Integrated chemical processes [[electronic resource] ] : synthesis, operation, analysis, and control / / edited by Kai Sundmacher, Achim Kienle and Andreas Seidel-Morgenstern |
Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2005 |
Descrizione fisica | 1 online resource (568 p.) |
Disciplina | 660.284 |
Altri autori (Persone) |
KienleAchim
Seidel-MorgensternAndreas SundmacherKai |
Soggetto topico |
Chemical processes
Chemical reactions |
ISBN |
1-280-52061-2
9786610520619 3-527-60573-8 3-527-60555-X |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Integrated Chemical Processes; Contents; Preface; List of Contributors; Part I Integration of Heat Transfer and Chemical Reactions; 1 Enhancing Productivity and Thermal Efficiency of High-Temperature Endothermic Processes in Heat-Integrated Fixed-Bed Reactors; Abstract; 1.1 Introduction; 1.2 Heat-Integrated Processes for Endothermic Reactions; 1.2.1 Optimality Conditions; 1.2.1.1 Efficiency of Heat Recovery; 1.2.1.2 Temperature Control; 1.3 Multifunctional Reactor Concepts; 1.3.1 Regenerative Processes; 1.3.1.1 Simultaneous Mode; 1.3.1.2 Asymmetric Mode
1.3.1.3 Symmetric Mode with Side Stream Injection1.3.1.4 Counter-cocurrent Mode; 1.3.1.5 Overheating During Oxidative Coke Removal; 1.3.2 Recuperative Processes; 1.3.2.1 Processes for Large-Scale Applications; 1.3.2.2 Processes for Small-scale Applications; 1.4 Conclusions; Symbols and Abbreviations; References; 2 Conceptual Design of Internal Reforming in High-Temperature Fuel Cells; 2.1 Introduction; 2.2 Technical Background; 2.3 Modeling; 2.3.1 Model Derivation; 2.3.1.1 Anode Channel; 2.3.1.2 Mixing Rules; 2.3.1.3 Cathode Channel; 2.3.1.4 Reaction Kinetics; 2.3.1.5 Cell Power 2.3.2 Conversion Diagram2.4 Applications; 2.4.1 Comparison of Reforming Concepts; 2.4.2 Anode Cascade; 2.4.3 Anode Exhaust Gas Recycling; 2.5 Summary and Conclusions; Symbols; References; 3 Instabilities in High-Temperature Fuel Cells due to Combined Heat and Charge Transport; 3.1 Introduction; 3.2 Modeling; 3.2.1 Model Assumptions; 3.2.2 Model Equations; 3.2.3 Simplified Model; 3.3 Potentiostatic Operation; 3.3.1 Cell with Infinite Length; 3.3.2 Cell with Finite Length; 3.4 Galvanostatic Operation; 3.5 Conclusions; Symbols Appendix: Numerical Methods for the Bifurcation Analysis in Section 3.0References; Part II Integration of Separations and Chemical Reactions; 4 Thermodynamic and Kinetic Effects on the Feasible Products of Reactive Distillation: A-zeo-tropes and A-rheo-tropes; 4.1 Introduction; 4.2 Azeotropes; 4.2.1 Reactive Condenser and Reboiler; 4.2.2 Conditions for Singular Points; 4.2.2.1 Potential Singular Point Surface; 4.2.2.2 Reaction Kinetic Surface; 4.2.3 Examples; 4.2.3.1 Hypothetical Ternary Systems; 4.2.3.2 Real Ternary System: MTBE-Synthesis 4.2.3.3 Real Ternary System with Phase Splitting: Methanol Dehydration4.2.3.4 Real Quaternary System: Isopropyl Acetate Hydrolysis; 4.2.4 Application of Feasibility Diagram: Column Feasible Split; 4.2.5 Remarks on Azeotropes; 4.3 Arheotropes; 4.3.1 Definition and Conditions; 4.3.2 Illustrative Examples; 4.3.2.1 Example 1: Stagnant Sweep Gas; 4.3.2.2 Example 2: Flowing Sweep Gas; 4.3.2.3 Example 3: Flowing Sweep Gas with Pervaporation; 4.3.2.4 Example 4: Reactive Liquid Mixture; 4.3.3 Remarks on Arheotropes; 4.4 Kinetic Arheotropes in Reactive Membrane Separation; 4.4.1 Model Formulation 4.4.1.1 Reaction Kinetics and Mass Balances |
