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Synthesis and Application of Organoboron Compounds / / edited by Elena Fernández, Andrew Whiting
| Synthesis and Application of Organoboron Compounds / / edited by Elena Fernández, Andrew Whiting |
| Edizione | [1st ed. 2015.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015 |
| Descrizione fisica | 1 online resource (VII, 331 p. 492 illus., 14 illus. in color.) |
| Disciplina | 547.05671 |
| Collana | Topics in Organometallic Chemistry |
| Soggetto topico |
Organometallic chemistry
Catalysis Chemical engineering Organometallic Chemistry Industrial Chemistry/Chemical Engineering |
| ISBN | 3-319-13054-4 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- Preface -- Contents -- Boryl Anions -- 1 Introduction: History of Boryl Anions Before 2006 -- 2 Chemistry of Boryl Anions -- 2.1 Base-Stabilized Boryl Anions -- 2.2 N-Heterocyclic Boryl Anions -- 2.3 Boryl Anion Derivatives as a Counterpart of Carboanions -- 2.4 Base-Coordinated Diborane(4) as Boryl Anion Equivalents -- 3 Chemistry of Boryl-Transition Metal Complexes Derived from Boryl Anion -- 3.1 Boryl Complexes of Late Transition Metals (Groups 11-12) -- 3.2 Boryl Complexes of Early Transition Metals (Groups 3-5) -- 4 Chemistry of Boryl-Substituted Main Group Element Compounds Derived from Boryl Anions -- 4.1 Boryl-Substituted Group 13 Element Compounds -- 4.2 Boryl-Substituted Group 14 Element Compounds -- 4.3 Boryl-Substituted Group 15 Element Compounds -- 5 Summary and Outlook -- References -- Fundamental and Applied Properties of Borocations -- 1 Introduction -- 2 Fundamentals -- 2.1 Select Synthetic Considerations -- 2.2 Electrophilicity of Borocations -- 2.3 General Reactivity Pathways of Borocations with Nucleophiles -- 3 Borocations in Dehydroboration -- 3.1 Intramolecular Electrophilic Aromatic Borylation -- 3.2 Intramolecular Electrophilic Aliphatic Borylation -- 3.3 Intermolecular Electrophilic Aromatic Borylation -- 4 Borocations in Elemento-Boration -- 4.1 Hydroboration -- 4.2 Other Elemento-Boration Reactions -- 5 Borocations in Catalysis -- 6 Miscellaneous Applications of Borocations -- 6.1 Materials Applications -- 6.2 Borocations as Precursors to Borylenes and Boryl Radicals -- 6.3 Structural Rearrangement of Borocations -- 7 Conclusions and Future Outlook -- References -- Asymmetric Catalytic Borylation of α,beta-Unsaturated Acceptors -- 1 Introduction -- 2 Asymmetric beta-Borylation with Transition Metal Catalysts -- 2.1 Cu-Catalyzed beta-Borylation -- 2.1.1 beta-Monosubstituted Acyclic Substrates.
