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Fluxional organometallic and coordination compounds [[electronic resource] /] / edited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer
| Fluxional organometallic and coordination compounds [[electronic resource] /] / edited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer |
| Pubbl/distr/stampa | Hoboken, NJ, : J. Wiley, c2004 |
| Descrizione fisica | 1 online resource (343 p.) |
| Disciplina | 541/.2242 |
| Altri autori (Persone) |
GielenM <1938-> (Marcel)
WillemR (Rudolf) WrackmeyerBernd <1947-> |
| Collana | Physical organometallic chemistry |
| Soggetto topico |
Coordination compounds
Organometallic chemistry Molecular dynamics Nuclear magnetic resonance spectroscopy |
| ISBN |
1-280-27095-0
9786610270958 0-470-30013-2 0-470-85845-1 0-470-85844-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fluxional Organometallic and Coordination Compounds; Contents; Contributors; Series Preface; Preface; 1 Polyhedral Dynamics and the Jahn-Teller Effect; 1 Introduction; 2 Polyhedron Topology; 3 Polyhedral Isomerizations: Microscopic Models; 3.1 Diamond-Square-Diamond Processes; 3.2 Gale Diagrams; 3.3 Generation of Metallaborane Structures by Diamond-Square-Diamond Transformations in Deltahedra; 4 Polyhedral Isomerizations: Macroscopic Models; 4.1 Topological Representations of Polyhedral Isomerizations; 4.2 Topological Representations of Jahn-Teller Distortions; 5 Acknowledgement; 6 References
2 NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes1 Introduction; 2 Discovery Activation Parameters of [1,3]-B Shifts; 3 Fluxional Linear Polyunsaturated Allylboranes; 3.1 2,4-Pentadienyl(di-n-propyl)borane; 3.2 2,4,6-Heptatrienyl(di-n-propyl)borane; 4 Dynamic Behavior of Cyclic Allylboranes; 4.1 Dynamic Equilibria Between 2-(Dialkylboryl)methylenecyclobutanes and 1-(Dialkylboryl)cyclobutenes; 4.2 Dynamic Properties of Cyclopentadienyl and Pentamethylcyclopentadienyl Derivatives of Boron; 4.3 Synthesis and Dynamic Properties of 1-Indenyl(diethyl)borane 4.4 Dynamic Behavior of Cycloheptadienyl(di-n-propyl)borane4.5 Synthesis and Dynamic Properties of Cycloheptatrienyl(di-n-propyl)borane. Equilibrium with 7-(Di-n-propylboryl)norcaradiene; 4.6 Three Independent Dynamic Processes in the Irontricarbonyl Complex of Cycloheptatrienyl(di-n-propyl)borane; 4.7 Cyclooctatetraenyl(di-n-propyl)borane; 4.8 Sigmatropic Migrations and Thermal Rearrangements in Cyclononatetraenyl(di-n-propyl)borane. Comparison with the Dynamic Properties of Cyclononatetraenyl(trimethyl)tin; 4.9 Borotropic Migrations in Phenalenyl(di-n-propyl)borane 24 5 Diverse Chemoselectivity of Cyclic Polyunsaturated Organoboranes5.1 Chemical Behavior of Borane 23; 5.2 Diverse Chemoselectivity of 9-Cyclopentyl-9-borabarbaralane 54e; 6 Conclusion; 7 References; 3 Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR; 1 Introduction; 2 Rotational Isomerism in Amido and Ketimido Complexes; 2.1 Rotational Isomerism in Oxofluoramido Complexes of Tungsten(VI); 2.2 Restricted M-NR(2) Rotation in the Dinuclear Complexes with M(2)(6+) Core (M = W, Mo) 2.3 Features of Dynamic Behavior of Amido Cyclopentadienyl Complexes of Group 5 Transition Metals2.4 Internal Hindered Rotation of Ketimido Ligands; 3 Dynamic Behavior of d(0) Transition Metal Complexes with n-Donor Two-Center Ligands; 3.1 Isomerization of Fluorocomplexes of Group 5-6 with O, N-Two-Center Ligands; 3.2 Isomerism of Transition Metal Complexes with N, N-Two-center Ligands; 3.3 Nature of Bonding of n-Donor Two-center Ligands in d(0) Transition Metal Complexes; 3.4 Mechanism of Internal Hindered Rotation of h(2)-Bound Ligands; 4 Conclusion; 5 References 4 Conformational Mobility in Chelated Square-planar Rh, Ir, Pd, and Pt Complexes |
