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Organofluorine chemistry [[electronic resource] /] / Kenji Uneyama
| Organofluorine chemistry [[electronic resource] /] / Kenji Uneyama |
| Autore | Uneyama Kenji |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (352 p.) |
| Disciplina |
547.02
547/.02 |
| Soggetto topico |
Organofluorine compounds - Synthesis
Hydrogen bonding Ligands (Biochemistry) |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-74823-0
9786610748235 0-470-98858-4 1-4051-7293-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organofluorine Chemistry; Contents; Preface; 1 Fundamentals in Organic Fluorine Chemistry; 1.1 Some physical properties of organic fluorine compounds; 1.1.1 Effect of the fluorine atom on the molecular orbital energy levels of organic molecules and refractive index; 1.1.2 Boiling points; 1.1.3 Miscibility; 1.1.4 Lipophilicity; 1.1.5 Gas solubility; 1.1.6 Surface tension; 1.1.7 Summary; 1.2 Electronic effect; 1.2.1 Electronic effects of the fluorine atom: insight fromHammett substituent constants; 1.2.2 Electronic effects on acidity, bond length, and bond energy of fluoroorganic molecules
1.2.3 Halogen bonding1.2.4 Electronic effect on the destabilization of carbonyl and imono groups; 1.2.5 pi-pi Stacking of fluoroaromatics; 1.2.6 Increased p-character (Bent's rule) and low-lying LUMO in carbon-fluorine bonding orbitals; 1.2.7 Negative hyperconjugation; 1.2.8 Electron-donating effect (stabilization of carbocation); 1.2.9 Effect of fluorine substituents on the structure, stability, and reactivity of fluoroalkyl radicals; 1.3 Steric effects of fluorine substituents; References; 2 Unique Reactions Induced by Fluorine; 2.1 Nucleophilic substitution on fluoroaromatic rings 2.2 SN2' reactions of alkenes bearing a trifluoromethyl group2.3 Nucleophilic substitution on the gem-difluoromethylene double bond; 2.4 Single electron transfer reaction of perfluoroalkyl halides; 2.5 Fluorine-activated electrophilic reagents (F-X and XFn); 2.5.1 Halogen monofluoride (F-halogen); 2.5.2 Bromine trifluoride (BrF3); 2.5.3 Iodine pentafluoride (IF5); 2.5.4 Iodoarene difluoride (ArIF2); 2.5.5 Benzeneselenenyl fluoride (PhSeF); 2.5.6 tert-Butyl and methyl hypofluorites; 2.5.7 Hypofluorous acid - MeCN complex (HOF - MeCN); References 3 Reactions Activated by a Strong Interaction Between Fluorine and Other Atoms3.1 Reaction induced by F-Li interaction; 3.1.1 Li-F interaction in aromatic C-F bonds; 3.1.2 Li-F interaction in aliphatic C-F bonds; 3.2 The fluorine-aluminum interaction; 3.3 Reactions induced by F-Si interaction; 3.3.1 Fluoride-ion mediated desilylative alkylations; 3.4 Reactions induced by B-F interaction; 3.5 Reactions activated by a strong interaction between fluorine and Sm, Yb, Sn, Ti; References; 4 Hydrogen Bonding in Organofluorine Compounds; 4.1 Organofluorine as a hydrogen-bonding acceptor 4.1.1 Definition and classifications of hydrogen bonds4.1.2 Some examples of O-H · · · F-C and N-H· · ·F -C hydrogen-bonding systems; 4.1.3 Some examples on nonconventional hydrogen bonding: C-H· · ·F-C interactions; 4.1.4 Summary of organic fluorine as hydrogen-bonding acceptor; 4.2 Hydrogen bonding of B-fluorinated alcohols, its structural character, and utilization in organic syntheses; 4.2.1 Use of TFE and HFIP for protonating agents and/or protonating solvents; 4.2.2 Use of TFE and HFIP for cation-stabilizing solvents; References; 5 Fluorinated Ligands for Selective Catalytic Reactions 5.1 Ligands with fluorine-substituted aryl groups |
| Record Nr. | UNINA-9910143294803321 |
