Info
- Utilizzare la checkbox di selezione a fianco di ciascun documento per attivare le funzionalità di stampa, invio email, download nei formati disponibili del (i) record.
Modern carbonyl olefination [[electronic resource] /] / Takeshi Takeda (ed.)
| Modern carbonyl olefination [[electronic resource] /] / Takeshi Takeda (ed.) |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (367 p.) |
| Disciplina |
547.036
547.05621046 |
| Altri autori (Persone) | TakedaTakeshi |
| Soggetto topico | Carbonyl compounds |
| ISBN |
1-280-52047-7
9786610520473 3-527-60538-X 3-527-60188-0 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Carbonyl Olefination; Contents; Preface; List of Authors; 1 The Wittig Reaction; 1.1 Introduction; 1.2 The ""Classic"" Wittig Reaction; 1.2.1 Mechanism and Stereoselectivity; 1.2.2 Nature of the Ylide and Carbonyl Compound; 1.2.3 Reagents and Reaction Conditions; 1.3 Horner-Wadsworth-Emmons Reaction; 1.3.1 Mechanism and Stereochemistry; 1.3.2 Reagents and Reaction Conditions; 1.4 Horner-Wittig (HW) Reaction; 1.4.1 Mechanism and Stereochemistry; 1.4.2 Reagents and Reaction Conditions; 1.5 Conclusion; References; 2 The Peterson and Related Reactions; 2.1 Introduction
2.2 Stereochemistry and the Reaction Mechanism of the Peterson Reaction2.2.1 Stereochemistry and the Reaction Mechanism of the Peterson Reaction of β-Hydroxyalkylsilanes; 2.2.1.1 Stepwise Mechanism; 2.2.1.2 Reaction Mechanism via a 1,2-Oxasiletanide; 2.2.2 Reaction Mechanism of the Addition Step of an α-Silyl Carbanion to a Carbonyl Compound; 2.2.2.1 Approach Control of the Transition State; 2.2.2.2 Concerted Mechanism; 2.2.2.3 Chelation Control Mechanism; 2.2.3 Theoretical Calculations on the Reaction Mechanism; 2.2.4 Convergently Stereoselective Peterson Reactions 2.3 Generation of α-Silyl Carbanions and their Peterson Reactions2.3.1 Generation of α-Silyl Carbanions from α-Silylalkyl Halides; 2.3.1.1 Generation of α-Silyl Grignard Reagents from α-Silylalkyl Halides; 2.3.1.2 Generation of α-Silyl Alkyllithium Reagents from α-Silylalkyl Halides; 2.3.1.3 Synthesis of Terminal Alkenes by the Use of α-Silyl Carbanions Generated from α-Silylalkyl Halides; 2.3.1.4 Reactions of α-Silyl Carbanions Generated from α-Silylalkyl Halides with Esters, Carboxylic Acids, and Acetals; 2.3.1.5 The Reformatsky-Peterson Reactions of α-Silylalkyl Halides 2.3.2 Generation of α-Silyl Carbanions by Deprotonation of Alkylsilanes2.3.2.1 Generation of α-Silyl Carbanions Bearing an Aryl or a Heteroaryl Group; 2.3.2.2 Generation of α-Silyl Carbanions Bearing an Alkoxy Group; 2.3.2.3 Generation of α-Silyl Carbanions Bearing a Nitrogen-Containing Group; 2.3.2.4 Generation of α-Silyl Carbanions Bearing a Sulfur-Containing Group; 2.3.2.5 Generation of α-Silyl Carbanions Bearing a Phosphorus-Containing Group; 2.3.2.6 Generation of α-Silyl Carbanions Bearing a Halogen Group; 2.3.2.7 Generation of α-Silyl Carbanions from α-Silyl Ketones 2.3.2.8 Generation of α-Silyl Carbanions Bearing an Ester Group2.3.2.9 Generation of α-Silyl Carbanions Bearing a Lactone Group; 2.3.2.10 Generation of α-Silyl Carbanions Bearing Thiocarboxylate or Dithiocarboxylate Ester Groups; 2.3.2.11 Generation of α-Silyl Carbanions Bearing an Imino Group; 2.3.2.12 Generation of α-Silyl Carbanions Bearing an Amide Group; 2.3.2.13 Generation of α-Silyl Carbanions Bearing a Cyano Group; 2.3.2.14 Generation of α-Silyl Carbanions from Allylsilanes; 2.3.2.15 Generation of α-Silyl Carbanions from Propargylsilanes 2.3.3 Generation of α-Silyl Carbanions by Substitution of a Heteroatom |
| Record Nr. | UNINA-9910146238103321 |
| Weinheim, : Wiley-VCH, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern carbonyl olefination [[electronic resource] /] / Takeshi Takeda (ed.)
| Modern carbonyl olefination [[electronic resource] /] / Takeshi Takeda (ed.) |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (367 p.) |
| Disciplina |
547.036
547.05621046 |
| Altri autori (Persone) | TakedaTakeshi |
| Soggetto topico | Carbonyl compounds |
| ISBN |
1-280-52047-7
9786610520473 3-527-60538-X 3-527-60188-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Carbonyl Olefination; Contents; Preface; List of Authors; 1 The Wittig Reaction; 1.1 Introduction; 1.2 The ""Classic"" Wittig Reaction; 1.2.1 Mechanism and Stereoselectivity; 1.2.2 Nature of the Ylide and Carbonyl Compound; 1.2.3 Reagents and Reaction Conditions; 1.3 Horner-Wadsworth-Emmons Reaction; 1.3.1 Mechanism and Stereochemistry; 1.3.2 Reagents and Reaction Conditions; 1.4 Horner-Wittig (HW) Reaction; 1.4.1 Mechanism and Stereochemistry; 1.4.2 Reagents and Reaction Conditions; 1.5 Conclusion; References; 2 The Peterson and Related Reactions; 2.1 Introduction
2.2 Stereochemistry and the Reaction Mechanism of the Peterson Reaction2.2.1 Stereochemistry and the Reaction Mechanism of the Peterson Reaction of β-Hydroxyalkylsilanes; 2.2.1.1 Stepwise Mechanism; 2.2.1.2 Reaction Mechanism via a 1,2-Oxasiletanide; 2.2.2 Reaction Mechanism of the Addition Step of an α-Silyl Carbanion to a Carbonyl Compound; 2.2.2.1 Approach Control of the Transition State; 2.2.2.2 Concerted Mechanism; 2.2.2.3 Chelation Control Mechanism; 2.2.3 Theoretical Calculations on the Reaction Mechanism; 2.2.4 Convergently Stereoselective Peterson Reactions 2.3 Generation of α-Silyl Carbanions and their Peterson Reactions2.3.1 Generation of α-Silyl Carbanions from α-Silylalkyl Halides; 2.3.1.1 Generation of α-Silyl Grignard Reagents from α-Silylalkyl Halides; 2.3.1.2 Generation of α-Silyl Alkyllithium Reagents from α-Silylalkyl Halides; 2.3.1.3 Synthesis of Terminal Alkenes by the Use of α-Silyl Carbanions Generated from α-Silylalkyl Halides; 2.3.1.4 Reactions of α-Silyl Carbanions Generated from α-Silylalkyl Halides with Esters, Carboxylic Acids, and Acetals; 2.3.1.5 The Reformatsky-Peterson Reactions of α-Silylalkyl Halides 2.3.2 Generation of α-Silyl Carbanions by Deprotonation of Alkylsilanes2.3.2.1 Generation of α-Silyl Carbanions Bearing an Aryl or a Heteroaryl Group; 2.3.2.2 Generation of α-Silyl Carbanions Bearing an Alkoxy Group; 2.3.2.3 Generation of α-Silyl Carbanions Bearing a Nitrogen-Containing Group; 2.3.2.4 Generation of α-Silyl Carbanions Bearing a Sulfur-Containing Group; 2.3.2.5 Generation of α-Silyl Carbanions Bearing a Phosphorus-Containing Group; 2.3.2.6 Generation of α-Silyl Carbanions Bearing a Halogen Group; 2.3.2.7 Generation of α-Silyl Carbanions from α-Silyl Ketones 2.3.2.8 Generation of α-Silyl Carbanions Bearing an Ester Group2.3.2.9 Generation of α-Silyl Carbanions Bearing a Lactone Group; 2.3.2.10 Generation of α-Silyl Carbanions Bearing Thiocarboxylate or Dithiocarboxylate Ester Groups; 2.3.2.11 Generation of α-Silyl Carbanions Bearing an Imino Group; 2.3.2.12 Generation of α-Silyl Carbanions Bearing an Amide Group; 2.3.2.13 Generation of α-Silyl Carbanions Bearing a Cyano Group; 2.3.2.14 Generation of α-Silyl Carbanions from Allylsilanes; 2.3.2.15 Generation of α-Silyl Carbanions from Propargylsilanes 2.3.3 Generation of α-Silyl Carbanions by Substitution of a Heteroatom |
| Record Nr. | UNINA-9910830654803321 |
| Weinheim, : Wiley-VCH, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Modern carbonyl olefination [[electronic resource] /] / Takeshi Takeda (ed.)
| Modern carbonyl olefination [[electronic resource] /] / Takeshi Takeda (ed.) |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2004 |
| Descrizione fisica | 1 online resource (367 p.) |
| Disciplina |
547.036
547.05621046 |
| Altri autori (Persone) | TakedaTakeshi |
| Soggetto topico | Carbonyl compounds |
| ISBN |
1-280-52047-7
9786610520473 3-527-60538-X 3-527-60188-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Modern Carbonyl Olefination; Contents; Preface; List of Authors; 1 The Wittig Reaction; 1.1 Introduction; 1.2 The ""Classic"" Wittig Reaction; 1.2.1 Mechanism and Stereoselectivity; 1.2.2 Nature of the Ylide and Carbonyl Compound; 1.2.3 Reagents and Reaction Conditions; 1.3 Horner-Wadsworth-Emmons Reaction; 1.3.1 Mechanism and Stereochemistry; 1.3.2 Reagents and Reaction Conditions; 1.4 Horner-Wittig (HW) Reaction; 1.4.1 Mechanism and Stereochemistry; 1.4.2 Reagents and Reaction Conditions; 1.5 Conclusion; References; 2 The Peterson and Related Reactions; 2.1 Introduction
2.2 Stereochemistry and the Reaction Mechanism of the Peterson Reaction2.2.1 Stereochemistry and the Reaction Mechanism of the Peterson Reaction of β-Hydroxyalkylsilanes; 2.2.1.1 Stepwise Mechanism; 2.2.1.2 Reaction Mechanism via a 1,2-Oxasiletanide; 2.2.2 Reaction Mechanism of the Addition Step of an α-Silyl Carbanion to a Carbonyl Compound; 2.2.2.1 Approach Control of the Transition State; 2.2.2.2 Concerted Mechanism; 2.2.2.3 Chelation Control Mechanism; 2.2.3 Theoretical Calculations on the Reaction Mechanism; 2.2.4 Convergently Stereoselective Peterson Reactions 2.3 Generation of α-Silyl Carbanions and their Peterson Reactions2.3.1 Generation of α-Silyl Carbanions from α-Silylalkyl Halides; 2.3.1.1 Generation of α-Silyl Grignard Reagents from α-Silylalkyl Halides; 2.3.1.2 Generation of α-Silyl Alkyllithium Reagents from α-Silylalkyl Halides; 2.3.1.3 Synthesis of Terminal Alkenes by the Use of α-Silyl Carbanions Generated from α-Silylalkyl Halides; 2.3.1.4 Reactions of α-Silyl Carbanions Generated from α-Silylalkyl Halides with Esters, Carboxylic Acids, and Acetals; 2.3.1.5 The Reformatsky-Peterson Reactions of α-Silylalkyl Halides 2.3.2 Generation of α-Silyl Carbanions by Deprotonation of Alkylsilanes2.3.2.1 Generation of α-Silyl Carbanions Bearing an Aryl or a Heteroaryl Group; 2.3.2.2 Generation of α-Silyl Carbanions Bearing an Alkoxy Group; 2.3.2.3 Generation of α-Silyl Carbanions Bearing a Nitrogen-Containing Group; 2.3.2.4 Generation of α-Silyl Carbanions Bearing a Sulfur-Containing Group; 2.3.2.5 Generation of α-Silyl Carbanions Bearing a Phosphorus-Containing Group; 2.3.2.6 Generation of α-Silyl Carbanions Bearing a Halogen Group; 2.3.2.7 Generation of α-Silyl Carbanions from α-Silyl Ketones 2.3.2.8 Generation of α-Silyl Carbanions Bearing an Ester Group2.3.2.9 Generation of α-Silyl Carbanions Bearing a Lactone Group; 2.3.2.10 Generation of α-Silyl Carbanions Bearing Thiocarboxylate or Dithiocarboxylate Ester Groups; 2.3.2.11 Generation of α-Silyl Carbanions Bearing an Imino Group; 2.3.2.12 Generation of α-Silyl Carbanions Bearing an Amide Group; 2.3.2.13 Generation of α-Silyl Carbanions Bearing a Cyano Group; 2.3.2.14 Generation of α-Silyl Carbanions from Allylsilanes; 2.3.2.15 Generation of α-Silyl Carbanions from Propargylsilanes 2.3.3 Generation of α-Silyl Carbanions by Substitution of a Heteroatom |
| Record Nr. | UNINA-9910841032103321 |
| Weinheim, : Wiley-VCH, c2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||