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Compendium of organic synthetic methods . Volume 4 [[electronic resource] /] / Leroy G. Wade, Jr
Compendium of organic synthetic methods . Volume 4 [[electronic resource] /] / Leroy G. Wade, Jr
Autore Wade L. G. <1947->
Pubbl/distr/stampa New York, : Wiley-Interscience, c1980
Descrizione fisica 1 online resource (516 p.)
Disciplina 547.2
547/.2
Collana Compendium of Organic Synthetic Methods
Soggetto topico Organic compounds - Synthesis
Soggetto genere / forma Electronic books.
ISBN 1-282-68388-8
9786612683886
0-470-12597-7
0-470-12625-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Compendium of Organic Synthetic Methods; CONTENTS; ABBREVIATIONS; INDEX, MONOFUNCTIONAL COMPOUNDS; INDEX, DIFUNCTIONAL COMPOUNDS; INTRODUCTION; PREPARATION OF ACETYLENES; PREPARATION OF CARBOXYLIC ACIDS, ACID HALIDES, AND ANHYDRIDES; PREPARATION OF ALCOHOLS AND PHENOLS; PREPARATION OF ALDEHYDES; PREPARATION OF ALKYLS, METHYLENES, AND ARYLS; PREPARATION OF AMIDES; PREPARATION OF AMINES; PREPARATION OF ESTERS; PREPARATION OF ETHERS AND EPOXIDES; PREPARATION OF HALIDES AND SULFONATES; PREPARATION OF HYDRIDES; PREPARATION OF KETONES; PREPARATION OF NITRILES; PREPARATION OF OLEFINS
PREPARATION OF DIFUNCTIONAL COMPOUNDS
Record Nr. UNINA-9910144318503321
Wade L. G. <1947->  
New York, : Wiley-Interscience, c1980
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Compendium of organic synthetic methods . Volume 4 [[electronic resource] /] / Leroy G. Wade, Jr
Compendium of organic synthetic methods . Volume 4 [[electronic resource] /] / Leroy G. Wade, Jr
Autore Wade L. G. <1947->
Pubbl/distr/stampa New York, : Wiley-Interscience, c1980
Descrizione fisica 1 online resource (516 p.)
Disciplina 547.2
547/.2
Collana Compendium of Organic Synthetic Methods
Soggetto topico Organic compounds - Synthesis
ISBN 1-282-68388-8
9786612683886
0-470-12597-7
0-470-12625-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Compendium of Organic Synthetic Methods; CONTENTS; ABBREVIATIONS; INDEX, MONOFUNCTIONAL COMPOUNDS; INDEX, DIFUNCTIONAL COMPOUNDS; INTRODUCTION; PREPARATION OF ACETYLENES; PREPARATION OF CARBOXYLIC ACIDS, ACID HALIDES, AND ANHYDRIDES; PREPARATION OF ALCOHOLS AND PHENOLS; PREPARATION OF ALDEHYDES; PREPARATION OF ALKYLS, METHYLENES, AND ARYLS; PREPARATION OF AMIDES; PREPARATION OF AMINES; PREPARATION OF ESTERS; PREPARATION OF ETHERS AND EPOXIDES; PREPARATION OF HALIDES AND SULFONATES; PREPARATION OF HYDRIDES; PREPARATION OF KETONES; PREPARATION OF NITRILES; PREPARATION OF OLEFINS
PREPARATION OF DIFUNCTIONAL COMPOUNDS
Record Nr. UNINA-9910643099503321
Wade L. G. <1947->  
New York, : Wiley-Interscience, c1980
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Compendium of organic synthetic methods . Volume 4 [[electronic resource] /] / Leroy G. Wade, Jr
Compendium of organic synthetic methods . Volume 4 [[electronic resource] /] / Leroy G. Wade, Jr
Autore Wade L. G. <1947->
Pubbl/distr/stampa New York, : Wiley-Interscience, c1980
Descrizione fisica 1 online resource (516 p.)