| Record Nr. | UNINA-9910145018103321 |
| Hoboken, NJ, : J. Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Fluxional organometallic and coordination compounds / / edited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer
| Fluxional organometallic and coordination compounds / / edited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hoboken, NJ, : J. Wiley, c2004 |
| Descrizione fisica | 1 online resource (343 p.) |
| Disciplina | 541/.2242 |
| Altri autori (Persone) |
GielenM <1938-> (Marcel)
WillemR (Rudolf) WrackmeyerBernd <1947-> |
| Collana | Physical organometallic chemistry |
| Soggetto topico |
Coordination compounds
Organometallic chemistry Molecular dynamics Nuclear magnetic resonance spectroscopy |
| ISBN |
1-280-27095-0
9786610270958 0-470-30013-2 0-470-85845-1 0-470-85844-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fluxional Organometallic and Coordination Compounds; Contents; Contributors; Series Preface; Preface; 1 Polyhedral Dynamics and the Jahn-Teller Effect; 1 Introduction; 2 Polyhedron Topology; 3 Polyhedral Isomerizations: Microscopic Models; 3.1 Diamond-Square-Diamond Processes; 3.2 Gale Diagrams; 3.3 Generation of Metallaborane Structures by Diamond-Square-Diamond Transformations in Deltahedra; 4 Polyhedral Isomerizations: Macroscopic Models; 4.1 Topological Representations of Polyhedral Isomerizations; 4.2 Topological Representations of Jahn-Teller Distortions; 5 Acknowledgement; 6 References
2 NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes1 Introduction; 2 Discovery Activation Parameters of [1,3]-B Shifts; 3 Fluxional Linear Polyunsaturated Allylboranes; 3.1 2,4-Pentadienyl(di-n-propyl)borane; 3.2 2,4,6-Heptatrienyl(di-n-propyl)borane; 4 Dynamic Behavior of Cyclic Allylboranes; 4.1 Dynamic Equilibria Between 2-(Dialkylboryl)methylenecyclobutanes and 1-(Dialkylboryl)cyclobutenes; 4.2 Dynamic Properties of Cyclopentadienyl and Pentamethylcyclopentadienyl Derivatives of Boron; 4.3 Synthesis and Dynamic Properties of 1-Indenyl(diethyl)borane 4.4 Dynamic Behavior of Cycloheptadienyl(di-n-propyl)borane4.5 Synthesis and Dynamic Properties of Cycloheptatrienyl(di-n-propyl)borane. Equilibrium with 7-(Di-n-propylboryl)norcaradiene; 4.6 Three Independent Dynamic Processes in the Irontricarbonyl Complex of Cycloheptatrienyl(di-n-propyl)borane; 4.7 Cyclooctatetraenyl(di-n-propyl)borane; 4.8 Sigmatropic Migrations and Thermal Rearrangements in Cyclononatetraenyl(di-n-propyl)borane. Comparison with the Dynamic Properties of Cyclononatetraenyl(trimethyl)tin; 4.9 Borotropic Migrations in Phenalenyl(di-n-propyl)borane 24 5 Diverse Chemoselectivity of Cyclic Polyunsaturated Organoboranes5.1 Chemical Behavior of Borane 23; 5.2 Diverse Chemoselectivity of 9-Cyclopentyl-9-borabarbaralane 54e; 6 Conclusion; 7 References; 3 Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR; 1 Introduction; 2 Rotational Isomerism in Amido and Ketimido Complexes; 2.1 Rotational Isomerism in Oxofluoramido Complexes of Tungsten(VI); 2.2 Restricted M-NR(2) Rotation in the Dinuclear Complexes with M(2)(6+) Core (M = W, Mo) 2.3 Features of Dynamic Behavior of Amido Cyclopentadienyl Complexes of Group 5 Transition Metals2.4 Internal Hindered Rotation of Ketimido Ligands; 3 Dynamic Behavior of d(0) Transition Metal Complexes with n-Donor Two-Center Ligands; 3.1 Isomerization of Fluorocomplexes of Group 5-6 with O, N-Two-Center Ligands; 3.2 Isomerism of Transition Metal Complexes with N, N-Two-center Ligands; 3.3 Nature of Bonding of n-Donor Two-center Ligands in d(0) Transition Metal Complexes; 3.4 Mechanism of Internal Hindered Rotation of h(2)-Bound Ligands; 4 Conclusion; 5 References 4 Conformational Mobility in Chelated Square-planar Rh, Ir, Pd, and Pt Complexes |
