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Hydrolysis, oxidation and reduction / / edited by Stan M. Roberts and Geraldine Poignant
Hydrolysis, oxidation and reduction / / edited by Stan M. Roberts and Geraldine Poignant
Pubbl/distr/stampa Chichester, West Sussex, England ; ; New York, : Wiley, c2002
Descrizione fisica 1 online resource (245 p.)
Disciplina 660.634
660/.28443
Altri autori (Persone) RobertsStanley M
PoignantGeraldine
Collana Catalysts for fine chemical synthesis
Soggetto topico Enzymes - Biotechnology
Organic compounds - Synthesis
Hydrolysis
Oxidation-reduction reaction
ISBN 1-280-27032-2
9786610270323
0-470-36296-0
0-470-85579-7
0-470-85580-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Catalysts for Fine Chemical Synthesis Volume 1; Contents; Series Preface; Preface to Volume 1; Abbreviations; PART I: REVIEW; 1 The Integration of Biotransformations into the Catalyst Portfolio; 1.1 Hydrolysis of esters, amides, nitriles and oxiranes; 1.2 Reduction reactions; 1.2.1 Reduction of carbonyl compounds; 1.2.2 Reduction of alkenes; 1.3 Oxidative transformations; 1.4 Carbon-carbon bond-forming reactions; 1.5 Conclusions; References; PART II: PROCEDURES; 2 General Information; 3 Asymmetric Epoxidation; 3.1 Introduction; References; 4 Epoxidation of a, b-Unsaturated Carbonyl Compounds
4.1 Non-asymmetric epoxidation4.2 Asymmetric epoxidation using poly-D-leucine; 4.2.1 Synthesis of leucine N-carboxyanhydride; 4.2.2 Synthesis of immobilized poly-D-leucine; 4.2.3 Asymmetric epoxidation of (E)-benzylideneacetophenone; 4.2.4 Conclusion; 4.3 Asymmetric epoxidation using chiral modified diethylzinc; 4.3.1 Epoxidation of 2-isobutylidene-1-tetralone; 4.3.2 Conclusion; 4.4 Asymmetric epoxidation of (E)-benzylideneacetophenone using the La-(R)-BINOL-Ph(3)PO/cumene hydroperoxide system; 4.4.1 Merits of the system; References; 5 Epoxidation of Allylic Alcohols
5.1 Non-asymmetric epoxidation5.2 Asymmetric epoxidation using a chiral titanium complex; 5.2.1 Epoxidation of cinnamyl alcohol; 5.2.2 Epoxidation of (E)-2-methyl-3-phenyl-2-propenol; 5.2.3 Epoxidation of (E)-2-hexen-1-ol; 5.2.4 Conclusion; 5.3 Asymmetric epoxidation of (E)-undec-2-en-1-ol using poly(octamethylene tartrate); 5.3.1 Synthesis of branched poly (octamethylene-L-(+)-tartrate); 5.3.2 Asymmetric epoxidation of (E)-undec-2-en-1-ol; References; 6 Epoxidation of Unfunctionalized Alkenes and a, b-Unsaturated Esters
6.1 Asymmetric epoxidation of disubstituted Z-alkenes using a chiral salen-manganese complex6.1.1 Epoxidation of (Z)-methyl styrene; 6.1.2 Epoxidation of (Z)-ethyl cinnamate; 6.1.3 Conclusion; 6.2 Asymmetric epoxidation of disubstituted E-alkanes using a D-fructose based catalyst; 6.2.1 Epoxidation of (E)-stilbene; 6.2.2 Conclusion; 6.3 Enantioselective epoxidation of (E)-b-methylstyrene by D(2)-symmetric chiral trans-dioxoruthenium (VI) porphyrins; 6.3.1 Preparation of the trans-dioxoruthenium(VI) complexes with D(2)-symmetric porphyrins (H(2)L(1-3))
6.3.2 Enantioselective epoxidation of (E)-b-methylstyrene6.3.3 Conclusion; References; 7 Asymmetric Hydroxylation and Aminohydroxylation; 7.1 Asymmetric aminohydroxylation of 4-methoxystyrene; 7.1.1 Conclusion; 7.2 Asymmetric dihydroxylation of (1-cyclohexenyl)acetonitrile; 7.2.1 (R,R)-(1,2-Dihydroxycyclohexyl)acetonitrile acetonide; 7.2.2 Conclusion; References; 8 Asymmetric Sulfoxidation; 8.1 Asymmetric oxidation of sulfides and kinetic resolution of sulfoxides; 8.1.1 Asymmetric oxidation of 4-bromothioanisole; 8.1.2 Kinetic resolution of racemic 4-bromophenyl methyl sulfoxide; References
9 Asymmetric Reduction of Ketones Using Organometallic Catalysts
Record Nr. UNINA-9910877844303321
Chichester, West Sussex, England ; ; New York, : Wiley, c2002
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Metal catalysed carbon-carbon bond-forming reactions [[electronic resource] /] / edited by Stanley M. Roberts ... [et al.]
Metal catalysed carbon-carbon bond-forming reactions [[electronic resource] /] / edited by Stanley M. Roberts ... [et al.]
Pubbl/distr/stampa Chichester, West Sussex, England ; ; Hoboken, N.J., : John Wiley, c2004
Descrizione fisica 1 online resource (282 p.)
Disciplina 660
660.28443
660.2995
Altri autori (Persone) RobertsStanley M
Collana Catalysts for fine chemical synthesis
Soggetto topico Organic compounds - Synthesis
Metal catalysts
Chemical bonds
ISBN 1-280-27141-8
9786610271412
0-470-34184-X
0-470-86201-7
0-470-86200-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Catalysts for Fine Chemical Synthesis Volume 3; Contents; Series Preface; Preface to Volume 3; Abbreviations; List of Chemical Names Used; 1 Considerations of Industrial Fine Chemical Synthesis; 1.1 Introduction; 1.2 Types of processes - flow charts; 1.2.1 Classical process; 1.2.2 General catalytic process; 1.3 Costs associated with use of catalysts; 1.3.1 Catalyst fabrication costs; 1.3.2 Intellectual property right (IPR) issues; 1.3.3 Separation costs; 1.3.4 Pre-reaction/immobilisation; 1.3.5 Post reaction - separation; 1.3.6 Industrial examples; References
2 Alkylation and Allylation Adjacent to a Carbonyl Group2.1 The RuH(2)(CO)(PPh(3))(3)-catalysed alkylation, alkenylation and arylation of aromatic ketones via carbon-hydrogen bond cleavage; 2.1.1 Preparation of carbonyldihydrotris(triphenylphosphine) ruthenium; 2.1.2 Synthesis of 8-(2-triethoxysilanylethyl)-3,4-dihydro-2H-naphthalen-1-one; 2.1.3 Synthesis of 8-(1-methyl-2-trimethylsilanylvinyl)-3,4-dihydro-2H-naphthalen-1-one; 2.1.4 Synthesis of 1-biphenyl-2-yl-2,2-dimethylpropan-1-one; 2.1.5 Conclusion; References
2.2 Catalytic, asymmetric synthesis of a,a-disubstituted amino acids using a chiral copper-salen complex as a phase transfer catalyst2.2.1 Synthesis of (chsalen); 2.2.2 Synthesis of copper(II) (chsalen); 2.2.3 Alkylation of alanine methyl ester Schiff base by chiral salen-metal catalysts, a-benzyl-alanine methyl ester; 2.2.4 Conclusion; References; 2.3 Asymmetric phase-transfer catalysed alkylation of glycine imines using cinchona alkaloid derived quaternary ammonium salts
2.3.1 Synthesis of (1S,2S,4S,5R,1 ́R)-1-(anthracen-9-ylmethyl)-5-ethyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azoniabicyclo[2.2.2]octane bromide2.3.2 Synthesis of (1S,2S,4S,5R,1 ́R)-1-(anthracen-9-ylmethyl)-5-ethyl-2-[benzyloxy(quinolin-4-yl)methyl]-1-azoniabicyclo[2.2.2]octane bromide; 2.3.3 Synthesis of (2S)-tert-butyl 2-amino-4-bromopent-4-enoate; 2.3.4 Conclusion; References; 3 Asymmetric Alkylation or Amination of Allylic Esters; 3.1 Synthesis and application in palladium-catalysed asymmetric allylic substitution of enantiopure cyclic b-iminophosphine ligands
3.1.1 Synthesis of (2,6-dimethyl-phenyl)-(1-phenyl-2,3,3a,8a-tetrahydro-1H-1-phospha-cyclopenta[a]inden-8-ylidene)-amines 1R(p)3.1.2 Synthesis of (E)-Methyl 2-carbomethoxy-3,5-diphenylpent-4-enoate; 3.1.3 Synthesis of benzyl(1,3-diphenylprop-2-enyl)amine; 3.1.4 Conclusion; References; 3.2 (9H,9 ́H,10H,10 ́H,11H,11H ́,13H,13 ́H,14H,14 ́H,15H,15 ́H-perfluorotricosane-12,12 ́-diyl)bis[(4S)-4-phenyl-2-oxazoline as a ligand for asymmetric palladium-catalysed alkylation of allylic acetates in fluorous media; 3.2.1 Synthesis of 2-iodo-1-(1H,1 ́H,2H,2 ́H,3H,3 ́H-perfluorooctyl)-3-propanol
3.2.2 Synthesis of 3-(1H,1 ́H,2H,2 ́H,3H,3 ́H-perfluorooctyl)-1-propanol
Record Nr. UNINA-9910144299903321
Chichester, West Sussex, England ; ; Hoboken, N.J., : John Wiley, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Metal catalysed carbon-carbon bond-forming reactions [[electronic resource] /] / edited by Stanley M. Roberts ... [et al.]
Metal catalysed carbon-carbon bond-forming reactions [[electronic resource] /] / edited by Stanley M. Roberts ... [et al.]
Pubbl/distr/stampa Chichester, West Sussex, England ; ; Hoboken, N.J., : John Wiley, c2004
Descrizione fisica 1 online resource (282 p.)
Disciplina 660
660.28443
660.2995
Altri autori (Persone) RobertsStanley M
Collana Catalysts for fine chemical synthesis
Soggetto topico Organic compounds - Synthesis
Metal catalysts
Chemical bonds
ISBN 1-280-27141-8
9786610271412
0-470-34184-X
0-470-86201-7
0-470-86200-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Catalysts for Fine Chemical Synthesis Volume 3; Contents; Series Preface; Preface to Volume 3; Abbreviations; List of Chemical Names Used; 1 Considerations of Industrial Fine Chemical Synthesis; 1.1 Introduction; 1.2 Types of processes - flow charts; 1.2.1 Classical process; 1.2.2 General catalytic process; 1.3 Costs associated with use of catalysts; 1.3.1 Catalyst fabrication costs; 1.3.2 Intellectual property right (IPR) issues; 1.3.3 Separation costs; 1.3.4 Pre-reaction/immobilisation; 1.3.5 Post reaction - separation; 1.3.6 Industrial examples; References
2 Alkylation and Allylation Adjacent to a Carbonyl Group2.1 The RuH(2)(CO)(PPh(3))(3)-catalysed alkylation, alkenylation and arylation of aromatic ketones via carbon-hydrogen bond cleavage; 2.1.1 Preparation of carbonyldihydrotris(triphenylphosphine) ruthenium; 2.1.2 Synthesis of 8-(2-triethoxysilanylethyl)-3,4-dihydro-2H-naphthalen-1-one; 2.1.3 Synthesis of 8-(1-methyl-2-trimethylsilanylvinyl)-3,4-dihydro-2H-naphthalen-1-one; 2.1.4 Synthesis of 1-biphenyl-2-yl-2,2-dimethylpropan-1-one; 2.1.5 Conclusion; References
2.2 Catalytic, asymmetric synthesis of a,a-disubstituted amino acids using a chiral copper-salen complex as a phase transfer catalyst2.2.1 Synthesis of (chsalen); 2.2.2 Synthesis of copper(II) (chsalen); 2.2.3 Alkylation of alanine methyl ester Schiff base by chiral salen-metal catalysts, a-benzyl-alanine methyl ester; 2.2.4 Conclusion; References; 2.3 Asymmetric phase-transfer catalysed alkylation of glycine imines using cinchona alkaloid derived quaternary ammonium salts
2.3.1 Synthesis of (1S,2S,4S,5R,1 ́R)-1-(anthracen-9-ylmethyl)-5-ethyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azoniabicyclo[2.2.2]octane bromide2.3.2 Synthesis of (1S,2S,4S,5R,1 ́R)-1-(anthracen-9-ylmethyl)-5-ethyl-2-[benzyloxy(quinolin-4-yl)methyl]-1-azoniabicyclo[2.2.2]octane bromide; 2.3.3 Synthesis of (2S)-tert-butyl 2-amino-4-bromopent-4-enoate; 2.3.4 Conclusion; References; 3 Asymmetric Alkylation or Amination of Allylic Esters; 3.1 Synthesis and application in palladium-catalysed asymmetric allylic substitution of enantiopure cyclic b-iminophosphine ligands
3.1.1 Synthesis of (2,6-dimethyl-phenyl)-(1-phenyl-2,3,3a,8a-tetrahydro-1H-1-phospha-cyclopenta[a]inden-8-ylidene)-amines 1R(p)3.1.2 Synthesis of (E)-Methyl 2-carbomethoxy-3,5-diphenylpent-4-enoate; 3.1.3 Synthesis of benzyl(1,3-diphenylprop-2-enyl)amine; 3.1.4 Conclusion; References; 3.2 (9H,9 ́H,10H,10 ́H,11H,11H ́,13H,13 ́H,14H,14 ́H,15H,15 ́H-perfluorotricosane-12,12 ́-diyl)bis[(4S)-4-phenyl-2-oxazoline as a ligand for asymmetric palladium-catalysed alkylation of allylic acetates in fluorous media; 3.2.1 Synthesis of 2-iodo-1-(1H,1 ́H,2H,2 ́H,3H,3 ́H-perfluorooctyl)-3-propanol
3.2.2 Synthesis of 3-(1H,1 ́H,2H,2 ́H,3H,3 ́H-perfluorooctyl)-1-propanol
Record Nr. UNINA-9910831084803321
Chichester, West Sussex, England ; ; Hoboken, N.J., : John Wiley, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Metal catalysed carbon-carbon bond-forming reactions / / edited by Stanley M. Roberts ... [et al.]
Metal catalysed carbon-carbon bond-forming reactions / / edited by Stanley M. Roberts ... [et al.]
Pubbl/distr/stampa Chichester, West Sussex, England ; ; Hoboken, N.J., : John Wiley, c2004
Descrizione fisica 1 online resource (282 p.)
Disciplina 547.215
Altri autori (Persone) RobertsStanley M
Collana Catalysts for fine chemical synthesis
Soggetto topico Organic compounds - Synthesis
Metal catalysts
Chemical bonds
ISBN 1-280-27141-8
9786610271412
0-470-34184-X
0-470-86201-7
0-470-86200-9
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Catalysts for Fine Chemical Synthesis Volume 3; Contents; Series Preface; Preface to Volume 3; Abbreviations; List of Chemical Names Used; 1 Considerations of Industrial Fine Chemical Synthesis; 1.1 Introduction; 1.2 Types of processes - flow charts; 1.2.1 Classical process; 1.2.2 General catalytic process; 1.3 Costs associated with use of catalysts; 1.3.1 Catalyst fabrication costs; 1.3.2 Intellectual property right (IPR) issues; 1.3.3 Separation costs; 1.3.4 Pre-reaction/immobilisation; 1.3.5 Post reaction - separation; 1.3.6 Industrial examples; References
2 Alkylation and Allylation Adjacent to a Carbonyl Group2.1 The RuH(2)(CO)(PPh(3))(3)-catalysed alkylation, alkenylation and arylation of aromatic ketones via carbon-hydrogen bond cleavage; 2.1.1 Preparation of carbonyldihydrotris(triphenylphosphine) ruthenium; 2.1.2 Synthesis of 8-(2-triethoxysilanylethyl)-3,4-dihydro-2H-naphthalen-1-one; 2.1.3 Synthesis of 8-(1-methyl-2-trimethylsilanylvinyl)-3,4-dihydro-2H-naphthalen-1-one; 2.1.4 Synthesis of 1-biphenyl-2-yl-2,2-dimethylpropan-1-one; 2.1.5 Conclusion; References
2.2 Catalytic, asymmetric synthesis of a,a-disubstituted amino acids using a chiral copper-salen complex as a phase transfer catalyst2.2.1 Synthesis of (chsalen); 2.2.2 Synthesis of copper(II) (chsalen); 2.2.3 Alkylation of alanine methyl ester Schiff base by chiral salen-metal catalysts, a-benzyl-alanine methyl ester; 2.2.4 Conclusion; References; 2.3 Asymmetric phase-transfer catalysed alkylation of glycine imines using cinchona alkaloid derived quaternary ammonium salts
2.3.1 Synthesis of (1S,2S,4S,5R,1 ́R)-1-(anthracen-9-ylmethyl)-5-ethyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azoniabicyclo[2.2.2]octane bromide2.3.2 Synthesis of (1S,2S,4S,5R,1 ́R)-1-(anthracen-9-ylmethyl)-5-ethyl-2-[benzyloxy(quinolin-4-yl)methyl]-1-azoniabicyclo[2.2.2]octane bromide; 2.3.3 Synthesis of (2S)-tert-butyl 2-amino-4-bromopent-4-enoate; 2.3.4 Conclusion; References; 3 Asymmetric Alkylation or Amination of Allylic Esters; 3.1 Synthesis and application in palladium-catalysed asymmetric allylic substitution of enantiopure cyclic b-iminophosphine ligands
3.1.1 Synthesis of (2,6-dimethyl-phenyl)-(1-phenyl-2,3,3a,8a-tetrahydro-1H-1-phospha-cyclopenta[a]inden-8-ylidene)-amines 1R(p)3.1.2 Synthesis of (E)-Methyl 2-carbomethoxy-3,5-diphenylpent-4-enoate; 3.1.3 Synthesis of benzyl(1,3-diphenylprop-2-enyl)amine; 3.1.4 Conclusion; References; 3.2 (9H,9 ́H,10H,10 ́H,11H,11H ́,13H,13 ́H,14H,14 ́H,15H,15 ́H-perfluorotricosane-12,12 ́-diyl)bis[(4S)-4-phenyl-2-oxazoline as a ligand for asymmetric palladium-catalysed alkylation of allylic acetates in fluorous media; 3.2.1 Synthesis of 2-iodo-1-(1H,1 ́H,2H,2 ́H,3H,3 ́H-perfluorooctyl)-3-propanol
3.2.2 Synthesis of 3-(1H,1 ́H,2H,2 ́H,3H,3 ́H-perfluorooctyl)-1-propanol
Record Nr. UNINA-9910877843903321
Chichester, West Sussex, England ; ; Hoboken, N.J., : John Wiley, c2004
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Regio- and stereo-controlled oxidations and reductions [[electronic resource] /] / edited by Stanley M. Roberts, John Whittall
Regio- and stereo-controlled oxidations and reductions [[electronic resource] /] / edited by Stanley M. Roberts, John Whittall
Pubbl/distr/stampa Chichester, England ; ; Hoboken, NJ, : John Wiley, c2007
Descrizione fisica 1 online resource (336 p.)
Disciplina 547.215
547/.23
Altri autori (Persone) RobertsStanley M
WhittallJohn
Collana Catalysts for fine chemical synthesis
Soggetto topico Oxidation
Reduction (Chemistry)
Organic compounds - Synthesis
Catalysts
ISBN 1-281-03233-6
9786611032333
0-470-09024-3
0-470-09023-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Catalysts for Fine Chemical Synthesis; Contents; Series Preface.; Preface to Volume 5; Abbreviations; 1 Industrial Catalysts for Regio- or Stereo-Selective Oxidations and Reductions A Review of Key Technologies and Targets; 1.1 Introduction; 1.2 Reduction of Carbon-Carbon Double Bonds; 1.2.1 Privileged structures: a-amino acids and itaconic acids; 1.2.2 b-Amino acids; 1.2.3 a-Alkyl substituted acids; 1.2.4 a-Alkoxy substituted acids; 1.2.5 Unsaturated nitriles; 1.2.6 Alkenes and allyl alcohols; 1.2.7 a,b-Unsaturated aldehyde reduction.; 1.3 Ketone and Imine Reduction
1.3.1 Catalytic hydrogenation of ketones and imines1.3.2 Asymmetric transfer hydrogenation (ATH) catalysts; 1.3.3 Modified borane reagents; 1.3.4 Biocatalysts (alcohol dehydrogenases and ketoreductases); 1.4 Oxidation; 1.4.1 Sharpless chiral epoxidation of allyl alcohols; 1.4.2 Dioxirane catalyzed epoxidation; 1.4.3 Amines and iminium salts; 1.4.4 Phase transfer catalysts; 1.4.5 The Julia ́-Colonna method (polyleucine oxidation); 1.4.6 Organocatalytic alfa-hydroxylation of ketones; 1.4.7 Baeyer-Villiger oxidation.; 1.4.8 Chiral sulfoxides.; References
2 Asymmetric Hydrogenation of Alkenes, Enones, Ene-Esters and Ene-Acids2.1 (S)-2,20-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,50,6,60,7,70,8,80-octahydro-1,10-binaphthyl as a ligand for rhodium-catalyzed asymmetric hydrogenation; 2.1.1 Synthesis of (S)-5,50,6,60,7,70,8,80-Octahydro-1,10-bi-2-naphthol; 2.1.2 Synthesis of (S)-2,20-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,50,6,60,7,70,8,80-octahydro-1,10-binaphthyl.; 2.1.3 Asymmetric hydrogenation of Dimethyl itaconate; Conclusion; References
2.2 Synthesis and application of phosphinite oxazoline iridium complexes for the asymmetric hydrogenation of alkenes2.2.1 Synthesis of (4S,5S)-2-(5-Methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-propan-2-ol; 2.2.2 Synthesis of (4S,5S)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenyl-ethyl]-diphenylphosphinite; 2.2.3 Synthesis of (4S,5S)-[(Z4-1,5-Cyclooctadiene)-{2-(2-phenyl-5-methyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-2-diphenylphosphinite-propane}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 2.2.4 Asymmetric hydrogenation of trans-a-Methylstilbene
Conclusion.References; 2.3 Synthesis and application of heterocyclic phosphine oxazoline (HetPHOX) iridium complexes for the asymmetric hydrogenation of alkenes; 2.3.3 Synthesis of (4S)-[(Z4-1,5-Cyclooctadiene)-{4-tert-butyl-2-(3-diphenylphosphino-thiophene-2-yl)-4,5-dihydrooxazole}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 2.3.4 Asymmetric hydrogenation of trans-a-Methylstilbene; Conclusion; 2.3.1 Synthesis of (4S)-tert-Butyl-2-(thiophene-2-yl)-4,5-dihydrooxazole; 2.3.2 Synthesis of (4S)-tert-Butyl-2-(3-diphenylphosphinothiophene-2-yl)-4,5-dihydrooxazole; References
2.4 (R)-2,20,6,60-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphino]-3,30-bipyridine [(R)-Xyl-P-Phos] as a ligand for rhodiumcatalyzed asymmetric hydrogenation of a-dehydroamino acids.
Record Nr. UNINA-9910144722603321
Chichester, England ; ; Hoboken, NJ, : John Wiley, c2007
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Regio- and stereo-controlled oxidations and reductions [[electronic resource] /] / edited by Stanley M. Roberts, John Whittall
Regio- and stereo-controlled oxidations and reductions [[electronic resource] /] / edited by Stanley M. Roberts, John Whittall
Pubbl/distr/stampa Chichester, England ; ; Hoboken, NJ, : John Wiley, c2007
Descrizione fisica 1 online resource (336 p.)
