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Fine chemicals through heterogenous catalysis [[electronic resource] /] / Roger Arthur Sheldon, Hermann van Bekkum
| Fine chemicals through heterogenous catalysis [[electronic resource] /] / Roger Arthur Sheldon, Hermann van Bekkum |
| Autore | Sheldon Roger A |
| Pubbl/distr/stampa | Weinheim ; ; Toronto, : Wiley-VCH, 2002, c2001 |
| Descrizione fisica | 1 online resource (639 p.) |
| Disciplina |
541.395
660.2995 |
| Altri autori (Persone) | BekkumHerman van |
| Soggetto topico |
Heterogeneous catalysis
Organic compounds - Synthesis |
| ISBN |
1-281-76401-9
9786611764012 3-527-61296-3 3-527-61297-1 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fine Chemicals through Heterogeneous Catalysis; Contents; 1 Introduction; 1.1 What are Fine Chemicals?; 1.2 The Environmental Factor; 1.3 The Development of Organic Synthesis and Catalysis; 1.4 Why Heterogeneous Catalysis?; 1.5 Types of Catalysts and Reactions; 1.5.1 Solid-Acid Catalysis; 1.5.2 Solid-Base Catalysis; 1.5.3 Catalytic Hydrogenation; 1.5.4 Catalytic Oxidations; 1.5.5 Catalytic C-C Bond Formation; 1.6 Alternative Approaches; 1.7 Heterogeneous Catalysis in Multi-step Synthesis: Vanillin; 2 Basic Principles/General; 2.1 General Considerations and Types of Catalyst
2.1.1 Introduction2.1.2 Catalytically Active Surface Area; 2.1.3 Reactors Employed in the Fine-chemical Industry; 2.1.4 Slurry-phase Catalysts; 2.1.5 Fixed-bed Catalysts; 2.1.6 Integration of the Catalyst and the Reactor; 2.1.7 Solid Catalysts Employed in the Fine-chemical Industry; 2.1.8 Metal Catalysts; 2.1.9 Solid-Acid Catalysts; 2.2 Preparation of Solid Catalysts; 2.2.1 Demands on Solid Catalysts; 2.2.2 Preparation Procedures [2]; 2.2.3 Conclusions; 2.3 Characterization of Solid Catalysts; 2.3.1 Total Surface Area and Pore-size Distribution 2.3.2 Catalytically Active Surface Area Per Unit Weight of Catalyst2.3.3 Extent of Reduction of Metal Catalysts; 2.3.4 Solid-acid Catalysts; 2.3.5 Dispersion of Active Component(s) Over the Support; 2.3.6 Conclusions; 2.4 Reactors; 2.4.1 Introduction; 2.4.2 Three-phase Catalytic Reactions (G-L-S); 2.4.3 Characteristics of Three-phase Catalytic Reactors for Fine-chemicals Production; 2.4.3.1 Reactors with Moving Catalyst; 2.4.3.2 Reactors with a Fixed Bed of Catalyst; 2.4.3.3 Comparison-Reactor Choice; 2.4.4 Design Aspects of Stirred Tank Batch Reactor 2.4.5 Scale-up of Stirred-Tank Batch Reactors-Runaway Reactions3 Solid-acid Catalysts-General; 3.1 Acidic Clays; 3.1.1 Introduction; 3.1.2 Structure; 3.1.3 Main Properties and Catalytic Applications; 3.1.4 Pillared Interlayer Clays (PILC); 3.1.5 Conclusions; 3.2 Zeolites as Catalysts; 3.2.1 Introduction; 3.2.2 Acid Zeolites; 3.2.2.1 Framework Composition; 3.2.2.2 Extra-framework Composition; 3.2.3 Basicity in Zeolites; 3.2.3.1 Basic Zeolites-Framework Composition; 3.2.3.2 Basic Zeolites-Extra-framework Composition; 3.2.4 Redox Molecular Sieves; 3.2.4.1 Oxidation Sites in Framework Positions 3.2.4.2 Oxidation Sites in Extra-framework Positions3.2.5 Conclusions; 3.3 Sulfonated Polysiloxanes; 3.3.1 Motivation and Expected Advantages; 3.3.2 Synthetic Approaches; 3.3.2.1 Grafting of Silanes to Silica; 3.3.2.2 Copolycondensation and Sol-Gel Processing; 3.3.2.3 Sulfonation of Arylsiloxanes; 3.3.2.4 Oxidation of Sulfur-functionalized Siloxanes; 3.3.3 Characterization of the Polysiloxanes; 3.3.3.1 General; 3.3.3.2 Analytical Determination of Capacity; 3.3.3.3 NMR Spectroscopy; 3.3.3.4 Thermal Stability; 3.3.4 Applications and Reactions; 3.3.5 Summary; 3.4 Silica-occluded Heteropolyacids 3.4.1 Introduction |
