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Key chiral auxiliary applications / / Gregory Roos
| Key chiral auxiliary applications / / Gregory Roos |
| Autore | Roos Gregory |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Waltham, [Massachusetts] ; ; Amsterdam, The Netherlands : , : Academic Press, , 2014 |
| Descrizione fisica | 1 online resource (1271 p.) |
| Disciplina | 547 |
| Soggetto topico |
Asymmetric synthesis
Enantioselective catalysis Enantiomers |
| Soggetto genere / forma | Electronic books. |
| ISBN | 0-12-417115-X |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Front Cover; Key Chiral Auxiliary Applications; Copyright; CONTENTS; ACKNOWLEDGEMENTS; FOREWORD; PREFACE TO THE 2ND EDITION; ABBREVIATIONS; 1.INTRODUCTION; 1.1. BACKGROUND; 1.2. THE CHIRAL AUXILIARY APPROACH; 1.3. THIS COLLECTION; REFERENCES; 2.ALKYLATION AND RELATED REACTIONS I; 2.1 ALLYL AND BENZYL RELATED CARBANIONS; 2.2 ALLENIC ETHER TANDEM ACYLATION-CYCLIZATION; 2.3 ALDEHYDE DERIVED NUCLEOPHILES; 2.4 KETONE DERIVED NUCLEOPHILES; 2.5 ALDEHYDE AND KETONE ENOLATES WITH AUXILIARY-CONTAINING ELECTROPHILES; REFERENCES; 3.ALKYLATION AND RELATED REACTIONS II
3.1 α-ALKYLATION OF CARBOXYLIC ACID DERIVED NUCLEOPHILESREFERENCES; 4.ALKYLATION AND RELATED REACTIONS III; 4.1 α-ALKYLATION OF -HETEROATOM SUBSTITUTED ACID DERIVATIVES; 4.2 α-ALKYLATION OF CYCLIC CARBOXYLIC ACID DERIVATIVES; REFERENCES; 5.ALKYLATION AND RELATED REACTIONS IV; 5.3 α-HYDROXYLATION OF ACID DERIVATIVES; 5.1 α-ACYLATION OF ACID DERIVATIVES; 5.2 α-AMINATION OF ACYL DERIVATIVES; 5.4 α-SILYLATION, α-THIOLATION, AND α-SELENATION OF ACID DERIVATIVES; 5.5 α-HALOGENATION OF ACID DERIVATIVES; 5.6 REACTION OF PHOSPHORIC ACID DERIVATIVES WITH ELECTROPHILES 5.7 α-ALKYLATION OF SULFONIC ACID DERIVATIVES5.8 AROMATIC SUBSTITUTION; 5.9 NUCLEOPHILIC ALLYLIC SUBSTITUTION; 5.10 MISCELLANEOUS REACTIONS; REFERENCES; 6.ELECTROPHILIC RELATED ADDITION TO C=C; 6.1 REDUCTION AND RELATED REACTIONS; 6.2 ADDITION OF HALO-CONTAINING ADDENDS; 6.3 BISAMINATION; 6.4 ADDITION OF OXY-ADDENDS; 6.5 CYCLOPROPANATION; 6.6 CYCLOPROPENATION; 6.7 AZIRIDINATION; 6.8 ALKOXYSELENATION; 6.9 RADICAL ADDITION; REFERENCES; 7.CONJUGATE ADDITION I; 7.1 AUXILIARY ON DONOR NUCLEOPHILE - SIMPLE ADDITION; 7.2 AUXILIARY ON DONOR NUCLEOPHILE - TANDEM ADDITION; REFERENCES 8.CONJUGATE ADDITION II8.1 AUXILIARY ON ACCEPTOR α,β-UNSATURATED SYSTEM - SIMPLE ADDITION; REFERENCES; 9.CONJUGATE ADDITION III; 9.1 α,β-UNSATURATED ACYL DERIVATIVES - ADDITION OF HETERONUCLEOPHILES; 9.2 OTHER ACTIVATED SYSTEMS; 9.3 INTRAMOLECULAR REACTIONS; 9.4 AUXILIARY ON α,β-UNSATURATED SYSTEM - TANDEM ADDITION OFCARBON NUCLEOPHILES; 9.5 AUXILIARY ON ACCEPTOR α,β-UNSATURATED SYSTEM - TANDEM ADDITION OFHETERONUCLEOPHILES; 9.6 AUXILIARY ON ACCEPTOR α,β-UNSATURATED SYSTEM - RADICAL ADDITION; 9.7 NUCLEOPHILIC ADDITION TO TRANSITION-METAL ALKENE/ARENE COMPLEXES; REFERENCES 10.ADDITION TO C=N BONDS10.1 REDUCTION OF IMINES, IMINIUM IONS, HYDRAZONES AND OXIMES; 10.2 NUCLEOPHILIC ADDITION; 10.3 RADICAL ADDITION; 10.4 UGI COUPLING; REFERENCES; 11.ADDITION TO C=O BONDS I; 11.1 REDUCTION; 11.2 WITTIG & RELATED OLEFINATION; 11.3 ADDITION OF ORGANOMETALLIC AND RELATED REAGENTS; REFERENCES; 12.ADDITION TO C=O BONDS II; 12.1 ADDITION OF ENOLATES (ALDOL AND RELATED REACTIONS); REFERENCES; 13.ADDITION TO C=O BONDS III; 13.1 ADDITION OF ENOLATES (ALDOL AND RELATED REACTIONS); 13.2 TANDEM REACTIONS; 13.3 RADICAL REACTIONS; REFERENCES; 14. CYCLOADDITIONS I 14.1 [2+2]-CYCLOADDITIONS |
| Record Nr. | UNISA-996426337703316 |
Roos Gregory
|
||
| Waltham, [Massachusetts] ; ; Amsterdam, The Netherlands : , : Academic Press, , 2014 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
Organic chemistry concepts : an EFL approach / / Gregory Roos, Murdoch University, Perth, Australia, Cathryn Roos, Zayed University, Dubai, UAE
| Organic chemistry concepts : an EFL approach / / Gregory Roos, Murdoch University, Perth, Australia, Cathryn Roos, Zayed University, Dubai, UAE |
| Autore | Roos Gregory |
| Pubbl/distr/stampa | London : , : Elsevier, , [2015] |
| Descrizione fisica | 1 online resource (237 p.) |
| Soggetto topico | Chemistry, Organic |
| ISBN | 0-12-801809-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
FrontCover; Organic Chemistry Concepts:An EFL Approach; Copyright; Contents; PREFACE; How to Use This Book; Self-Learning Programs; CHAPTER 1 -Organic Structures; 1.1 WHAT IS ORGANIC CHEMISTRY?; 1.2 WHAT MAKES CARBON SPECIAL?; 1.3 MOLECULES, FORMULAE, AND STRUCTURES; 1.4 BONDS AND SHAPE: THE HYBRIDIZATION MODEL; 1.5 POLAR BONDS AND ELECTRONEGATIVITY; 1.6 FORCES BETWEEN MOLECULES; QUESTIONS AND PROGRAMS; Chapter 2 - Functional Classes I, Structure and Naming; 2.1 DRAWING AND NAMING MOLECULES; 2.2 SATURATED HYDROCARBONS; 2.3 SIMPLE UNSATURATED HYDROCARBONS (ALKENES AND ALKYNES)
2.4 COMPLEX UNSATURATED SYSTEMS (POLYENES AND AROMATICS)2.5 ALKYL HALIDES; 2.6 ALCOHOLS, PHENOLS, ETHERS, AND THEIR SULFUR EQUIVALENTS (THIOLS AND THIOETHERS); 2.7 AMINES; 2.8 COMPOUNDS WITH CARBONYL GROUPS; QUESTIONS AND PROGRAMS; Chapter 3 - Isomers and Stereochemistry; 3.1 WHAT ARE ISOMERS?; 3.2 STRUCTURAL ISOMERS; 3.3 CONFORMATIONAL ISOMERS; 3.4 GEOMETRIC (CIS-TRANS) ISOMERS; 3.5 CONFIGURATIONAL ISOMERS; 3.6 SUMMARY OF ISOMER RELATIONSHIPS; QUESTIONS AND PROGRAMS; Chapter 4 - Resonance and Delocalization; 4.1 WHAT IS RESONANCE?; 4.2 DRAWING USEFUL RESONANCE STRUCTURES 4.3 USING CURLY ARROWS TO COUNT ELECTRONSQUESTIONS AND PROGRAMS; Chapter 5 - Reactivity: How and Why; 5.1 WHY DO REACTIONS OCCUR?; 5.2 BOND BREAKING AND MAKING; 5.3 REACTIVE SPECIES; 5.4 REACTION TYPES; 5.5 REACTION MECHANISM: THE PATH FROM REACTANT TO PRODUCT; 5.6 REACTION ENERGY; 5.7 ORGANIC REDOX REACTIONS; QUESTIONS AND PROGRAMS; Chapter 6 - Acids and Bases; 6.1 WHY ARE ACIDS AND BASES IMPORTANT?; 6.2 GENERAL DEFINITIONS; 6.3 ACIDITY OF CARBOXYLIC ACIDS; 6.4 GENERAL FUNCTIONAL GROUP ACIDITY; 6.5 GENERAL FUNCTIONAL GROUP BASICITY; QUESTIONS AND PROGRAMS Chapter 7 - Functional Classes II, Reactions7.1 FUNCTIONAL GROUP INTERCONVERSIONS; 7.2 ALKANES; 7.3 ALKENES; 7.4 ALKYNES; 7.5 ALKYL HALIDES; 7.6 ALCOHOLS AND ETHERS; 7.7 ALDEHYDES AND KETONES; 7.8 CARBOXYLIC ACIDS AND ACYL DERIVATIVES; 7.9 AMINES; 7.10 AROMATIC COMPOUNDS; QUESTIONS AND PROGRAMS; Chapter 8 - Natural Product Biomolecules; 8.1 WHAT ARE BIOMOLECULES?; 8.2 CARBOHYDRATES; 8.3 LIPIDS; 8.4 AMINO ACIDS, PEPTIDES, AND PROTEINS; 8.5 NUCLEIC ACIDS; QUESTIONS AND PROGRAMS; APPENDICES; APPENDIX 1: Electronegativity and Bond Polarity APPENDIX 2: KEY IUPAC RULES FOR SUBSTITUTIVE NAMING OF ORGANIC COMPOUNDSAPPENDIX 3: SUBSTITUTIVE NAME PREFIXES AND SUFFIXES IN DECREASING ORDER OF PRIORITY; APPENDIX 4: FURTHER AMINE NOMENCLATURE; APPENDIX 5: E, Z-SEQUENCE RULES FOR GEOMETRIC ISOMERISM IN ALKENES; APPENDIX 6: CAHN-INGOLD-PRELOG R/S SEQUENCE RULES; APPENDIX 7: SELECTED AVERAGE BOND ENERGIES (KJ/MOL); APPENDIX 8: SYN- AND ANTI-ADDITION; APPENDIX 9: SUBSTITUTION STEREOCHEMISTRY; APPENDIX 10: FUNCTIONAL GROUP PREPARATIONS; APPENDIX 11: FUNCTIONAL GROUP TESTS; APPENDIX 12: MOST COMMON AMINO ACIDS APPENDIX 12: MOST COMMON AMINO ACIDS-CONT'D |
| Record Nr. | UNINA-9910788088003321 |
|
Roos Gregory
|
||
| London : , : Elsevier, , [2015] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic chemistry concepts : an EFL approach / / Gregory Roos, Murdoch University, Perth, Australia, Cathryn Roos, Zayed University, Dubai, UAE
| Organic chemistry concepts : an EFL approach / / Gregory Roos, Murdoch University, Perth, Australia, Cathryn Roos, Zayed University, Dubai, UAE |
| Autore | Roos Gregory |
| Pubbl/distr/stampa | London : , : Elsevier, , [2015] |
| Descrizione fisica | 1 online resource (237 p.) |
| Soggetto topico | Chemistry, Organic |
| ISBN | 0-12-801809-7 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
FrontCover; Organic Chemistry Concepts:An EFL Approach; Copyright; Contents; PREFACE; How to Use This Book; Self-Learning Programs; CHAPTER 1 -Organic Structures; 1.1 WHAT IS ORGANIC CHEMISTRY?; 1.2 WHAT MAKES CARBON SPECIAL?; 1.3 MOLECULES, FORMULAE, AND STRUCTURES; 1.4 BONDS AND SHAPE: THE HYBRIDIZATION MODEL; 1.5 POLAR BONDS AND ELECTRONEGATIVITY; 1.6 FORCES BETWEEN MOLECULES; QUESTIONS AND PROGRAMS; Chapter 2 - Functional Classes I, Structure and Naming; 2.1 DRAWING AND NAMING MOLECULES; 2.2 SATURATED HYDROCARBONS; 2.3 SIMPLE UNSATURATED HYDROCARBONS (ALKENES AND ALKYNES)
2.4 COMPLEX UNSATURATED SYSTEMS (POLYENES AND AROMATICS)2.5 ALKYL HALIDES; 2.6 ALCOHOLS, PHENOLS, ETHERS, AND THEIR SULFUR EQUIVALENTS (THIOLS AND THIOETHERS); 2.7 AMINES; 2.8 COMPOUNDS WITH CARBONYL GROUPS; QUESTIONS AND PROGRAMS; Chapter 3 - Isomers and Stereochemistry; 3.1 WHAT ARE ISOMERS?; 3.2 STRUCTURAL ISOMERS; 3.3 CONFORMATIONAL ISOMERS; 3.4 GEOMETRIC (CIS-TRANS) ISOMERS; 3.5 CONFIGURATIONAL ISOMERS; 3.6 SUMMARY OF ISOMER RELATIONSHIPS; QUESTIONS AND PROGRAMS; Chapter 4 - Resonance and Delocalization; 4.1 WHAT IS RESONANCE?; 4.2 DRAWING USEFUL RESONANCE STRUCTURES 4.3 USING CURLY ARROWS TO COUNT ELECTRONSQUESTIONS AND PROGRAMS; Chapter 5 - Reactivity: How and Why; 5.1 WHY DO REACTIONS OCCUR?; 5.2 BOND BREAKING AND MAKING; 5.3 REACTIVE SPECIES; 5.4 REACTION TYPES; 5.5 REACTION MECHANISM: THE PATH FROM REACTANT TO PRODUCT; 5.6 REACTION ENERGY; 5.7 ORGANIC REDOX REACTIONS; QUESTIONS AND PROGRAMS; Chapter 6 - Acids and Bases; 6.1 WHY ARE ACIDS AND BASES IMPORTANT?; 6.2 GENERAL DEFINITIONS; 6.3 ACIDITY OF CARBOXYLIC ACIDS; 6.4 GENERAL FUNCTIONAL GROUP ACIDITY; 6.5 GENERAL FUNCTIONAL GROUP BASICITY; QUESTIONS AND PROGRAMS Chapter 7 - Functional Classes II, Reactions7.1 FUNCTIONAL GROUP INTERCONVERSIONS; 7.2 ALKANES; 7.3 ALKENES; 7.4 ALKYNES; 7.5 ALKYL HALIDES; 7.6 ALCOHOLS AND ETHERS; 7.7 ALDEHYDES AND KETONES; 7.8 CARBOXYLIC ACIDS AND ACYL DERIVATIVES; 7.9 AMINES; 7.10 AROMATIC COMPOUNDS; QUESTIONS AND PROGRAMS; Chapter 8 - Natural Product Biomolecules; 8.1 WHAT ARE BIOMOLECULES?; 8.2 CARBOHYDRATES; 8.3 LIPIDS; 8.4 AMINO ACIDS, PEPTIDES, AND PROTEINS; 8.5 NUCLEIC ACIDS; QUESTIONS AND PROGRAMS; APPENDICES; APPENDIX 1: Electronegativity and Bond Polarity APPENDIX 2: KEY IUPAC RULES FOR SUBSTITUTIVE NAMING OF ORGANIC COMPOUNDSAPPENDIX 3: SUBSTITUTIVE NAME PREFIXES AND SUFFIXES IN DECREASING ORDER OF PRIORITY; APPENDIX 4: FURTHER AMINE NOMENCLATURE; APPENDIX 5: E, Z-SEQUENCE RULES FOR GEOMETRIC ISOMERISM IN ALKENES; APPENDIX 6: CAHN-INGOLD-PRELOG R/S SEQUENCE RULES; APPENDIX 7: SELECTED AVERAGE BOND ENERGIES (KJ/MOL); APPENDIX 8: SYN- AND ANTI-ADDITION; APPENDIX 9: SUBSTITUTION STEREOCHEMISTRY; APPENDIX 10: FUNCTIONAL GROUP PREPARATIONS; APPENDIX 11: FUNCTIONAL GROUP TESTS; APPENDIX 12: MOST COMMON AMINO ACIDS APPENDIX 12: MOST COMMON AMINO ACIDS-CONT'D |
| Record Nr. | UNINA-9910825776703321 |
|
Roos Gregory
|
||
| London : , : Elsevier, , [2015] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||