Uneyama Kenji
|
||
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organofluorine chemistry [[electronic resource] /] / Kenji Uneyama
| Organofluorine chemistry [[electronic resource] /] / Kenji Uneyama |
| Autore | Uneyama Kenji |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (352 p.) |
| Disciplina |
547.02
547/.02 |
| Soggetto topico |
Organofluorine compounds - Synthesis
Hydrogen bonding Ligands (Biochemistry) |
| ISBN |
1-280-74823-0
9786610748235 0-470-98858-4 1-4051-7293-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organofluorine Chemistry; Contents; Preface; 1 Fundamentals in Organic Fluorine Chemistry; 1.1 Some physical properties of organic fluorine compounds; 1.1.1 Effect of the fluorine atom on the molecular orbital energy levels of organic molecules and refractive index; 1.1.2 Boiling points; 1.1.3 Miscibility; 1.1.4 Lipophilicity; 1.1.5 Gas solubility; 1.1.6 Surface tension; 1.1.7 Summary; 1.2 Electronic effect; 1.2.1 Electronic effects of the fluorine atom: insight fromHammett substituent constants; 1.2.2 Electronic effects on acidity, bond length, and bond energy of fluoroorganic molecules
1.2.3 Halogen bonding1.2.4 Electronic effect on the destabilization of carbonyl and imono groups; 1.2.5 pi-pi Stacking of fluoroaromatics; 1.2.6 Increased p-character (Bent's rule) and low-lying LUMO in carbon-fluorine bonding orbitals; 1.2.7 Negative hyperconjugation; 1.2.8 Electron-donating effect (stabilization of carbocation); 1.2.9 Effect of fluorine substituents on the structure, stability, and reactivity of fluoroalkyl radicals; 1.3 Steric effects of fluorine substituents; References; 2 Unique Reactions Induced by Fluorine; 2.1 Nucleophilic substitution on fluoroaromatic rings 2.2 SN2' reactions of alkenes bearing a trifluoromethyl group2.3 Nucleophilic substitution on the gem-difluoromethylene double bond; 2.4 Single electron transfer reaction of perfluoroalkyl halides; 2.5 Fluorine-activated electrophilic reagents (F-X and XFn); 2.5.1 Halogen monofluoride (F-halogen); 2.5.2 Bromine trifluoride (BrF3); 2.5.3 Iodine pentafluoride (IF5); 2.5.4 Iodoarene difluoride (ArIF2); 2.5.5 Benzeneselenenyl fluoride (PhSeF); 2.5.6 tert-Butyl and methyl hypofluorites; 2.5.7 Hypofluorous acid - MeCN complex (HOF - MeCN); References 3 Reactions Activated by a Strong Interaction Between Fluorine and Other Atoms3.1 Reaction induced by F-Li interaction; 3.1.1 Li-F interaction in aromatic C-F bonds; 3.1.2 Li-F interaction in aliphatic C-F bonds; 3.2 The fluorine-aluminum interaction; 3.3 Reactions induced by F-Si interaction; 3.3.1 Fluoride-ion mediated desilylative alkylations; 3.4 Reactions induced by B-F interaction; 3.5 Reactions activated by a strong interaction between fluorine and Sm, Yb, Sn, Ti; References; 4 Hydrogen Bonding in Organofluorine Compounds; 4.1 Organofluorine as a hydrogen-bonding acceptor 4.1.1 Definition and classifications of hydrogen bonds4.1.2 Some examples of O-H · · · F-C and N-H· · ·F -C hydrogen-bonding systems; 4.1.3 Some examples on nonconventional hydrogen bonding: C-H· · ·F-C interactions; 4.1.4 Summary of organic fluorine as hydrogen-bonding acceptor; 4.2 Hydrogen bonding of B-fluorinated alcohols, its structural character, and utilization in organic syntheses; 4.2.1 Use of TFE and HFIP for protonating agents and/or protonating solvents; 4.2.2 Use of TFE and HFIP for cation-stabilizing solvents; References; 5 Fluorinated Ligands for Selective Catalytic Reactions 5.1 Ligands with fluorine-substituted aryl groups |
| Record Nr. | UNISA-996205537903316 |
|
Uneyama Kenji
|
||
