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Catalytic kinetics : chemistry and engineering / / Dmitry Yu. Murzin and Tapio Salmi
| Catalytic kinetics : chemistry and engineering / / Dmitry Yu. Murzin and Tapio Salmi |
| Autore | Murzin Dmitry <1963-> |
| Edizione | [Second edition.] |
| Pubbl/distr/stampa | Amsterdam, : Elsevier, 2016 |
| Descrizione fisica | 1 online resource |
| Disciplina | 541/.395 |
| Soggetto topico |
Catalysis
Chemical kinetics |
| ISBN | 0-444-63753-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Machine generated contents note: ; 1.1. History -- ; 1.2. Catalysis -- ; 1.3. Formal Kinetics -- ; 1.4. Acquisition of Kinetic Data -- ; 1.5. Kinetics and Thermodynamics -- ; 1.6. Examples and Exercises -- Reference -- ; 2.1. Homogeneous Catalysis -- ; 2.2. Heterogeneous Catalysis -- ; 2.3. Organocatalysis -- ; 2.4. Examples and Exercises -- Reference -- ; 3.1. Reaction Rate Theory -- ; 3.2. Elementary Reactions in Solutions -- ; 3.3. Reaction Mechanism -- ; 3.4. Quasi-equilibrium Approximation -- ; 3.5. Relationship Between Thermodynamics and Kinetics -- ; 3.6. Transition State Theory of Surface Reactions -- ; 3.7. Rates of Reactions on Nonideal Surfaces -- ; 3.8. Deterministic and Stochastic Models -- ; 3.9. Microkinetic Modeling -- ; 3.10. Compensation Effect -- ; 3.11. Isotope Effects -- ; 3.12. Examples and Exercises -- References -- ; 4.1. Steady State Kinetics of Complex Reactions -- ; 4.2. Basic Routes of Complex Reactions -- ; 4.3. Single-Route Steady-State Reaction -- ; 4.4. Topological Analysis of Complex Reactions -- ; 4.5. Electrical Analogy of Reaction Networks -- ; 4.6. Thermodynamic Consistency of Rate Constants for Complex Networks -- ; 4.7. Kinetic Aspects of Selectivity -- ; 4.8. Parallel Reactions: Kinetic Coupling -- ; 4.9. Reduction of Complexity -- ; 4.10. Polynomial Kinetics -- ; 4.11. Examples and Exercises -- References -- ; 5.1. Homogeneous Acid-Base Catalysis -- ; 5.2. Nucleophilic Catalysis -- ; 5.3. Catalysis by Metal Ions -- ; 5.4. Catalysis by Organometallic Complexes -- ; 5.5. Organocatalysis -- ; 5.6. Polymerization Catalysis -- ; 5.7. Examples and Exercises -- References -- ; 6.1. Enzymatic Catalysis -- ; 6.2. Cooperative Kinetics -- ; 6.3. Inhibition -- ; 6.4. Effects of pH -- ; 6.5. Single Molecule Enzymology -- ; 6.6. Enantioselectivity in Enzyme Catalyzed Reactions -- ; 6.7. Generalized Rate Laws for Enzymatic Reactions -- ; 6.8. Heterogeneous Systems/Immobilized Enzymes -- ; 6.9. Examples and Exercises -- References -- ; 7.1. Reactions on Ideal Surfaces -- ; 7.2. Reactions on Nonideal Surfaces -- ; 7.3. Selectivity -- ; 7.4. Polyatomic Nature of Reactants and Coverage-Dependent Adsorption Mode -- ; 7.5. Solvent Effects -- ; 7.6. Ionic Species -- ; 7.7. Transfer of Labeled Atoms in Heterogeneous Catalytic Reactions -- ; 7.8. Electrocatalytic Kinetics -- ; 7.9. Photocatalytic Kinetics -- ; 7.10. Nanokinetics -- ; 7.11. Examples and Exercises -- References -- ; 8.1. General -- ; 8.2. Combined Catalytic and Noncatalytic Reactions -- ; 8.3. Multiple Catalysts of the Same Type -- ; 8.4. Multiple Catalysts of Different Types -- ; 8.5. Examples and Exercises -- References -- ; 9.1. Transient Kinetics -- ; 9.2. Relaxation Methods -- ; 9.3. Temperature-Programmed Desorption -- ; 9.4. Oscillations -- ; 9.5. Dynamic Catalyst Changes -- ; 9.6. Examples and Exercises -- References -- ; 10.1. Catalytic Multi-Phase Systems -- ; 10.2. Simultaneous Reaction and Diffusion in Fluid Films and in Porous Materials -- ; 10.3. Liquid-Liquid Diffusion, Phase-Transfer Catalysis -- ; 10.4. Catalytic Two-Phase Systems -- ; 10.5. Mass Transfer and Enzymatic Kinetics -- ; 10.6. External Mass Transfer -- ; 10.7. Internal Diffusion and Selectivity -- ; 10.8. Internal Diffusion and Deactivation -- ; 10.9. Elucidation of the Impact of Mass Transfer -- ; 10.10. Three-Phase Systems -- ; 10.11. Examples and Exercises -- References -- ; 11.1. Basic Principles -- ; 11.2. Heuristic Design of Experiments -- ; 11.3. Parameter Estimation: Classical Methods -- ; 11.4. Parameter Estimation: Regression -- ; 11.5. Numerical Strategies -- ; 11.6. Analysis of Parameters -- ; 11.7. Model Discrimination -- ; 11.8. Software -- ; 11.9. Case Studies -- References. |
