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Acetylene chemistry [[electronic resource] ] : chemistry, biology, and material science / / edited by F. Diederich, P.J. Stang, R.R. Tykwinski
| Acetylene chemistry [[electronic resource] ] : chemistry, biology, and material science / / edited by F. Diederich, P.J. Stang, R.R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (530 p.) |
| Disciplina | 547.413 |
| Altri autori (Persone) |
DiederichFrançois
StangPeter J TykwinskiR. R (Rik R.) |
| Soggetto topico |
Acetylene
Alkynes |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-51994-0
9786610519941 3-527-60548-7 3-527-60470-7 |
| Classificazione | 35.68 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Acetylene Chemistry; Preface; Contents; Symbols and Abbreviations; List of Contributors; 1 Theoretical Studies on Acetylenic Scaffolds; 1.1 Introduction; 1.2 Linear Acetylenic Scaffolds; 1.2.1 The Dicarbon Molecule and Acetylene; 1.2.2 Uncapped Pure sp Carbon Chains; 1.2.3 Capped All-sp Oligoacetylenic Chains; 1.2.4 Hybrid sp-sp(2) Oligoacetylenic Molecules; 1.2.5 Hybrid sp-sp(3) Oligoacetylenic Molecules; 1.3 Cyclic Acetylenic Scaffolds; 1.3.1 Hybrid sp-sp(3) Rings; 1.3.2 Hybrid sp-sp(2) Rings (Dehydroannulenes); 1.3.3 carbo-Heteroannulenes; 1.4 Star-Shaped Acetylenic Scaffolds
1.4.1 Atomic Cores1.4.2 Rod Cores; 1.4.3 Cyclic Cores; 1.5 Cage Acetylenic Scaffolds; 1.6 Conclusion; Acknowledgements; 2 Synthesis of Heterocycles and Carbocycles by Electrophilic Cyclization of Alkynes; 2.1 Introduction; 2.2 Cyclization of Oxygen Compounds; 2.2.1 Cyclization of Acetylenic Alcohols; 2.2.2 Cyclization of Acetylenic Phenols; 2.2.3 Cyclization of Acetylenic Ethers; 2.2.4 Cyclization of Acetylenic Acids and Derivatives; 2.2.5 Cyclization of Acetylenic Aldehydes and Ketones; 2.3 Cyclization of Sulfur and Selenium Compounds; 2.4 Cyclization of Nitrogen Compounds 2.4.1 Cyclization of Acetylenic Amines2.4.2 Cyclization of Acetylenic Amides; 2.4.3 Cyclization of Acetylenic Carbamates; 2.4.4 Cyclization of Acetylenic Sulfonamides; 2.4.5 Cyclization of Acetylenic Enamines and Imines; 2.4.6 Cyclization of Other Acetylenic Nitrogen Functional Groups; 2.5 Cyclization of Carbon onto Acetylenes; 2.5.1 Cyclization of Acetylenic Carbonyl Compounds and Derivatives; 2.5.2 Cyclization of Diacetylenes; 2.5.3 Cyclization of Aryl Acetylenes; 2.5.4 Cyclization of Acetylenic Organometallics; 2.6 Conclusions; 2.7 Representative Experimental Procedures 2.7.1 Synthesis of α-Methylene-γ-butyrolactones by Carbonylation of 1-Alkyn-4-ols2.7.2 Synthesis of 1-Alkoxyisochromenes by Cyclization of 2-(1-Alkynyl)benzaldehydes; 2.7.3 Synthesis of 3-Aryl(vinylic)indoles by Palladium-catalyzed Cross-coupling of Aryl Halides or Vinylic Triflates and 2-(1-Alkynyl)trifluoroacetanilides; 2.7.4 Synthesis of Pyridines by the Gold-catalyzed Cross-coupling of Ketones and Propargyl Amine; 2.7.5 Synthesis of 4-Iodoisoquinolines by the Cyclization of Iminoalkynes; 2.7.6 Synthesis of Cyclic Amines by Acetylene-Iminium Ion Cyclizations; Acknowledgements 3 Addition of Terminal Acetylides to CO and CN Electrophiles3.1 Introduction; 3.2 Background; 3.3 Additions with Stoichiometric Amounts of Metal Acetylides; 3.4 Nucleophilic CO Additions involving the Use of Zn(II) Salts; 3.5 Acetylene Additions to CN Electrophiles; 3.6 Conclusion; 3.7 Experimental Procedures; 3.7.1 General Procedure for the Enantioselective Alkynylation of Aldehydes by the Use of Stoichiometric Amounts of Zn(OTf)(2); 3.7.2 General Procedure for the Zn(OTf)(2)-Catalyzed Enantioselective Alkynylation of Aldehydes 3.7.3 General Procedure for the Enantioselective Alkynylation of Ketones Catalyzed by Zn(salen) Complexes |