2.1.2 beta,beta-Disubstituted Acyclic Substrates: Formation of Organoboronates with a Quaternary Carbon -- 2.1.3 Cyclic Compounds -- 2.1.4 α,beta-Unsaturated C=N Compounds and N-Containing Compounds -- 2.1.5 Extended Michael Acceptors -- 2.2 Rh-Catalyzed beta-Borylation -- 2.3 Ni- and Pd-Catalyzed beta-Borylation -- 3 Asymmetric beta-Borylation with Organocatalysts -- 4 Asymmetric beta-Borylation in Water -- 5 Conclusions -- References -- Reactions of Alkynylboron Compounds -- 1 Introduction -- 2 Alkynylboronates (Esters of Alkynylboronic Acids) -- 2.1 Preparations -- 2.2 Insertion Reactions -- 2.3 Cycloaddition Reactions -- 2.4 Miscellaneous -- 3 Alkynylborates (Ate-Complexes) -- 3.1 Preparations -- 3.2 Uncatalyzed Reactions -- 3.3 Transition Metal-Catalyzed Reactions -- 3.4 Reactions Through Intermediacy of Alkynyl(Triorganyl)Borates -- 4 Conclusions -- References -- Improving Transformations Through Organotrifluoroborates -- 1 Introduction -- 2 Improvements Toward Organotrifluoroborate Synthesis -- 3 Recent Advances in C-C Bond Formation with Organotrifluoroborates -- 3.1 Cross-Coupling of Novel Organotrifluoroborates -- 3.2 Improved Incorporation of Important Scaffolds -- 3.3 C-H Functionalization with Organotrifluoroborates -- 3.4 Enantioselective C-C Bond Formation -- 3.5 Radical Reactions with Organotrifluoroborates -- 4 C-Y Bond Formation from Organotrifluoroborates -- 4.1 C-O Bond Formation -- 4.2 C-N Bond Formation -- 4.3 C-X Bond Formation -- 5 Using Organotrifluoroborates to Construct Novel Scaffolds -- 6 Conclusions and Outlook -- References -- The Catalytic Dehydrocoupling of Amine-Boranes and Phosphine-Boranes -- 1 Introduction -- 2 Transition-Metal-Catalysed Dehydrocoupling of Amine-Boranes -- 2.1 General Considerations -- 2.2 Aminoboranes: Observation and Trapping -- 2.3 Linear Diborazanes. 2.4 Early Examples of Metal-Catalysed Dehydrocoupling -- 2.5 Heterogeneous Catalysts for the Dehydrocoupling of Amine-Boranes -- 2.6 Transition-Metal-Catalysed Dehydrocoupling of H3BNH3 Promoted by Ionic Liquids -- 2.7 Homogeneous Dehydrocoupling of Amine-Boranes -- 2.7.1 Sigma Complexes of Amine-Boranes -- 2.8 Mechanistic Studies on Homogeneous Dehydrocoupling Systems -- 2.8.1 Early Transition Metals -- 2.8.2 Mid-Transition Metals -- 2.8.3 Late Transition Metals -- 2.8.4 Dehydrocoupling of Amine-Boranes Involving Ligand Cooperativity -- 2.8.5 The Role of Solvent in Dehydrocoupling Using Late Transition Metals -- 2.9 Generic Mechanisms for Dehydrocoupling of H3BNMe2H Using Transition Metals -- 2.10 Main-Group Element-Catalysed Dehydrocoupling of Amine-Boranes -- 2.10.1 Main-Group Amidoboranes: Stoichiometric Studies -- 2.10.2 Group 2 Metal-Catalysed Dehydrocoupling of Amine-Boranes -- 2.10.3 Group 3 Metal-Catalysed Dehydrocoupling of Amine-Boranes -- 2.10.4 P-Block-Catalysed Dehydrocoupling of Amine-Boranes -- 2.10.5 Frustrated Lewis Pair Dehydrogenation of Amine-Boranes -- 3 Dehydrocoupling of Phosphine-Boranes -- 3.1 Transition-Metal-Catalysed Dehydrocoupling of Phosphine-Boranes -- 3.2 Determination of the Active Catalytic Species: Hetero- or Homogeneous -- 3.3 Sigma Complexes and B-Agostic Interactions of Phosphine-Boranes -- 3.4 Stabilised Phosphinoboranes -- 3.5 Group 8 Metal-Catalysed Dehydrocoupling of Phosphine-Boranes -- 3.6 Mechanistic Investigations into the Rhodium-Catalysed Dehydrocoupling of Secondary Phosphine-Boranes -- 3.7 Mechanistic Investigation into the Rhodium-Catalysed Dehydrocoupling of Primary Phosphine-Boranes -- 3.8 Lewis Acid-Catalysed Dehydrocoupling of Phosphine-Boranes -- 4 Future Prospects -- References -- At the Forefront of the Suzuki-Miyaura Reaction: Advances in Stereoselective Cross-Couplings -- 1 Introduction. 