| Autore |
Wu Xiao-Feng
|
| Edizione | [1st ed.] |
| Pubbl/distr/stampa |
Newark : , : John Wiley & Sons, Incorporated, , 2024
|
| Descrizione fisica |
1 online resource (467 pages)
|
| Disciplina |
660.0286
|
| Altri autori (Persone) |
YinZhiping
HeLiang-nian
WangFeng
|
| Soggetto topico |
Green chemistry
Organic solvents
|
| ISBN |
9783527841943
3527841946
9783527841929
352784192X
|
| Formato |
Materiale a stampa  |
| Livello bibliografico |
Monografia |
| Lingua di pubblicazione |
eng
|
| Nota di contenuto |
Cover -- Title Page -- Copyright -- Contents -- Chapter 1 Recent Achievements in Organic Reactions in Alcohols -- 1.1 Introduction -- 1.2 Alcohols as Green Solvents -- 1.2.1 Hydrogenation/Reduction Reaction -- 1.2.2 Oxidation Reaction -- 1.2.3 Substitution Reaction -- 1.2.4 Addition Reaction -- 1.2.5 Cyclization Reaction -- 1.2.6 Coupling Reaction -- 1.2.7 Condensation/Ring Condensation Reaction -- 1.3 Alcohols as Green Solvents and Catalysts -- 1.3.1 Addition Reaction -- 1.3.2 Cyclization Reaction -- 1.3.3 Coupling Reaction -- 1.3.4 Condensation Reaction -- 1.3.5 Metathesis Reaction -- 1.4 Alcohols as Green Solvents and Hydrogen Donors -- 1.5 Miscellaneous -- 1.5.1 Polyethylene Glycol as a Solvent for CO2 Capture and Conversion -- 1.5.2 Polyethylene Glycol Radical‐Initiated Oxidation Reactions in Compressed Carbon Dioxide -- 1.5.3 Ring‐Opening Reaction -- 1.6 Summary and Concluding Remarks -- Acknowledgments -- References -- Chapter 2 Recent Achievements in Organic Reactions in MeCN -- 2.1 Introduction -- 2.2 MeCN in Transition Metal‐catalyzed Reactions Without Radicals Involved -- 2.2.1 Transition Metal‐catalyzed Addition Reactions in MeCN -- 2.2.2 Transition Metal‐catalyzed Oxidation Reactions in MeCN -- 2.2.3 Transition Metal‐catalyzed Reduction Reactions in MeCN -- 2.2.4 Transition Metal‐catalyzed Substitution Reactions in MeCN -- 2.2.5 Transition Metal‐catalyzed Cyclization Reactions in MeCN -- 2.3 MeCN in Transition Metal‐free Catalyzed Reactions Without Radicals Involved -- 2.3.1 Transition Metal‐free Catalyzed Cyclization Reactions in MeCN -- 2.3.2 Transition Metal‐free Catalyzed Multicomponent Reactions in MeCN -- 2.3.3 Transition Metal‐free Catalyzed C X Bond Formation in MeCN -- 2.4 MeCN in C X Bonds Formation With Radicals Involved -- 2.4.1 C C, C Si Bond Formation in MeCN -- 2.4.2 C N, C P Bond Formation in MeCN.
2.4.3 C O, C S Bond Formation in MeCN -- 2.4.4 C‐Halogen Bond Formation in MeCN -- 2.5 Conclusion -- References -- Chapter 3 Recent Achievements in Organic Reactions in Bio‐based Solvents -- 3.1 Introduction -- 3.2 Glycerol -- 3.3 Polyethylene Glycols (PEGs) -- 3.4 2‐Methyltetrahydrofuran (2‐MeTHF) -- 3.5 Cyclopentyl Methyl Ether (CPME) -- 3.6 Organic Carbonates -- 3.7 γ‐Valerolactone (GVL) -- 3.8 Ethyl Lactate (EL) -- 3.9 Miscellaneous -- 3.10 Conclusions and Outlook -- References -- Chapter 4 Recent Achievements in Organic Reactions in DMSO -- 4.1 Pummerer‐type Activation of DMSO -- 4.2 Selectfluor‐enabled Activation of DMSO -- 4.3 Activation of DMSO Enabled by Single‐electron Transformation -- 4.4 Electrocatalytic Synthesis Enabled Activation of DMSO -- 4.5 Photocatalytic Reaction Enabled Activation of DMSO -- 4.6 DMSO Acts as the Metal Ligand -- 4.7 Some Special Activation or Usage of DMSO -- 4.8 Summary and Outlook -- References -- Chapter 5 The Use of DMC as Green Solvent in Organic Synthesis -- 5.1 Introduction -- 5.2 Organic Reactions in DMC -- References -- Chapter 6 Applications of Green Deep Eutectic Solvents (DESs) in Synthetic Transformations -- 6.1 Introduction -- 6.2 Cross‐coupling Reactions in Deep Eutectic Solvents -- 6.2.1 C C Bond Couplings -- 6.2.2 C N Bond Couplings -- 6.2.3 C O Bond Couplings -- 6.2.4 C S Bond Couplings -- 6.3 Oxidation Reactions in Deep Eutectic Solvents -- 6.3.1 Metal‐catalyzed Oxidation -- 6.3.2 Other Oxidative Processes -- 6.4 Reduction Reactions in Deep Eutectic Solvents -- 6.4.1 Metal‐catalyzed Reduction -- 6.4.2 Other Catalytic Reduction -- 6.5 Cyclization Reactions in Deep Eutectic Solvents -- 6.5.1 Synthesis of Five‐membered Ring -- 6.5.2 Synthesis of Six‐membered Ring -- 6.6 Condensation Reactions in Deep Eutectic Solvents -- 6.6.1 DES as the Catalyst/Solvent System for Condensation.
6.6.2 Other Catalytic System for Condensation -- 6.7 Multicomponent Reactions in Deep Eutectic Solvents -- 6.7.1 One‐pot Three‐component Reaction -- 6.7.2 One‐pot Four‐component Reaction -- 6.8 Other Organic Reactions in Deep Eutectic Solvents -- 6.8.1 Isomerization Reaction -- 6.8.2 Ring‐opening Reaction -- 6.8.3 Esterification Reaction -- 6.9 Polymerization in DSEs -- 6.9.1 Anionic Polymerization of Alkenes -- 6.9.2 Glycolysis and Polyesterification -- 6.9.3 Oxidative Polymerization -- 6.9.4 Visible‐light‐driven RAFT Polymerization -- 6.10 Conclusion -- References -- Chapter 7 Recent Achievements in Organic Reactions in Ionic Liquids -- 7.1 Introduction -- 7.2 Transition Metal‐catalyzed Reactions -- 7.2.1 Palladium‐catalyzed Cascade Cyclization Reaction -- 7.2.2 Carbonylation Reactions -- 7.2.3 Sonogashira Coupling Reactions -- 7.2.4 Suzuki Coupling Reactions -- 7.2.5 Copper‐catalyzed Coupling Reactions -- 7.3 Outlook -- References -- Chapter 8 Recent Achievements in Organic Reactions in Ketones and Esters -- 8.1 Introduction -- 8.2 Organic Reactions in Ketones -- 8.2.1 Organic Reactions in Cyrene -- 8.2.2 Organic Reactions in NBP -- 8.3 Organic Reactions in Esters -- 8.3.1 Organic Reactions in Organic Carbonates -- 8.3.2 Organic Reactions in γ‐Valerolactone -- 8.3.3 Organic Reactions in Ethyl Lactate -- 8.4 Conclusion -- References -- Chapter 9 Recent Achievements in Organic Reactions in Polyethylene Glycol -- 9.1 Introduction -- 9.2 PEG in Pd‐catalyzed Coupling Reactions -- 9.2.1 Pd‐catalyzed C C, C Si Bonds Formation in PEG -- 9.2.2 Pd‐catalyzed C N, C P Bond Formation in PEG -- 9.2.3 Pd‐catalyzed C O Bond Formation in PEG -- 9.2.4 Pd‐catalyzed C B Bond Formation in PEG -- 9.3 PEG in Cu‐catalyzed Reactions -- 9.3.1 Cu‐catalyzed C C Bond Formation in PEG -- 9.3.2 Cu‐catalyzed C N Bond Formation in PEG.
9.3.3 Cu‐catalyzed C O, C S, and C Se Bond Formation in PEG -- 9.4 PEG in Ni, Ru, and Pt‐catalyzed Reactions -- 9.5 PEG in Organocatalysis Reactions -- 9.6 PEG in Multicomponent Reactions -- 9.7 PEG in Cyclization Reactions -- 9.7.1 Synthesis of Five‐membered Ring Systems -- 9.7.2 Synthesis of Six and Seven‐membered Ring Systems -- 9.8 Conclusion -- Acknowledgments -- References -- Chapter 10 Recent Advances in Organic Reactions Using Water as Solvent -- 10.1 Introduction -- 10.2 Cross‐Coupling Reactions -- 10.2.1 C C Cross‐Coupling -- 10.2.2 C-N Cross‐Coupling -- 10.2.3 C-S Cross‐Coupling -- 10.2.4 C-P Cross‐Coupling -- 10.3 C-H Functionalization -- 10.3.1 C-C Bond Formation -- 10.3.2 C-N Bond Formation -- 10.3.3 C-O Bond Formation -- 10.3.4 C-X Bond Formation -- 10.3.5 C-H Annulation/Cyclization -- 10.4 C-C Activation -- 10.5 C-O Cleavage Reactions -- 10.6 Oxidative and Reductive Reactions -- 10.6.1 Electrochemical Oxidation -- 10.6.2 Reduction and Related Reactions -- 10.7 Substitution Reactions -- 10.7.1 Nucleophilic Substitution -- 10.7.2 Electrophilic Substitution -- 10.7.3 Radical Substitution -- 10.8 Addition Reactions -- 10.8.1 Nucleophilic Addition -- 10.8.2 Alkene/Alkyne Functionalization via Radical Addition -- 10.8.3 Alkene or Alkyne Functionalization via Radical‐Free Addition -- 10.8.4 Cycloaddition Reactions -- 10.9 Cyclization or Annulation Reactions -- 10.9.1 Radical‐Free Cyclization/Annulation -- 10.9.2 Radical Cyclization -- 10.10 Multicomponent Reaction (MCR) -- 10.11 Domino/Tandem/Cascade Reactions -- 10.11.1 Chemo‐Domino/Tandem/Cascade Reactions -- 10.11.2 Chemoenzymatic Reactions -- 10.12 Rearrangement or Insertion Reactions -- 10.12.1 Rearrangement Reactions -- 10.12.2 Carbene Insertion/Transfer Reactions -- 10.13 Amide Condensation Reactions -- 10.14 Summary and Conclusions -- Acknowledgments -- References -- Index -- EULA.
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| Record Nr. | UNINA-9911019602803321 |
Info
C-C Cross Couplings with 3d Base Metal Catalysts / / Xiao-Feng Wu
