the Joule-Thomson Coefficients; 4 THE LAWS OF THERMODYNAMICS II; 4.1 The Second Law-Traditional Approach; 4.2 Engine Efficiency: Absolute Temperature; 4.2.1 Ideal Gas; 4.2.2 Coupled Cycles; 4.3 Generalization: Arbitrary Cycle; 4.4 The Clausius Inequality; 4.5 The Second Law-Axiomatic Approach (Carathéodory); 4.6 Mathematical Interlude III: Pfaffian Differential Forms; 4.7 Pfaffian Expressions in Two Variables; 4.8 Pfaffian Expressions in More Than Two Dimensions; 4.9 Carathéodory's Theorem; 4.10 Entropy-Axiomatic Approach 4.11 Entropy Changes for Nonisolated Systems4.12 Summary; 4.13 Some Applications of the Second Law; 4.13.1 Reversible Processes (PV Work Only); 4.13.2 Irreversible Processes; 5 USEFUL FUNCTIONS: THE FREE ENERGY FUNCTIONS; 5.1 Mathematical Interlude IV: Legendre Transformations; 5.1.1 Application of the Legendre Transformation; 5.2 Maxwell Relations; 5.3 The Gibbs-Helmholtz Equations; 5.4 Relation of DA and DG to Work: Criteria for Spontaneity; 5.4.1 Expansion and Other Types of Work; 5.4.2 Comments; 5.5 Generalization to Open Systems and Systems of Variable Composition 5.5.1 Single Component System5.5.2 Multicomponent Systems; 5.6 The Chemical Potential; 5.7 Mathematical Interlude V: Euler's Theorem; 5.8 Thermodynamic Potentials; 6 THE THIRD LAW OF THERMODYNAMICS; 6.1 Statements of the Third Law; 6.2 Additional Comments and Conclusions; 7 GENERAL CONDITIONS FOR EQUILIBRIUM AND STABILITY; 7.1 Virtual Variations; 7.2 Thermodynamic Potentials-Inequalities; 7.3 Equilibrium Condition From Energy; 7.3.1 Boundary Fully Heat Conducting, Deformable, Permeable (Normal System); 7.3.2 Special Cases: Boundary Semi-Heat Conducting, Semi-Deformable, or Semi-Permeable 7.4 Equilibrium Conditions From Other Potentials |
| Record Nr. | UNINA-9911020053503321 |
|
Linder Bruno
|
||
| Hoboken, N.J., : Wiley-Interscience, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||