Disciplina 547.2
547/.2
Collana Compendium of Organic Synthetic Methods
Soggetto topico Organic compounds - Synthesis
ISBN 1-282-68388-8
9786612683886
0-470-12597-7
0-470-12625-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Compendium of Organic Synthetic Methods; CONTENTS; ABBREVIATIONS; INDEX, MONOFUNCTIONAL COMPOUNDS; INDEX, DIFUNCTIONAL COMPOUNDS; INTRODUCTION; PREPARATION OF ACETYLENES; PREPARATION OF CARBOXYLIC ACIDS, ACID HALIDES, AND ANHYDRIDES; PREPARATION OF ALCOHOLS AND PHENOLS; PREPARATION OF ALDEHYDES; PREPARATION OF ALKYLS, METHYLENES, AND ARYLS; PREPARATION OF AMIDES; PREPARATION OF AMINES; PREPARATION OF ESTERS; PREPARATION OF ETHERS AND EPOXIDES; PREPARATION OF HALIDES AND SULFONATES; PREPARATION OF HYDRIDES; PREPARATION OF KETONES; PREPARATION OF NITRILES; PREPARATION OF OLEFINS
PREPARATION OF DIFUNCTIONAL COMPOUNDS
Record Nr. UNINA-9910830391703321
Wade L. G. <1947->  
New York, : Wiley-Interscience, c1980
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Compendium of organic synthetic methods . Volume 4 [[electronic resource] /] / Leroy G. Wade, Jr
Compendium of organic synthetic methods . Volume 4 [[electronic resource] /] / Leroy G. Wade, Jr
Autore Wade L. G. <1947->
Pubbl/distr/stampa New York, : Wiley-Interscience, c1980
Descrizione fisica 1 online resource (516 p.)
Disciplina 547.2
547/.2
Collana Compendium of Organic Synthetic Methods
Soggetto topico Organic compounds - Synthesis
ISBN 1-282-68388-8
9786612683886
0-470-12597-7
0-470-12625-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Compendium of Organic Synthetic Methods; CONTENTS; ABBREVIATIONS; INDEX, MONOFUNCTIONAL COMPOUNDS; INDEX, DIFUNCTIONAL COMPOUNDS; INTRODUCTION; PREPARATION OF ACETYLENES; PREPARATION OF CARBOXYLIC ACIDS, ACID HALIDES, AND ANHYDRIDES; PREPARATION OF ALCOHOLS AND PHENOLS; PREPARATION OF ALDEHYDES; PREPARATION OF ALKYLS, METHYLENES, AND ARYLS; PREPARATION OF AMIDES; PREPARATION OF AMINES; PREPARATION OF ESTERS; PREPARATION OF ETHERS AND EPOXIDES; PREPARATION OF HALIDES AND SULFONATES; PREPARATION OF HYDRIDES; PREPARATION OF KETONES; PREPARATION OF NITRILES; PREPARATION OF OLEFINS
PREPARATION OF DIFUNCTIONAL COMPOUNDS
Record Nr. UNINA-9910841732803321
Wade L. G. <1947->  
New York, : Wiley-Interscience, c1980
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Organic chemistry / / Leroy G. Wade, Jr. ; contributing author, Jan William Simek
Organic chemistry / / Leroy G. Wade, Jr. ; contributing author, Jan William Simek
Autore Wade L. G. <1947->
Edizione [Ninth, global edition.]
Pubbl/distr/stampa Harlow, England : , : Pearson, , [2017]
Descrizione fisica 1 online resource (1,398 pages) : illustrations (some color), photographs, tables
Disciplina 547
Collana Always learning
Soggetto topico Chemistry, Organic
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover -- Title Page 1 -- Copyright Page 2 -- About the Authors 3 -- Contents 5 -- Preface 25 -- 1 STRUCTURE AND BONDING 37 -- 1-1 The Origins of Organic Chemistry 37 -- 1-2 Principles of Atomic Structure 39 -- 1-3 Bond Formation: The Octet Rule 43 -- 1-4 Lewis Structures 44 -- 1-5 Multiple Bonding 45 -- Summary: Common Bonding Patterns (Uncharged) 45 -- 1-6 Electronegativity and Bond Polarity 46 -- 1-7 Formal Charges 47 -- 1-8 Ionic Structures 49 -- 1-9 Resonance 50 -- PROBLEM-SOLVING STRATEGY: Drawing and Evaluating Resonance Forms 54 -- 1-10 Structural Formulas 58 -- 1-11 Molecular Formulas and Empirical Formulas 61 -- 1-12 Wave Properties of Electrons in Orbitals 63 -- 1-13 Molecular Orbitals 64 -- 1-14 Pi Bonding 67 -- 1-15 Hybridization and Molecular Shapes 68 -- 1-16 Drawing Three-Dimensional Molecules 72 -- 1-17 General Rules of Hybridization and Geometry 73 -- Summary: Hybridization and Geometry 73 -- 1-18 Bond Rotation 78 -- 1-19 Isomerism 80 -- Essential Terms 83 -- Study Problems 86 -- 2 ACIDS AND BASES -- FUNCTIONAL GROUPS 91 -- 2-1 Polarity of Bonds and Molecules 92 -- 2-2 Intermolecular Forces 96 -- 2-3 Polarity Effects on Solubilities 100 -- 2-4 Arrhenius Acids and Bases 103 -- 2-5 Brønsted-Lowry Acids and Bases 104 -- 2-6 Strengths of Acids and Bases 105 -- 2-7 Equilibrium Positions of Acid-Base Reactions 109 -- PROBLEM-SOLVING STRATEGY: Predicting Acid-Base Equilibrium Positions 111 -- 2-8 Solvent Effects on Acidity and Basicity 112 -- Summary: Acidity and Basicity Limitations in Common Solvents 114 -- 2-9 Effects of Size and Electronegativity on Acidity 114 -- 2-10 Inductive Effects on Acidity 116 -- 2-11 Hybridization Effects on Acidity 117 -- 2-12 Resonance Effects on Acidity and Basicity 119 -- 2-13 Lewis Acids and Bases 122 -- 2-14 The Curved-Arrow Formalism 124 -- 2-15 Hydrocarbons 126.
