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Discovering the future of molecular sciences / / edited by Bruno Pignataro
Discovering the future of molecular sciences / / edited by Bruno Pignataro
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH Verlag, , 2014
Descrizione fisica 1 online resource (435 p.)
Disciplina 572.0287
Soggetto topico Biotechnology - Data processing
Nanotechnology - Mathematical models
ISBN 3-527-67324-5
3-527-67322-9
3-527-67325-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Discovering the Future of Molecular Sciences; Contents; Preface; List of Contributors; Part I Advanced Methodologies; Chapter 1 Supramolecular Receptors for the Recognition of Bioanalytes; 1.1 Introduction; 1.2 Bioanalytes; 1.3 Metal Complexes as Receptors for Biological Phosphates; 1.3.1 Fluorescent Zn(II) Based Metal Complexes and Their Applications in Live Cell Imaging; 1.3.2 Chromogenic Zn(II)-Based Metal Receptors and Their Applications in Biological Cell Staining; 1.4 Functionalized Vesicles for the Recognition of Bioanalytes; 1.4.1 Polydiacetylene Based Chromatic Vesicles
1.4.1.1 PDA Based Receptors for Biological Phosphate1.4.1.2 PDA Based Receptors for Lipopolysaccharide; 1.4.1.3 PDA Based Receptors for Oligonucleotides and Nucleic Acids; 1.5 Boronic Acid Receptors for Diol-Containing Bioanalytes; 1.6 Conclusion and Outlook; Acknowledgment; References; Chapter 2 Methods of DNA Recognition; 2.1 Introduction; 2.2 Historical Outline: The Central Dogma; 2.3 Intermolecular Interaction between the Transcription Factors and the DNA; 2.3.1 The Structure of DNA and Its Role in the Recognition; 2.3.2 DNA Binding Domains of the TF
2.3.3 General Aspects of the Intermolecular Interactions between the TFs and the DNA2.4 Miniature Versions of Transcription Factors; 2.4.1 Synthetic Modification of bZIP Transcription Factors; 2.4.2 Residue Grafting; 2.4.3 Conjugation in Order to Develop DNA Binding Peptides; 2.5 Intermolecular Interaction Between Small Molecules and the DNA; 2.5.1 General Concepts; 2.5.2 Metallo-DNA Binders: From Cisplatin to Rh Metallo-Insertors; 2.5.3 Polypyrroles and Bis(benzamidine) Minor Groove Binders and Their Use as Specific dsDNA Sensors; 2.6 Outlook; Acknowledgments; References
Chapter 3 Structural Analysis of Complex Molecular Systems by High-Resolution and Tandem Mass Spectrometry3.1 Dissecting Molecular Complexity with Mass Spectrometry; 3.2 Advances in Fourier Transform Mass Spectrometry; 3.3 Advances in Mass Analyzers for FT-ICR MS; 3.4 Advances in Mass Analyzers for Orbitrap FTMS; 3.5 Applications of High-Resolution Mass Spectrometry; 3.6 Advances in Tandem Mass Spectrometry; 3.7 Outlook: Quo vadis FTMS?; 3.8 Summary and Future Issues; Acknowledgments; References
Chapter 4 Coherent Electronic Energy Transfer in Biological and Artificial Multichromophoric Systems4.1 Introduction to Electronic Energy Transfer in Complex Systems; 4.2 The Meaning of Electronic Coherence in Energy Transfer; 4.3 Energy Migration in Terms of Occupation Probability: a Unified Approach; 4.4 Experimental Detection of Quantum Coherence; 4.5 Electronic Coherence Measured by Two-Dimensional Photon Echo; 4.6 Future Perspectives and Conclusive Remarks; Acknowledgments; References; Chapter 5 Ultrafast Studies of Carrier Dynamics in Quantum Dots for Next Generation Photovoltaics
5.1 Introduction
Record Nr. UNINA-9910132197303321
Weinheim, Germany : , : Wiley-VCH Verlag, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Discovering the future of molecular sciences / / edited by Bruno Pignataro
Discovering the future of molecular sciences / / edited by Bruno Pignataro
Pubbl/distr/stampa Weinheim, Germany : , : Wiley-VCH Verlag, , 2014
Descrizione fisica 1 online resource (435 p.)
