Info
- Utilizzare la checkbox di selezione a fianco di ciascun documento per attivare le funzionalità di stampa, invio email, download nei formati disponibili del (i) record.
Homogeneous catalysis with metal complexes [[electronic resource] ] : kinetic aspects and mechanisms / / O.N. Temkin ; translated from the Russian by P.P. Pozdeev
| Homogeneous catalysis with metal complexes [[electronic resource] ] : kinetic aspects and mechanisms / / O.N. Temkin ; translated from the Russian by P.P. Pozdeev |
| Autore | Temkin O. N |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2012 |
| Descrizione fisica | 1 online resource (832 p.) |
| Disciplina | 541.395 |
| Soggetto topico |
Catalysis
Metal catalysts Metal complexes |
| ISBN |
1-119-96682-5
1-283-42537-8 9786613425379 1-119-96622-1 1-119-96623-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Homogeneous Catalysis with Metal Complexes; Contents; Notations and Abbreviations; Preface to English Edition; Preface; Acknowledgments; About the Author; Introduction; 1 State-of-the-Art in the Theory of Kinetics of Complex Reactions; 1.1 Main concepts of the Horiuti-Temkin theory of steady-state reactions; 1.1.1 Reaction mechanism: Stoichiometry and routes; 1.1.2 Kinetics: Reaction rates with respect to substances and over routes; 1.1.3 Kinetic polynomial; 1.1.4 Determining the number of independent parameters in a kinetic model. The problem of identifiability of parameters
1.2 Quasi-steady-state and quasi-equilibrium approximations in chemical kinetics1.2.1 Theoretical criteria of quasi-steady-state intermediate concentrations and quasi-equilibrium steps; 1.2.2 Experimental criteria of applicability of quasi-steady-state approximation in various systems; 1.3 Methods of graph theory in chemical kinetics and in theory of complex reaction mechanisms; 1.3.1 Linear mechanisms; 1.3.2 Nonlinear mechanisms; 1.3.3 Other fields of application of kinetic and bipartite graphs in chemical kinetics and in theory of complex reaction mechanisms 1.4 Elementary steps - Selection rules1.4.1 Main postulates, laws, and principles; 1.4.2 Energy selection rules for elementary steps; 1.4.3 Quantum-chemical selection rules for elementary steps; 1.4.4 Topological selection rules for elementary steps; References; 2 Complexity Functions of Catalysts and Reactants in Reactions Involving Metal Complexes; 2.1 Mononuclear metal complexes; 2.1.1 Complexity functions: variants I and II; 2.1.2 Complexity functions: variants III and IV; 2.1.3 General problems and recommendations 2.2 Polynuclear complexes in homogeneous catalytic and noncatalytic reactions2.2.1 Systems with formation of associates; 2.2.2 Systems with mononuclear and polynuclear complexes of various types; 2.3 Catalysis with polynuclear copper(I) halide complexes in superconcentrated solutions; 2.3.1 Copper(I) chloride complexes in solution and in crystalline state; 2.3.2 Kinetics of catalytic reactions of alkynes in concentrated NH4Cl-CuCl aqueous solutions at constant complexity functions FCu and FCl; 2.3.3 Determination of compositions of catalytically active copper(I) complexes in various reactions 2.3.4 Studying p and s complexes of copper(I) with alkynes in crystalline state and in solution2.3.5 Mechanisms of acetylene dimerization and hydrocyanation reactions. Crystallochemical aspects; References; 3 Multi-Route Mechanisms in Reactions Involving Metal Complexes; 3.1 Factors accounting for the appearance and kinetic features of multi-route mechanisms; 3.2 Analysis of multi-route reaction kinetics; 3.3 Conjugation nodes and artificial multi-route character; 3.4 Conjugate processes; 3.4.1 Classical approach; 3.4.2 Kinetic and thermodynamic conjugation in consecutive reactions 3.4.3 Conjugation in chain reactions |
| Record Nr. | UNINA-9910139294503321 |
Temkin O. N
|
||
| Chichester, U.K., : Wiley, 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Homogeneous catalysis with metal complexes : kinetic aspects and mechanisms / / O.N. Temkin ; translated from the Russian by P.P. Pozdeev
| Homogeneous catalysis with metal complexes : kinetic aspects and mechanisms / / O.N. Temkin ; translated from the Russian by P.P. Pozdeev |
| Autore | Temkin O. N |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Chichester, U.K., : Wiley, 2012 |
| Descrizione fisica | 1 online resource (832 p.) |
| Disciplina | 541.395 |
| Soggetto topico |
Catalysis
Metal catalysts Metal complexes |
| ISBN |
1-119-96682-5
1-283-42537-8 9786613425379 1-119-96622-1 1-119-96623-X |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Homogeneous Catalysis with Metal Complexes; Contents; Notations and Abbreviations; Preface to English Edition; Preface; Acknowledgments; About the Author; Introduction; 1 State-of-the-Art in the Theory of Kinetics of Complex Reactions; 1.1 Main concepts of the Horiuti-Temkin theory of steady-state reactions; 1.1.1 Reaction mechanism: Stoichiometry and routes; 1.1.2 Kinetics: Reaction rates with respect to substances and over routes; 1.1.3 Kinetic polynomial; 1.1.4 Determining the number of independent parameters in a kinetic model. The problem of identifiability of parameters
1.2 Quasi-steady-state and quasi-equilibrium approximations in chemical kinetics1.2.1 Theoretical criteria of quasi-steady-state intermediate concentrations and quasi-equilibrium steps; 1.2.2 Experimental criteria of applicability of quasi-steady-state approximation in various systems; 1.3 Methods of graph theory in chemical kinetics and in theory of complex reaction mechanisms; 1.3.1 Linear mechanisms; 1.3.2 Nonlinear mechanisms; 1.3.3 Other fields of application of kinetic and bipartite graphs in chemical kinetics and in theory of complex reaction mechanisms 1.4 Elementary steps - Selection rules1.4.1 Main postulates, laws, and principles; 1.4.2 Energy selection rules for elementary steps; 1.4.3 Quantum-chemical selection rules for elementary steps; 1.4.4 Topological selection rules for elementary steps; References; 2 Complexity Functions of Catalysts and Reactants in Reactions Involving Metal Complexes; 2.1 Mononuclear metal complexes; 2.1.1 Complexity functions: variants I and II; 2.1.2 Complexity functions: variants III and IV; 2.1.3 General problems and recommendations 2.2 Polynuclear complexes in homogeneous catalytic and noncatalytic reactions2.2.1 Systems with formation of associates; 2.2.2 Systems with mononuclear and polynuclear complexes of various types; 2.3 Catalysis with polynuclear copper(I) halide complexes in superconcentrated solutions; 2.3.1 Copper(I) chloride complexes in solution and in crystalline state; 2.3.2 Kinetics of catalytic reactions of alkynes in concentrated NH4Cl-CuCl aqueous solutions at constant complexity functions FCu and FCl; 2.3.3 Determination of compositions of catalytically active copper(I) complexes in various reactions 2.3.4 Studying p and s complexes of copper(I) with alkynes in crystalline state and in solution2.3.5 Mechanisms of acetylene dimerization and hydrocyanation reactions. Crystallochemical aspects; References; 3 Multi-Route Mechanisms in Reactions Involving Metal Complexes; 3.1 Factors accounting for the appearance and kinetic features of multi-route mechanisms; 3.2 Analysis of multi-route reaction kinetics; 3.3 Conjugation nodes and artificial multi-route character; 3.4 Conjugate processes; 3.4.1 Classical approach; 3.4.2 Kinetic and thermodynamic conjugation in consecutive reactions 3.4.3 Conjugation in chain reactions |
| Record Nr. | UNINA-9910817073903321 |
|
Temkin O. N
|
||
| Chichester, U.K., : Wiley, 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||