| Record Nr. | UNINA-9910147219703321 |
Sheldon Roger A
|
||
| Weinheim ; ; Toronto, : Wiley-VCH, 2002, c2001 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Fine chemicals through heterogenous catalysis [[electronic resource] /] / Roger Arthur Sheldon, Hermann van Bekkum
| Fine chemicals through heterogenous catalysis [[electronic resource] /] / Roger Arthur Sheldon, Hermann van Bekkum |
| Autore | Sheldon Roger A |
| Pubbl/distr/stampa | Weinheim ; ; Toronto, : Wiley-VCH, 2002, c2001 |
| Descrizione fisica | 1 online resource (639 p.) |
| Disciplina |
541.395
660.2995 |
| Altri autori (Persone) | BekkumHerman van |
| Soggetto topico |
Heterogeneous catalysis
Organic compounds - Synthesis |
| ISBN |
1-281-76401-9
9786611764012 3-527-61296-3 3-527-61297-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fine Chemicals through Heterogeneous Catalysis; Contents; 1 Introduction; 1.1 What are Fine Chemicals?; 1.2 The Environmental Factor; 1.3 The Development of Organic Synthesis and Catalysis; 1.4 Why Heterogeneous Catalysis?; 1.5 Types of Catalysts and Reactions; 1.5.1 Solid-Acid Catalysis; 1.5.2 Solid-Base Catalysis; 1.5.3 Catalytic Hydrogenation; 1.5.4 Catalytic Oxidations; 1.5.5 Catalytic C-C Bond Formation; 1.6 Alternative Approaches; 1.7 Heterogeneous Catalysis in Multi-step Synthesis: Vanillin; 2 Basic Principles/General; 2.1 General Considerations and Types of Catalyst
2.1.1 Introduction2.1.2 Catalytically Active Surface Area; 2.1.3 Reactors Employed in the Fine-chemical Industry; 2.1.4 Slurry-phase Catalysts; 2.1.5 Fixed-bed Catalysts; 2.1.6 Integration of the Catalyst and the Reactor; 2.1.7 Solid Catalysts Employed in the Fine-chemical Industry; 2.1.8 Metal Catalysts; 2.1.9 Solid-Acid Catalysts; 2.2 Preparation of Solid Catalysts; 2.2.1 Demands on Solid Catalysts; 2.2.2 Preparation Procedures [2]; 2.2.3 Conclusions; 2.3 Characterization of Solid Catalysts; 2.3.1 Total Surface Area and Pore-size Distribution 2.3.2 Catalytically Active Surface Area Per Unit Weight of Catalyst2.3.3 Extent of Reduction of Metal Catalysts; 2.3.4 Solid-acid Catalysts; 2.3.5 Dispersion of Active Component(s) Over the Support; 2.3.6 Conclusions; 2.4 Reactors; 2.4.1 Introduction; 2.4.2 Three-phase Catalytic Reactions (G-L-S); 2.4.3 Characteristics of Three-phase Catalytic Reactors for Fine-chemicals Production; 2.4.3.1 Reactors with Moving Catalyst; 2.4.3.2 Reactors with a Fixed Bed of Catalyst; 2.4.3.3 Comparison-Reactor Choice; 2.4.4 Design Aspects of Stirred Tank Batch Reactor 2.4.5 Scale-up of Stirred-Tank Batch Reactors-Runaway Reactions3 Solid-acid Catalysts-General; 3.1 Acidic Clays; 3.1.1 Introduction; 3.1.2 Structure; 3.1.3 Main Properties and Catalytic Applications; 3.1.4 Pillared Interlayer Clays (PILC); 3.1.5 Conclusions; 3.2 Zeolites as Catalysts; 3.2.1 Introduction; 3.2.2 Acid Zeolites; 3.2.2.1 Framework Composition; 3.2.2.2 Extra-framework Composition; 3.2.3 Basicity in Zeolites; 3.2.3.1 Basic Zeolites-Framework Composition; 3.2.3.2 Basic Zeolites-Extra-framework Composition; 3.2.4 Redox Molecular Sieves; 3.2.4.1 Oxidation Sites in Framework Positions 3.2.4.2 Oxidation Sites in Extra-framework Positions3.2.5 Conclusions; 3.3 Sulfonated Polysiloxanes; 3.3.1 Motivation and Expected Advantages; 3.3.2 Synthetic Approaches; 3.3.2.1 Grafting of Silanes to Silica; 3.3.2.2 Copolycondensation and Sol-Gel Processing; 3.3.2.3 Sulfonation of Arylsiloxanes; 3.3.2.4 Oxidation of Sulfur-functionalized Siloxanes; 3.3.3 Characterization of the Polysiloxanes; 3.3.3.1 General; 3.3.3.2 Analytical Determination of Capacity; 3.3.3.3 NMR Spectroscopy; 3.3.3.4 Thermal Stability; 3.3.4 Applications and Reactions; 3.3.5 Summary; 3.4 Silica-occluded Heteropolyacids 3.4.1 Introduction |
| Record Nr. | UNINA-9910831177403321 |
|
Sheldon Roger A
|
||
| Weinheim ; ; Toronto, : Wiley-VCH, 2002, c2001 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Fine chemicals through heterogenous catalysis / / Roger Arthur Sheldon, Hermann van Bekkum
| Fine chemicals through heterogenous catalysis / / Roger Arthur Sheldon, Hermann van Bekkum |
| Autore | Sheldon Roger A |
| Pubbl/distr/stampa | Weinheim ; ; Toronto, : Wiley-VCH, 2002, c2001 |
| Descrizione fisica | 1 online resource (639 p.) |
| Disciplina |
541.395
660.2995 |
| Altri autori (Persone) | BekkumHerman van |
| Soggetto topico |
Heterogeneous catalysis
Organic compounds - Synthesis |
| ISBN |
1-281-76401-9
9786611764012 3-527-61296-3 3-527-61297-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Fine Chemicals through Heterogeneous Catalysis; Contents; 1 Introduction; 1.1 What are Fine Chemicals?; 1.2 The Environmental Factor; 1.3 The Development of Organic Synthesis and Catalysis; 1.4 Why Heterogeneous Catalysis?; 1.5 Types of Catalysts and Reactions; 1.5.1 Solid-Acid Catalysis; 1.5.2 Solid-Base Catalysis; 1.5.3 Catalytic Hydrogenation; 1.5.4 Catalytic Oxidations; 1.5.5 Catalytic C-C Bond Formation; 1.6 Alternative Approaches; 1.7 Heterogeneous Catalysis in Multi-step Synthesis: Vanillin; 2 Basic Principles/General; 2.1 General Considerations and Types of Catalyst
2.1.1 Introduction2.1.2 Catalytically Active Surface Area; 2.1.3 Reactors Employed in the Fine-chemical Industry; 2.1.4 Slurry-phase Catalysts; 2.1.5 Fixed-bed Catalysts; 2.1.6 Integration of the Catalyst and the Reactor; 2.1.7 Solid Catalysts Employed in the Fine-chemical Industry; 2.1.8 Metal Catalysts; 2.1.9 Solid-Acid Catalysts; 2.2 Preparation of Solid Catalysts; 2.2.1 Demands on Solid Catalysts; 2.2.2 Preparation Procedures [2]; 2.2.3 Conclusions; 2.3 Characterization of Solid Catalysts; 2.3.1 Total Surface Area and Pore-size Distribution 2.3.2 Catalytically Active Surface Area Per Unit Weight of Catalyst2.3.3 Extent of Reduction of Metal Catalysts; 2.3.4 Solid-acid Catalysts; 2.3.5 Dispersion of Active Component(s) Over the Support; 2.3.6 Conclusions; 2.4 Reactors; 2.4.1 Introduction; 2.4.2 Three-phase Catalytic Reactions (G-L-S); 2.4.3 Characteristics of Three-phase Catalytic Reactors for