| Record Nr. | UNINA-9910144327303321 |
| Weinheim, : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Acetylene chemistry [[electronic resource] ] : chemistry, biology, and material science / / edited by F. Diederich, P.J. Stang, R.R. Tykwinski
| Acetylene chemistry [[electronic resource] ] : chemistry, biology, and material science / / edited by F. Diederich, P.J. Stang, R.R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (530 p.) |
| Disciplina | 547.413 |
| Altri autori (Persone) |
DiederichFrançois
StangPeter J TykwinskiR. R (Rik R.) |
| Soggetto topico |
Acetylene
Alkynes |
| ISBN |
1-280-51994-0
9786610519941 3-527-60548-7 3-527-60470-7 |
| Classificazione | 35.68 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Acetylene Chemistry; Preface; Contents; Symbols and Abbreviations; List of Contributors; 1 Theoretical Studies on Acetylenic Scaffolds; 1.1 Introduction; 1.2 Linear Acetylenic Scaffolds; 1.2.1 The Dicarbon Molecule and Acetylene; 1.2.2 Uncapped Pure sp Carbon Chains; 1.2.3 Capped All-sp Oligoacetylenic Chains; 1.2.4 Hybrid sp-sp(2) Oligoacetylenic Molecules; 1.2.5 Hybrid sp-sp(3) Oligoacetylenic Molecules; 1.3 Cyclic Acetylenic Scaffolds; 1.3.1 Hybrid sp-sp(3) Rings; 1.3.2 Hybrid sp-sp(2) Rings (Dehydroannulenes); 1.3.3 carbo-Heteroannulenes; 1.4 Star-Shaped Acetylenic Scaffolds
1.4.1 Atomic Cores1.4.2 Rod Cores; 1.4.3 Cyclic Cores; 1.5 Cage Acetylenic Scaffolds; 1.6 Conclusion; Acknowledgements; 2 Synthesis of Heterocycles and Carbocycles by Electrophilic Cyclization of Alkynes; 2.1 Introduction; 2.2 Cyclization of Oxygen Compounds; 2.2.1 Cyclization of Acetylenic Alcohols; 2.2.2 Cyclization of Acetylenic Phenols; 2.2.3 Cyclization of Acetylenic Ethers; 2.2.4 Cyclization of Acetylenic Acids and Derivatives; 2.2.5 Cyclization of Acetylenic Aldehydes and Ketones; 2.3 Cyclization of Sulfur and Selenium Compounds; 2.4 Cyclization of Nitrogen Compounds 2.4.1 Cyclization of Acetylenic Amines2.4.2 Cyclization of Acetylenic Amides; 2.4.3 Cyclization of Acetylenic Carbamates; 2.4.4 Cyclization of Acetylenic Sulfonamides; 2.4.5 Cyclization of Acetylenic Enamines and Imines; 2.4.6 Cyclization of Other Acetylenic Nitrogen Functional Groups; 2.5 Cyclization of Carbon onto Acetylenes; 2.5.1 Cyclization of Acetylenic Carbonyl Compounds and Derivatives; 2.5.2 Cyclization of Diacetylenes; 2.5.3 Cyclization of Aryl Acetylenes; 2.5.4 Cyclization of Acetylenic Organometallics; 2.6 Conclusions; 2.7 Representative Experimental Procedures 2.7.1 Synthesis of α-Methylene-γ-butyrolactones by Carbonylation of 1-Alkyn-4-ols2.7.2 Synthesis of 1-Alkoxyisochromenes by Cyclization of 2-(1-Alkynyl)benzaldehydes; 2.7.3 Synthesis of 3-Aryl(vinylic)indoles by Palladium-catalyzed Cross-coupling of Aryl Halides or Vinylic Triflates and 2-(1-Alkynyl)trifluoroacetanilides; 2.7.4 Synthesis of Pyridines by the Gold-catalyzed Cross-coupling of Ketones and Propargyl Amine; 2.7.5 Synthesis of 4-Iodoisoquinolines by the Cyclization of Iminoalkynes; 2.7.6 Synthesis of Cyclic Amines by Acetylene-Iminium Ion Cyclizations; Acknowledgements 3 Addition of Terminal Acetylides to CO and CN Electrophiles3.1 Introduction; 3.2 Background; 3.3 Additions with Stoichiometric Amounts of Metal Acetylides; 3.4 Nucleophilic CO Additions involving the Use of Zn(II) Salts; 3.5 Acetylene Additions to CN Electrophiles; 3.6 Conclusion; 3.7 Experimental Procedures; 3.7.1 General Procedure for the Enantioselective Alkynylation of Aldehydes by the Use of Stoichiometric Amounts of Zn(OTf)(2); 3.7.2 General Procedure for the Zn(OTf)(2)-Catalyzed Enantioselective Alkynylation of Aldehydes 3.7.3 General Procedure for the Enantioselective Alkynylation of Ketones Catalyzed by Zn(salen) Complexes |