2-16 Functional Groups with Oxygen 129 -- 2-17 Functional Groups with Nitrogen 132 -- Essential Terms 134 -- Study Problems 137 -- 3 STRUCTURE AND STEREOCHEMISTRY OF ALKANES 143 -- 3-1 Classification of Hydrocarbons (Review) 144 -- 3-2 Molecular Formulas of Alkanes 144 -- 3-3 Nomenclature of Alkanes 146 -- Summary: Rules for Naming Alkanes 151 -- 3-4 Physical Properties of Alkanes 153 -- 3-5 Uses and Sources of Alkanes 154 -- 3-6 Reactions of Alkanes 157 -- 3-7 Structure and Conformations of Alkanes 158 -- 3-8 Conformations of Butane 162 -- 3-9 Conformations of Higher Alkanes 165 -- 3-10 Cycloalkanes 165 -- 3-11 Cis-trans Isomerism in Cycloalkanes 167 -- 3-12 Stabilities of Cycloalkanes -- Ring Strain 168 -- 3-13 Cyclohexane Conformations 172 -- PROBLEM-SOLVING STRATEGY: Drawing Chair Conformations 174 -- 3-14 Conformations of Monosubstituted Cyclohexanes 176 -- 3-15 Conformations of Disubstituted Cyclohexanes 179 -- PROBLEM-SOLVING STRATEGY: Recognizing Cis and Trans Isomers 179 -- 3-16 Bicyclic Molecules 182 -- Essential Terms 184 -- Study Problems 188 -- 4 THE STUDY OF CHEMICAL REACTIONS 191 -- 4-1 Introduction 191 -- 4-2 Chlorination of Methane 192 -- 4-3 The Free-Radical Chain Reaction 193 -- 4-4 Equilibrium Constants and Free Energy 197 -- 4-5 Enthalpy and Entropy 199 -- 4-6 Bond-Dissociation Enthalpies 201 -- 4-7 Enthalpy Changes in Chlorination 202 -- 4-8 Kinetics and the Rate Equation 205 -- 4-9 Activation Energy and the Temperature Dependence of Rates 207 -- 4-10 Transition States 208 -- 4-11 Rates of Multistep Reactions 210 -- 4-12 Temperature Dependence of Halogenation 211 -- 4-13 Selectivity in Halogenation 212 -- 4-14 Hammond's Postulate 218 -- PROBLEM-SOLVING STRATEGY: Proposing Reaction Mechanisms 219 -- 4-15 Radical Inhibitors 222 -- 4-16 Reactive Intermediates 223 -- Summary: Reactive Intermediates 230 -- Essential Terms 230.
Study Problems 233 -- 5 STEREOCHEMISTRY 237 -- 5-1 Introduction 237 -- 5-2 Chirality 238 -- 5-3 (R) and (S) Nomenclature of Asymmetric Carbon Atoms 244 -- 5-4 Optical Activity 249 -- 5-5 Biological Discrimination of Enantiomers 254 -- 5-6 Racemic Mixtures 255 -- 5-7 Enantiomeric Excess and Optical Purity 256 -- 5-8 Chirality of Conformationally Mobile Systems 257 -- 5-9 Chiral Compounds Without Asymmetric Atoms 260 -- 5-10 Fischer Projections 262 -- Summary: Fischer Projections and Their Use 266 -- 5-11 Diastereomers 266 -- Summary: Types of Isomers 268 -- 5-12 Stereochemistry of Molecules with Two or More Asymmetric Carbons 269 -- 5-13 Meso Compounds 269 -- 5-14 Absolute and Relative Configuration 271 -- 5-15 Physical Properties of Diastereomers 273 -- 5-16 Resolution of Enantiomers 274 -- Essential Terms 277 -- Study Problems 280 -- 6 ALKYL HALIDES -- NUCLEOPHILIC SUBSTITUTION 283 -- 6-1 Introduction 283 -- 6-2 Nomenclature of Alkyl Halides 284 -- 6-3 Common Uses of Alkyl Halides 286 -- 6-4 Structure of Alkyl Halides 288 -- 6-5 Physical Properties of Alkyl Halides 289 -- 6-6 Preparation of Alkyl Halides 291 -- Summary: Methods for Preparing Alkyl Halides 295 -- 6-7 Reactions of Alkyl Halides: Substitution and Elimination 296 -- 6-8 Bimolecular Nucleophilic Substitution: The SN2 Reaction 297 -- 6-9 Generality of the SN2 Reaction 299 -- Summary: SN2 Reactions of Alkyl Halides 300 -- 6-10 Factors Affecting SN2 Reactions: Strength of the Nucleophile 301 -- Summary: Trends in Nucleophilicity 302 -- 6-11 Reactivity of the Substrate in SN2 Reactions 305 -- 6-12 Stereochemistry of the SN2 Reaction 309 -- 6-13 Unimolecular Nucleophilic Substitution: The SN1 Reaction 311 -- 6-14 Stereochemistry of the SN1 Reaction 315 -- 6-15 Rearrangements in SN1 Reactions 317 -- 6-16 Comparison of SN1 and SN2 Reactions 320 -- Summary: Nucleophilic Substitutions 322.
Summary: Reactions of Alkyl Halides 323 -- Essential Terms 324 -- Study Problems 327 -- 7 STRUCTURE AND SYNTHESIS OF ALKENES -- ELIMINATION 332 -- 7-1 Introduction 332 -- 7-2 The Orbital Description of the Alkene Double Bond 333 -- 7-3 Elements of Unsaturation 335 -- 7-4 Nomenclature of Alkenes 337 -- 7-5 Nomenclature of Cis-Trans Isomers 339 -- Summary: Rules for Naming Alkenes 341 -- 7-6 Commercial Importance of Alkenes 342 -- 7-7 Physical Properties of Alkenes 344 -- 7-8 Stability of Alkenes 346 -- 7-9 Formation of Alkenes by Dehydrohalogenation of Alkyl Halides 354 -- 7-10 Unimolecular Elimination: The E1 Reaction 355 -- Summary: Carbocation Reactions 359 -- 7-11 Positional Orientation of Elimination: Zaitsev's Rule 360 -- 7-12 Bimolecular Elimination: The E2 Reaction 362 -- 7-13 Bulky Bases in E2 Eliminations -- Hofmann Orientation 364 -- 7-14 Stereochemistry of the E2 Reaction 365 -- 7-15 E2 Reactions in Cyclohexane Systems 368 -- 7-16 Comparison of E1 and E2 Elimination Mechanisms 370 -- Summary: Elimination Reactions 371 -- Summary: Substitution and Elimination Reactions of Alkyl Halides 374 -- PROBLEM-SOLVING STRATEGY: Predicting Substitutions and Eliminations 376 -- 7-18 Alkene Synthesis by Dehydration of Alcohols 377 -- 7-19 Alkene Synthesis by High-Temperature Industrial Methods 380 -- PROBLEM-SOLVING STRATEGY: Proposing Reaction Mechanisms 382 -- Summary: Methods for Synthesis of Alkenes 385 -- Essential Terms 386 -- Study Problems 389 -- 8 REACTIONS OF ALKENES 395 -- 8-1 Reactivity of the Carbon-Carbon Double Bond 395 -- 8-2 Electrophilic Addition to Alkenes 396 -- 8-3 Addition of Hydrogen Halides to Alkenes 398 -- 8-4 Addition of Water: Hydration of Alkenes 406 -- 8-5 Hydration by Oxymercuration-Demercuration 408 -- 8-6 Alkoxymercuration-Demercuration 411 -- 8-7 Hydroboration of Alkenes 412 -- 8-8 Addition of Halogens to Alkenes 418.
8-9 Formation of Halohydrins 421 -- 8-10 Catalytic Hydrogenation of Alkenes 425 -- 8-11 Addition of Carbenes to Alkenes 427 -- 8-12 Epoxidation of Alkenes 429 -- 8-13 Acid-Catalyzed Opening of Epoxides 431 -- 8-14 Syn Dihydroxylation of Alkenes 434 -- 8-15 Oxidative Cleavage of Alkenes 436 -- 8-16 Polymerization of Alkenes 439 -- 8-17 Olefin Metathesis 443 -- PROBLEM-SOLVING STRATEGY: Organic Synthesis 446 -- Summary: Reactions of Alkenes 448 -- Summary: Electrophilic Additions to Alkenes 451 -- Summary: Oxidation and Cyclopropanation Reactions of Alkenes 452 -- Essential Terms 453 -- Study Problems 457 -- 9 ALKYNES 464 -- 9-1 Introduction 464 -- 9-2 Nomenclature of Alkynes 465 -- 9-3 Physical Properties of Alkynes 467 -- 9-4 Commercial Importance of Alkynes 467 -- 9-5 Electronic Structure of Alkynes 469 -- 9-6 Acidity of Alkynes -- Formation of Acetylide Ions 470 -- 9-7 Synthesis of Alkynes from Acetylides 472 -- 9-8 Synthesis of Alkynes by Elimination Reactions 475 -- Summary: Syntheses of Alkynes 477 -- 9-9 Addition Reactions of Alkynes 477 -- 9-10 Oxidation of Alkynes 486 -- PROBLEM-SOLVING STRATEGY: Multistep Synthesis 488 -- Summary: Reactions of Alkynes 490 -- Summary: Reactions of Terminal Alkynes 491 -- Essential Terms 492 -- Study Problems 493 -- 10 STRUCTURE AND SYNTHESIS OF ALCOHOLS 496 -- 10-1 Introduction 496 -- 10-2 Structure and Classification of Alcohols 496 -- 10-3 Nomenclature of Alcohols and Phenols 497 -- 10-4 Physical Properties of Alcohols 502 -- 10-5 Commercially Important Alcohols 504 -- 10-6 Acidity of Alcohols and Phenols 506 -- 10-7 Synthesis of Alcohols: Introduction and Review 510 -- Summary: Previous Alcohol Syntheses 510 -- 10-8 Organometallic Reagents for Alcohol Synthesis 511 -- 10-9 Reactions of Organometallic Compounds 514 -- Summary: Grignard Reactions 520.
10-10 Side Reactions of Organometallic Reagents: Reduction of Alkyl Halides 522.
Record Nr. UNINA-9910154956203321
Wade L. G. <1947->  
Harlow, England : , : Pearson, , [2017]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Solutions manual for organic chemistry / / LeRoy G. Wade, Jan W. Simek
Solutions manual for organic chemistry / / LeRoy G. Wade, Jan W. Simek
Autore Wade L. G. <1947->
Edizione [Eighth edition.]
Pubbl/distr/stampa Harlow, England : , : Pearson Education, Limited, , [2014]
Descrizione fisica 1 online resource (681 pages) : illustrations
Disciplina 454
Soggetto topico Chemistry, Organic
ISBN 1-292-03557-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Cover -- Table of Contents -- Symbols and Abbreviations -- 1. Solutions for Introduction and Review -- 2. Solutions for Structure and Properties of Organic Molecules -- 3. Solutions for Structure and Stereochemistry of Alkanes -- 4. Solutions for The Study of Chemical Reactions -- 5. Solutions for Stereochemistry -- 6. Solutions for Alkyl Halides: Nucleophilic Substitution and Elimination -- 7. Solutions for Structure and Synthesis of Alkenes -- 8. Solutions for Reactions of Alkenes -- 9. Solutions for Alkynes -- 10. Solutions for Structure and Synthesis of Alcohols -- 11. Solutions for Reactions of Alcohols -- 12. Solutions for Infrared Spectroscopy and Mass Spectrometry -- 13. Solutions for Nuclear Magnetic Resonance Spectroscopy -- 14. Solutions for Ethers, Expoxides, and Thioethers -- 15. Solutions for Conjugated Systems, Orbital Symmetry, and Ultraviolet Spectroscopy -- 16. Solutions for Aromatic Compounds -- 17. Solutions for Reactions of Aromatic Compounds -- 18. Solutions for Ketones and Aldehydes -- 19. Solutions for Amines -- 20. Solutions for Carboxylic Acids -- 21. Solutions for Carboxylic Acid Derivatives -- 22. Solutions for Condensations and Alpha Substitutions of Carbonyl Compounds -- 23. Solutions for Carbohydrates and Nucleic Acids -- 24. Solutions for Amino Acids, Peptides, and Proteins -- 25. Solutions for Lipids -- Index -- 1 -- 2.
Record Nr. UNINA-9910153126003321
Wade L. G. <1947->  
Harlow, England : , : Pearson Education, Limited, , [2014]
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui