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Fluxional organometallic and coordination compounds [[electronic resource] /] / edited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer
| Fluxional organometallic and coordination compounds [[electronic resource] /] / edited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer |
| Pubbl/distr/stampa | Hoboken, NJ, : J. Wiley, c2004 |
| Descrizione fisica | 1 online resource (343 p.) |
| Disciplina | 541/.2242 |
| Altri autori (Persone) |
GielenM <1938-> (Marcel)
WillemR (Rudolf) WrackmeyerBernd <1947-> |
| Collana | Physical organometallic chemistry |
| Soggetto topico |
Coordination compounds
Organometallic chemistry Molecular dynamics Nuclear magnetic resonance spectroscopy |
| ISBN |
1-280-27095-0
9786610270958 0-470-30013-2 0-470-85845-1 0-470-85844-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fluxional Organometallic and Coordination Compounds; Contents; Contributors; Series Preface; Preface; 1 Polyhedral Dynamics and the Jahn-Teller Effect; 1 Introduction; 2 Polyhedron Topology; 3 Polyhedral Isomerizations: Microscopic Models; 3.1 Diamond-Square-Diamond Processes; 3.2 Gale Diagrams; 3.3 Generation of Metallaborane Structures by Diamond-Square-Diamond Transformations in Deltahedra; 4 Polyhedral Isomerizations: Macroscopic Models; 4.1 Topological Representations of Polyhedral Isomerizations; 4.2 Topological Representations of Jahn-Teller Distortions; 5 Acknowledgement; 6 References
2 NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes1 Introduction; 2 Discovery Activation Parameters of [1,3]-B Shifts; 3 Fluxional Linear Polyunsaturated Allylboranes; 3.1 2,4-Pentadienyl(di-n-propyl)borane; 3.2 2,4,6-Heptatrienyl(di-n-propyl)borane; 4 Dynamic Behavior of Cyclic Allylboranes; 4.1 Dynamic Equilibria Between 2-(Dialkylboryl)methylenecyclobutanes and 1-(Dialkylboryl)cyclobutenes; 4.2 Dynamic Properties of Cyclopentadienyl and Pentamethylcyclopentadienyl Derivatives of Boron; 4.3 Synthesis and Dynamic Properties of 1-Indenyl(diethyl)borane 4.4 Dynamic Behavior of Cycloheptadienyl(di-n-propyl)borane4.5 Synthesis and Dynamic Properties of Cycloheptatrienyl(di-n-propyl)borane. Equilibrium with 7-(Di-n-propylboryl)norcaradiene; 4.6 Three Independent Dynamic Processes in the Irontricarbonyl Complex of Cycloheptatrienyl(di-n-propyl)borane; 4.7 Cyclooctatetraenyl(di-n-propyl)borane; 4.8 Sigmatropic Migrations and Thermal Rearrangements in Cyclononatetraenyl(di-n-propyl)borane. Comparison with the Dynamic Properties of Cyclononatetraenyl(trimethyl)tin; 4.9 Borotropic Migrations in Phenalenyl(di-n-propyl)borane 24 5 Diverse Chemoselectivity of Cyclic Polyunsaturated Organoboranes5.1 Chemical Behavior of Borane 23; 5.2 Diverse Chemoselectivity of 9-Cyclopentyl-9-borabarbaralane 54e; 6 Conclusion; 7 References; 3 Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR; 1 Introduction; 2 Rotational Isomerism in Amido and Ketimido Complexes; 2.1 Rotational Isomerism in Oxofluoramido Complexes of Tungsten(VI); 2.2 Restricted M-NR(2) Rotation in the Dinuclear Complexes with M(2)(6+) Core (M = W, Mo) 2.3 Features of Dynamic Behavior of Amido Cyclopentadienyl Complexes of Group 5 Transition Metals2.4 Internal Hindered Rotation of Ketimido Ligands; 3 Dynamic Behavior of d(0) Transition Metal Complexes with n-Donor Two-Center Ligands; 3.1 Isomerization of Fluorocomplexes of Group 5-6 with O, N-Two-Center Ligands; 3.2 Isomerism of Transition Metal Complexes with N, N-Two-center Ligands; 3.3 Nature of Bonding of n-Donor Two-center Ligands in d(0) Transition Metal Complexes; 3.4 Mechanism of Internal Hindered Rotation of h(2)-Bound Ligands; 4 Conclusion; 5 References 4 Conformational Mobility in Chelated Square-planar Rh, Ir, Pd, and Pt Complexes |
| Record Nr. | UNINA-9910145018103321 |