| Record Nr. | UNINA-9910817898003321 |
| Hoboken, NJ, : J. Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Functionalised N-heterocyclic carbene complexes / / Olaf Kuhl
| Functionalised N-heterocyclic carbene complexes / / Olaf Kuhl |
| Autore | Kuhl Olaf |
| Pubbl/distr/stampa | Chichester, West Sussex, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (365 p.) |
| Disciplina | 541/.2242 |
| Soggetto topico |
Ligands
Heterocyclic compounds Transition metal complexes |
| ISBN |
1-282-48220-3
9786612482205 0-470-68583-2 0-470-68584-0 |
| Classificazione |
CHE 330f
CHE 612f CHE 670f |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Contents; Abbreviations; Introduction; Chapter 1 The Nature of N-Heterocyclic Carbenes; 1.1 Synthesis; 1.1.1 Synthesis of the Imidazolium Salts; 1.1.2 Closing the Ring; 1.1.3 Synthesis of the Free Carbenes; 1.1.4 Synthesis of Transition Metal Complexes of NHC; 1.2 Properties of NHC; 1.2.1 The Internal Electronic Structure; 1.2.2 Basicity of NHC; 1.2.3 Steric Properties; 1.2.4 The Carbene-Metal Bond; 1.2.5 Decomposition Pathways; References; Chapter 2 Why Functionalisation?; 2.1 Phosphane Mimic; 2.2 Hemilability; 2.3 Chirality; 2.3.1 Planar Chirality; 2.3.2 Axial Chirality
2.4 Ligand Geometry2.5 Catalysis; 2.5.1 Allylic Alkylation; 2.5.2 Coupling Reactions; 2.5.3 Olefin Metathesis; 2.5.4 Polymerisations; 2.5.5 Organocatalysis; References; Chapter 3 N-Heterocyclic Carbenes with Neutral Tethers; 3.1 Amine Functionalities; 3.1.1 Heteroaromatic Functional Groups; 3.1.2 Oxazolines; 3.1.3 Imino Functional Groups; 3.1.4 Amino Functionalised NHC; 3.2 Oxygen-Containing Groups; 3.3 Phosphane Functionalities; 3.4 Bis-Carbene Ligands; 3.5 Tris-N-Heterocyclic Carbene Ligands; 3.6 Pincer Carbenes; References; Chapter 4 N-Heterocyclic Carbenes with Anionic Functional Groups 4.1 Oxygen-Containing Groups4.2 Nitrogen-Containing Groups; 4.3 NHC Ligands Incorporating Cp Moieties; 4.4 Transition Metal NHC Complexes Involved in the Activation of C-H Bonds; 4.5 Immobilisation of the Catalyst; 4.6 Sulfur-Containing Functional Groups; References; Chapter 5 Chiral N-Heterocyclic Carbenes; References; Chapter 6 Natural Products; 6.1 Thiazole; 6.1.1 Isolation and Stability of Thiazolylidene; 6.1.2 Benzothiazoles; 6.1.3 Metal Complexes; 6.2 Amino Acids; 6.3 Purines and Xanthines; 6.4 Carbohydrates; 6.5 Miscellaneous; References; Index; A; B; C; D; E; F; G; H; I; J; K; L; M; N OP; Q; R; S; T; U; V; W; X; Z |
| Record Nr. | UNINA-9910877181203321 |
Kuhl Olaf
|
||
| Chichester, West Sussex, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern coordination chemistry [[electronic resource] ] : the legacy of Joseph Chatt / / edited by G.J. Leigh and N. Winterton
| Modern coordination chemistry [[electronic resource] ] : the legacy of Joseph Chatt / / edited by G.J. Leigh and N. Winterton |
| Pubbl/distr/stampa | Cambridge, : Royal Society of Chemistry, c2002 |
| Descrizione fisica | 1 online resource (416 p.) |
| Disciplina | 541/.2242 |
| Altri autori (Persone) |
ChattJ
LeighG. J WintertonN |
| Soggetto topico | Coordination compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN | 1-84755-148-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | section A. Reminiscences of Joseph Chatt Drawn from conversations and from the recollections of co-workers -- section B. Recent developments in the synthesis, bonding modes and reactivity of hydrido and dihydrogen complexes -- section C. The chemistry of phosphines -- section D. Transition metal complexes of olefins, acetylenes, arenes and related isolobal ligands -- section E. Chemistry related to dinitrogen complexes -- section F. The biological work of the ARC unit of nitrogen fixation at the University of Sussex, and later developments -- section G. Pattern and generalisations in stability and reactivity -- section H. Other papers presented at the 34th International Conference on Coordination Chemistry, Edinburgh, Scotland, July 2000. |
| Record Nr. | UNINA-9910455217503321 |
| Cambridge, : Royal Society of Chemistry, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern coordination chemistry [[electronic resource] ] : the legacy of Joseph Chatt / / edited by G.J. Leigh and N. Winterton
| Modern coordination chemistry [[electronic resource] ] : the legacy of Joseph Chatt / / edited by G.J. Leigh and N. Winterton |
| Pubbl/distr/stampa | Cambridge, : Royal Society of Chemistry, c2002 |
| Descrizione fisica | 1 online resource (416 p.) |
| Disciplina | 541/.2242 |
| Altri autori (Persone) |
ChattJ
LeighG. J WintertonN |
| Soggetto topico | Coordination compounds |
| ISBN | 1-84755-148-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | section A. Reminiscences of Joseph Chatt Drawn from conversations and from the recollections of co-workers -- section B. Recent developments in the synthesis, bonding modes and reactivity of hydrido and dihydrogen complexes -- section C. The chemistry of phosphines -- section D. Transition metal complexes of olefins, acetylenes, arenes and related isolobal ligands -- section E. Chemistry related to dinitrogen complexes -- section F. The biological work of the ARC unit of nitrogen fixation at the University of Sussex, and later developments -- section G. Pattern and generalisations in stability and reactivity -- section H. Other papers presented at the 34th International Conference on Coordination Chemistry, Edinburgh, Scotland, July 2000. |
| Record Nr. | UNINA-9910778310903321 |
| Cambridge, : Royal Society of Chemistry, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern coordination chemistry : the legacy of Joseph Chatt / / edited by G.J. Leigh and N. Winterton
| Modern coordination chemistry : the legacy of Joseph Chatt / / edited by G.J. Leigh and N. Winterton |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Cambridge, : Royal Society of Chemistry, c2002 |
| Descrizione fisica | 1 online resource (416 p.) |
| Disciplina | 541/.2242 |
| Altri autori (Persone) |
ChattJ
LeighG. J WintertonN |
| Soggetto topico | Coordination compounds |
| ISBN | 1-84755-148-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | section A. Reminiscences of Joseph Chatt Drawn from conversations and from the recollections of co-workers -- section B. Recent developments in the synthesis, bonding modes and reactivity of hydrido and dihydrogen complexes -- section C. The chemistry of phosphines -- section D. Transition metal complexes of olefins, acetylenes, arenes and related isolobal ligands -- section E. Chemistry related to dinitrogen complexes -- section F. The biological work of the ARC unit of nitrogen fixation at the University of Sussex, and later developments -- section G. Pattern and generalisations in stability and reactivity -- section H. Other papers presented at the 34th International Conference on Coordination Chemistry, Edinburgh, Scotland, July 2000. |
| Record Nr. | UNINA-9910828916203321 |
| Cambridge, : Royal Society of Chemistry, c2002 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||