Copper-catalyzed asymmetric synthesis / / edited by Alexandre Alexakis, Norbert Krause, and Simon Woodward ; Shinya Adachi [and thirty-one others] ; contributors |
Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2014 |
Descrizione fisica | 1 online resource (472 p.) |
Disciplina | 547.2 |
Altri autori (Persone) |
AlexakisAlexandre
KrauseNorbert WoodwardSimon AdachiShinya |
Soggetto topico |
Asymmetric synthesis
Copper catalysts Organocopper compounds Organic compounds - Synthesis |
ISBN |
3-527-66457-2
3-527-66459-9 3-527-66460-2 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Copper-Catalyzed Asymmetric Synthesis; Contents; List of Contributors; Introduction; Chapter 1 The Primary Organometallic in Copper-Catalyzed Reactions; 1.1 Scope and Introduction; 1.2 Terminal Organometallics Sources Available; 1.3 Coordination Motifs in Asymmetric Copper Chemistry; 1.3.1 Classical Cuprate Structure and Accepted Modes of Reaction; 1.3.1.1 Conjugate Addition; 1.3.1.2 SN2 Allylation Reactions; 1.3.2 Motifs in Copper-Main Group Bimetallics and Substrate Binding; 1.4 Asymmetric Organolithium-Copper Reagents; 1.5 Asymmetric Grignard-Copper Reagents
1.6 Asymmetric Organozinc-Copper Reagents1.7 Asymmetric Organoboron-Copper Reagents; 1.8 Asymmetric Organoaluminium-Copper Reagents; 1.9 Asymmetric Silane and Stannane Copper-Promoted Reagents; 1.10 Conclusions; References; Chapter 2 Copper-Catalyzed Asymmetric Conjugate Addition; 2.1 Introduction; 2.2 Conjugate Addition; 2.2.1 The Nucleophile; 2.2.2 The Copper Salt; 2.2.3 The Ligand; 2.2.4 Scope of Michael Acceptors; 2.2.4.1 Enones; 2.2.4.2 Enals; 2.2.4.3 Nitroalkenes; 2.2.4.4 α,β-Unsaturated Amide and Ester Derivatives; 2.2.4.5 Other Michael Acceptors 2.2.5 Formation of All-Carbon Quaternary Stereocenters2.3 Trapping of Enolates; References; Chapter 3 Copper-Catalyzed Asymmetric Conjugate Addition and Allylic Substitution of Organometallic Reagents to Extended Multiple-Bond Systems; 3.1 Introduction; 3.2 Copper-Catalyzed Asymmetric Conjugate Addition (ACA) to Polyconjugated Michael Acceptors; 3.2.1 Background; 3.2.2 1,6 Selectivity in ACA to Polyconjugated Systems; 3.2.3 1,4 Selectivity in ACA to Polyconjugated Systems; 3.3 Copper-Catalyzed Asymmetric Allylic Substitution on Extended Multiple-Bond Systems; 3.3.1 Background 3.3.2 Copper-Catalyzed Enantioselective Allylic Substitution on Extended Multiple-Bond Systems3.4 Conclusion; References; Chapter 4 Asymmetric Allylic Alkylation; 4.1 Introduction; 4.2 Nucleophiles in Enantioselective Process Development; 4.2.1 Grignard Nucleophiles; 4.2.2 Diorganozinc Nucleophiles; 4.2.3 Triorganoaluminium Nucleophiles; 4.2.4 Organoboranes Nucleophiles; 4.2.5 Organolithium Nucleophiles; 4.3 Functionalized Substrates; 4.3.1 Trisubstituted Substrates; 4.3.2 Ester Derivatives; 4.3.3 Heterofunctionalized Substrates; 4.3.4 Vinylic Boronates and Silanes 4.3.5 Substrates Bearing Two Leaving Groups (1,4 or 1,1')4.3.6 Enyne-Type Substrates; 4.4 Desymmetrization of meso-Allylic Substrates; 4.4.1 Polycyclic Hydrazines, Symmetric Allylic Epoxides, Oxabicyclic Alkenes; 4.4.2 Cyclic Allylic Bis(Diethyl phosphates); 4.4.3 Miscellaneous Desymmetrization; 4.5 Kinetic Resolution Processes; 4.5.1 Allylic Epoxides and Aziridines, Oxabicyclic Alkenes, Bicyclic Oxazines; 4.5.2 Stereodivergent Kinetic Resolution on Acyclic Allylic Halides; 4.6 Direct Enantioconvergent Transformation; 4.7 Conclusion and Perspectives; References Chapter 5 Ring Opening of Epoxides and Related Systems |
Record Nr. | UNINA-9910138966103321 |
Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2014 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Copper-catalyzed asymmetric synthesis / / edited by Alexandre Alexakis, Norbert Krause, and Simon Woodward ; Shinya Adachi [and thirty-one others] ; contributors |
Pubbl/distr/stampa | Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2014 |
Descrizione fisica | 1 online resource (472 p.) |
Disciplina | 547.2 |
Altri autori (Persone) |
AlexakisAlexandre
KrauseNorbert WoodwardSimon AdachiShinya |
Soggetto topico |
Asymmetric synthesis
Copper catalysts Organocopper compounds Organic compounds - Synthesis |
ISBN |
3-527-66457-2
3-527-66459-9 3-527-66460-2 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Copper-Catalyzed Asymmetric Synthesis; Contents; List of Contributors; Introduction; Chapter 1 The Primary Organometallic in Copper-Catalyzed Reactions; 1.1 Scope and Introduction; 1.2 Terminal Organometallics Sources Available; 1.3 Coordination Motifs in Asymmetric Copper Chemistry; 1.3.1 Classical Cuprate Structure and Accepted Modes of Reaction; 1.3.1.1 Conjugate Addition; 1.3.1.2 SN2 Allylation Reactions; 1.3.2 Motifs in Copper-Main Group Bimetallics and Substrate Binding; 1.4 Asymmetric Organolithium-Copper Reagents; 1.5 Asymmetric Grignard-Copper Reagents
1.6 Asymmetric Organozinc-Copper Reagents1.7 Asymmetric Organoboron-Copper Reagents; 1.8 Asymmetric Organoaluminium-Copper Reagents; 1.9 Asymmetric Silane and Stannane Copper-Promoted Reagents; 1.10 Conclusions; References; Chapter 2 Copper-Catalyzed Asymmetric Conjugate Addition; 2.1 Introduction; 2.2 Conjugate Addition; 2.2.1 The Nucleophile; 2.2.2 The Copper Salt; 2.2.3 The Ligand; 2.2.4 Scope of Michael Acceptors; 2.2.4.1 Enones; 2.2.4.2 Enals; 2.2.4.3 Nitroalkenes; 2.2.4.4 α,β-Unsaturated Amide and Ester Derivatives; 2.2.4.5 Other Michael Acceptors 2.2.5 Formation of All-Carbon Quaternary Stereocenters2.3 Trapping of Enolates; References; Chapter 3 Copper-Catalyzed Asymmetric Conjugate Addition and Allylic Substitution of Organometallic Reagents to Extended Multiple-Bond Systems; 3.1 Introduction; 3.2 Copper-Catalyzed Asymmetric Conjugate Addition (ACA) to Polyconjugated Michael Acceptors; 3.2.1 Background; 3.2.2 1,6 Selectivity in ACA to Polyconjugated Systems; 3.2.3 1,4 Selectivity in ACA to Polyconjugated Systems; 3.3 Copper-Catalyzed Asymmetric Allylic Substitution on Extended Multiple-Bond Systems; 3.3.1 Background 3.3.2 Copper-Catalyzed Enantioselective Allylic Substitution on Extended Multiple-Bond Systems3.4 Conclusion; References; Chapter 4 Asymmetric Allylic Alkylation; 4.1 Introduction; 4.2 Nucleophiles in Enantioselective Process Development; 4.2.1 Grignard Nucleophiles; 4.2.2 Diorganozinc Nucleophiles; 4.2.3 Triorganoaluminium Nucleophiles; 4.2.4 Organoboranes Nucleophiles; 4.2.5 Organolithium Nucleophiles; 4.3 Functionalized Substrates; 4.3.1 Trisubstituted Substrates; 4.3.2 Ester Derivatives; 4.3.3 Heterofunctionalized Substrates; 4.3.4 Vinylic Boronates and Silanes 4.3.5 Substrates Bearing Two Leaving Groups (1,4 or 1,1')4.3.6 Enyne-Type Substrates; 4.4 Desymmetrization of meso-Allylic Substrates; 4.4.1 Polycyclic Hydrazines, Symmetric Allylic Epoxides, Oxabicyclic Alkenes; 4.4.2 Cyclic Allylic Bis(Diethyl phosphates); 4.4.3 Miscellaneous Desymmetrization; 4.5 Kinetic Resolution Processes; 4.5.1 Allylic Epoxides and Aziridines, Oxabicyclic Alkenes, Bicyclic Oxazines; 4.5.2 Stereodivergent Kinetic Resolution on Acyclic Allylic Halides; 4.6 Direct Enantioconvergent Transformation; 4.7 Conclusion and Perspectives; References Chapter 5 Ring Opening of Epoxides and Related Systems |
Record Nr. | UNINA-9910824691103321 |
Weinheim an der Bergstrasse, Germany : , : Wiley-VCH Verlag GmbH & Co., , 2014 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|
Modern Organoaluminum Reagents : Preparation, Structure, Reactivity and Use / / edited by Simon Woodward, Samuel Dagorne |
Edizione | [1st ed. 2013.] |
Pubbl/distr/stampa | Berlin, Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2013 |
Descrizione fisica | 1 online resource (XI, 312 p. 131 illus., 42 illus. in color.) |
Disciplina | 547.05 |
Collana | Topics in Organometallic Chemistry |
Soggetto topico |
Organometallic chemistry
Catalysis Organic chemistry Organometallic Chemistry Organic Chemistry |
ISBN | 3-642-33672-8 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto | Janusz Lewiński and Andrew E. H. Wheatley: Simple trivalent organoaluminum species: perspectives on structure, bonding and reactivity -- Stephan Schulz: Organoaluminum complexes with bonds to s-block, p-block, d-block, and f-block metal centers -- Samuel Dagorne and Christophe Fliedel: Low valent organoaluminium (+I, +II) species -- Rudolf Wehmschulte: Organoaluminum species in homogeneous polymerization catalysis -- Paul Knochel, Tobias Blümke, Klaus Groll and Yi-Hung Chen: Preparation of Organoalanes for Organic Synthesis -- Yuki Naganawa and Keiji Maruoka: Reactions Triggered by Lewis Acidic Organoaluminum Species -- Usein M. Dzhemilev and Vladimir A. D'yakonov: Hydro-, Carbo- and Cycloalumination of Unsaturated Compounds -- Andreas Kolb and Paultheo von Zezschwitz: Organoaluminum Couplings to Carbonyls, Imines and Halides -- Oscar Pàmies and Montserrat Diéguez: Conjugate Addition of Organoaluminum Species to Michael Acceptors and Related Processes. |
Record Nr. | UNINA-9910768189003321 |
Berlin, Heidelberg : , : Springer Berlin Heidelberg : , : Imprint : Springer, , 2013 | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
|