| Hoboken, NJ, : J. Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Fluxional organometallic and coordination compounds / / edited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer
| Fluxional organometallic and coordination compounds / / edited by Marcel Gielen, Rudolph Willem, Bernd Wrackmeyer |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hoboken, NJ, : J. Wiley, c2004 |
| Descrizione fisica | 1 online resource (343 p.) |
| Disciplina | 541/.2242 |
| Altri autori (Persone) |
GielenM <1938-> (Marcel)
WillemR (Rudolf) WrackmeyerBernd <1947-> |
| Collana | Physical organometallic chemistry |
| Soggetto topico |
Coordination compounds
Organometallic chemistry Molecular dynamics Nuclear magnetic resonance spectroscopy |
| ISBN |
1-280-27095-0
9786610270958 0-470-30013-2 0-470-85845-1 0-470-85844-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fluxional Organometallic and Coordination Compounds; Contents; Contributors; Series Preface; Preface; 1 Polyhedral Dynamics and the Jahn-Teller Effect; 1 Introduction; 2 Polyhedron Topology; 3 Polyhedral Isomerizations: Microscopic Models; 3.1 Diamond-Square-Diamond Processes; 3.2 Gale Diagrams; 3.3 Generation of Metallaborane Structures by Diamond-Square-Diamond Transformations in Deltahedra; 4 Polyhedral Isomerizations: Macroscopic Models; 4.1 Topological Representations of Polyhedral Isomerizations; 4.2 Topological Representations of Jahn-Teller Distortions; 5 Acknowledgement; 6 References
2 NMR Studies of Intramolecular Dynamics in Allylic Type Triorganoboranes1 Introduction; 2 Discovery Activation Parameters of [1,3]-B Shifts; 3 Fluxional Linear Polyunsaturated Allylboranes; 3.1 2,4-Pentadienyl(di-n-propyl)borane; 3.2 2,4,6-Heptatrienyl(di-n-propyl)borane; 4 Dynamic Behavior of Cyclic Allylboranes; 4.1 Dynamic Equilibria Between 2-(Dialkylboryl)methylenecyclobutanes and 1-(Dialkylboryl)cyclobutenes; 4.2 Dynamic Properties of Cyclopentadienyl and Pentamethylcyclopentadienyl Derivatives of Boron; 4.3 Synthesis and Dynamic Properties of 1-Indenyl(diethyl)borane 4.4 Dynamic Behavior of Cycloheptadienyl(di-n-propyl)borane4.5 Synthesis and Dynamic Properties of Cycloheptatrienyl(di-n-propyl)borane. Equilibrium with 7-(Di-n-propylboryl)norcaradiene; 4.6 Three Independent Dynamic Processes in the Irontricarbonyl Complex of Cycloheptatrienyl(di-n-propyl)borane; 4.7 Cyclooctatetraenyl(di-n-propyl)borane; 4.8 Sigmatropic Migrations and Thermal Rearrangements in Cyclononatetraenyl(di-n-propyl)borane. Comparison with the Dynamic Properties of Cyclononatetraenyl(trimethyl)tin; 4.9 Borotropic Migrations in Phenalenyl(di-n-propyl)borane 24 5 Diverse Chemoselectivity of Cyclic Polyunsaturated Organoboranes5.1 Chemical Behavior of Borane 23; 5.2 Diverse Chemoselectivity of 9-Cyclopentyl-9-borabarbaralane 54e; 6 Conclusion; 7 References; 3 Dynamic Behavior of Group 5 and 6 Transition Metal Complexes with NMR; 1 Introduction; 2 Rotational Isomerism in Amido and Ketimido Complexes; 2.1 Rotational Isomerism in Oxofluoramido Complexes of Tungsten(VI); 2.2 Restricted M-NR(2) Rotation in the Dinuclear Complexes with M(2)(6+) Core (M = W, Mo) 2.3 Features of Dynamic Behavior of Amido Cyclopentadienyl Complexes of Group 5 Transition Metals2.4 Internal Hindered Rotation of Ketimido Ligands; 3 Dynamic Behavior of d(0) Transition Metal Complexes with n-Donor Two-Center Ligands; 3.1 Isomerization of Fluorocomplexes of Group 5-6 with O, N-Two-Center Ligands; 3.2 Isomerism of Transition Metal Complexes with N, N-Two-center Ligands; 3.3 Nature of Bonding of n-Donor Two-center Ligands in d(0) Transition Metal Complexes; 3.4 Mechanism of Internal Hindered Rotation of h(2)-Bound Ligands; 4 Conclusion; 5 References 4 Conformational Mobility in Chelated Square-planar Rh, Ir, Pd, and Pt Complexes |
| Record Nr. | UNINA-9910817898003321 |
| Hoboken, NJ, : J. Wiley, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||