Record Nr. | UNINA-9910829926503321 |
Weinheim, : Wiley-VCH, c2005 | ||
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Lo trovi qui: Univ. Federico II | ||
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Integrated chemical processes : synthesis, operation, analysis, and control / / edited by Kai Sundmacher, Achim Kienle and Andreas Seidel-Morgenstern |
Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2005 |
Descrizione fisica | 1 online resource (568 p.) |
Disciplina | 660.284 |
Altri autori (Persone) |
KienleAchim
Seidel-MorgensternAndreas SundmacherKai |
Soggetto topico |
Chemical processes
Chemical reactions |
ISBN |
1-280-52061-2
9786610520619 3-527-60573-8 3-527-60555-X |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Integrated Chemical Processes; Contents; Preface; List of Contributors; Part I Integration of Heat Transfer and Chemical Reactions; 1 Enhancing Productivity and Thermal Efficiency of High-Temperature Endothermic Processes in Heat-Integrated Fixed-Bed Reactors; Abstract; 1.1 Introduction; 1.2 Heat-Integrated Processes for Endothermic Reactions; 1.2.1 Optimality Conditions; 1.2.1.1 Efficiency of Heat Recovery; 1.2.1.2 Temperature Control; 1.3 Multifunctional Reactor Concepts; 1.3.1 Regenerative Processes; 1.3.1.1 Simultaneous Mode; 1.3.1.2 Asymmetric Mode
1.3.1.3 Symmetric Mode with Side Stream Injection1.3.1.4 Counter-cocurrent Mode; 1.3.1.5 Overheating During Oxidative Coke Removal; 1.3.2 Recuperative Processes; 1.3.2.1 Processes for Large-Scale Applications; 1.3.2.2 Processes for Small-scale Applications; 1.4 Conclusions; Symbols and Abbreviations; References; 2 Conceptual Design of Internal Reforming in High-Temperature Fuel Cells; 2.1 Introduction; 2.2 Technical Background; 2.3 Modeling; 2.3.1 Model Derivation; 2.3.1.1 Anode Channel; 2.3.1.2 Mixing Rules; 2.3.1.3 Cathode Channel; 2.3.1.4 Reaction Kinetics; 2.3.1.5 Cell Power 2.3.2 Conversion Diagram2.4 Applications; 2.4.1 Comparison of Reforming Concepts; 2.4.2 Anode Cascade; 2.4.3 Anode Exhaust Gas Recycling; 2.5 Summary and Conclusions; Symbols; References; 3 Instabilities in High-Temperature Fuel Cells due to Combined Heat and Charge Transport; 3.1 Introduction; 3.2 Modeling; 3.2.1 Model Assumptions; 3.2.2 Model Equations; 3.2.3 Simplified Model; 3.3 Potentiostatic Operation; 3.3.1 Cell with Infinite Length; 3.3.2 Cell with Finite Length; 3.4 Galvanostatic Operation; 3.5 Conclusions; Symbols Appendix: Numerical Methods for the Bifurcation Analysis in Section 3.0References; Part II Integration of Separations and Chemical Reactions; 4 Thermodynamic and Kinetic Effects on the Feasible Products of Reactive Distillation: A-zeo-tropes and A-rheo-tropes; 4.1 Introduction; 4.2 Azeotropes; 4.2.1 Reactive Condenser and Reboiler; 4.2.2 Conditions for Singular Points; 4.2.2.1 Potential Singular Point Surface; 4.2.2.2 Reaction Kinetic Surface; 4.2.3 Examples; 4.2.3.1 Hypothetical Ternary Systems; 4.2.3.2 Real Ternary System: MTBE-Synthesis 4.2.3.3 Real Ternary System with Phase Splitting: Methanol Dehydration4.2.3.4 