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Organofluorine chemistry [[electronic resource] /] / Kenji Uneyama
| Organofluorine chemistry [[electronic resource] /] / Kenji Uneyama |
| Autore | Uneyama Kenji |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (352 p.) |
| Disciplina |
547.02
547/.02 |
| Soggetto topico |
Organofluorine compounds - Synthesis
Hydrogen bonding Ligands (Biochemistry) |
| ISBN |
1-280-74823-0
9786610748235 0-470-98858-4 1-4051-7293-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organofluorine Chemistry; Contents; Preface; 1 Fundamentals in Organic Fluorine Chemistry; 1.1 Some physical properties of organic fluorine compounds; 1.1.1 Effect of the fluorine atom on the molecular orbital energy levels of organic molecules and refractive index; 1.1.2 Boiling points; 1.1.3 Miscibility; 1.1.4 Lipophilicity; 1.1.5 Gas solubility; 1.1.6 Surface tension; 1.1.7 Summary; 1.2 Electronic effect; 1.2.1 Electronic effects of the fluorine atom: insight fromHammett substituent constants; 1.2.2 Electronic effects on acidity, bond length, and bond energy of fluoroorganic molecules
1.2.3 Halogen bonding1.2.4 Electronic effect on the destabilization of carbonyl and imono groups; 1.2.5 pi-pi Stacking of fluoroaromatics; 1.2.6 Increased p-character (Bent's rule) and low-lying LUMO in carbon-fluorine bonding orbitals; 1.2.7 Negative hyperconjugation; 1.2.8 Electron-donating effect (stabilization of carbocation); 1.2.9 Effect of fluorine substituents on the structure, stability, and reactivity of fluoroalkyl radicals; 1.3 Steric effects of fluorine substituents; References; 2 Unique Reactions Induced by Fluorine; 2.1 Nucleophilic substitution on fluoroaromatic rings 2.2 SN2' reactions of alkenes bearing a trifluoromethyl group2.3 Nucleophilic substitution on the gem-difluoromethylene double bond; 2.4 Single electron transfer reaction of perfluoroalkyl halides; 2.5 Fluorine-activated electrophilic reagents (F-X and XFn); 2.5.1 Halogen monofluoride (F-halogen); 2.5.2 Bromine trifluoride (BrF3); 2.5.3 Iodine pentafluoride (IF5); 2.5.4 Iodoarene difluoride (ArIF2); 2.5.5 Benzeneselenenyl fluoride (PhSeF); 2.5.6 tert-Butyl and methyl hypofluorites; 2.5.7 Hypofluorous acid - MeCN complex (HOF - MeCN); References 3 Reactions Activated by a Strong Interaction Between Fluorine and Other Atoms3.1 Reaction induced by F-Li interaction; 3.1.1 Li-F interaction in aromatic C-F bonds; 3.1.2 Li-F interaction in aliphatic C-F bonds; 3.2 The fluorine-aluminum interaction; 3.3 Reactions induced by F-Si interaction; 3.3.1 Fluoride-ion mediated desilylative alkylations; 3.4 Reactions induced by B-F interaction; 3.5 Reactions activated by a strong interaction between fluorine and Sm, Yb, Sn, Ti; References; 4 Hydrogen Bonding in Organofluorine Compounds; 4.1 Organofluorine as a hydrogen-bonding acceptor 4.1.1 Definition and classifications of hydrogen bonds4.1.2 Some examples of O-H · · · F-C and N-H· · ·F -C hydrogen-bonding systems; 4.1.3 Some examples on nonconventional hydrogen bonding: C-H· · ·F-C interactions; 4.1.4 Summary of organic fluorine as hydrogen-bonding acceptor; 4.2 Hydrogen bonding of B-fluorinated alcohols, its structural character, and utilization in organic syntheses; 4.2.1 Use of TFE and HFIP for protonating agents and/or protonating solvents; 4.2.2 Use of TFE and HFIP for cation-stabilizing solvents; References; 5 Fluorinated Ligands for Selective Catalytic Reactions 5.1 Ligands with fluorine-substituted aryl groups |
| Record Nr. | UNINA-9910830426503321 |
|
Uneyama Kenji
|
||
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organofluorine chemistry [[electronic resource] /] / Kenji Uneyama
| Organofluorine chemistry [[electronic resource] /] / Kenji Uneyama |
| Autore | Uneyama Kenji |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (352 p.) |
| Disciplina |
547.02
547/.02 |
| Soggetto topico |
Organofluorine compounds - Synthesis
Hydrogen bonding Ligands (Biochemistry) |
| ISBN |
1-280-74823-0
9786610748235 0-470-98858-4 1-4051-7293-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Organofluorine Chemistry; Contents; Preface; 1 Fundamentals in Organic Fluorine Chemistry; 1.1 Some physical properties of organic fluorine compounds; 1.1.1 Effect of the fluorine atom on the molecular orbital energy levels of organic molecules and refractive index; 1.1.2 Boiling points; 1.1.3 Miscibility; 1.1.4 Lipophilicity; 1.1.5 Gas solubility; 1.1.6 Surface tension; 1.1.7 Summary; 1.2 Electronic effect; 1.2.1 Electronic effects of the fluorine atom: insight fromHammett substituent constants; 1.2.2 Electronic effects on acidity, bond length, and bond energy of fluoroorganic molecules
1.2.3 Halogen bonding1.2.4 Electronic effect on the destabilization of carbonyl and imono groups; 1.2.5 pi-pi Stacking of fluoroaromatics; 1.2.6 Increased p-character (Bent's rule) and low-lying LUMO in carbon-fluorine bonding orbitals; 1.2.7 Negative hyperconjugation; 1.2.8 Electron-donating effect (stabilization of carbocation); 1.2.9 Effect of fluorine substituents on the structure, stability, and reactivity of fluoroalkyl radicals; 1.3 Steric effects of fluorine substituents; References; 2 Unique Reactions Induced by Fluorine; 2.1 Nucleophilic substitution on fluoroaromatic rings 2.2 SN2' reactions of alkenes bearing a trifluoromethyl group2.3 Nucleophilic substitution on the gem-difluoromethylene double bond; 2.4 Single electron transfer reaction of perfluoroalkyl halides; 2.5 Fluorine-activated electrophilic reagents (F-X and XFn); 2.5.1 Halogen monofluoride (F-halogen); 2.5.2 Bromine trifluoride (BrF3); 2.5.3 Iodine pentafluoride (IF5); 2.5.4 Iodoarene difluoride (ArIF2); 2.5.5 Benzeneselenenyl fluoride (PhSeF); 2.5.6 tert-Butyl and methyl hypofluorites; 2.5.7 Hypofluorous acid - MeCN complex (HOF - MeCN); References 3 Reactions Activated by a Strong Interaction Between Fluorine and Other Atoms3.1 Reaction induced by F-Li interaction; 3.1.1 Li-F interaction in aromatic C-F bonds; 3.1.2 Li-F interaction in aliphatic C-F bonds; 3.2 The fluorine-aluminum interaction; 3.3 Reactions induced by F-Si interaction; 3.3.1 Fluoride-ion mediated desilylative alkylations; 3.4 Reactions induced by B-F interaction; 3.5 Reactions activated by a strong interaction between fluorine and Sm, Yb, Sn, Ti; References; 4 Hydrogen Bonding in Organofluorine Compounds; 4.1 Organofluorine as a hydrogen-bonding acceptor 4.1.1 Definition and classifications of hydrogen bonds4.1.2 Some examples of O-H · · · F-C and N-H· · ·F -C hydrogen-bonding systems; 4.1.3 Some examples on nonconventional hydrogen bonding: C-H· · ·F-C interactions; 4.1.4 Summary of organic fluorine as hydrogen-bonding acceptor; 4.2 Hydrogen bonding of B-fluorinated alcohols, its structural character, and utilization in organic syntheses; 4.2.1 Use of TFE and HFIP for protonating agents and/or protonating solvents; 4.2.2 Use of TFE and HFIP for cation-stabilizing solvents; References; 5 Fluorinated Ligands for Selective Catalytic Reactions 5.1 Ligands with fluorine-substituted aryl groups |
| Record Nr. | UNINA-9910840793603321 |
|
Uneyama Kenji
|
||
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||