Autore	Survila Arvydas
Pubbl/distr/stampa	Weinheim, Germany : , : Wiley-VCH, , 2015
Descrizione fisica	1 online resource (306 p.)
Disciplina	541.37
Soggetto topico	Electrochemistry Metal complexes Chemical equilibrium
ISBN	3-527-69125-1 3-527-69124-3
Formato	Materiale a stampa
Livello bibliografico	Monografia
Lingua di pubblicazione	eng
Nota di contenuto	Cover; Title Page; Copyright; Contents; Preface; Symbols and Abbreviations; Chapter 1 Introduction; 1.1 Equilibrium Properties of Complex Systems; 1.1.1 General Definitions; 1.1.2 Equilibrium in the Solutions of Complex Compounds; 1.1.3 Distribution of Complexes and Ligands in the Solution; References; Chapter 2 Equilibrium Electrode Potentials; 2.1 Electrodes of the First Kind; 2.2 Equilibria Involving Ions of the Intermediate Oxidation State; 2.3 Electrodes of the Second Kind; 2.4 Open-Circuit Potentials: Examples of Experimental Investigations; 2.4.1 System Cu/Cu(I),CN- 2.4.2 System Cu/Cu(II), β-AlanineReferences; Chapter 3 Mass Transport; 3.1 Two Models of Linear Mass Transport; 3.2 Other Cases of Diffusional Mass Transport; 3.3 Mass Transport of Chemically Interacting Particles; 3.4 Concentration Profiles; 3.4.1 Concentration Profiles in Ideally Labile Systems; 4.2 Potential Transients; 3.4.2 Concentration Profiles in Systems of Limited Lability; References; Chapter 4 Peculiarities of Electrochemical Processes Involving Labile Complexes; 4.1 Steady-State Voltammograms; 4.3 Current Transients; References Chapter 5 Quantitative Modeling of Quasi-Reversible Electrochemical Processes Involving Labile Complexes of Metals5.1 Kinetic Equations; 5.2 Employment of Voltammetric Data; 5.2.1 Tafel Plots Normalized with Respect to the Surface Concentration of EAC; 5.2.2 Analysis of LPS Current Maxima; 5.3 Techniques Based on the Control of the Intensity of Forced Convection; 5.3.1 Isosurface Concentration Voltammetry; 5.3.2 Determination of the Exchange Current Density from Polarization Resistance; 5.3.3 Electrochemical Impedance Spectroscopy (EIS) under Forced Convection Conditions; References Chapter 6 Determination of Mechanism of Electrochemical Processes Involving Metal Complexes6.1 Determination of the Mechanism by Reaction Orders; 6.2 Method of Isopotential Solutions; References; Chapter 7 Adsorption; 7.1 Thermodynamic Aspects; 7.2 Model Aspects; References; Chapter 8 Electrochemical Processes in Real Systems; 8.1 Experimental Details; 8.2 Cyanide Systems; 8.2.1 System Cu\|Cu(I), CN-; 8.2.2 System Ag\|Ag(I), CN-; 8.2.3 System Au\|Au(I), CN-; 8.3 Ecological Systems Containing Hydroxy Acids; 8.3.1 Electroreduction of Cu(II) Complexes; 8.3.2 Electroreduction of Sn(II) Complexes 8.3.3 Electroreduction of Zn(II) ComplexesAppendix; References; Chapter 9 Electrochemical Deposition of Alloys; 9.1 Mass Transport during the Codeposition of Metals; 9.2 Codeposition of Cobalt and Tin; 9.3 Deposition of Brass Coatings; 9.4 Deposition of Bronze Coatings; 9.4.1 Surface Activity of Polyethers on Copper and Tin Substrates; 9.4.2 Effect of Halides. Formation of Surface Complexes; 9.4.3 Effect of Length of the Hydrocarbon Chain; 9.4.4 Codeposition of Copper and Tin; 9.4.5 Related Phenomena: Current Oscillations; 9.5 Codeposition of Cobalt and Molybdenum; References Chapter 10 Spontaneous Formation of Photosensitive Cuprous Oxide Layers
Record Nr.	UNINA-9910140494103321