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Microreactors in organic synthesis and catalysis / / edited by Thomas Wirth
| Microreactors in organic synthesis and catalysis / / edited by Thomas Wirth |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (299 p.) |
| Disciplina |
547.2
660.2832 |
| Soggetto topico |
Microreactors
Organic compounds - Synthesis Catalysis |
| ISBN |
1-281-94705-9
9786611947057 3-527-62285-3 3-527-62286-1 |
| Classificazione | 35.52 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Microreactors in Organic Synthesis and Catalysis; Contents; Preface; List of Contributors; 1 Fabrication of Microreactors Made from Metals and Ceramics; 1.1 Manufacturing Techniques for Metals; 1.1.1 Etching; 1.1.2 Machining; 1.1.3 Generative Method: Selective Laser Melting (SLM); 1.1.4 Metal-Forming Techniques; 1.1.5 Assembling and Bonding of Metal Microstructures; 1.2 Ceramic Devices; 1.2.1 Joining and Sealing; References; 2 Fabrication and Assembling of Microreactors Made from Glass and Silicon; 2.1 How Microreactors are Constructed; 2.2 Glass as Material; 2.3 Silicon as Material
2.4 The Structuring of Glass and Silicon2.5 Structuring by Means of Masked Etching in Microsystems Technology; 2.6 Etching Technologies; 2.6.1 Anisotropic (Crystallographic) Wet Chemical Etching of Silicon (KOH); 2.6.2 Isotropic Wet Chemical Etching of Silicon; 2.6.3 Anisotropic Dry Etching of Silicon; 2.6.4 Isotropic Wet Chemical Etching of Silicon Glass; 2.6.5 Photostructuring of Special Glass; 2.7 Chip Removing Processing; 2.7.1 Drilling, Diamond Lapping, Ultrasonic Lapping; 2.7.2 Micropowder Blasting; 2.7.3 Summary; 2.8 Bonding Methods; 2.8.1 Anodic Bonding of Glass and Silicon 2.8.2 Silicon Direct Bonding (Silicon Fusion Bonding)2.8.3 Glass Fusion Bonding; 2.9 Establishing Fluid Contact; 2.10 Other Materials; References; 3 Properties and Use of Microreactors; 3.1 Introduction; 3.2 Physical Characteristics of Microreactors; 3.2.1 Geometries; 3.2.2 Constructional Materials and Their Properties; 3.3 Fluid Flow and Delivery Regimes; 3.3.1 Fluid Flow; 3.3.2 Fluid Delivery; 3.3.3 Mixing Mechanisms; 3.4 Multifunctional Integration; 3.5 Uses of Microreactors; 3.5.1 Overview; 3.5.2 Unstable Intermediates Fast and Exothermic Reactions; 3.5.3 Precision Particle Manufacture 3.5.4 Wider Industrial Context3.5.4.1 Sustainability Agenda; 3.5.4.2 Point-of-Demand Synthesis; References; 4 Organic Chemistry in Microreactors; 4.1 Homogeneous Reactions; 4.1.1 Acid-Promoted Reactions; 4.1.2 Base-Promoted Reactions; 4.1.3 Condensation Reactions; 4.1.4 Metal-Catalyzed Reactions; 4.1.5 Photochemical Reactions; 4.1.6 Electrochemical Reactions; 4.1.7 Miscellaneous; 4.1.7.1 Swern Oxidation; 4.1.7.2 Grignard Exchange Reaction; 4.1.7.3 Lithium-Halogen Exchange Reaction; 4.1.7.4 Phenyl Boronic Acid Synthesis; References; 4.2 Heterogeneous Reactions; 4.2.1 Introduction 4.2.2 Concepts in Flow Mode Synthesis4.2.3 Methods of Conducting Flow Chemistry; 4.2.3.1 On-Bead Synthesis; 4.2.3.2 Solution-Phase Synthesis; 4.2.3.3 Library Synthesis in Flow; 4.2.3.4 Heterocycle Synthesis; 4.2.4 Introduction to Monoliths; 4.2.5 Transition Metal Chemistry Under Flow Conditions; 4.2.5.1 Reduction; 4.2.5.2 Oxidation; 4.2.5.3 Cross-Coupling Reactions; 4.2.5.4 Olefin Metathesis; 4.2.6 Enantioselective Reactions; 4.2.6.1 Hydrolytic Kinetic Resolution; 4.2.6.2 Organometallic Additions; 4.2.6.3 Enantioselective Diels-Alder Reactions; 4.2.6.4 Ene Reactions; 4.2.6.5 Cyclopropanation 4.2.6.6 Asymmetric Conjugate Addition |
| Record Nr. | UNINA-9910144109703321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Microreactors in organic synthesis and catalysis / / edited by Thomas Wirth
| Microreactors in organic synthesis and catalysis / / edited by Thomas Wirth |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (299 p.) |
| Disciplina |
547.2
660.2832 |
| Soggetto topico |
Microreactors
Organic compounds - Synthesis Catalysis |
| ISBN |
1-281-94705-9
9786611947057 3-527-62285-3 3-527-62286-1 |
| Classificazione | 35.52 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Microreactors in Organic Synthesis and Catalysis; Contents; Preface; List of Contributors; 1 Fabrication of Microreactors Made from Metals and Ceramics; 1.1 Manufacturing Techniques for Metals; 1.1.1 Etching; 1.1.2 Machining; 1.1.3 Generative Method: Selective Laser Melting (SLM); 1.1.4 Metal-Forming Techniques; 1.1.5 Assembling and Bonding of Metal Microstructures; 1.2 Ceramic Devices; 1.2.1 Joining and Sealing; References; 2 Fabrication and Assembling of Microreactors Made from Glass and Silicon; 2.1 How Microreactors are Constructed; 2.2 Glass as Material; 2.3 Silicon as Material
2.4 The Structuring of Glass and Silicon2.5 Structuring by Means of Masked Etching in Microsystems Technology; 2.6 Etching Technologies; 2.6.1 Anisotropic (Crystallographic) Wet Chemical Etching of Silicon (KOH); 2.6.2 Isotropic Wet Chemical Etching of Silicon; 2.6.3 Anisotropic Dry Etching of Silicon; 2.6.4 Isotropic Wet Chemical Etching of Silicon Glass; 2.6.5 Photostructuring of Special Glass; 2.7 Chip Removing Processing; 2.7.1 Drilling, Diamond Lapping, Ultrasonic Lapping; 2.7.2 Micropowder Blasting; 2.7.3 Summary; 2.8 Bonding Methods; 2.8.1 Anodic Bonding of Glass and Silicon 2.8.2 Silicon Direct Bonding (Silicon Fusion Bonding)2.8.3 Glass Fusion Bonding; 2.9 Establishing Fluid Contact; 2.10 Other Materials; References; 3 Properties and Use of Microreactors; 3.1 Introduction; 3.2 Physical Characteristics of Microreactors; 3.2.1 Geometries; 3.2.2 Constructional Materials and Their Properties; 3.3 Fluid Flow and Delivery Regimes; 3.3.1 Fluid Flow; 3.3.2 Fluid Delivery; 3.3.3 Mixing Mechanisms; 3.4 Multifunctional Integration; 3.5 Uses of Microreactors; 3.5.1 Overview; 3.5.2 Unstable Intermediates Fast and Exothermic Reactions; 3.5.3 Precision Particle Manufacture 3.5.4 Wider Industrial Context3.5.4.1 Sustainability Agenda; 3.5.4.2 Point-of-Demand Synthesis; References; 4 Organic Chemistry in Microreactors; 4.1 Homogeneous Reactions; 4.1.1 Acid-Promoted Reactions; 4.1.2 Base-Promoted Reactions; 4.1.3 Condensation Reactions; 4.1.4 Metal-Catalyzed Reactions; 4.1.5 Photochemical Reactions; 4.1.6 Electrochemical Reactions; 4.1.7 Miscellaneous; 4.1.7.1 Swern Oxidation; 4.1.7.2 Grignard Exchange Reaction; 4.1.7.3 Lithium-Halogen Exchange Reaction; 4.1.7.4 Phenyl Boronic Acid Synthesis; References; 4.2 Heterogeneous Reactions; 4.2.1 Introduction 4.2.2 Concepts in Flow Mode Synthesis4.2.3 Methods of Conducting Flow Chemistry; 4.2.3.1 On-Bead Synthesis; 4.2.3.2 Solution-Phase Synthesis; 4.2.3.3 Library Synthesis in Flow; 4.2.3.4 Heterocycle Synthesis; 4.2.4 Introduction to Monoliths; 4.2.5 Transition Metal Chemistry Under Flow Conditions; 4.2.5.1 Reduction; 4.2.5.2 Oxidation; 4.2.5.3 Cross-Coupling Reactions; 4.2.5.4 Olefin Metathesis; 4.2.6 Enantioselective Reactions; 4.2.6.1 Hydrolytic Kinetic Resolution; 4.2.6.2 Organometallic Additions; 4.2.6.3 Enantioselective Diels-Alder Reactions; 4.2.6.4 Ene Reactions; 4.2.6.5 Cyclopropanation 4.2.6.6 Asymmetric Conjugate Addition |
| Record Nr. | UNINA-9910830276603321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic synthesis highlights V / / edited by Hans-Cunther Schmalz and Thomas Wirth
| Organic synthesis highlights V / / edited by Hans-Cunther Schmalz and Thomas Wirth |
| Pubbl/distr/stampa | Weinheim : , : WILEY-VCH Verlag, , 2003 |
| Descrizione fisica | 1 online resource (454 p.) |
| Disciplina | 547.2 |
| Soggetto topico | Organic compounds - Synthesis |
| ISBN |
1-281-84284-2
9786611842840 3-527-61998-4 3-527-62049-4 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organic Synthesis Highlights V; Contents; Preface; List of Contributors; Part I. Synthetic Methods; Direct Conversion of Sugar Glycosides into Carbocycles; Synthesis of Diaryl Ethers: A Long-standing Problem Has Been Solved; Take The Right Catalyst: Palladium-Catalyzed CC-, CN- and CO-Bond Formation on Chloro-Arenes; Alkyne Metathesis in Natural Product Synthesis; Transition Metal-Catalyzed Functionalization of Alkanes; An Eldorado for Homogeneous Catalysis?; New and Selective Transition Metal Catalyzed Reactions of Allenes
Controlling Stereoselectivity with the Aid of a Reagent-Directing GroupSolvent-Free Organic Syntheses; Fluorous Techniques: Progress in Reaction-Processing and Purification; Recent Developments in Using Ionic Liquids as Solvents and Catalysts for Organic Synthesis; Recent Advances on the Sharpless Asymmetric Aminohydroxylation; Asymmetric Phase Transfer Catalysis; Asymmetric Catalytic Aminoalkylations: New Powerful Methods for the Enantioselective Synthesis of Amino Acid Derivatives, Mannich Bases, and Homoallylic Amines; IBX - New Reactions with an Old Reagent; Parallel Kinetic Resolutions The Asymmetric Baylis-Hillman-ReactionSimple Amino Acids and Short-Chain Peptides as Efficient Metal-free Catalysts in Asymmetric Synthesis; Recent Developments in Catalytic Asymmetric Strecker-Type Reactions; Highly Enantioselective or Not? - Chiral Monodentate Monophosphorus Ligands in the Asymmetric Hydrogenation; Improving Enantioselective Fluorination Reactions: Chiral N-Fluoro Ammonium Salts and Transition Metal Catalysts; Catalytic Asymmetric Olefin Metathesis; Activating Protecting Groups for the Solid Phase Synthesis and Modification of Peptides, Oligonucleotides and Oligosaccharides Traceless Linkers for Solid-Phase Organic SynthesisMerging Solid-Phase and Solution-Phase Synthesis: The "Resin-Capture-Release" Hybrid Technique; Polymeric Scavenger Reagents in Organic Synthesis; Part II. Applications; Total Syntheses of Vancomycin; Bryostatin and Their Analogues; Eleutherobin: Synthesis, Structure/Activity Relationship, and Pharmacophore; Total Synthesis of the Natural Products CP-263,114 and CP-225,917; Polyene Cyclization to Adociasulfate 1; Sanglifehrin A: an Immunosuppressant Natural Product from Malawi; Short Syntheses of the Spirotryprostatins The Chemical Total Synthesis of ProteinsSolid-Phase Synthesis of Oligosaccharides; Polymer-Supported Synthesis of Non-Oligomeric Natural Products; Explosions as a Synthetic Tool? Cycloalkynes as Precursors to Fullerenes, Buckytubes and Buckyonions; Dendralenes: From a Neglected Class of Polyenes to Versatile Starting Materials in Organic Synthesis; Fascinating Natural and Artificial Cyclopropane Architectures; Index |
| Record Nr. | UNINA-9910829991803321 |
| Weinheim : , : WILEY-VCH Verlag, , 2003 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organoselenium chemistry [[electronic resource] ] : synthesis and reactions / / edited by Thomas Wirth
| Organoselenium chemistry [[electronic resource] ] : synthesis and reactions / / edited by Thomas Wirth |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2012 |
| Descrizione fisica | 1 online resource (464 p.) |
| Disciplina | 547.05724 |
| Altri autori (Persone) | WirthThomas <1964-> |
| Soggetto topico |
Organoselenium compounds
Selenium compounds |
| ISBN |
3-527-64195-5
1-283-86988-8 3-527-64196-3 3-527-64194-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organoselenium Chemistry: Synthesis and Reactions; Contents; Preface; List of Contributors; 1: Electrophilic Selenium; 1.1 General Introduction; 1.1.1 Synthesis of Electrophilic Selenium Reagents; 1.1.2 Reactivity and Properties; 1.2 Addition Reactions to Double Bonds; 1.2.1 Addition Reaction Involving Oxygen-Centered Nucleophiles; 1.2.2 Addition Reaction Involving Nitrogen-Centered Nucleophiles; 1.2.3 Addition Reactions Involving Carbon-Centered Nucleophiles; 1.2.4 Addition Reaction Involving Chiral Nucleophiles or Chiral Substrates; 1.3 Selenocyclizations; 1.3.1 Oxygen Nucleophiles
1.3.2 Nitrogen Nucleophiles1.3.3 Competition between Oxygen and Nitrogen Nucleophiles; 1.3.4 Carbon Nucleophiles; 1.3.5 Double Cyclization Reactions; References; 2: Nucleophilic Selenium; 2.1 Introduction; 2.1.1 Development of Nucleophilic Selenium Reagents; 2.1.2 Examples of Recent Applications; 2.2 Properties of Selenols and Selenolates; 2.2.1 Electronegativity of Selenium; 2.2.2 Tautomerism of Selenols; 2.2.3 Nucleophilicity of Selenolates; 2.3 Inorganic Nucleophilic Selenium Reagents; 2.3.1 Conventional Reagents; 2.3.2 New Reagents; 2.4 Organic Nucleophilic Selenium Reagents 2.4.1 Preparation 2.4.2 Structure; 2.4.3 Ammonium Selenolates (NH4+); 2.4.4 Selenolates of Group 1 Elements (Li, Na, K, and Cs); 2.4.5 Selenolates of Group 2 Elements (Mg, Ca, and Ba); 2.4.6 Selenolates of Group 3 Elements (Sm, Ce, Pr, Nb, and U); 2.4.7 Selenolates of Group 4 Elements (Ti, Zr, and Hf); 2.4.8 Selenolates of Group 5 Elements (V, Nb, and Ta); 2.4.9 Selenolates of Group 6 Elements (Mo and W); 2.4.10 Selenolates of Group 7 Elements (Mn and Re); 2.4.11 Selenolates of Group 8 Elements (Fe, Ru, and Os); 2.4.12 Selenolates of Group 9 Elements (Co, Rh, and Ir) 2.4.13 Selenolates of Group 10 Elements (Ni, Pd, and Pt)2.4.14 Selenolates of Group 11 Elements (Cu, Ag, and Au); 2.4.15 Selenolates of Group 12 Elements (Zn, Cd, and Hg); 2.4.16 Selenolates of Group 13 Elements (B, Al, Ga, and In); 2.4.17 Selenolates of Group 14 Elements (Si, Ge, Sn, and Pb); 2.4.18 Selenolates of Group 15 Elements (P, As, Sb, and Bi); References; 3: Selenium Compounds in Radical Reactions; 3.1 Homolytic Substitution at Selenium to Generate Radical Precursors; 3.1.1 Bimolecular SH2 Reactions: Synthetic Considerations; 3.1.1.1 Radical Reagents 3.1.2 Alkyl Radicals from Selenide Precursors 3.1.3 Acyl Radicals from Acyl Selenide Precursors; 3.1.4 Imidoyl Radicals from Imidoyl Selenides; 3.1.5 Other Radicals from Selenide Precursors; 3.2 Selenide Building Blocks; 3.3 Solid-Phase Synthesis; 3.4 Selenide Precursors in Radical Domino Reactions; 3.5 Homolytic Substitution at Selenium for the Synthesis of Se-Containing Products; 3.5.1 Intermolecular SH2 onto Se; 3.5.2 Intramolecular SH2: Cyclization onto Se; 3.6 Seleno Group Transfer onto Alkenes and Alkynes; 3.6.1 Seleno-Selenation; 3.6.2 Seleno-Sulfonation; 3.6.3 Seleno-Alkylation 3.7 PhSeH in Radical Reactions |
| Record Nr. | UNINA-9910137967603321 |
| Weinheim, : Wiley-VCH, c2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organoselenium chemistry : synthesis and reactions / / edited by Thomas Wirth
| Organoselenium chemistry : synthesis and reactions / / edited by Thomas Wirth |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2012 |
| Descrizione fisica | 1 online resource (464 p.) |
| Disciplina | 547.05724 |
| Altri autori (Persone) | WirthThomas <1964-> |
| Soggetto topico |
Organoselenium compounds
Selenium compounds |
| ISBN |
3-527-64195-5
1-283-86988-8 3-527-64196-3 3-527-64194-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organoselenium Chemistry: Synthesis and Reactions; Contents; Preface; List of Contributors; 1: Electrophilic Selenium; 1.1 General Introduction; 1.1.1 Synthesis of Electrophilic Selenium Reagents; 1.1.2 Reactivity and Properties; 1.2 Addition Reactions to Double Bonds; 1.2.1 Addition Reaction Involving Oxygen-Centered Nucleophiles; 1.2.2 Addition Reaction Involving Nitrogen-Centered Nucleophiles; 1.2.3 Addition Reactions Involving Carbon-Centered Nucleophiles; 1.2.4 Addition Reaction Involving Chiral Nucleophiles or Chiral Substrates; 1.3 Selenocyclizations; 1.3.1 Oxygen Nucleophiles
1.3.2 Nitrogen Nucleophiles1.3.3 Competition between Oxygen and Nitrogen Nucleophiles; 1.3.4 Carbon Nucleophiles; 1.3.5 Double Cyclization Reactions; References; 2: Nucleophilic Selenium; 2.1 Introduction; 2.1.1 Development of Nucleophilic Selenium Reagents; 2.1.2 Examples of Recent Applications; 2.2 Properties of Selenols and Selenolates; 2.2.1 Electronegativity of Selenium; 2.2.2 Tautomerism of Selenols; 2.2.3 Nucleophilicity of Selenolates; 2.3 Inorganic Nucleophilic Selenium Reagents; 2.3.1 Conventional Reagents; 2.3.2 New Reagents; 2.4 Organic Nucleophilic Selenium Reagents 2.4.1 Preparation 2.4.2 Structure; 2.4.3 Ammonium Selenolates (NH4+); 2.4.4 Selenolates of Group 1 Elements (Li, Na, K, and Cs); 2.4.5 Selenolates of Group 2 Elements (Mg, Ca, and Ba); 2.4.6 Selenolates of Group 3 Elements (Sm, Ce, Pr, Nb, and U); 2.4.7 Selenolates of Group 4 Elements (Ti, Zr, and Hf); 2.4.8 Selenolates of Group 5 Elements (V, Nb, and Ta); 2.4.9 Selenolates of Group 6 Elements (Mo and W); 2.4.10 Selenolates of Group 7 Elements (Mn and Re); 2.4.11 Selenolates of Group 8 Elements (Fe, Ru, and Os); 2.4.12 Selenolates of Group 9 Elements (Co, Rh, and Ir) 2.4.13 Selenolates of Group 10 Elements (Ni, Pd, and Pt)2.4.14 Selenolates of Group 11 Elements (Cu, Ag, and Au); 2.4.15 Selenolates of Group 12 Elements (Zn, Cd, and Hg); 2.4.16 Selenolates of Group 13 Elements (B, Al, Ga, and In); 2.4.17 Selenolates of Group 14 Elements (Si, Ge, Sn, and Pb); 2.4.18 Selenolates of Group 15 Elements (P, As, Sb, and Bi); References; 3: Selenium Compounds in Radical Reactions; 3.1 Homolytic Substitution at Selenium to Generate Radical Precursors; 3.1.1 Bimolecular SH2 Reactions: Synthetic Considerations; 3.1.1.1 Radical Reagents 3.1.2 Alkyl Radicals from Selenide Precursors 3.1.3 Acyl Radicals from Acyl Selenide Precursors; 3.1.4 Imidoyl Radicals from Imidoyl Selenides; 3.1.5 Other Radicals from Selenide Precursors; 3.2 Selenide Building Blocks; 3.3 Solid-Phase Synthesis; 3.4 Selenide Precursors in Radical Domino Reactions; 3.5 Homolytic Substitution at Selenium for the Synthesis of Se-Containing Products; 3.5.1 Intermolecular SH2 onto Se; 3.5.2 Intramolecular SH2: Cyclization onto Se; 3.6 Seleno Group Transfer onto Alkenes and Alkynes; 3.6.1 Seleno-Selenation; 3.6.2 Seleno-Sulfonation; 3.6.3 Seleno-Alkylation 3.7 PhSeH in Radical Reactions |
| Record Nr. | UNINA-9910827565403321 |
| Weinheim, : Wiley-VCH, c2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||