Ion Exchange Membranes : Design, Preparation, and Applications

• Autore: Xu Tongwen
• Pubblicazione: Newark : , : John Wiley & Sons, Incorporated, , 2024; ©2024
• Edizione: 1st ed.
• Descrizione fisica: 1 online resource (435 pages)
• Disciplina: 541.372
• Soggetto topico: Ion exchange resins; Membranes (Technology)
• Altri autori: WangYaoming
• Nota di contenuto: Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 Overview of Ion Exchange Membranes -- 1.1 Definition and Classifications -- 1.2 Profile of IEMs -- 1.3 Preparation of IEMs -- 1.4 Applications -- 1.5 Potentials -- References -- Chapter 2 Fundamentals and Characterizations -- 2.1 Donnan Equilibrium -- 2.2 Membrane Potential -- 2.3 Transference Number -- 2.4 Diffusion Coefficient and Ion Permeability -- 2.5 Ion Flux and Permselectivity -- 2.6 Area Resistance -- 2.7 Concentration Polarization -- 2.8 Limiting Current Density and Current-Voltage Curves -- 2.9 Water Transport -- 2.10 Membrane Scaling and Fouling -- 2.11 Zeta Potential -- 2.12 Other Conventional Characterization -- 2.12.1 Conductivity -- 2.12.2 Ion Exchange Capacity -- 2.12.3 Water Uptake and Swelling Ratio -- 2.12.4 Mechanical Strength -- References -- Chapter 3 Side‐chain Engineering for Ion Exchange Membrane Preparation -- 3.1 Principles of Side‐chain Engineering -- 3.1.1 Inspiration of Nafion -- 3.1.2 Microphase Separation of Grafted Polymers -- 3.2 Construction of Side‐chain Architecture -- 3.2.1 Design of Side‐chain CEMs -- 3.2.1.1 Design of Side‐chain CEMs with Similar Nafion Structures -- 3.2.1.2 Design of Side‐chain CEMs with Grafted Structures -- 3.2.2 Design of Side‐chain AEMs -- 3.2.2.1 Design of Side‐chain AEMs with Similar Nafion Structures -- 3.2.2.2 Design of Side‐chain AEMs with Grafted Structures -- 3.2.2.3 Design of Functional Groups for Side‐chain AEMs -- 3.3 Construction of the Cross‐linking Side Chain -- 3.4 Construction of Hyperbranched Networks -- 3.5 Construction of Dynamic Transfer Regions -- 3.6 Construction of Cation-Dipole Interactions -- References -- Chapter 4 Polyacylation for Ion Exchange Membrane Preparation -- 4.1 Principle of Polyacylation -- 4.2 Types of Acylation Reactions -- 4.2.1 Acylation of Alcohols. ; 4.2.2 Acylation of Amines -- 4.2.3 Acylation of Enols -- 4.2.4 Acylation of Carboxylic Acids -- 4.2.5 Acylation of Ketones -- 4.2.6 Acylation of Amides -- 4.2.7 Acylation of Sulfonamides -- 4.2.8 Polyacylation of Polymers -- 4.2.9 Advantages and Limitations of Polyacylation as a Synthetic Approach -- 4.2.10 Polyacylation and Polymers -- 4.3 Perylene‐based Polyimides -- 4.3.1 Traditional Route -- 4.3.2 Polyacylation Route -- 4.3.3 Synthesis of Perylene‐based Polyimide‐based Ion Exchange Membranes -- 4.3.4 Perylene and Polyimide‐based CEMs -- 4.3.5 Perylene and Polyimide‐based AEMs -- 4.4 Polyacylation of SPEK‐based IEMs -- 4.4.1 Polyacylation of SPEK‐based CEMs -- 4.4.2 Polyacylation of SPEK‐based AEMs -- 4.5 Polyacylation/Polyacylated Crown Ether IEMs -- 4.5.1 Acylation of Crown Ether -- 4.5.2 Poly‐Crown Ether‐based AEM -- 4.5.3 Poly‐crown Ether‐based Noncharged Selective Membrane (PCENS‐M) -- 4.6 Conclusion -- 4.6.1 Challenges/Opportunities for Further Development -- 4.6.2 Outlook for the Future of Polyacylation in Membrane Research -- References -- Chapter 5 Superacid-Catalyst Polymerization for IEMs Preparation -- 5.1 Definition and Types of Superacid -- 5.2 Principle of Superacid Catalyst -- 5.3 Superacid‐catalyzed Reaction for Polymer Synthesis -- 5.4 Superacid‐catalyst Polymerization for IEM Preparation -- 5.5 Others -- References -- Chapter 6 Microporous Polymers for IEM Preparation -- 6.1 Ion Transport Behavior in Nanospace‐confined Membranes -- 6.2 Principle of Microporous Polymers -- 6.3 IEMs Derived from Microporous Polymers -- 6.3.1 Positively Charged Microporous Polymers -- 6.3.2 Negatively Charged Microporous Polymers -- 6.3.2.1 Hydrolysis of Dibenzodioxin‐based Microporous Polymers -- 6.3.2.2 Amidoxime of Dibenzodioxin‐based PIMs -- 6.3.2.3 Post‐sulfonation of PIMs or Bottom‐up Approach -- 6.4 Conclusion and Outlook -- References. ; Chapter 7 In Situ Polymerization for IEM Preparation -- 7.1 Conventional Methods for IEM Preparation -- 7.2 Semi‐interpenetrating Polymer Network -- 7.3 Pore Filling -- 7.4 Solvent‐free Strategy -- 7.5 In Situ Polymerization -- References -- Chapter 8 Special IEMs Preparation -- 8.1 Metal-Organic Framework Membranes -- 8.1.1 Introduction -- 8.1.2 Structural Properties of MOFs -- 8.1.2.1 Structural Diversity -- 8.1.2.2 Structural Tunability -- 8.1.2.3 High Stability -- 8.1.3 Preparation of MOF Membranes -- 8.1.3.1 UiO‐66‐NH2 Membrane -- 8.1.3.2 UiO‐66‐SO3H Membrane -- 8.1.3.3 UiO‐66(Zr/Ti)‐NH2/Polyamide Mixed Matrix Membrane -- 8.1.3.4 PolyMOF Membrane -- 8.2 Porous Organic Cage Membranes -- 8.2.1 Introduction -- 8.2.2 Structural Properties of POCs -- 8.2.3 Preparation of POC Membranes -- 8.2.3.1 POC Membranes of Versatile Channels -- 8.2.3.2 High Ion‐Permselective CC3 Membrane -- 8.3 Covalent Organic Framework Membranes -- 8.3.1 Introduction -- 8.3.2 Design Strategies of the COF Structure -- 8.3.2.1 Pore Structure Design -- 8.3.2.2 Pore Surface Engineering -- 8.3.3 Preparation of COF Membranes -- 8.3.3.1 COF Membrane with Sub‐2‐nm Channels -- 8.3.3.2 Cationic COF Membrane -- 8.3.3.3 Self‐Standing COF Membrane -- 8.4 Electro‐Nanofiltration Membranes -- 8.4.1 Introduction -- 8.4.2 The Preparation of ENMs -- 8.4.3 The Performance of ENMs -- 8.5 Conclusion and Perspective -- References -- Chapter 9 Applications -- 9.1 Diffusion Dialysis (DD) -- 9.1.1 The Basic Theory of Diffusion Dialysis -- 9.1.1.1 High‐performance Diffusion Dialysis Membranes -- 9.1.2 Diffusion Dialysis Components -- 9.1.3 Diffusion Dialysis Application Field -- 9.1.3.1 Recovery of Waste Acid -- 9.1.3.2 Alkali Recovery -- 9.2 Reverse Electrodialysis (RED) -- 9.2.1 Basic Theory of RED -- 9.2.2 The Main Components of RED -- 9.2.2.1 Ion Exchange Membrane -- 9.2.2.2 Spacers. ; 9.2.2.3 Electrode System -- 9.3 Donnan Dialysis -- 9.3.1 Basic Theory of Donnan Dialysis -- 9.3.1.1 The Parameters Affecting Donnan Dialysis -- 9.4 Electrodialysis (ED) -- 9.5 Application of ED -- 9.5.1 Desalination -- 9.5.2 Concentration -- 9.5.3 The Influencing Parameters on ED Concentration -- 9.5.3.1 Approaches to Improve the Concentration on ED -- 9.5.4 Resource Conversion -- 9.5.5 CO2 Capture -- 9.6 Electrodialysis with Bipolar Membranes (BMED) -- 9.6.1 The Basic Theory of Bipolar Membranes -- 9.6.2 Application of the BMED Process -- 9.6.2.1 The Production of Alkali -- 9.6.2.2 The Production of Acid -- 9.6.2.3 Production of CO2 Conversion -- 9.6.3 The Limitations of BMED -- 9.7 Electrodialysis Metathesis (EDM) -- 9.7.1 Application of the EDM Process -- 9.7.1.1 The Production of Ionic Liquid -- 9.7.1.2 High‐Salinity Wastewater Conversion -- 9.7.1.3 The Production of Potassium Fertilizers -- 9.8 Ion‐Distillation Technology -- 9.9 Fuel Cells -- 9.10 Water Electrolysis -- 9.11 Industrial Applications -- 9.11.1 Acid Recovery Using Diffusion Dialysis -- 9.11.2 Resource Recovery Using Electrodialysis -- 9.11.3 Clean Production Using Bipolar Membrane Electrodialysis -- References -- Index -- EULA.
• Sommario/riassunto: This book provides a comprehensive exploration of ion exchange membranes (IEMs), including their design, preparation, and applications. It covers the fundamental principles of IEMs, including the different types such as anion exchange membranes and cation exchange membranes, and their structural and chemical properties. The authors, Tongwen Xu and Yaoming Wang, delve into various methods of IEM preparation, such as polyacylation and superacid catalysis, and discuss the optimization of membrane properties for specific applications like fuel cells and water desalination. The book aims to bridge the gap between academia and industry by highlighting recent technological advancements and practical applications of IEMs, making it a valuable resource for researchers, engineers, and industry professionals in the fields of chemistry and material sciences.
• Titolo autorizzato: Ion Exchange Membranes
• ISBN: 9783527841424; 3527841423; 9783527841448; 352784144X
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 9911019772803321
• Lo trovi qui: Univ. Federico II