Disciplina 547.215
547/.23
Altri autori (Persone) RobertsStanley M
WhittallJohn
Collana Catalysts for fine chemical synthesis
Soggetto topico Oxidation
Reduction (Chemistry)
Organic compounds - Synthesis
Catalysts
ISBN 1-281-03233-6
9786611032333
0-470-09024-3
0-470-09023-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Catalysts for Fine Chemical Synthesis; Contents; Series Preface.; Preface to Volume 5; Abbreviations; 1 Industrial Catalysts for Regio- or Stereo-Selective Oxidations and Reductions A Review of Key Technologies and Targets; 1.1 Introduction; 1.2 Reduction of Carbon-Carbon Double Bonds; 1.2.1 Privileged structures: a-amino acids and itaconic acids; 1.2.2 b-Amino acids; 1.2.3 a-Alkyl substituted acids; 1.2.4 a-Alkoxy substituted acids; 1.2.5 Unsaturated nitriles; 1.2.6 Alkenes and allyl alcohols; 1.2.7 a,b-Unsaturated aldehyde reduction.; 1.3 Ketone and Imine Reduction
1.3.1 Catalytic hydrogenation of ketones and imines1.3.2 Asymmetric transfer hydrogenation (ATH) catalysts; 1.3.3 Modified borane reagents; 1.3.4 Biocatalysts (alcohol dehydrogenases and ketoreductases); 1.4 Oxidation; 1.4.1 Sharpless chiral epoxidation of allyl alcohols; 1.4.2 Dioxirane catalyzed epoxidation; 1.4.3 Amines and iminium salts; 1.4.4 Phase transfer catalysts; 1.4.5 The Julia ́-Colonna method (polyleucine oxidation); 1.4.6 Organocatalytic alfa-hydroxylation of ketones; 1.4.7 Baeyer-Villiger oxidation.; 1.4.8 Chiral sulfoxides.; References
2 Asymmetric Hydrogenation of Alkenes, Enones, Ene-Esters and Ene-Acids2.1 (S)-2,20-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,50,6,60,7,70,8,80-octahydro-1,10-binaphthyl as a ligand for rhodium-catalyzed asymmetric hydrogenation; 2.1.1 Synthesis of (S)-5,50,6,60,7,70,8,80-Octahydro-1,10-bi-2-naphthol; 2.1.2 Synthesis of (S)-2,20-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,50,6,60,7,70,8,80-octahydro-1,10-binaphthyl.; 2.1.3 Asymmetric hydrogenation of Dimethyl itaconate; Conclusion; References
2.2 Synthesis and application of phosphinite oxazoline iridium complexes for the asymmetric hydrogenation of alkenes2.2.1 Synthesis of (4S,5S)-2-(5-Methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-propan-2-ol; 2.2.2 Synthesis of (4S,5S)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenyl-ethyl]-diphenylphosphinite; 2.2.3 Synthesis of (4S,5S)-[(Z4-1,5-Cyclooctadiene)-{2-(2-phenyl-5-methyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-2-diphenylphosphinite-propane}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 2.2.4 Asymmetric hydrogenation of trans-a-Methylstilbene
Conclusion.References; 2.3 Synthesis and application of heterocyclic phosphine oxazoline (HetPHOX) iridium complexes for the asymmetric hydrogenation of alkenes; 2.3.3 Synthesis of (4S)-[(Z4-1,5-Cyclooctadiene)-{4-tert-butyl-2-(3-diphenylphosphino-thiophene-2-yl)-4,5-dihydrooxazole}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 2.3.4 Asymmetric hydrogenation of trans-a-Methylstilbene; Conclusion; 2.3.1 Synthesis of (4S)-tert-Butyl-2-(thiophene-2-yl)-4,5-dihydrooxazole; 2.3.2 Synthesis of (4S)-tert-Butyl-2-(3-diphenylphosphinothiophene-2-yl)-4,5-dihydrooxazole; References
2.4 (R)-2,20,6,60-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphino]-3,30-bipyridine [(R)-Xyl-P-Phos] as a ligand for rhodiumcatalyzed asymmetric hydrogenation of a-dehydroamino acids.
Record Nr. UNINA-9910829848003321
Chichester, England ; ; Hoboken, NJ, : John Wiley, c2007
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Regio- and stereo-controlled oxidations and reductions / / edited by Stanley M. Roberts, John Whittall
Regio- and stereo-controlled oxidations and reductions / / edited by Stanley M. Roberts, John Whittall
Pubbl/distr/stampa Chichester, England ; ; Hoboken, NJ, : John Wiley, c2007
Descrizione fisica 1 online resource (336 p.)
Disciplina 547/.23
Altri autori (Persone) RobertsStanley M
WhittallJohn
Collana Catalysts for fine chemical synthesis
Soggetto topico Oxidation
Reduction (Chemistry)
Organic compounds - Synthesis
Catalysts
ISBN 1-281-03233-6
9786611032333
0-470-09024-3
0-470-09023-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Catalysts for Fine Chemical Synthesis; Contents; Series Preface.; Preface to Volume 5; Abbreviations; 1 Industrial Catalysts for Regio- or Stereo-Selective Oxidations and Reductions A Review of Key Technologies and Targets; 1.1 Introduction; 1.2 Reduction of Carbon-Carbon Double Bonds; 1.2.1 Privileged structures: a-amino acids and itaconic acids; 1.2.2 b-Amino acids; 1.2.3 a-Alkyl substituted acids; 1.2.4 a-Alkoxy substituted acids; 1.2.5 Unsaturated nitriles; 1.2.6 Alkenes and allyl alcohols; 1.2.7 a,b-Unsaturated aldehyde reduction.; 1.3 Ketone and Imine Reduction
1.3.1 Catalytic hydrogenation of ketones and imines1.3.2 Asymmetric transfer hydrogenation (ATH) catalysts; 1.3.3 Modified borane reagents; 1.3.4 Biocatalysts (alcohol dehydrogenases and ketoreductases); 1.4 Oxidation; 1.4.1 Sharpless chiral epoxidation of allyl alcohols; 1.4.2 Dioxirane catalyzed epoxidation; 1.4.3 Amines and iminium salts; 1.4.4 Phase transfer catalysts; 1.4.5 The Julia ́-Colonna method (polyleucine oxidation); 1.4.6 Organocatalytic alfa-hydroxylation of ketones; 1.4.7 Baeyer-Villiger oxidation.; 1.4.8 Chiral sulfoxides.; References
2 Asymmetric Hydrogenation of Alkenes, Enones, Ene-Esters and Ene-Acids2.1 (S)-2,20-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,50,6,60,7,70,8,80-octahydro-1,10-binaphthyl as a ligand for rhodium-catalyzed asymmetric hydrogenation; 2.1.1 Synthesis of (S)-5,50,6,60,7,70,8,80-Octahydro-1,10-bi-2-naphthol; 2.1.2 Synthesis of (S)-2,20-Bis{[di(4-methoxyphenyl)phosphinyl]oxy}-5,50,6,60,7,70,8,80-octahydro-1,10-binaphthyl.; 2.1.3 Asymmetric hydrogenation of Dimethyl itaconate; Conclusion; References
2.2 Synthesis and application of phosphinite oxazoline iridium complexes for the asymmetric hydrogenation of alkenes2.2.1 Synthesis of (4S,5S)-2-(5-Methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-propan-2-ol; 2.2.2 Synthesis of (4S,5S)-O-[1-Benzyl-1-(5-methyl-2-phenyl-4,5-dihydro-oxazol-4-yl)-2-phenyl-ethyl]-diphenylphosphinite; 2.2.3 Synthesis of (4S,5S)-[(Z4-1,5-Cyclooctadiene)-{2-(2-phenyl-5-methyl-4,5-dihydro-oxazol-4-yl)-1,3-diphenyl-2-diphenylphosphinite-propane}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 2.2.4 Asymmetric hydrogenation of trans-a-Methylstilbene
Conclusion.References; 2.3 Synthesis and application of heterocyclic phosphine oxazoline (HetPHOX) iridium complexes for the asymmetric hydrogenation of alkenes; 2.3.3 Synthesis of (4S)-[(Z4-1,5-Cyclooctadiene)-{4-tert-butyl-2-(3-diphenylphosphino-thiophene-2-yl)-4,5-dihydrooxazole}iridium(I)]-tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; 2.3.4 Asymmetric hydrogenation of trans-a-Methylstilbene; Conclusion; 2.3.1 Synthesis of (4S)-tert-Butyl-2-(thiophene-2-yl)-4,5-dihydrooxazole; 2.3.2 Synthesis of (4S)-tert-Butyl-2-(3-diphenylphosphinothiophene-2-yl)-4,5-dihydrooxazole; References
2.4 (R)-2,20,6,60-Tetramethoxy-bis[di(3,5-dimethylphenyl)phosphino]-3,30-bipyridine [(R)-Xyl-P-Phos] as a ligand for rhodiumcatalyzed asymmetric hydrogenation of a-dehydroamino acids.
Record Nr. UNINA-9910876841603321
Chichester, England ; ; Hoboken, NJ, : John Wiley, c2007
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui