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Halogen Bonding I : Impact on Materials Chemistry and Life Sciences / / edited by Pierangelo Metrangolo, Giuseppe Resnati
| Halogen Bonding I : Impact on Materials Chemistry and Life Sciences / / edited by Pierangelo Metrangolo, Giuseppe Resnati |
| Edizione | [1st ed. 2015.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015 |
| Descrizione fisica | 1 online resource (IX, 280 p. 191 illus., 83 illus. in color.) |
| Disciplina | 546 |
| Collana | Topics in Current Chemistry |
| Soggetto topico |
Inorganic chemistry
Organic chemistry Medicinal chemistry Inorganic Chemistry Organic Chemistry Medicinal Chemistry |
| ISBN | 3-319-14057-4 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | From the Contents: The nature and directionality of halogen bonding; the sigma hole -- Solid-state NMR study of halogen-bonded adducts -- Infrared and Raman measurements of halogen bonding in cryogenic solutions -- Halogen bonding in the gas phase -- Halogen bonding in solution -- Unconventional motifs for halogen bonding. |
| Record Nr. | UNINA-9910298625903321 |
| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Halogen Bonding II : Impact on Materials Chemistry and Life Sciences / / edited by Pierangelo Metrangolo, Giuseppe Resnati
| Halogen Bonding II : Impact on Materials Chemistry and Life Sciences / / edited by Pierangelo Metrangolo, Giuseppe Resnati |
| Edizione | [1st ed. 2015.] |
| Pubbl/distr/stampa | Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015 |
| Descrizione fisica | 1 online resource (IX, 208 p. 130 illus., 66 illus. in color.) |
| Disciplina | 546.73 |
| Collana | Topics in Current Chemistry |
| Soggetto topico |
Inorganic chemistry
Organic chemistry Medicinal chemistry Inorganic Chemistry Organic Chemistry Medicinal Chemistry |
| ISBN | 3-319-15732-9 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Intro -- Preface -- References -- Contents -- Characteristics of a sigma-Hole and the Nature of a Halogen Bond -- 1 Introduction -- 2 Methods -- 2.1 Isolated Subsystems -- 2.2 SAPT Decomposition -- 2.3 Complexes -- 3 Results and Discussion -- 3.1 Halogenated Molecules -- 3.2 Complexes -- 4 Conclusions -- References -- Anion Recognition in Solution via Halogen Bonding -- 1 Introduction -- 2 Interactions of Anions with Monodentate Halogen Bond Donors -- 2.1 Molecular Halogen or Interhalogen Donors -- 2.2 Monodentate Haloorganic Donors -- 3 Multidentate Halogen Bond Donors as Anion Receptors -- 4 Anion Recognition with Cationic Halogen Bond Donors -- 5 Anion Recognition Through Combinations of Halogen and Hydrogen Bonding -- 6 Summary, Conclusions, and Outlook -- References -- Halogen Bonding in Solution -- 1 Introduction -- 2 Neutral, Two-Center Halogen Bond Complexes -- 3 Charged, Two-Center Halogen Bond Complexes -- 4 Neutral, Three-Center Halogen Bond Complexes -- 5 Charged, Three-Center Halogen Bond Complexes -- 6 Conclusions and Outlook -- 7 Addendum -- References -- Halonium Ions as Halogen Bond Donors in the Solid State [XL2]Y Complexes -- 1 Introduction -- 1.1 Halogen Bond: The Long Lost Brother of the Hydrogen Bond -- 1.2 . or Simply a Charge Transfer Interaction? -- 2 Halonium-Nitrogen Complexes -- 2.1 Aromatic sp2 Nitrogen -- 2.2 Halonium to sp and Other sp2 Nitrogens -- 2.3 Halonium to sp3 Nitrogens -- 3 Halonium-Sulfur Complexes -- 4 Halonium-Selenium and Halonium-Tellurium Complexes -- References -- Organizing Radical Species in the Solid State with Halogen Bonding -- 1 Introduction -- 2 Radicals as Halogen Bond Donors -- 2.1 Halogenated Trioxytriangulene Radical -- 2.2 TTF Radical Cations Salts: Toward Chiral Conductors -- 2.2.1 IodoTTFs with Non-centrosymmetric ClO4- Anion -- 2.2.2 IodoTTFs with Halogen Bonding to Chiral Anions.
2.2.3 Chiral IodoTTF Salts -- 2.3 Paramagnetic Metal Complexes with Halogenated Ligands -- 2.3.1 Halopyridine Complexes of Metal Halides -- 2.3.2 Spin Crossover Cooperativity and Halogen Bonding -- 3 Radicals as Halogen Bond Acceptors -- 3.1 Nitronyl Radicals -- 3.2 Metal Complexes with Essentially Metallic Spin Density -- 3.3 Metal Complexes with Non-innocent Ligands -- 4 Halogen-Bonded Charge Transfer Salts -- 5 Summary, Conclusions, and Outlook -- References -- Halogen Bonding in the Design of Organic Phosphors -- 1 Introduction -- 2 New Strategy of Introducing Metal-Free Heavy Atom Perturber by Halogen Bonding in Defined Stoichiometry -- 2.1 Halogen Bonding Acceptors as Phosphors -- 2.2 Donors as Heavy Atom Perturbing Sources -- 2.3 Advantages of Halogen Bonding -- 3 Phosphorescent Cocrystals Assembled by the New Strategy -- 3.1 Structural Features of Cocrystals -- 3.1.1 Cocrystals by PAHs and Haloperfluorobenzenes -- 3.1.2 Cocrystals by Fluorene and Its Heterocyclic Analogues and Haloperfluorobenzenes -- 3.2 Phosphorescent Properties of Cocrystals -- 3.2.1 Emission from PAHs in Cocrystals -- 3.2.2 Emission from Fluorene or Its Heterocyclic Analogues in Cocrystals -- 4 Concluding Remarks -- References -- Halogen-Bonded Photoresponsive Materials -- 1 Preface -- 2 Introduction to Azobenzene -- 3 Photoinduced Surface Patterning in Azopolymers: What Does Halogen Bonding Have to Offer? -- 4 Photoactive Halogen-Bonded Liquid Crystals -- 5 Halogen-Bonded Crystals That Move -- 6 Conclusions -- References -- Halogen Bonds in Organic Synthesis and Organocatalysis -- 1 Hydrogen Bonding in Non-covalent Organocatalysis -- 2 Halogen Bonding in Organic Synthesis and Non-covalent Organocatalysis -- 2.1 Further Directional Interaction: Halogen Bonding -- 2.2 Overview and Scope -- 2.3 Solely-Halogen-Based Halogen-Bond Donors -- 2.3.1 Elemental Halogens. 2.3.2 Interhalogen Compounds -- 2.4 N-X-Based Halogen-Bond Donors -- 2.5 C-X-Based Halogen-Bond Donors -- 2.5.1 Monodentate Halogen-Bond Donors -- 2.5.2 Multidentate Halogen-Bond Donors -- Proof-of-Principle Reaction -- Isothermal Calorimetric Titrations -- Halopyridinium-Based Halogen-Bond Donors as Activators -- Triazolium-Based Halogen-Bond Donors as Activators -- Polyfluorinated Azo-Bridged Halogen-Bond Donors -- Polyfluorinated Halogen-Bond Donors as Organocatalysts -- 3 Summary and Outlook -- References -- Index. |
| Record Nr. | UNINA-9910298608903321 |
| Cham : , : Springer International Publishing : , : Imprint : Springer, , 2015 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||