Real Quaternary System: Isopropyl Acetate Hydrolysis; 4.2.4 Application of Feasibility Diagram: Column Feasible Split; 4.2.5 Remarks on Azeotropes; 4.3 Arheotropes; 4.3.1 Definition and Conditions; 4.3.2 Illustrative Examples; 4.3.2.1 Example 1: Stagnant Sweep Gas; 4.3.2.2 Example 2: Flowing Sweep Gas; 4.3.2.3 Example 3: Flowing Sweep Gas with Pervaporation; 4.3.2.4 Example 4: Reactive Liquid Mixture; 4.3.3 Remarks on Arheotropes; 4.4 Kinetic Arheotropes in Reactive Membrane Separation; 4.4.1 Model Formulation 4.4.1.1 Reaction Kinetics and Mass Balances |
Record Nr. | UNINA-9910876643003321 |
Weinheim, : Wiley-VCH, c2005 | ||
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Lo trovi qui: Univ. Federico II | ||
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Membrane reactors [[electronic resource] ] : distributing reactants to improve selectivity and yield / / edited by Andreas Seidel-Morgenstern |
Pubbl/distr/stampa | Weinheim, : Wiley-VCH Verlag GmbH & Co., 2010 |
Descrizione fisica | 1 online resource (294 p.) |
Disciplina | 660.2832 |
Altri autori (Persone) | Seidel-MorgensternAndreas |
Soggetto topico |
Membrane reactors
Bioreactors |
Soggetto genere / forma | Electronic books. |
ISBN |
1-282-68781-6
9786612687815 3-527-62972-6 3-527-62973-4 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Membrane Reactors: Distributing Reactants to Improve Selectivity and Yield; Contents; Preface; List of Contributors; 1: Basic Problems of Chemical Reaction Engineering and Potential of Membrane Reactors; 1.1 Challenges in Chemical Reaction Engineering; 1.2 Concepts of Membrane Reactors; 1.3 Available Membranes; 1.4 Illustration of the Selectivity Problem; 1.5 Reaction Rate, Conversion, Selectivity and Yield; 1.5.1 Reaction Rates; 1.5.2 Conversion; 1.5.3 Mass Balance of a Plug Flow Tubular Reactor; 1.5.4 Selectivity and Yield; 1.6 Distributed Dosing in Packed-Bed and Membrane Reactors
1.6.1 Adjusting Local Concentrations to Enhance Selectivities1.6.2 Optimization of Dosing Profiles; 1.7 Kinetic Compatibility in Membrane Reactors; 1.8 Current Status of Membrane Reactors of the Distributor Type; Notation used in this Chapter; Greek Symbols; Superscripts and Subscripts; Abbreviations; References; 2: Modeling of Membrane Reactors; 2.1 Introduction; 2.2 Momentum, Mass and Heat Balances; 2.3 Transport Kinetics; 2.3.1 Fluid-Filled Regions; 2.3.1.1 Molecular Transport of Momentum; 2.3.1.2 Heat Conduction; 2.3.1.3 Molecular Diffusion; 2.3.2 Porous Domains 2.3.2.1 Molecular Diffusion2.3.2.2 K nudsen Diffusion; 2.3.2.3 Viscous Flow; 2.3.2.4 Models for Description of Gas Phase Transport in Porous Media; 2.4 Reduced Models; 2.5 Solvability, Discretization Methods and Fast Solution; 2.6 Implementation in FLUENT, MooNMD, COMSOL and ProM oT; 2.6.1 Application of FLUENT; 2.6.2 Application of MooNMD; 2.6.3 Application of ProM oT; 2.7 Conclusion; Notation used in this Chapter; Latin Notation; Greek Notation; Super- and Subscripts; References; 3: Catalysis and Reaction Kinetics of a Model Reaction; 3.1 Introduction 3.2 The Reaction Network of the Oxidative Dehydrogenation of Ethane3.3 Catalysts and Structure-Activity Relations; 3.3.1 Catalyst Preparation and Characterization; 3.3.2 Mechanistic Aspects: Correlation Between Structure and Activity; 3.4 Derivation of a Kinetic Model; 3.4.1 Experimental; 3.4.1.1 Catalyst; 3.4.1.2 Set-Up; 3.4.1.3 Procedures; 3.4.2 Qualitative Trends; 3.4.2.1 Overall Catalyst Performance; 3.4.2.2 Evaluation of Intraparticle Mass Transfer Limitations; 3.4.3 Quantitative Evaluation; 3.4.3.1 Simplified Reactor Model and Data Analysis; 3.4.3.2 Kinetic Models 3.4.3.3 Parameter Estimation3.4.4 Suggested Simplified Model; Special Notation not Mentioned in Chapter 2; Latin Notation; Greek Notation; References; 4: Transport Phenomena in Porous Membranes and Membrane Reactors; 4.1 Introduction; 4.2 Aspects of Discretizing Convection-Diffusion Equations; 4.3 Velocity Fields in Membrane Reactors; 4.4 Determination of Transport Coefficients and Validation of Models; 4.4.1 Mass Transport Parameters of Multilayer Ceramic Membranes-Precursors Available; 4.4.1.1 Task and Tools; 4.4.1.2 Identification by Single Gas Permeation 4.4.1.3 Validation by Isobaric Diffusion and by Transient Diffusion |
Record Nr. | UNINA-9910140598703321 |
Weinheim, : Wiley-VCH Verlag GmbH & Co., 2010 | ||
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Lo trovi qui: Univ. Federico II | ||
|
Membrane reactors [[electronic resource] ] : distributing reactants to improve selectivity and yield / / edited by Andreas Seidel-Morgenstern |
Pubbl/distr/stampa | Weinheim, : Wiley-VCH Verlag GmbH & Co., 2010 |
Descrizione fisica | 1 online resource (294 p.) |
Disciplina | 660.2832 |
Altri autori (Persone) | Seidel-MorgensternAndreas |
Soggetto topico |
Membrane reactors
Bioreactors |
ISBN |
1-282-68781-6
9786612687815 3-527-62972-6 3-527-62973-4 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Membrane Reactors: Distributing Reactants to Improve Selectivity and Yield; Contents; Preface; List of Contributors; 1: Basic Problems of Chemical Reaction Engineering and Potential of Membrane Reactors; 1.1 Challenges in Chemical Reaction Engineering; 1.2 Concepts of Membrane Reactors; 1.3 Available Membranes; 1.4 Illustration of the Selectivity Problem; 1.5 Reaction Rate, Conversion, Selectivity and Yield; 1.5.1 Reaction Rates; 1.5.2 Conversion; 1.5.3 Mass Balance of a Plug Flow Tubular Reactor; 1.5.4 Selectivity and Yield; 1.6 Distributed Dosing in Packed-Bed and Membrane Reactors
1.6.1 Adjusting Local Concentrations to Enhance Selectivities1.6.2 Optimization of Dosing Profiles; 1.7 Kinetic Compatibility in Membrane Reactors; 1.8 Current Status of Membrane Reactors of the Distributor Type; Notation used in this Chapter; Greek Symbols; Superscripts and Subscripts; Abbreviations; References; 2: Modeling of Membrane Reactors; 2.1 Introduction; 2.2 Momentum, Mass and Heat Balances; 2.3 Transport Kinetics; 2.3.1 Fluid-Filled Regions; 2.3.1.1 Molecular Transport of Momentum; 2.3.1.2 Heat Conduction; 2.3.1.3 Molecular Diffusion; 2.3.2 Porous Domains 2.3.2.1 Molecular Diffusion2.3.2.2 K nudsen Diffusion; 2.3.2.3 Viscous Flow; 2.3.2.4 Models for Description of Gas Phase Transport in Porous Media; 2.4 Reduced Models; 2.5 Solvability, Discretization Methods and Fast Solution; 2.6 Implementation in FLUENT, MooNMD, COMSOL and ProM oT; 2.6.1 Application of FLUENT; 2.6.2 Application of MooNMD; 2.6.3 Application of ProM oT; 2.7 Conclusion; Notation used in this Chapter; Latin Notation; Greek Notation; Super- and Subscripts; References; 3: Catalysis and Reaction Kinetics of a Model Reaction; 3.1 Introduction 3.2 The Reaction Network of the Oxidative Dehydrogenation of Ethane3.3 Catalysts and Structure-Activity Relations; 3.3.1 Catalyst Preparation and Characterization; 3.3.2 Mechanistic Aspects: Correlation Between Structure and Activity; 3.4 Derivation of a Kinetic Model; 3.4.1 Experimental; 3.4.1.1 Catalyst; 3.4.1.2 Set-Up; 3.4.1.3 Procedures; 3.4.2 Qualitative Trends; 3.4.2.1 Overall Catalyst Performance; 3.4.2.2 Evaluation of Intraparticle Mass Transfer Limitations; 3.4.3 Quantitative Evaluation; 3.4.3.1 Simplified Reactor Model and Data Analysis; 3.4.3.2 Kinetic Models 3.4.3.3 Parameter Estimation3.4.4 Suggested Simplified Model; Special Notation not Mentioned in Chapter 2; Latin Notation; Greek Notation; References; 4: Transport Phenomena in Porous Membranes and Membrane Reactors; 4.1 Introduction; 4.2 Aspects of Discretizing Convection-Diffusion Equations; 4.3 Velocity Fields in Membrane Reactors; 4.4 Determination of Transport Coefficients and Validation of Models; 4.4.1 Mass Transport Parameters of Multilayer Ceramic Membranes-Precursors Available; 4.4.1.1 Task and Tools; 4.4.1.2 Identification by Single Gas Permeation 4.4.1.3 Validation by Isobaric Diffusion and by Transient Diffusion |
Record Nr. | UNINA-9910830940203321 |
Weinheim, : Wiley-VCH Verlag GmbH & Co., 2010 | ||
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Lo trovi qui: Univ. Federico II | ||
|
Membrane reactors : distributing reactants to improve selectivity and yield / / edited by Andreas Seidel-Morgenstern |
Pubbl/distr/stampa | Weinheim, : Wiley-VCH Verlag GmbH & Co., 2010 |
Descrizione fisica | 1 online resource (294 p.) |
Disciplina | 660.2832 |
Altri autori (Persone) | Seidel-MorgensternAndreas |
Soggetto topico |
Membrane reactors
Bioreactors |
ISBN |
1-282-68781-6
9786612687815 3-527-62972-6 3-527-62973-4 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
Membrane Reactors: Distributing Reactants to Improve Selectivity and Yield; Contents; Preface; List of Contributors; 1: Basic Problems of Chemical Reaction Engineering and Potential of Membrane Reactors; 1.1 Challenges in Chemical Reaction Engineering; 1.2 Concepts of Membrane Reactors; 1.3 Available Membranes; 1.4 Illustration of the Selectivity Problem; 1.5 Reaction Rate, Conversion, Selectivity and Yield; 1.5.1 Reaction Rates; 1.5.2 Conversion; 1.5.3 Mass Balance of a Plug Flow Tubular Reactor; 1.5.4 Selectivity and Yield; 1.6 Distributed Dosing in Packed-Bed and Membrane Reactors
1.6.1 Adjusting Local Concentrations to Enhance Selectivities1.6.2 Optimization of Dosing Profiles; 1.7 Kinetic Compatibility in Membrane Reactors; 1.8 Current Status of Membrane Reactors of the Distributor Type; Notation used in this Chapter; Greek Symbols; Superscripts and Subscripts; Abbreviations; References; 2: Modeling of Membrane Reactors; 2.1 Introduction; 2.2 Momentum, Mass and Heat Balances; 2.3 Transport Kinetics; 2.3.1 Fluid-Filled Regions; 2.3.1.1 Molecular Transport of Momentum; 2.3.1.2 Heat Conduction; 2.3.1.3 Molecular Diffusion; 2.3.2 Porous Domains 2.3.2.1 Molecular Diffusion2.3.2.2 K nudsen Diffusion; 2.3.2.3 Viscous Flow; 2.3.2.4 Models for Description of Gas Phase Transport in Porous Media; 2.4 Reduced Models; 2.5 Solvability, Discretization Methods and Fast Solution; 2.6 Implementation in FLUENT, MooNMD, COMSOL and ProM oT; 2.6.1 Application of FLUENT; 2.6.2 Application of MooNMD; 2.6.3 Application of ProM oT; 2.7 Conclusion; Notation used in this Chapter; Latin Notation; Greek Notation; Super- and Subscripts; References; 3: Catalysis and Reaction Kinetics of a Model Reaction; 3.1 Introduction 3.2 The Reaction Network of the Oxidative Dehydrogenation of Ethane3.3 Catalysts and Structure-Activity Relations; 3.3.1 Catalyst Preparation and Characterization; 3.3.2 Mechanistic Aspects: Correlation Between Structure and Activity; 3.4 Derivation of a Kinetic Model; 3.4.1 Experimental; 3.4.1.1 Catalyst; 3.4.1.2 Set-Up; 3.4.1.3 Procedures; 3.4.2 Qualitative Trends; 3.4.2.1 Overall Catalyst Performance; 3.4.2.2 Evaluation of Intraparticle Mass Transfer Limitations; 3.4.3 Quantitative Evaluation; 3.4.3.1 Simplified Reactor Model and Data Analysis; 3.4.3.2 Kinetic Models 3.4.3.3 Parameter Estimation3.4.4 Suggested Simplified Model; Special Notation not Mentioned in Chapter 2; Latin Notation; Greek Notation; References; 4: Transport Phenomena in Porous Membranes and Membrane Reactors; 4.1 Introduction; 4.2 Aspects of Discretizing Convection-Diffusion Equations; 4.3 Velocity Fields in Membrane Reactors; 4.4 Determination of Transport Coefficients and Validation of Models; 4.4.1 Mass Transport Parameters of Multilayer Ceramic Membranes-Precursors Available; 4.4.1.1 Task and Tools; 4.4.1.2 Identification by Single Gas Permeation 4.4.1.3 Validation by Isobaric Diffusion and by Transient Diffusion |
Record Nr. | UNINA-9910877538403321 |
Weinheim, : Wiley-VCH Verlag GmbH & Co., 2010 | ||
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Lo trovi qui: Univ. Federico II | ||
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Preparative chromatography / / edited by H. Schmidt-Traub, Michael Schulte, Andreas Seidel-Morgenstern |
Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2020] |
Descrizione fisica | 1 online resource (651 pages) |
Disciplina | 543.8 |
Soggetto topico | Preparative layer chromatography |
Soggetto genere / forma | Electronic books. |
ISBN |
3-527-81633-X
3-527-81634-8 3-527-81631-3 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910555159403321 |
Weinheim, Germany : , : Wiley-VCH, , [2020] | ||
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Lo trovi qui: Univ. Federico II | ||
|
Preparative chromatography / / edited by H. Schmidt-Traub, Michael Schulte, Andreas Seidel-Morgenstern |
Pubbl/distr/stampa | Weinheim, Germany : , : Wiley-VCH, , [2020] |
Descrizione fisica | 1 online resource (651 pages) |
Disciplina | 543.8 |
Soggetto topico | Preparative layer chromatography |
ISBN |
3-527-81633-X
3-527-81634-8 3-527-81631-3 |
Formato | Materiale a stampa ![]() |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Record Nr. | UNINA-9910830500603321 |
Weinheim, Germany : , : Wiley-VCH, , [2020] | ||
![]() | ||
Lo trovi qui: Univ. Federico II | ||
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