| Record Nr. | UNINA-9910829862803321 |
| Weinheim, : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Acetylene chemistry : chemistry, biology, and material science / / edited by F. Diederich, P.J. Stang, R.R. Tykwinski
| Acetylene chemistry : chemistry, biology, and material science / / edited by F. Diederich, P.J. Stang, R.R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2005 |
| Descrizione fisica | 1 online resource (530 p.) |
| Disciplina | 547.413 |
| Altri autori (Persone) |
DiederichFrançois
StangPeter J TykwinskiR. R (Rik R.) |
| Soggetto topico |
Acetylene
Alkynes |
| ISBN |
1-280-51994-0
9786610519941 3-527-60548-7 3-527-60470-7 |
| Classificazione | 35.68 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Acetylene Chemistry; Preface; Contents; Symbols and Abbreviations; List of Contributors; 1 Theoretical Studies on Acetylenic Scaffolds; 1.1 Introduction; 1.2 Linear Acetylenic Scaffolds; 1.2.1 The Dicarbon Molecule and Acetylene; 1.2.2 Uncapped Pure sp Carbon Chains; 1.2.3 Capped All-sp Oligoacetylenic Chains; 1.2.4 Hybrid sp-sp(2) Oligoacetylenic Molecules; 1.2.5 Hybrid sp-sp(3) Oligoacetylenic Molecules; 1.3 Cyclic Acetylenic Scaffolds; 1.3.1 Hybrid sp-sp(3) Rings; 1.3.2 Hybrid sp-sp(2) Rings (Dehydroannulenes); 1.3.3 carbo-Heteroannulenes; 1.4 Star-Shaped Acetylenic Scaffolds
1.4.1 Atomic Cores1.4.2 Rod Cores; 1.4.3 Cyclic Cores; 1.5 Cage Acetylenic Scaffolds; 1.6 Conclusion; Acknowledgements; 2 Synthesis of Heterocycles and Carbocycles by Electrophilic Cyclization of Alkynes; 2.1 Introduction; 2.2 Cyclization of Oxygen Compounds; 2.2.1 Cyclization of Acetylenic Alcohols; 2.2.2 Cyclization of Acetylenic Phenols; 2.2.3 Cyclization of Acetylenic Ethers; 2.2.4 Cyclization of Acetylenic Acids and Derivatives; 2.2.5 Cyclization of Acetylenic Aldehydes and Ketones; 2.3 Cyclization of Sulfur and Selenium Compounds; 2.4 Cyclization of Nitrogen Compounds 2.4.1 Cyclization of Acetylenic Amines2.4.2 Cyclization of Acetylenic Amides; 2.4.3 Cyclization of Acetylenic Carbamates; 2.4.4 Cyclization of Acetylenic Sulfonamides; 2.4.5 Cyclization of Acetylenic Enamines and Imines; 2.4.6 Cyclization of Other Acetylenic Nitrogen Functional Groups; 2.5 Cyclization of Carbon onto Acetylenes; 2.5.1 Cyclization of Acetylenic Carbonyl Compounds and Derivatives; 2.5.2 Cyclization of Diacetylenes; 2.5.3 Cyclization of Aryl Acetylenes; 2.5.4 Cyclization of Acetylenic Organometallics; 2.6 Conclusions; 2.7 Representative Experimental Procedures 2.7.1 Synthesis of α-Methylene-γ-butyrolactones by Carbonylation of 1-Alkyn-4-ols2.7.2 Synthesis of 1-Alkoxyisochromenes by Cyclization of 2-(1-Alkynyl)benzaldehydes; 2.7.3 Synthesis of 3-Aryl(vinylic)indoles by Palladium-catalyzed Cross-coupling of Aryl Halides or Vinylic Triflates and 2-(1-Alkynyl)trifluoroacetanilides; 2.7.4 Synthesis of Pyridines by the Gold-catalyzed Cross-coupling of Ketones and Propargyl Amine; 2.7.5 Synthesis of 4-Iodoisoquinolines by the Cyclization of Iminoalkynes; 2.7.6 Synthesis of Cyclic Amines by Acetylene-Iminium Ion Cyclizations; Acknowledgements 3 Addition of Terminal Acetylides to CO and CN Electrophiles3.1 Introduction; 3.2 Background; 3.3 Additions with Stoichiometric Amounts of Metal Acetylides; 3.4 Nucleophilic CO Additions involving the Use of Zn(II) Salts; 3.5 Acetylene Additions to CN Electrophiles; 3.6 Conclusion; 3.7 Experimental Procedures; 3.7.1 General Procedure for the Enantioselective Alkynylation of Aldehydes by the Use of Stoichiometric Amounts of Zn(OTf)(2); 3.7.2 General Procedure for the Zn(OTf)(2)-Catalyzed Enantioselective Alkynylation of Aldehydes 3.7.3 General Procedure for the Enantioselective Alkynylation of Ketones Catalyzed by Zn(salen) Complexes |