Fine-chemicals Production; 2.4.3.1 Reactors with Moving Catalyst; 2.4.3.2 Reactors with a Fixed Bed of Catalyst; 2.4.3.3 Comparison-Reactor Choice; 2.4.4 Design Aspects of Stirred Tank Batch Reactor 2.4.5 Scale-up of Stirred-Tank Batch Reactors-Runaway Reactions3 Solid-acid Catalysts-General; 3.1 Acidic Clays; 3.1.1 Introduction; 3.1.2 Structure; 3.1.3 Main Properties and Catalytic Applications; 3.1.4 Pillared Interlayer Clays (PILC); 3.1.5 Conclusions; 3.2 Zeolites as Catalysts; 3.2.1 Introduction; 3.2.2 Acid Zeolites; 3.2.2.1 Framework Composition; 3.2.2.2 Extra-framework Composition; 3.2.3 Basicity in Zeolites; 3.2.3.1 Basic Zeolites-Framework Composition; 3.2.3.2 Basic Zeolites-Extra-framework Composition; 3.2.4 Redox Molecular Sieves; 3.2.4.1 Oxidation Sites in Framework Positions 3.2.4.2 Oxidation Sites in Extra-framework Positions3.2.5 Conclusions; 3.3 Sulfonated Polysiloxanes; 3.3.1 Motivation and Expected Advantages; 3.3.2 Synthetic Approaches; 3.3.2.1 Grafting of Silanes to Silica; 3.3.2.2 Copolycondensation and Sol-Gel Processing; 3.3.2.3 Sulfonation of Arylsiloxanes; 3.3.2.4 Oxidation of Sulfur-functionalized Siloxanes; 3.3.3 Characterization of the Polysiloxanes; 3.3.3.1 General; 3.3.3.2 Analytical Determination of Capacity; 3.3.3.3 NMR Spectroscopy; 3.3.3.4 Thermal Stability; 3.3.4 Applications and Reactions; 3.3.5 Summary; 3.4 Silica-occluded Heteropolyacids 3.4.1 Introduction |
| Record Nr. | UNINA-9910877819003321 |
|
Sheldon Roger A
|
||
| Weinheim ; ; Toronto, : Wiley-VCH, 2002, c2001 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Green chemistry and catalysis [[electronic resource] /] / Roger Arthur Sheldon, Isabel Arends, and Ulf Hanefeld
| Green chemistry and catalysis [[electronic resource] /] / Roger Arthur Sheldon, Isabel Arends, and Ulf Hanefeld |
| Autore | Sheldon Roger A |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, 2007 |
| Descrizione fisica | 1 online resource (451 p.) |
| Disciplina | 660.2995 |
| Altri autori (Persone) |
ArendsIsabel
HanefeldUlf |
| Soggetto topico |
Catalysis
Industrial applications Sustainable development |
| ISBN |
1-280-92171-4
9786610921713 3-527-61100-2 3-527-61101-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Green Chemistry and Catalysis; Contents; Preface; Foreword; 1 Introduction: Green Chemistry and Catalysis; 1.1 Introduction; 1.2. E Factors and Atom Efficiency; 1.3 The Role of Catalysis; 1.4 The Development of Organic Synthesis; 1.5 Catalysis by Solid Acids and Bases; 1.6 Catalytic Reduction; 1.7 Catalytic Oxidation; 1.8 Catalytic C-C Bond Formation; 1.9 The Question of Solvents: Alternative Reaction Media; 1.10 Biocatalysis; 1.11 Renewable Raw Materials and White Biotechnology; 1.12 Enantioselective Catalysis; 1.13 Risky Reagents; 1.14 Process Integration and Catalytic Cascades; References
2 Solid Acids and Bases as Catalysts2.1 Introduction; 2.2 Solid Acid Catalysis; 2.2.1 Acidic Clays; 2.2.2 Zeolites and Zeotypes: Synthesis and Structure; 2.2.3 Zeolite-catalyzed Reactions in Organic Synthesis; 2.2.3.1 Electrophilic Aromatic Substitutions; 2.2.3.2 Additions and Eliminations; 2.2.3.3 Rearrangements and Isomerizations; 2.2.3.4 Cyclizations; 2.2.4 Solid Acids Containing Surface SO(3)H Functionality; 2.2.5 Heteropoly Acids; 2.3 Solid Base Catalysis; 2.3.1 Anionic Clays: Hydrotalcites; 2.3.2 Basic Zeolites; 2.3.3 Organic Bases Attached to Mesoporous Silicas; 2.4 Other Approaches References3 Catalytic Reductions; 3.1 Introduction; 3.2 Heterogeneous Reduction Catalysts; 3.2.1 General Properties; 3.2.2 Transfer Hydrogenation Using Heterogeneous Catalysts; 3.2.3 Chiral Heterogeneous Reduction Catalysts; 3.3 Homogeneous Reduction Catalysts; 3.3.1 Wilkinson Catalyst; 3.3.2 Chiral Homogeneous Hydrogenation Catalysts and Reduction of the C= C Double Bond; 3.3.3 Chiral Homogeneous Catalysts and Ketone Hydrogenation; 3.3.4 Imine Hydrogenation; 3.3.5 Transfer Hydrogenation using Homogeneous Catalysts; 3.4 Biocatalytic Reductions; 3.4.1 Introduction 3.4.2 Enzyme Technology in Biocatalytic Reduction3.4.3 Whole Cell Technology for Biocatalytic Reduction; 3.5 Conclusions; References; 4 Catalytic Oxidations; 4.1 Introduction; 4.2 Mechanisms of Metal-catalyzed Oxidations: General Considerations; 4.2.1 Homolytic Mechanisms; 4.2.1.1 Direct Homolytic Oxidation of Organic Substrates; 4.2.2 Heterolytic Mechanisms; 4.2.2.1 Catalytic Oxygen Transfer; 4.2.3 Ligand Design in Oxidation Catalysis; 4.2.4 Enzyme Catalyzed Oxidations; 4.3 Alkenes; 4.3.1 Epoxidation; 4.3.1.1 Tungsten Catalysts; 4.3.1.2 Rhenium Catalysts; 4.3.1.3 Ruthenium Catalysts 4.3.1.4 Manganese Catalysts4.3.1.5 Iron Catalysts; 4.3.1.6 Selenium and Organocatalysts; 4.3.1.7 Hydrotalcite and Alumina Systems; 4.3.1.8 Biocatalytic Systems; 4.3.2 Vicinal Dihydroxylation; 4.3.3 Oxidative Cleavage of Olefins; 4.3.4 Oxidative Ketonization; 4.3.5 Allylic Oxidations; 4.4 Alkanes and Alkylaromatics; 4.4.1 Oxidation of Alkanes; 4.4.2 Oxidation of Aromatic Side Chains; 4.4.3 Aromatic Ring Oxidation; 4.5 Oxygen-containing Compounds; 4.5.1 Oxidation of Alcohols; 4.5.1.1 Ruthenium Catalysts; 4.5.1.2 Palladium-catalyzed Oxidations with O(2); 4.5.1.3 Gold Catalysts 4.5.1.4 Copper Catalysts |
| Record Nr. | UNINA-9910144290603321 |
|
Sheldon Roger A
|
||
| Weinheim, : Wiley-VCH, 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Green chemistry and catalysis [[electronic resource] /] / Roger Arthur Sheldon, Isabel Arends, and Ulf Hanefeld
| Green chemistry and catalysis [[electronic resource] /] / Roger Arthur Sheldon, Isabel Arends, and Ulf Hanefeld |
| Autore | Sheldon Roger A |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, 2007 |
| Descrizione fisica | 1 online resource (451 p.) |
| Disciplina | 660.2995 |
| Altri autori (Persone) |
ArendsIsabel
HanefeldUlf |
| Soggetto topico |
Catalysis
Industrial applications Sustainable development |
| ISBN |
1-280-92171-4
9786610921713 3-527-61100-2 3-527-61101-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Green Chemistry and Catalysis; Contents; Preface; Foreword; 1 Introduction: Green Chemistry and Catalysis; 1.1 Introduction; 1.2. E Factors and Atom Efficiency; 1.3 The Role of Catalysis; 1.4 The Development of Organic Synthesis; 1.5 Catalysis by Solid Acids and Bases; 1.6 Catalytic Reduction; 1.7 Catalytic Oxidation; 1.8 Catalytic C-C Bond Formation; 1.9 The Question of Solvents: Alternative Reaction Media; 1.10 Biocatalysis; 1.11 Renewable Raw Materials and White Biotechnology; 1.12 Enantioselective Catalysis; 1.13 Risky Reagents; 1.14 Process Integration and Catalytic Cascades; References
2 Solid Acids and Bases as Catalysts2.1 Introduction; 2.2 Solid Acid Catalysis; 2.2.1 Acidic Clays; 2.2.2 Zeolites and Zeotypes: Synthesis and Structure; 2.2.3 Zeolite-catalyzed Reactions in Organic Synthesis; 2.2.3.1 Electrophilic Aromatic Substitutions; 2.2.3.2 Additions and Eliminations; 2.2.3.3 Rearrangements and Isomerizations; 2.2.3.4 Cyclizations; 2.2.4 Solid Acids Containing Surface SO(3)H Functionality; 2.2.5 Heteropoly Acids; 2.3 Solid Base Catalysis; 2.3.1 Anionic Clays: Hydrotalcites; 2.3.2 Basic Zeolites; 2.3.3 Organic Bases Attached to Mesoporous Silicas; 2.4 Other Approaches References3 Catalytic Reductions; 3.1 Introduction; 3.2 Heterogeneous Reduction Catalysts; 3.2.1 General Properties; 3.2.2 Transfer Hydrogenation Using Heterogeneous Catalysts; 3.2.3 Chiral Heterogeneous Reduction Catalysts; 3.3 Homogeneous Reduction Catalysts; 3.3.1 Wilkinson Catalyst; 3.3.2 Chiral Homogeneous Hydrogenation Catalysts and Reduction of the C= C Double Bond; 3.3.3 Chiral Homogeneous Catalysts and Ketone Hydrogenation; 3.3.4 Imine Hydrogenation; 3.3.5 Transfer Hydrogenation using Homogeneous Catalysts; 3.4 Biocatalytic Reductions; 3.4.1 Introduction 3.4.2 Enzyme Technology in Biocatalytic Reduction3.4.3 Whole Cell Technology for Biocatalytic Reduction; 3.5 Conclusions; References; 4 Catalytic Oxidations; 4.1 Introduction; 4.2 Mechanisms of Metal-catalyzed Oxidations: General Considerations; 4.2.1 Homolytic Mechanisms; 4.2.1.1 Direct Homolytic Oxidation of Organic Substrates; 4.2.2 Heterolytic Mechanisms; 4.2.2.1 Catalytic Oxygen Transfer; 4.2.3 Ligand Design in Oxidation Catalysis; 4.2.4 Enzyme Catalyzed Oxidations; 4.3 Alkenes; 4.3.1 Epoxidation; 4.3.1.1 Tungsten Catalysts; 4.3.1.2 Rhenium Catalysts; 4.3.1.3 Ruthenium Catalysts 4.3.1.4 Manganese Catalysts4.3.1.5 Iron Catalysts; 4.3.1.6 Selenium and Organocatalysts; 4.3.1.7 Hydrotalcite and Alumina Systems; 4.3.1.8 Biocatalytic Systems; 4.3.2 Vicinal Dihydroxylation; 4.3.3 Oxidative Cleavage of Olefins; 4.3.4 Oxidative Ketonization; 4.3.5 Allylic Oxidations; 4.4 Alkanes and Alkylaromatics; 4.4.1 Oxidation of Alkanes; 4.4.2 Oxidation of Aromatic Side Chains; 4.4.3 Aromatic Ring Oxidation; 4.5 Oxygen-containing Compounds; 4.5.1 Oxidation of Alcohols; 4.5.1.1 Ruthenium Catalysts; 4.5.1.2 Palladium-catalyzed Oxidations with O(2); 4.5.1.3 Gold Catalysts 4.5.1.4 Copper Catalysts |
| Record Nr. | UNINA-9910830749703321 |
|
Sheldon Roger A
|
||
| Weinheim, : Wiley-VCH, 2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Green chemistry and catalysis / / Roger Arthur Sheldon, Isabel Arends, and Ulf Hanefeld
| Green chemistry and catalysis / / Roger Arthur Sheldon, Isabel Arends, and Ulf Hanefeld |
| Autore | Sheldon Roger A |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2007 |
| Descrizione fisica | 1 online resource (451 p.) |
| Disciplina | 660.2995 |
| Altri autori (Persone) |
ArendsIsabel
HanefeldUlf |
| Soggetto topico |
Catalysis
Environmental chemistry - Industrial applications Sustainable development |
| ISBN |
1-280-92171-4
9786610921713 3-527-61100-2 3-527-61101-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Green Chemistry and Catalysis; Contents; Preface; Foreword; 1 Introduction: Green Chemistry and Catalysis; 1.1 Introduction; 1.2. E Factors and Atom Efficiency; 1.3 The Role of Catalysis; 1.4 The Development of Organic Synthesis; 1.5 Catalysis by Solid Acids and Bases; 1.6 Catalytic Reduction; 1.7 Catalytic Oxidation; 1.8 Catalytic C-C Bond Formation; 1.9 The Question of Solvents: Alternative Reaction Media; 1.10 Biocatalysis; 1.11 Renewable Raw Materials and White Biotechnology; 1.12 Enantioselective Catalysis; 1.13 Risky Reagents; 1.14 Process Integration and Catalytic Cascades; References
2 Solid Acids and Bases as Catalysts2.1 Introduction; 2.2 Solid Acid Catalysis; 2.2.1 Acidic Clays; 2.2.2 Zeolites and Zeotypes: Synthesis and Structure; 2.2.3 Zeolite-catalyzed Reactions in Organic Synthesis; 2.2.3.1 Electrophilic Aromatic Substitutions; 2.2.3.2 Additions and Eliminations; 2.2.3.3 Rearrangements and Isomerizations; 2.2.3.4 Cyclizations; 2.2.4 Solid Acids Containing Surface SO(3)H Functionality; 2.2.5 Heteropoly Acids; 2.3 Solid Base Catalysis; 2.3.1 Anionic Clays: Hydrotalcites; 2.3.2 Basic Zeolites; 2.3.3 Organic Bases Attached to Mesoporous Silicas; 2.4 Other Approaches References3 Catalytic Reductions; 3.1 Introduction; 3.2 Heterogeneous Reduction Catalysts; 3.2.1 General Properties; 3.2.2 Transfer Hydrogenation Using Heterogeneous Catalysts; 3.2.3 Chiral Heterogeneous Reduction Catalysts; 3.3 Homogeneous Reduction Catalysts; 3.3.1 Wilkinson Catalyst; 3.3.2 Chiral Homogeneous Hydrogenation Catalysts and Reduction of the C= C Double Bond; 3.3.3 Chiral Homogeneous Catalysts and Ketone Hydrogenation; 3.3.4 Imine Hydrogenation; 3.3.5 Transfer Hydrogenation using Homogeneous Catalysts; 3.4 Biocatalytic Reductions; 3.4.1 Introduction 3.4.2 Enzyme Technology in Biocatalytic Reduction3.4.3 Whole Cell Technology for Biocatalytic Reduction; 3.5 Conclusions; References; 4 Catalytic Oxidations; 4.1 Introduction; 4.2 Mechanisms of Metal-catalyzed Oxidations: General Considerations; 4.2.1 Homolytic Mechanisms; 4.2.1.1 Direct Homolytic Oxidation of Organic Substrates; 4.2.2 Heterolytic Mechanisms; 4.2.2.1 Catalytic Oxygen Transfer; 4.2.3 Ligand Design in Oxidation Catalysis; 4.2.4 Enzyme Catalyzed Oxidations; 4.3 Alkenes; 4.3.1 Epoxidation; 4.3.1.1 Tungsten Catalysts; 4.3.1.2 Rhenium Catalysts; 4.3.1.3 Ruthenium Catalysts 4.3.1.4 Manganese Catalysts4.3.1.5 Iron Catalysts; 4.3.1.6 Selenium and Organocatalysts; 4.3.1.7 Hydrotalcite and Alumina Systems; 4.3.1.8 Biocatalytic Systems; 4.3.2 Vicinal Dihydroxylation; 4.3.3 Oxidative Cleavage of Olefins; 4.3.4 Oxidative Ketonization; 4.3.5 Allylic Oxidations; 4.4 Alkanes and Alkylaromatics; 4.4.1 Oxidation of Alkanes; 4.4.2 Oxidation of Aromatic Side Chains; 4.4.3 Aromatic Ring Oxidation; 4.5 Oxygen-containing Compounds; 4.5.1 Oxidation of Alcohols; 4.5.1.1 Ruthenium Catalysts; 4.5.1.2 Palladium-catalyzed Oxidations with O(2); 4.5.1.3 Gold Catalysts 4.5.1.4 Copper Catalysts |
| Record Nr. | UNINA-9910877657103321 |
|
Sheldon Roger A
|
||
| Weinheim, : Wiley-VCH, c2007 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||