| Record Nr. | UNINA-9911034968803321 |
Murzin Dmitry <1963->
|
||
| Amsterdam, : Elsevier, 2016 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Catalytic kinetics / / Dmitry Murzin, Tapio Salmi
| Catalytic kinetics / / Dmitry Murzin, Tapio Salmi |
| Autore | Murzin Dmitry |
| Pubbl/distr/stampa | Amsterdam, : Elsevier, 2005 |
| Descrizione fisica | 1 online resource (493 p.) |
| Disciplina | 541.395 |
| Altri autori (Persone) | SalmiTapio |
| Soggetto topico |
Catalysis
Chemical kinetics |
| ISBN |
9780444516053
1-280-63817-6 9786610638178 0-08-045546-8 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Cover; Preface; Setting the scene; History; Catalysis; Formal kinetics; Acquisition of kinetic data; Batch reactors; CSTR; Plug flow reactors; Gradient-free recycle reactors; Kinetics and thermodynamics; Catalysis; Homogeneous catalysis; Gas-phase catalysis; Acid-base catalysis; Catalysis by transition metals; Biocatalysis (catalysis by enzymes); Heterogeneous catalysis; Classification; Kinetics in heterogeneous catalysis; Elementary steps; Adsorption isotherms - ideal surfaces; Adsorption isotherms - real surfaces; Adsorption isotherms - induced nonuniformity
Adsorption isotherms - multicentered adsorptionDifferent adsorption modes; Elementary reactions; Reaction rate theory; Reaction mechanism; Quasi-equilibrium approximation; Relationship between thermodynamics and kinetics; Transition state theory of surface reactions; Rates of reactions on nonideal surfaces; Biographical nonuniformity; Lateral interactions; Limited mobility of adsorbed species; Determenistic and stochastic models; Micro kinetic modelling; Compensation effect; Complex reactions; Steady-state kinetics of complex reactions; Basic routes of complex reactions Single-route steady-state reactionTopological analysis of complex reactions; Kinetic aspects of selectivity; Parallel reactions : kinetic coupling; Reduction of complexity; Homogeneous catalytic kinetics; Homogeneous acid-base catalysis; Nucleophilic catalysis; Catalysis by metal ions; Catalysis by organometallic compexes; Single catalytic cycles; Ligand deficient catalysis and inhibition; Multiple cycles; Enzymatic kinetics; Enzymatic catalysis; Cooperative kinetics; Inhibition; Effects of pH; Heterogeneos systems/immobilized enzymes; Heterogeneous catalytic kinetics Reactions on ideal surfacesReactions on nonideal surfaces; Intrinsic nonuniformity; Induced nonuniformity; Thermodynamic considerations of kinetics on non-ideal surfaces; Ammonia synthesis; Linear sequence on nonuniform surfaces; Kinetic considerations of optimum catalyst for two-step sequence; Selectivity; Polyatomic nature of reactants and coverage dependent adsorption mode; Ionic species; Transfer of labeled atoms in heterogeneous catalytic reactions; Electrocatalytic kinetics; Combined heterogeneous-homogeneous reactions; Dynamic catalysis; Transient kinetics; Relaxation to steady state Relaxation methodsTemperature programmed desorption; Oscillations; Homogeneous catalysis; Enzymatic catalysis; Heterogeneous catalysis; Activity changes (deactivation); Heterogeneous catalysis; Coking; Batch reactors; Multilayer coking; Poisoning; Enhancement of activity while deactivating; Enzyme deactivation; Mass transfer and catalytic reactions; Catalytic multi-phase systems; Simultaneous reaction and diffusion in fluid films and in porous materials; Gas-liquid reactions; Slow reactions; Reactions with a finite liquid film reaction velocity; Zero-order reactions; First order reactions Utilization factor |
| Record Nr. | UNINA-9911006646603321 |
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Murzin Dmitry
|
||
| Amsterdam, : Elsevier, 2005 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||