| Record Nr. | UNINA-9910840661603321 |
| Weinheim, : Wiley-VCH, c2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon-rich compounds [[electronic resource] ] : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski
| Carbon-rich compounds [[electronic resource] ] : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (665 p.) |
| Disciplina | 547 |
| Altri autori (Persone) |
HaleyMichael
TykwinskiR. R (Rik R.) |
| Soggetto topico |
Carbon compounds
Chemistry, Organic |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-85431-6
9786610854318 3-527-60799-4 3-527-60724-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Carbon-Rich Compounds; Foreword; Contents; Preface; List of Contributors; 1 Pioneers of Carbon-rich Compounds; 1.1 Introduction; 1.2 19th Century Achievements; 1.3 1900-1928: Dawn of the Twentieth Century; 1.4 1929-1949: Rise of the Polycyclic Aromatic Hydrocarbon; 1.5 1950-1969; 1.5.1 The Annulenes, Dehydrobenzoannulenes, and Phenylacetylene Scaffolding; 1.5.2 Fused Polycyclic and peri-Condensed Benzenoid Systems; 1.5.3 The Helicenes, Radialenes, Fulvalenes, and Circulenes; 1.6 1970-Present: The Way Ahead; References; 2 Electronic Conduction in Photoactive Metallo-wires; 2.1 Introduction
2.2 Attenuation along Molecular Bridges2.3 Information Transfer; 2.3.1 Intramolecular Triplet Energy Transfer; 2.3.2 Short Covalent Bridges; 2.3.3 Supramolecular Systems; 2.3.4 Prolonging the Excited State Lifetime; 2.3.5 Long-range Triplet Energy Transfer; 2.4 Molecular-scale Switches; 2.5 Perspectives; 2.6 Experimental: Selected Procedures; 2.6.1 General Procedure for the Preparation of the Mononuclear [RuL(n)]; 2.6.2 General Procedure for the Preparation of the Hetero-Dinuclear Complexes 81(1) and 81(5); 2.6.3 Synthesis at the Complex; Acknowledgements; Abbreviations; References 3 All-benzenoid Polycyclic Aromatic Hydrocarbons: Synthesis, Self-assembly and Applications in Organic Electronics3.1 A Brief Introduction to Polycyclic Aromatic Hydrocarbons; 3.2 All-benzenoid PAHs - Synthesis, Structural Characterizations and Electronic Properties; 3.2.1 Hexa-peri-hexabenzocoronene - An Old Story with New Discoveries; 3.2.2 All-benzenoid Graphitic PAHs Larger than HBCs; 3.2.3 PAHs with Varying Peripheries; 3.2.4 ''Superbenzene'' Chemistry and Others; 3.3 Self-assembly and Application of Columnar Liquid Crystals based on PBAHs 3.3.1 Columnar Superstructures in the Bulk State3.3.2 Alignment on Substrates and Device Applications of Columnar Liquid Crystals; 3.3.3 Controlled Self-assembly in Solution; 3.3.4 Two-dimensional Crystals at the Solid/Liquid Interface; 3.4 Conclusion; 3.5 Experimental: Selected Procedures; 3.5.1 Synthesis of hexa-peri-hexabenzocoronene 10 by Cu(II)-mediated oxidative cyclodehydrogenation - a general procedure to prepare unsubstituted graphitic molecules [35] 3.5.2 Synthesis of hexakis(4-dodecylphenyl)-peri-hexabenzocoronene (HBC-PhC12) - a general synthetic method towards six-fold alkyl- and alkylphenyl-substituted HBCs [38]3.5.3 Functionalization of insoluble HBC building blocks 30-32 by Sonogashira coupling reactions [48]. Synthesis of hexakis(1-dodecynylphenyl)-peri-hexabenzocoronene (34a) as a representative example; 3.5.4 Synthesis of C96-C12 precursor 1,3,5-tris[3 ́,4 ́-di(4 ́ ́-dodecylphenyl)-2 ́,5 ́-diphenylphenyl]benzene (44a) by Diels-Alder cycloaddition reaction - a representative procedure for the synthesis of branched oligophenylenes [50] 3.5.5 Hydrogenation of hexakis-dodecyl-peri-hexabenzocoronenes 74 [66] |
