Organic Synthesis Highlights II [[electronic resource]]

• Autore: Waldmann Herbert
• Pubblicazione: Hoboken, : Wiley, 2008
• Descrizione fisica: 1 online resource (426 p.)
• Disciplina: 547; 547.2
• Soggetto topico: Organic compounds --Synthesis; Organic compounds; Science in organic compounds; Organic Chemistry; Chemistry; Physical Sciences & Mathematics
• Note generali: Description based upon print version of record.
• Nota di contenuto: Organic Synthesis Highlights II; Contents; Part I. New Methods and Reagents for Organic Synthesis; A. Asymmetric Synthesis; The Sharpless Epoxidation; Enantioselective cis-Dihydroxylation; Enantioselective Deprotonation and Protonation; Carbohydrate Complexes in Enantioselective Carbon-Carbon Bond Formation.; Asymmetric Aza-Diels-Alder Reactions; C2--Symmetric Amines as Chiral Auxiliaries; B. Organometallic Reagents in Organic Synthesis; Iron η5-Complexes in Organic Synthesis; Rhodium-Catalyzed Carbenoid Cyclizations; Nickel- Activated C1-Synthons ; Aminocarbene Complexes in Ligand- and Metal-Centered Carbon-Carbon Bond FormationOrganolanthanides in Reduction and Nucleophilic Addition Methodology; Carbon-Carbon Bond Formation with Group Four Metallocenes; Aluminum Enolates; C. Silicon in Organic Synthesis; Selective Transformations with Pentacoordinate Silicon Compounds; Oxidative Cleavage of Silicon-Carbon Bonds; Temporary Silicon Connections; D. Enzymes in Organic Synthesis; Enzymatic Carbon-Carbon Bond Formation; Enzymatic Synthesis of 0-Glycosides; E. Cyclization Reactions; Electrophilic Cyclizations to Heterocycles: Iminium Systems ; Electrophilic Cyclizations to Heterocycles : Oxonium SystemsElectrophilic Cyclizations to Heterocycles: Sulfonium Systems.; Polycyclization as a Strategy in the Synthesis of Complex Alkaloids; F. General Methods and Reagents for Organic Synthesis; Domino Reactions; Group Selective Reactions; Hypervalent Iodine Reagents; Furan as a Building Block in Synthesis; Fluorine in Organic Synthesis; Part II. Applications in Total Synthesis; A. Synthetic Routes to Different Classes of Natural Products and Analogs Thereof; Synthesis of Hydroxyethylene Isosteric Dipeptides ; Synthesis of Natural Products for Plant Protection.Penems: A New Generation of β-Lactam Antibiotics; Synthesis of 0-Glycosides; Carbacyclines: Stable Analogs of Prostacyclines; Synthesis of Mitomycins; Syntheses of Ergot Alkaloids; Enantioselective Synthesis of Piperidine Alkaloids.; Taxanes: An Unusual Class of Natural Products; B. Synthesis of Individual Natural Products; CC-1065: One of the Most Powerful Anti-Tumor Compounds; Syntheses of Morphine; Synthesis of Calicheamicin y1; ; Total Synthesis of Rapamycin
• Sommario/riassunto: Like its predecessor, Organic Synthesis Highlights II surveys recent accomplishments and current trends in synthetic organic chemistry. Part I describes new methods and reagents including asymmetric carbon-carbon bond formation with metallocenes and with enzymes, via temporary silicon connections, and by means of carbohydrate complexes. Part II describes landmarks in the synthesis of natural products and surveys synthetic strategies to different classes of natural products.The forty essays in this volume bear witness to the creativity and talent which have led to the recent adv
• Altri titoli varianti: Organic Synthesis Highlights II
• Titolo autorizzato: Organic Synthesis Highlights II
• ISBN: 1-281-84283-4; 9786611842833; 3-527-61994-1; 3-527-62045-1
• Formato: Materiale a stampa
• Livello bibliografico: Monografia
• Lingua di pubblicazione: Inglese
• Record Nr.: 996209705003316
• Lo trovi qui: Univ. di Salerno