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Aziridines and epoxides in organic synthesis [[electronic resource] /] / edited by Andrei K. Yudin
| Aziridines and epoxides in organic synthesis [[electronic resource] /] / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim ; ; Chichester, : Wiley, 2006 |
| Descrizione fisica | 1 online resource (516 p.) |
| Disciplina | 547.2 |
| Altri autori (Persone) | YudinAndrei K |
| Soggetto topico |
Epoxy compounds
Organic compounds - Synthesis |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-72273-8
9786610722730 3-527-60786-2 3-527-60748-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Aziridines and Epoxides in Organic Synthesis; Foreword; Table of Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Epoxides and Aziridines from Aldehydes and Imines; 1.1 Introduction; 1.2 Asymmetric Epoxidation of Carbonyl Compounds; 1.2.1 Aryl, Vinyl, and Alkyl Epoxides; 1.2.1.1 Stoichiometric Ylide-mediated Epoxidation; 1.2.1.2 Catalytic Ylide-mediated Epoxidation; 1.2.1.3 Discussion of Factors Affecting Diastereo- and Enantioselectivity; 1.2.2 Terminal Epoxides; 1.2.3 Epoxy Esters, Amides, Acids, Ketones, and Sulfones; 1.2.3.1 Sulfur Ylide-mediated Epoxidation
1.2.3.2 Darzens Reaction1.2.3.3 Darzens Reactions in the Presence of Chiral Auxiliaries; 1.2.3.4 Darzens Reactions with Chiral Reagents; 1.2.3.5 Darzens Reactions with Chiral Catalysts; 1.3 Asymmetric Aziridination of Imines; 1.3.1 Aziridines Bearing Electron-withdrawing Groups: Esters and Amides; 1.3.1.1 Aza-Darzens Route; 1.3.1.2 Reactions between Imines and Carbenes; 1.3.1.3 Aziridines by Guanidinium Ylide Chemistry; 1.3.2 Aziridines Bearing Alkyl, Aryl, Propargyl, and Vinyl Groups; 1.3.2.1 Aryl, Vinyl, and Alkyl Aziridines: Stoichiometric Asymmetric Ylide-mediated Aziridination 1.3.2.2 Aryl, Vinyl, and Alkyl Aziridines: Catalytic Asymmetric Ylide-mediated Aziridination1.4 Summary and Outlook; References; 2 Vinylaziridines in Organic Synthesis; 2.1 Introduction; 2.2 Direct Synthesis of Vinylaziridines [1]; 2.2.1 Addition of Nitrene to Dienes; 2.2.2 Addition of Allylic Ylides and Related Reagents to Imines; 2.2.3 Cyclization of Amino Alcohols and Related Compounds; 2.2.4 Cyclization of Amino Allenes; 2.2.5 Aziridination of α,β-unsaturated Oximes and Hydrazones; 2.3 Ring-opening Reactions with Nucleophiles; 2.3.1 Hydride Reduction 2.3.2 Organocopper-mediated Alkylation2.3.3 Reactions with Oxygen Nucleophiles; 2.3.4 Reactions with Other Nucleophiles; 2.4 Isomerization Including Rearrangement; 2.4.1 Aza-[3,3]-Claisen Rearrangement; 2.4.2 Pyrroline Formation; 2.4.3 Aza-[2,3]-Wittig Rearrangement; 2.4.4 Hydrogen Shift; 2.4.5 Rearrangement with an Aryl Group on the Aziridine Carbon; 2.4.6 Epimerization; 2.5 Cycloaddition; 2.5.1 Cycloadditions of Isocyanates and Related Compounds; 2.5.2 Carbonylative Ring-expansion to Lactams; 2.6 Electron Transfer to Vinylaziridines; 2.7 Conclusions; References 3 Asymmetric Syntheses with Aziridinecarboxylate and Aziridinephosphonate Building Blocks3.1 Introduction; 3.2 Preparation of Aziridine-2-carboxylates and Aziridine-2-phosphonates; 3.2.1 Preparation of Aziridine-2-carboxylates; 3.2.1.1 Cyclization of Hydroxy Amino Esters; 3.2.1.2 Cyclization of Hydroxy Azido Esters; 3.2.1.3 Cyclization of α-Halo- and α-Sulfonyloxy-β-amino Esters and Amides; 3.2.1.4 Aziridination of α,β-unsaturated Esters; 3.2.1.5 Aziridination of Imines; 3.2.1.6 Aziridination of Aldehydes; 3.2.1.7 2-Carboxylation of Aziridines 3.2.1.8 Resolution of Racemic Aziridine-2-carboxylates |
| Record Nr. | UNINA-9910144322703321 |
| Weinheim ; ; Chichester, : Wiley, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Aziridines and epoxides in organic synthesis [[electronic resource] /] / edited by Andrei K. Yudin
| Aziridines and epoxides in organic synthesis [[electronic resource] /] / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim ; ; Chichester, : Wiley, 2006 |
| Descrizione fisica | 1 online resource (516 p.) |
| Disciplina | 547.2 |
| Altri autori (Persone) | YudinAndrei K |
| Soggetto topico |
Epoxy compounds
Organic compounds - Synthesis |
| ISBN |
1-280-72273-8
9786610722730 3-527-60786-2 3-527-60748-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Aziridines and Epoxides in Organic Synthesis; Foreword; Table of Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Epoxides and Aziridines from Aldehydes and Imines; 1.1 Introduction; 1.2 Asymmetric Epoxidation of Carbonyl Compounds; 1.2.1 Aryl, Vinyl, and Alkyl Epoxides; 1.2.1.1 Stoichiometric Ylide-mediated Epoxidation; 1.2.1.2 Catalytic Ylide-mediated Epoxidation; 1.2.1.3 Discussion of Factors Affecting Diastereo- and Enantioselectivity; 1.2.2 Terminal Epoxides; 1.2.3 Epoxy Esters, Amides, Acids, Ketones, and Sulfones; 1.2.3.1 Sulfur Ylide-mediated Epoxidation
1.2.3.2 Darzens Reaction1.2.3.3 Darzens Reactions in the Presence of Chiral Auxiliaries; 1.2.3.4 Darzens Reactions with Chiral Reagents; 1.2.3.5 Darzens Reactions with Chiral Catalysts; 1.3 Asymmetric Aziridination of Imines; 1.3.1 Aziridines Bearing Electron-withdrawing Groups: Esters and Amides; 1.3.1.1 Aza-Darzens Route; 1.3.1.2 Reactions between Imines and Carbenes; 1.3.1.3 Aziridines by Guanidinium Ylide Chemistry; 1.3.2 Aziridines Bearing Alkyl, Aryl, Propargyl, and Vinyl Groups; 1.3.2.1 Aryl, Vinyl, and Alkyl Aziridines: Stoichiometric Asymmetric Ylide-mediated Aziridination 1.3.2.2 Aryl, Vinyl, and Alkyl Aziridines: Catalytic Asymmetric Ylide-mediated Aziridination1.4 Summary and Outlook; References; 2 Vinylaziridines in Organic Synthesis; 2.1 Introduction; 2.2 Direct Synthesis of Vinylaziridines [1]; 2.2.1 Addition of Nitrene to Dienes; 2.2.2 Addition of Allylic Ylides and Related Reagents to Imines; 2.2.3 Cyclization of Amino Alcohols and Related Compounds; 2.2.4 Cyclization of Amino Allenes; 2.2.5 Aziridination of α,β-unsaturated Oximes and Hydrazones; 2.3 Ring-opening Reactions with Nucleophiles; 2.3.1 Hydride Reduction 2.3.2 Organocopper-mediated Alkylation2.3.3 Reactions with Oxygen Nucleophiles; 2.3.4 Reactions with Other Nucleophiles; 2.4 Isomerization Including Rearrangement; 2.4.1 Aza-[3,3]-Claisen Rearrangement; 2.4.2 Pyrroline Formation; 2.4.3 Aza-[2,3]-Wittig Rearrangement; 2.4.4 Hydrogen Shift; 2.4.5 Rearrangement with an Aryl Group on the Aziridine Carbon; 2.4.6 Epimerization; 2.5 Cycloaddition; 2.5.1 Cycloadditions of Isocyanates and Related Compounds; 2.5.2 Carbonylative Ring-expansion to Lactams; 2.6 Electron Transfer to Vinylaziridines; 2.7 Conclusions; References 3 Asymmetric Syntheses with Aziridinecarboxylate and Aziridinephosphonate Building Blocks3.1 Introduction; 3.2 Preparation of Aziridine-2-carboxylates and Aziridine-2-phosphonates; 3.2.1 Preparation of Aziridine-2-carboxylates; 3.2.1.1 Cyclization of Hydroxy Amino Esters; 3.2.1.2 Cyclization of Hydroxy Azido Esters; 3.2.1.3 Cyclization of α-Halo- and α-Sulfonyloxy-β-amino Esters and Amides; 3.2.1.4 Aziridination of α,β-unsaturated Esters; 3.2.1.5 Aziridination of Imines; 3.2.1.6 Aziridination of Aldehydes; 3.2.1.7 2-Carboxylation of Aziridines 3.2.1.8 Resolution of Racemic Aziridine-2-carboxylates |
| Record Nr. | UNINA-9910830455203321 |
| Weinheim ; ; Chichester, : Wiley, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Aziridines and epoxides in organic synthesis / / edited by Andrei K. Yudin
| Aziridines and epoxides in organic synthesis / / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim ; ; Chichester, : Wiley, 2006 |
| Descrizione fisica | 1 online resource (516 p.) |
| Disciplina | 547.2 |
| Altri autori (Persone) | YudinAndrei K |
| Soggetto topico |
Epoxy compounds
Organic compounds - Synthesis |
| ISBN |
1-280-72273-8
9786610722730 3-527-60786-2 3-527-60748-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Aziridines and Epoxides in Organic Synthesis; Foreword; Table of Contents; Preface; List of Contributors; 1 Asymmetric Synthesis of Epoxides and Aziridines from Aldehydes and Imines; 1.1 Introduction; 1.2 Asymmetric Epoxidation of Carbonyl Compounds; 1.2.1 Aryl, Vinyl, and Alkyl Epoxides; 1.2.1.1 Stoichiometric Ylide-mediated Epoxidation; 1.2.1.2 Catalytic Ylide-mediated Epoxidation; 1.2.1.3 Discussion of Factors Affecting Diastereo- and Enantioselectivity; 1.2.2 Terminal Epoxides; 1.2.3 Epoxy Esters, Amides, Acids, Ketones, and Sulfones; 1.2.3.1 Sulfur Ylide-mediated Epoxidation
1.2.3.2 Darzens Reaction1.2.3.3 Darzens Reactions in the Presence of Chiral Auxiliaries; 1.2.3.4 Darzens Reactions with Chiral Reagents; 1.2.3.5 Darzens Reactions with Chiral Catalysts; 1.3 Asymmetric Aziridination of Imines; 1.3.1 Aziridines Bearing Electron-withdrawing Groups: Esters and Amides; 1.3.1.1 Aza-Darzens Route; 1.3.1.2 Reactions between Imines and Carbenes; 1.3.1.3 Aziridines by Guanidinium Ylide Chemistry; 1.3.2 Aziridines Bearing Alkyl, Aryl, Propargyl, and Vinyl Groups; 1.3.2.1 Aryl, Vinyl, and Alkyl Aziridines: Stoichiometric Asymmetric Ylide-mediated Aziridination 1.3.2.2 Aryl, Vinyl, and Alkyl Aziridines: Catalytic Asymmetric Ylide-mediated Aziridination1.4 Summary and Outlook; References; 2 Vinylaziridines in Organic Synthesis; 2.1 Introduction; 2.2 Direct Synthesis of Vinylaziridines [1]; 2.2.1 Addition of Nitrene to Dienes; 2.2.2 Addition of Allylic Ylides and Related Reagents to Imines; 2.2.3 Cyclization of Amino Alcohols and Related Compounds; 2.2.4 Cyclization of Amino Allenes; 2.2.5 Aziridination of α,β-unsaturated Oximes and Hydrazones; 2.3 Ring-opening Reactions with Nucleophiles; 2.3.1 Hydride Reduction 2.3.2 Organocopper-mediated Alkylation2.3.3 Reactions with Oxygen Nucleophiles; 2.3.4 Reactions with Other Nucleophiles; 2.4 Isomerization Including Rearrangement; 2.4.1 Aza-[3,3]-Claisen Rearrangement; 2.4.2 Pyrroline Formation; 2.4.3 Aza-[2,3]-Wittig Rearrangement; 2.4.4 Hydrogen Shift; 2.4.5 Rearrangement with an Aryl Group on the Aziridine Carbon; 2.4.6 Epimerization; 2.5 Cycloaddition; 2.5.1 Cycloadditions of Isocyanates and Related Compounds; 2.5.2 Carbonylative Ring-expansion to Lactams; 2.6 Electron Transfer to Vinylaziridines; 2.7 Conclusions; References 3 Asymmetric Syntheses with Aziridinecarboxylate and Aziridinephosphonate Building Blocks3.1 Introduction; 3.2 Preparation of Aziridine-2-carboxylates and Aziridine-2-phosphonates; 3.2.1 Preparation of Aziridine-2-carboxylates; 3.2.1.1 Cyclization of Hydroxy Amino Esters; 3.2.1.2 Cyclization of Hydroxy Azido Esters; 3.2.1.3 Cyclization of α-Halo- and α-Sulfonyloxy-β-amino Esters and Amides; 3.2.1.4 Aziridination of α,β-unsaturated Esters; 3.2.1.5 Aziridination of Imines; 3.2.1.6 Aziridination of Aldehydes; 3.2.1.7 2-Carboxylation of Aziridines 3.2.1.8 Resolution of Racemic Aziridine-2-carboxylates |
| Record Nr. | UNINA-9910877069203321 |
| Weinheim ; ; Chichester, : Wiley, 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalyzed carbon-heteroatom bond formation [[electronic resource] /] / edited by Andrei K. Yudin
| Catalyzed carbon-heteroatom bond formation [[electronic resource] /] / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, 2011 |
| Descrizione fisica | 1 online resource (523 p.) |
| Disciplina | 546.6812 |
| Altri autori (Persone) | YudinAndrei K |
| Soggetto topico |
Carbon compounds
Chemical bonds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
3-527-63340-5
1-282-84957-3 9786612849572 3-527-63338-3 3-527-63339-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
1.3.5 Pd-Catalyzed Carboamination Reactions of Alkynes, Allenes, and Dienes1.3.6 Vicinal Difunctionalization of Alkenes and Allenes; 1.4 Synthesis of Nitrogen Heterocycles via Intermediate π-Allylpalladium Complexes; 1.4.1 Reactions Involving Oxidative Addition of Allylic Electrophiles; 1.4.2 Reactions Involving π-Allylpalladium Intermediates Generated via Alkene Carbopalladation; 1.4.3 Reactions Involving Aminopalladation of 1,3-Dienes; 1.4.4 Generation of Allylpalladium Intermediates through C-H Activation
2.5.2 Reductive Cyclization of Ketoacids and Ketoesters2.5.3 C-H Oxygenation; 2.5.4 Ring Closure of Benzoic Acids with Dihaloalkanes; 2.5.5 Baeyer-Villiger Oxidation of Cyclic Ketones; 2.5.6 Ring Opening of Cyclopropanes with Carboxylic Acids; 2.5.7 Ring Closure of o-Iodobenzoates with Aldehydes; 2.5.8 Synthesis of Lactones Involving CO2; 2.5.9 Michael Addition of α,β-Unsaturated N-Acylpyrrolidines; 2.5.10 [2 + 2] Cycloaddition of Ketenes and Aldehydes; 2.5.11 Tandem Cross-Metathesis/Hydrogenation Route to Lactones; 2.5.12 Modern Catalytic Variants of Classical Macrolactonizations 2.6 Conclusions and Outlook |
| Record Nr. | UNINA-9910140759103321 |
| Weinheim, Germany, : Wiley-VCH, 2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalyzed carbon-heteroatom bond formation [[electronic resource] /] / edited by Andrei K. Yudin
| Catalyzed carbon-heteroatom bond formation [[electronic resource] /] / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, 2011 |
| Descrizione fisica | 1 online resource (523 p.) |
| Disciplina | 546.6812 |
| Altri autori (Persone) | YudinAndrei K |
| Soggetto topico |
Carbon compounds
Chemical bonds |
| ISBN |
3-527-63340-5
1-282-84957-3 9786612849572 3-527-63338-3 3-527-63339-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
1.3.5 Pd-Catalyzed Carboamination Reactions of Alkynes, Allenes, and Dienes1.3.6 Vicinal Difunctionalization of Alkenes and Allenes; 1.4 Synthesis of Nitrogen Heterocycles via Intermediate π-Allylpalladium Complexes; 1.4.1 Reactions Involving Oxidative Addition of Allylic Electrophiles; 1.4.2 Reactions Involving π-Allylpalladium Intermediates Generated via Alkene Carbopalladation; 1.4.3 Reactions Involving Aminopalladation of 1,3-Dienes; 1.4.4 Generation of Allylpalladium Intermediates through C-H Activation
2.5.2 Reductive Cyclization of Ketoacids and Ketoesters2.5.3 C-H Oxygenation; 2.5.4 Ring Closure of Benzoic Acids with Dihaloalkanes; 2.5.5 Baeyer-Villiger Oxidation of Cyclic Ketones; 2.5.6 Ring Opening of Cyclopropanes with Carboxylic Acids; 2.5.7 Ring Closure of o-Iodobenzoates with Aldehydes; 2.5.8 Synthesis of Lactones Involving CO2; 2.5.9 Michael Addition of α,β-Unsaturated N-Acylpyrrolidines; 2.5.10 [2 + 2] Cycloaddition of Ketenes and Aldehydes; 2.5.11 Tandem Cross-Metathesis/Hydrogenation Route to Lactones; 2.5.12 Modern Catalytic Variants of Classical Macrolactonizations 2.6 Conclusions and Outlook |
| Record Nr. | UNINA-9910830263203321 |
| Weinheim, Germany, : Wiley-VCH, 2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalyzed carbon-heteroatom bond formation / / edited by Andrei K. Yudin
| Catalyzed carbon-heteroatom bond formation / / edited by Andrei K. Yudin |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, 2011 |
| Descrizione fisica | 1 online resource (523 p.) |
| Disciplina | 546.6812 |
| Altri autori (Persone) | YudinAndrei K |
| Soggetto topico |
Carbon compounds
Chemical bonds |
| ISBN |
3-527-63340-5
1-282-84957-3 9786612849572 3-527-63338-3 3-527-63339-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
1.3.5 Pd-Catalyzed Carboamination Reactions of Alkynes, Allenes, and Dienes1.3.6 Vicinal Difunctionalization of Alkenes and Allenes; 1.4 Synthesis of Nitrogen Heterocycles via Intermediate π-Allylpalladium Complexes; 1.4.1 Reactions Involving Oxidative Addition of Allylic Electrophiles; 1.4.2 Reactions Involving π-Allylpalladium Intermediates Generated via Alkene Carbopalladation; 1.4.3 Reactions Involving Aminopalladation of 1,3-Dienes; 1.4.4 Generation of Allylpalladium Intermediates through C-H Activation
2.5.2 Reductive Cyclization of Ketoacids and Ketoesters2.5.3 C-H Oxygenation; 2.5.4 Ring Closure of Benzoic Acids with Dihaloalkanes; 2.5.5 Baeyer-Villiger Oxidation of Cyclic Ketones; 2.5.6 Ring Opening of Cyclopropanes with Carboxylic Acids; 2.5.7 Ring Closure of o-Iodobenzoates with Aldehydes; 2.5.8 Synthesis of Lactones Involving CO2; 2.5.9 Michael Addition of α,β-Unsaturated N-Acylpyrrolidines; 2.5.10 [2 + 2] Cycloaddition of Ketenes and Aldehydes; 2.5.11 Tandem Cross-Metathesis/Hydrogenation Route to Lactones; 2.5.12 Modern Catalytic Variants of Classical Macrolactonizations 2.6 Conclusions and Outlook |
| Record Nr. | UNINA-9910877137103321 |
| Weinheim, Germany, : Wiley-VCH, 2011 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||