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1,1'-binaphthyl-based chiral materials [[electronic resource] ] : our journey / / Lin Pu
| 1,1'-binaphthyl-based chiral materials [[electronic resource] ] : our journey / / Lin Pu |
| Autore | Pu Lin <1965-> |
| Pubbl/distr/stampa | London, : Imperial College Press, c2010 |
| Descrizione fisica | 1 online resource (346 p.) |
| Disciplina | 547 |
| Soggetto topico |
Chirality
Asymmetric synthesis Molecular theory |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-75993-0
9786612759932 1-84816-412-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Preface; Contents; References; 1. Introduction About 1,1 -Binaphthyls; References; 2. Main Chain Chiral-Conjugated Polymers; 2.1. Introduction About Chiral-Conjugated Polymers; 2.2. Binaphthyl-Based Polyarylenevinylenes; 2.3. Binaphthyl-Based Polyarylenes; 2.4. Binaphthyl-Based Polyaryleneethynylenes; 2.5. Binaphthyl-Thiophene Copolymers; 2.5.1. Copolymerization of Binaphthyl and Oligothiophene Monomers; 2.5.2. Electroluminescence Study; 2.6. Copolymers of BINAM and Thiophene-Containing Conjugated Linkers; 2.7. Polybinaphthyls Without Conjugated Linkers
2.7.1. Using Nickel Complexes to Promote Polymerization212.7.2. Synthesis of the Binaphthyl-Based Polydendrimers by Using Ni Complexes to Promote Polymerization23; 2.7.3. Using the Suzuki Coupling Reaction for Polymerization21b; 2.7.4. Electroluminescence Study of the Polybinaphthyls26; 2.8. Propeller-Like Polybinaphthyls; 2.8.1. Synthesis of the Propeller-Like Polymers Derived from BINOL27,28; 2.8.2. Synthesis of the Propeller-Like Polymers Derived from BINAM31; 2.8.3. Study of the Non-linear Optical Properties of the Propeller-Like Polymers32; 2.9. Dipole-Oriented Propeller-Like Polymers 2.10. Binaphthyl-Based Polysalophens2.11. Helical Ladder Polybinaphthyls; References; 3. Polybinaphthyls in Asymmetric Catalysis; 3.1. Introduction about Chiral Polymers in Asymmetric Catalysis; 3.2. Synthesis of Major-Groove Poly(BINOL)s; 3.2.1. Synthesis of Polybinaphthyls with Various Protecting Groups5; 3.2.2. Hydrolysis of the Polybinaphthyls to Generate Poly(BINOL)s5; 3.2.3. Synthesis of Poly(BINOL)s Containing Alkyl-Substituted Phenylene Linkers6; 3.3. Application of the Major-Groove Poly(BINOL)s to Catalyze the Mukaiyama Aldol Reaction 3.4. Application of the Major-Groove Poly(BINOL)s to Catalyze the Hetero-Diels-Alder Reaction3.5. Using the Ti(IV) Complex of the Major-Groove Poly(BINOL) to Catalyze the Diethylzinc Addition to Aldehydes; 3.6. Synthesis of the Minor-Groove Poly(BINOL)s; 3.7. Application of the Major- and Minor-Groove Poly(BINOL)s to Catalyze the Asymmetric Organozinc Addition to Aldehydes; 3.7.1. Asymmetric Diethylzinc Addition to Aldehydes Catalyzed by the Poly(BINOL)s; 3.7.2. Study of the Reactions of the Minor-Groove Poly(BINOL) and a Few Monomeric BINOL Derivatives with Diethylzinc 3.7.3. Synthesis of the Monomeric Model Compound of the Minor-Groove Poly(BINOL) to Catalyze the Dialkylzinc Addition to Aldehydes10b,c3.7.4. Converting the Highly Enantioselective Mono(BINOL) Catalyst to a Highly Enantioselective Poly(BINOL) Catalyst for the Asymmetric Organozinc Additions10; 3.8. Asymmetric Reduction of Prochiral Ketones Catalyzed by the Chiral BINOL Monomer and Polymer Catalysts; 3.9. Asymmetric Epoxidation of α, β-UnsaturatedKetones Catalyzed by the Minor- and Major-GroovePoly(BINOL)s 3.9.1. Asymmetric Epoxidation of α,β-Unsaturated Ketonesin the Presence of a Stoichiometric Amount of theMajor-Groove Poly(BINOL)s, Diethylzincand Oxygen |
| Record Nr. | UNINA-9910456159103321 |
Pu Lin <1965->
|
||
| London, : Imperial College Press, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
1,1'-binaphthyl-based chiral materials [[electronic resource] ] : our journey / / Lin Pu
| 1,1'-binaphthyl-based chiral materials [[electronic resource] ] : our journey / / Lin Pu |
| Autore | Pu Lin <1965-> |
| Pubbl/distr/stampa | London, : Imperial College Press, c2010 |
| Descrizione fisica | 1 online resource (346 p.) |
| Disciplina | 547 |
| Soggetto topico |
Chirality
Asymmetric synthesis Molecular theory |
| ISBN |
1-282-75993-0
9786612759932 1-84816-412-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Preface; Contents; References; 1. Introduction About 1,1 -Binaphthyls; References; 2. Main Chain Chiral-Conjugated Polymers; 2.1. Introduction About Chiral-Conjugated Polymers; 2.2. Binaphthyl-Based Polyarylenevinylenes; 2.3. Binaphthyl-Based Polyarylenes; 2.4. Binaphthyl-Based Polyaryleneethynylenes; 2.5. Binaphthyl-Thiophene Copolymers; 2.5.1. Copolymerization of Binaphthyl and Oligothiophene Monomers; 2.5.2. Electroluminescence Study; 2.6. Copolymers of BINAM and Thiophene-Containing Conjugated Linkers; 2.7. Polybinaphthyls Without Conjugated Linkers
2.7.1. Using Nickel Complexes to Promote Polymerization212.7.2. Synthesis of the Binaphthyl-Based Polydendrimers by Using Ni Complexes to Promote Polymerization23; 2.7.3. Using the Suzuki Coupling Reaction for Polymerization21b; 2.7.4. Electroluminescence Study of the Polybinaphthyls26; 2.8. Propeller-Like Polybinaphthyls; 2.8.1. Synthesis of the Propeller-Like Polymers Derived from BINOL27,28; 2.8.2. Synthesis of the Propeller-Like Polymers Derived from BINAM31; 2.8.3. Study of the Non-linear Optical Properties of the Propeller-Like Polymers32; 2.9. Dipole-Oriented Propeller-Like Polymers 2.10. Binaphthyl-Based Polysalophens2.11. Helical Ladder Polybinaphthyls; References; 3. Polybinaphthyls in Asymmetric Catalysis; 3.1. Introduction about Chiral Polymers in Asymmetric Catalysis; 3.2. Synthesis of Major-Groove Poly(BINOL)s; 3.2.1. Synthesis of Polybinaphthyls with Various Protecting Groups5; 3.2.2. Hydrolysis of the Polybinaphthyls to Generate Poly(BINOL)s5; 3.2.3. Synthesis of Poly(BINOL)s Containing Alkyl-Substituted Phenylene Linkers6; 3.3. Application of the Major-Groove Poly(BINOL)s to Catalyze the Mukaiyama Aldol Reaction 3.4. Application of the Major-Groove Poly(BINOL)s to Catalyze the Hetero-Diels-Alder Reaction3.5. Using the Ti(IV) Complex of the Major-Groove Poly(BINOL) to Catalyze the Diethylzinc Addition to Aldehydes; 3.6. Synthesis of the Minor-Groove Poly(BINOL)s; 3.7. Application of the Major- and Minor-Groove Poly(BINOL)s to Catalyze the Asymmetric Organozinc Addition to Aldehydes; 3.7.1. Asymmetric Diethylzinc Addition to Aldehydes Catalyzed by the Poly(BINOL)s; 3.7.2. Study of the Reactions of the Minor-Groove Poly(BINOL) and a Few Monomeric BINOL Derivatives with Diethylzinc 3.7.3. Synthesis of the Monomeric Model Compound of the Minor-Groove Poly(BINOL) to Catalyze the Dialkylzinc Addition to Aldehydes10b,c3.7.4. Converting the Highly Enantioselective Mono(BINOL) Catalyst to a Highly Enantioselective Poly(BINOL) Catalyst for the Asymmetric Organozinc Additions10; 3.8. Asymmetric Reduction of Prochiral Ketones Catalyzed by the Chiral BINOL Monomer and Polymer Catalysts; 3.9. Asymmetric Epoxidation of α, β-UnsaturatedKetones Catalyzed by the Minor- and Major-GroovePoly(BINOL)s 3.9.1. Asymmetric Epoxidation of α,β-Unsaturated Ketonesin the Presence of a Stoichiometric Amount of theMajor-Groove Poly(BINOL)s, Diethylzincand Oxygen |
| Record Nr. | UNINA-9910780725203321 |
|
Pu Lin <1965->
|
||
| London, : Imperial College Press, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||