2 Applications to the Synthesis of Enantioenriched Atropisomers -- 3 Mechanistic Considerations in the Suzuki-Miyaura Cross-Coupling of sp3 Centres -- 3.1 Challenges Associated with the Coupling of Saturated Carbon Centres -- 3.2 Stereochemistry of Various Steps in the Suzuki-Miyaura Cross-Coupling Mechanism -- 4 Stereoselective C(sp3)-C(sp2) Suzuki-Miyaura Cross-Coupling Reactions -- 4.1 Stereoselective Couplings of Alkyl Boronates with Aryl or Alkenyl Halides -- 4.2 Stereoselective Couplings of Alkyl Halides and Pseudohalides with Aryl or Alkenyl Boronates -- 5 Stereoselective C(sp3)-C(sp3) Suzuki-Miyaura Cross-Coupling Reactions -- 5.1 Stereoselective Couplings of Alkyl Boranes with Alkyl Halides -- 6 Summary and Outlook -- References -- Boronic Acid-Catalyzed Reactions of Carboxylic Acids -- 1 Introduction -- 2 B(III)-Catalyzed Reactions of α,beta-Unsaturated Carboxylic Acids -- 3 B(III)-Catalyzed Dehydrative Condensation to Carboxamides -- 4 B(III)-Catalyzed Dehydrative Condensation to Carboxylic Acid Esters -- 5 B(III)-Catalyzed Dehydrative Condensation to Carboxylic Anhydrides -- 6 Other B(III)-Catalyzed Reactions -- 7 Conclusions -- References -- Reagent-Controlled Lithiation-Borylation -- 1 Introduction -- 2 Mechanism of Lithiation-Borylation Processes -- 3 α-Chloro-Stabilized Lithium Carbenoids -- 4 α-O-Stabilized Organolithiums -- 4.1 Primary Carbamates/Benzoates -- 4.2 Secondary Benzylic Carbamates -- 4.3 Secondary Allylic/Propargylic Carbamates -- 4.4 Secondary Benzoates -- 5 α-N-Stabilized Organolithiums -- 6 Conclusions and Outlook -- References -- Recent Advances in the Synthesis and Applications of Organoborane Polymers -- 1 Introduction -- 2 Synthesis of Organoborane Polymers -- 2.1 Polymer Modification Reactions on Polyolefins -- 2.2 Direct Polymerization of Borane Monomers by Chain Growth Methods. 2.3 Side-Chain Functionalization of Conjugated Polymers -- 2.4 Boron Incorporation into the Main Chain of Conjugated Polymers -- 3 Selected Examples of Polymers and Their Applications -- 3.1 Borane Polymers as Lewis Acids and Anion Sensors -- 3.2 Luminescent Polymers Based on Boron Chelate Complexes -- 3.2.1 Boron Quinolate-Functionalized Polymers -- 3.2.2 BODIPY-Functionalized Polymers -- 3.2.3 Boron Diketonate-Functionalized Polymers -- 3.3 Boronic and Borinic Acid-Functionalized Polymers for Biomedical Applications and as Smart Materials -- 3.4 Borate and Boronium-Functionalized Polymers as Polyelectrolytes and Polymeric Ligand -- 4 Conclusions -- References -- Index. |
| Record Nr. | UNINA-9910768440103321 |
| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Terrorism in the Classroom : Security, Surveillance and a Public Duty to Act / / by Imran Awan, Keith Spiller, Andrew Whiting
| Terrorism in the Classroom : Security, Surveillance and a Public Duty to Act / / by Imran Awan, Keith Spiller, Andrew Whiting |
| Autore | Awan Imran |
| Edizione | [1st ed. 2019.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Palgrave Pivot, , 2019 |
| Descrizione fisica | 1 online resource (v, 129 pages) |
| Disciplina |
344.41053256
370.115 |
| Collana | Palgrave Studies in Risk, Crime and Society |
| Soggetto topico |
Criminology
Critical criminology Political planning Education and state Crime Control and Security Critical Criminology Public Policy Educational Policy and Politics |
| ISBN | 3-030-01710-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | 1. Introduction -- 2. Contesting Terms: Radicalisation and Extremism -- 3. The Development of UK counter-terrorism policy and legislation -- 4. Surveillance and the 'Monitoring' of Citizens by the State -- 5. Governmentality and Managing Security Risks -- 6. Education and (Counter-) Terrorism -- 7. Investigating the Counter Terrorism and Security Act in Higher Education -- 8. Conclusion. . |
| Record Nr. | UNINA-9910337833103321 |
Awan Imran
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| Cham : , : Springer International Publishing : , : Imprint : Palgrave Pivot, , 2019 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||