| Record Nr. | UNINA-9910144321703321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon-rich compounds [[electronic resource] ] : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski
| Carbon-rich compounds [[electronic resource] ] : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (665 p.) |
| Disciplina | 547 |
| Altri autori (Persone) |
HaleyMichael
TykwinskiR. R (Rik R.) |
| Soggetto topico |
Carbon compounds
Chemistry, Organic |
| ISBN |
1-280-85431-6
9786610854318 3-527-60799-4 3-527-60724-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Carbon-Rich Compounds; Foreword; Contents; Preface; List of Contributors; 1 Pioneers of Carbon-rich Compounds; 1.1 Introduction; 1.2 19th Century Achievements; 1.3 1900-1928: Dawn of the Twentieth Century; 1.4 1929-1949: Rise of the Polycyclic Aromatic Hydrocarbon; 1.5 1950-1969; 1.5.1 The Annulenes, Dehydrobenzoannulenes, and Phenylacetylene Scaffolding; 1.5.2 Fused Polycyclic and peri-Condensed Benzenoid Systems; 1.5.3 The Helicenes, Radialenes, Fulvalenes, and Circulenes; 1.6 1970-Present: The Way Ahead; References; 2 Electronic Conduction in Photoactive Metallo-wires; 2.1 Introduction
2.2 Attenuation along Molecular Bridges2.3 Information Transfer; 2.3.1 Intramolecular Triplet Energy Transfer; 2.3.2 Short Covalent Bridges; 2.3.3 Supramolecular Systems; 2.3.4 Prolonging the Excited State Lifetime; 2.3.5 Long-range Triplet Energy Transfer; 2.4 Molecular-scale Switches; 2.5 Perspectives; 2.6 Experimental: Selected Procedures; 2.6.1 General Procedure for the Preparation of the Mononuclear [RuL(n)]; 2.6.2 General Procedure for the Preparation of the Hetero-Dinuclear Complexes 81(1) and 81(5); 2.6.3 Synthesis at the Complex; Acknowledgements; Abbreviations; References 3 All-benzenoid Polycyclic Aromatic Hydrocarbons: Synthesis, Self-assembly and Applications in Organic Electronics3.1 A Brief Introduction to Polycyclic Aromatic Hydrocarbons; 3.2 All-benzenoid PAHs - Synthesis, Structural Characterizations and Electronic Properties; 3.2.1 Hexa-peri-hexabenzocoronene - An Old Story with New Discoveries; 3.2.2 All-benzenoid Graphitic PAHs Larger than HBCs; 3.2.3 PAHs with Varying Peripheries; 3.2.4 ''Superbenzene'' Chemistry and Others; 3.3 Self-assembly and Application of Columnar Liquid Crystals based on PBAHs 3.3.1 Columnar Superstructures in the Bulk State3.3.2 Alignment on Substrates and Device Applications of Columnar Liquid Crystals; 3.3.3 Controlled Self-assembly in Solution; 3.3.4 Two-dimensional Crystals at the Solid/Liquid Interface; 3.4 Conclusion; 3.5 Experimental: Selected Procedures; 3.5.1 Synthesis of hexa-peri-hexabenzocoronene 10 by Cu(II)-mediated oxidative cyclodehydrogenation - a general procedure to prepare unsubstituted graphitic molecules [35] 3.5.2 Synthesis of hexakis(4-dodecylphenyl)-peri-hexabenzocoronene (HBC-PhC12) - a general synthetic method towards six-fold alkyl- and alkylphenyl-substituted HBCs [38]3.5.3 Functionalization of insoluble HBC building blocks 30-32 by Sonogashira coupling reactions [48]. Synthesis of hexakis(1-dodecynylphenyl)-peri-hexabenzocoronene (34a) as a representative example; 3.5.4 Synthesis of C96-C12 precursor 1,3,5-tris[3 ́,4 ́-di(4 ́ ́-dodecylphenyl)-2 ́,5 ́-diphenylphenyl]benzene (44a) by Diels-Alder cycloaddition reaction - a representative procedure for the synthesis of branched oligophenylenes [50] 3.5.5 Hydrogenation of hexakis-dodecyl-peri-hexabenzocoronenes 74 [66] |
| Record Nr. | UNINA-9910830795503321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Carbon-rich compounds : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski
| Carbon-rich compounds : from molecules to materials / / edited by Michael M. Haley and Rik R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH |
| Descrizione fisica | 1 online resource (665 p.) |
| Disciplina | 547 |
| Altri autori (Persone) |
HaleyMichael
TykwinskiR. R (Rik R.) |
| Soggetto topico |
Carbon compounds
Chemistry, Organic |
| ISBN |
1-280-85431-6
9786610854318 3-527-60799-4 3-527-60724-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Carbon-Rich Compounds; Foreword; Contents; Preface; List of Contributors; 1 Pioneers of Carbon-rich Compounds; 1.1 Introduction; 1.2 19th Century Achievements; 1.3 1900-1928: Dawn of the Twentieth Century; 1.4 1929-1949: Rise of the Polycyclic Aromatic Hydrocarbon; 1.5 1950-1969; 1.5.1 The Annulenes, Dehydrobenzoannulenes, and Phenylacetylene Scaffolding; 1.5.2 Fused Polycyclic and peri-Condensed Benzenoid Systems; 1.5.3 The Helicenes, Radialenes, Fulvalenes, and Circulenes; 1.6 1970-Present: The Way Ahead; References; 2 Electronic Conduction in Photoactive Metallo-wires; 2.1 Introduction
2.2 Attenuation along Molecular Bridges2.3 Information Transfer; 2.3.1 Intramolecular Triplet Energy Transfer; 2.3.2 Short Covalent Bridges; 2.3.3 Supramolecular Systems; 2.3.4 Prolonging the Excited State Lifetime; 2.3.5 Long-range Triplet Energy Transfer; 2.4 Molecular-scale Switches; 2.5 Perspectives; 2.6 Experimental: Selected Procedures; 2.6.1 General Procedure for the Preparation of the Mononuclear [RuL(n)]; 2.6.2 General Procedure for the Preparation of the Hetero-Dinuclear Complexes 81(1) and 81(5); 2.6.3 Synthesis at the Complex; Acknowledgements; Abbreviations; References 3 All-benzenoid Polycyclic Aromatic Hydrocarbons: Synthesis, Self-assembly and Applications in Organic Electronics3.1 A Brief Introduction to Polycyclic Aromatic Hydrocarbons; 3.2 All-benzenoid PAHs - Synthesis, Structural Characterizations and Electronic Properties; 3.2.1 Hexa-peri-hexabenzocoronene - An Old Story with New Discoveries; 3.2.2 All-benzenoid Graphitic PAHs Larger than HBCs; 3.2.3 PAHs with Varying Peripheries; 3.2.4 ''Superbenzene'' Chemistry and Others; 3.3 Self-assembly and Application of Columnar Liquid Crystals based on PBAHs 3.3.1 Columnar Superstructures in the Bulk State3.3.2 Alignment on Substrates and Device Applications of Columnar Liquid Crystals; 3.3.3 Controlled Self-assembly in Solution; 3.3.4 Two-dimensional Crystals at the Solid/Liquid Interface; 3.4 Conclusion; 3.5 Experimental: Selected Procedures; 3.5.1 Synthesis of hexa-peri-hexabenzocoronene 10 by Cu(II)-mediated oxidative cyclodehydrogenation - a general procedure to prepare unsubstituted graphitic molecules [35] 3.5.2 Synthesis of hexakis(4-dodecylphenyl)-peri-hexabenzocoronene (HBC-PhC12) - a general synthetic method towards six-fold alkyl- and alkylphenyl-substituted HBCs [38]3.5.3 Functionalization of insoluble HBC building blocks 30-32 by Sonogashira coupling reactions [48]. Synthesis of hexakis(1-dodecynylphenyl)-peri-hexabenzocoronene (34a) as a representative example; 3.5.4 Synthesis of C96-C12 precursor 1,3,5-tris[3 ́,4 ́-di(4 ́ ́-dodecylphenyl)-2 ́,5 ́-diphenylphenyl]benzene (44a) by Diels-Alder cycloaddition reaction - a representative procedure for the synthesis of branched oligophenylenes [50] 3.5.5 Hydrogenation of hexakis-dodecyl-peri-hexabenzocoronenes 74 [66] |
| Record Nr. | UNINA-9910841200803321 |
| Weinheim, : Wiley-VCH | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern supramolecular chemistry : strategies for macrocycle synthesis / / edited by Francois Diederich, Peter J. Stang and Rik R. Tykwinski
| Modern supramolecular chemistry : strategies for macrocycle synthesis / / edited by Francois Diederich, Peter J. Stang and Rik R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, Germany : , : WILEY-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (420 p.) |
| Disciplina | 547.2 |
| Soggetto topico | Supramolecular chemistry |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-283-14038-1
9786613140388 3-527-62148-2 3-527-62149-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Supramolecular Chemistry; Contents; Preface; List of Contributors; 1 Bioactive Macrocyclic Peptides and Peptide Mimics; 1.1 Introduction; 1.2 Selected Cyclic Peptides; 1.2.1 Vancomycin; 1.2.2 Lantibiotic: Nisin; 1.2.3 Cyclosporin A; 1.2.4 Cyclotheonamide A and B; 1.2.5 cyclo RGD Peptides as α(V)β(3) Antagonists; 1.2.6 SH2 Domain-Binding Peptides; 1.3 Conclusions; 1.4 Experimental: Selected Procedures; 1.4.1 Synthesis of Bicyclic Peptide 9: an Alkene-bridged Mimic of the Vancomycin C-D-E Cavity; 1.4.2 Synthesis of Cyclic Peptide 14: an Alkyne-bridged Mimic of the Nisin A-Ring Fragment
References2 Macrocycles by Ring-closure Metathesis; 2.1 Introduction; 2.2 How to Cyclize?; 2.2.1 A Thermodynamic versus Kinetic Issue; 2.2.2 General Experimental Conditions; 2.2.3 Influence of Polar Complexing Groups; 2.2.3.1 A Decisive Factor for Success; 2.2.3.2 The Titanium Trick; 2.2.3.3 A Particularly Favorable Case: The Template-Directed RCM; 2.2.4 Chemoselectivity; 2.2.5 Substrate ''Tuning''; 2.2.5.1 Configurational/Conformational Aspect; 2.2.5.2 Influence of Functional Group Protection; 2.3 Factors Influencing the Double-Bond Configuration; 2.3.1 A Thermodynamic versus Kinetic Issue 2.3.2 General Experimental Conditions2.3.3 Substrate ''Tuning''; 2.3.4 Solutions; 2.4 Ene-yne M-RCM; 2.5 Tandem Processes Involving M-RCM; 2.5.1 Tandem CM/RCM; 2.5.2 Tandem ROM/RCM; 2.5.3 Tandem RCM/ROM/RCM; 2.5.4 Ring-Expansion Metathesis; 2.5.5 Other One-Pot Multistep Processes; 2.5.6 M-RCM as Part of MCR Strategies; 2.6 Representative Synthetic Applications; 2.6.1 Salicylihalamides/Oximidines: Potent Antitumor Agents with Selective anti-V-ATPase Activity; 2.6.1.1 Salicylihalamides: Influence of the Catalyst; 2.6.1.2 Salicylihalamides: Influence of the Phenol Protecting Group 2.6.1.3 Salicylihalamides: Influence of the Alcohol-Protecting Group at C132.6.1.4 Salicylihalamides: Influence of the Nature of the C15 Side Chain; 2.6.1.5 Salicylihalamides: Miscellaneous; 2.6.1.6 Oximidines: Use of Relay Ring-closing Metathesis; 2.6.2 Radicicol-Type Macrolides: a Promising Family of Anticancer Resorcylides; 2.6.3 Coleophomones: a Versatile Access to this Class of Complex Polycyclic Diterpenes; 2.6.4 RCM in Supramolecular Chemistry; 2.7 Conclusion and Perspectives; 2.8 Experimental: Selected Procedures; 2.8.1 Synthesis of Compound 3 with Catalyst S1 [12] 2.8.2 Synthesis of Compound 6 with Catalyst G1 [13]2.8.3 Synthesis of Compound 8 with Catalyst G2 [14b]; 2.8.4 Synthesis of Compound 16 (R=SiMe(2)tBu) with Catalyst G1/Ti(OiPr)(4) [17]; 2.8.5 Synthesis of Compound 49 by RCAM [38]; 2.8.6 Synthesis of Compound 53 with G1 by ene-yne RCM [40a]; References; 3 Supramolecular Macrocycle Synthesis by H-bonding Assembly; 3.1 Introduction; 3.2 Strategies to Build up Supramolecular Macrocycles Based on Hydrogen Bonds; 3.3 Strategies to Build up Supramolecular Cavities and Capsules Based on Hydrogen Bonds; 3.4 Summary and Outlook 3.5 Experimental: Selected Procedures |
| Record Nr. | UNINA-9910144376203321 |
| Weinheim, Germany : , : WILEY-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
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Modern supramolecular chemistry : strategies for macrocycle synthesis / / edited by Francois Diederich, Peter J. Stang and Rik R. Tykwinski
| Modern supramolecular chemistry : strategies for macrocycle synthesis / / edited by Francois Diederich, Peter J. Stang and Rik R. Tykwinski |
| Pubbl/distr/stampa | Weinheim, Germany : , : WILEY-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (420 p.) |
| Disciplina | 547.2 |
| Soggetto topico | Supramolecular chemistry |
| ISBN |
1-283-14038-1
9786613140388 3-527-62148-2 3-527-62149-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Supramolecular Chemistry; Contents; Preface; List of Contributors; 1 Bioactive Macrocyclic Peptides and Peptide Mimics; 1.1 Introduction; 1.2 Selected Cyclic Peptides; 1.2.1 Vancomycin; 1.2.2 Lantibiotic: Nisin; 1.2.3 Cyclosporin A; 1.2.4 Cyclotheonamide A and B; 1.2.5 cyclo RGD Peptides as α(V)β(3) Antagonists; 1.2.6 SH2 Domain-Binding Peptides; 1.3 Conclusions; 1.4 Experimental: Selected Procedures; 1.4.1 Synthesis of Bicyclic Peptide 9: an Alkene-bridged Mimic of the Vancomycin C-D-E Cavity; 1.4.2 Synthesis of Cyclic Peptide 14: an Alkyne-bridged Mimic of the Nisin A-Ring Fragment
References2 Macrocycles by Ring-closure Metathesis; 2.1 Introduction; 2.2 How to Cyclize?; 2.2.1 A Thermodynamic versus Kinetic Issue; 2.2.2 General Experimental Conditions; 2.2.3 Influence of Polar Complexing Groups; 2.2.3.1 A Decisive Factor for Success; 2.2.3.2 The Titanium Trick; 2.2.3.3 A Particularly Favorable Case: The Template-Directed RCM; 2.2.4 Chemoselectivity; 2.2.5 Substrate ''Tuning''; 2.2.5.1 Configurational/Conformational Aspect; 2.2.5.2 Influence of Functional Group Protection; 2.3 Factors Influencing the Double-Bond Configuration; 2.3.1 A Thermodynamic versus Kinetic Issue 2.3.2 General Experimental Conditions2.3.3 Substrate ''Tuning''; 2.3.4 Solutions; 2.4 Ene-yne M-RCM; 2.5 Tandem Processes Involving M-RCM; 2.5.1 Tandem CM/RCM; 2.5.2 Tandem ROM/RCM; 2.5.3 Tandem RCM/ROM/RCM; 2.5.4 Ring-Expansion Metathesis; 2.5.5 Other One-Pot Multistep Processes; 2.5.6 M-RCM as Part of MCR Strategies; 2.6 Representative Synthetic Applications; 2.6.1 Salicylihalamides/Oximidines: Potent Antitumor Agents with Selective anti-V-ATPase Activity; 2.6.1.1 Salicylihalamides: Influence of the Catalyst; 2.6.1.2 Salicylihalamides: Influence of the Phenol Protecting Group 2.6.1.3 Salicylihalamides: Influence of the Alcohol-Protecting Group at C132.6.1.4 Salicylihalamides: Influence of the Nature of the C15 Side Chain; 2.6.1.5 Salicylihalamides: Miscellaneous; 2.6.1.6 Oximidines: Use of Relay Ring-closing Metathesis; 2.6.2 Radicicol-Type Macrolides: a Promising Family of Anticancer Resorcylides; 2.6.3 Coleophomones: a Versatile Access to this Class of Complex Polycyclic Diterpenes; 2.6.4 RCM in Supramolecular Chemistry; 2.7 Conclusion and Perspectives; 2.8 Experimental: Selected Procedures; 2.8.1 Synthesis of Compound 3 with Catalyst S1 [12] 2.8.2 Synthesis of Compound 6 with Catalyst G1 [13]2.8.3 Synthesis of Compound 8 with Catalyst G2 [14b]; 2.8.4 Synthesis of Compound 16 (R=SiMe(2)tBu) with Catalyst G1/Ti(OiPr)(4) [17]; 2.8.5 Synthesis of Compound 49 by RCAM [38]; 2.8.6 Synthesis of Compound 53 with G1 by ene-yne RCM [40a]; References; 3 Supramolecular Macrocycle Synthesis by H-bonding Assembly; 3.1 Introduction; 3.2 Strategies to Build up Supramolecular Macrocycles Based on Hydrogen Bonds; 3.3 Strategies to Build up Supramolecular Cavities and Capsules Based on Hydrogen Bonds; 3.4 Summary and Outlook 3.5 Experimental: Selected Procedures |
| Record Nr. | UNINA-9910830786903321 |
| Weinheim, Germany : , : WILEY-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||