Disciplina 572.0287
Soggetto topico Biotechnology - Data processing
Nanotechnology - Mathematical models
ISBN 3-527-67324-5
3-527-67322-9
3-527-67325-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Discovering the Future of Molecular Sciences; Contents; Preface; List of Contributors; Part I Advanced Methodologies; Chapter 1 Supramolecular Receptors for the Recognition of Bioanalytes; 1.1 Introduction; 1.2 Bioanalytes; 1.3 Metal Complexes as Receptors for Biological Phosphates; 1.3.1 Fluorescent Zn(II) Based Metal Complexes and Their Applications in Live Cell Imaging; 1.3.2 Chromogenic Zn(II)-Based Metal Receptors and Their Applications in Biological Cell Staining; 1.4 Functionalized Vesicles for the Recognition of Bioanalytes; 1.4.1 Polydiacetylene Based Chromatic Vesicles
1.4.1.1 PDA Based Receptors for Biological Phosphate1.4.1.2 PDA Based Receptors for Lipopolysaccharide; 1.4.1.3 PDA Based Receptors for Oligonucleotides and Nucleic Acids; 1.5 Boronic Acid Receptors for Diol-Containing Bioanalytes; 1.6 Conclusion and Outlook; Acknowledgment; References; Chapter 2 Methods of DNA Recognition; 2.1 Introduction; 2.2 Historical Outline: The Central Dogma; 2.3 Intermolecular Interaction between the Transcription Factors and the DNA; 2.3.1 The Structure of DNA and Its Role in the Recognition; 2.3.2 DNA Binding Domains of the TF
2.3.3 General Aspects of the Intermolecular Interactions between the TFs and the DNA2.4 Miniature Versions of Transcription Factors; 2.4.1 Synthetic Modification of bZIP Transcription Factors; 2.4.2 Residue Grafting; 2.4.3 Conjugation in Order to Develop DNA Binding Peptides; 2.5 Intermolecular Interaction Between Small Molecules and the DNA; 2.5.1 General Concepts; 2.5.2 Metallo-DNA Binders: From Cisplatin to Rh Metallo-Insertors; 2.5.3 Polypyrroles and Bis(benzamidine) Minor Groove Binders and Their Use as Specific dsDNA Sensors; 2.6 Outlook; Acknowledgments; References
Chapter 3 Structural Analysis of Complex Molecular Systems by High-Resolution and Tandem Mass Spectrometry3.1 Dissecting Molecular Complexity with Mass Spectrometry; 3.2 Advances in Fourier Transform Mass Spectrometry; 3.3 Advances in Mass Analyzers for FT-ICR MS; 3.4 Advances in Mass Analyzers for Orbitrap FTMS; 3.5 Applications of High-Resolution Mass Spectrometry; 3.6 Advances in Tandem Mass Spectrometry; 3.7 Outlook: Quo vadis FTMS?; 3.8 Summary and Future Issues; Acknowledgments; References
Chapter 4 Coherent Electronic Energy Transfer in Biological and Artificial Multichromophoric Systems4.1 Introduction to Electronic Energy Transfer in Complex Systems; 4.2 The Meaning of Electronic Coherence in Energy Transfer; 4.3 Energy Migration in Terms of Occupation Probability: a Unified Approach; 4.4 Experimental Detection of Quantum Coherence; 4.5 Electronic Coherence Measured by Two-Dimensional Photon Echo; 4.6 Future Perspectives and Conclusive Remarks; Acknowledgments; References; Chapter 5 Ultrafast Studies of Carrier Dynamics in Quantum Dots for Next Generation Photovoltaics
5.1 Introduction
Record Nr. UNINA-9910818940403321
Weinheim, Germany : , : Wiley-VCH Verlag, , 2014
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ideas in chemistry and molecular sciences Advances in nanotechnology, materials and devices [[electronic resource] /] / edited by Bruno Pignataro
Ideas in chemistry and molecular sciences Advances in nanotechnology, materials and devices [[electronic resource] /] / edited by Bruno Pignataro
Pubbl/distr/stampa Weinheim, : Wiley-VCH, 2010
Descrizione fisica 1 online resource (434 p.)
Disciplina 540
Altri autori (Persone) PignataroBruno
Soggetto topico Chemistry
Nanotechnology - Technological innovations
Soggetto genere / forma Electronic books.
ISBN 1-283-14049-7
9786613140494
3-527-63053-8
3-527-63054-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ideas in Chemistry and Molecular Sciences; Contents; Preface; List of Contributors; Part I Preparation of New Materials and Nanomaterials; 1 Self-Assembling Cyclic Peptide-Based Nanomaterials; 1.1 Introduction; 1.2 Types of Self-Assembling Cyclic Peptide Nanotubes; 1.2.1 Nanotubular Assemblies from Cyclic D,L-α-Peptides; 1.2.1.1 Solid-State Ensembles: Microcrystalline Cyclic Peptide Nanotubes; 1.2.1.2 Solution Phase Studies of Dimerization; 1.2.2 Nanotubular Assemblies from Cyclic β-Peptides; 1.2.3 Nanotubular Assemblies from Other Cyclic Peptides; 1.3 Applications of Cyclic Peptide Nanotubes
1.3.1 Antimicrobials1.3.2 Biosensors; 1.3.3 Biomaterials; 1.3.4 Electronic Devices; 1.3.5 Photoswitchable Materials; 1.3.6 Transmembrane Transport Channels; 1.4 Nanotubular Assemblies from Cyclic α, γ -Peptides; 1.4.1 Design; 1.4.2 Homodimers Formation; 1.4.3 Heterodimers Formation; 1.4.4 Applications; 1.4.4.1 Artificial Photosystems; 1.4.4.2 Multicomponent Networks: New Biosensors; 1.4.4.3 Other Applications; 1.5 Summary and Outlook; References; 2 Designer Nanomaterials for the Production of Energy and High Value-Added Chemicals; 2.1 Introduction
2.2 State of the Art in the Preparation of Designer Nanomaterials for the Production of Energy and Chemicals2.2.1 Preparation of Nanomaterials; 2.2.1.1 Physical Routes; 2.2.1.2 Chemical Routes; 2.2.1.3 Physicochemical Routes; 2.2.2 Production of Energy and Chemicals: the Biorefinery Concept; 2.2.2.1 Energy; 2.2.2.2 Catalysis; 2.2.2.3 Other Applications; 2.3 Highlights of Own Research; 2.3.1 Sustainable Preparation of SMNP and Catalytic Activities in the Production of Fine Chemicals; 2.3.1.1 Supported Metallic Nanoparticles: Preparation and Catalytic Activities
2.3.1.2 Supported Metal Oxide Nanoparticles: Preparation and Catalytic Activities2.3.1.3 Other Related Nanomaterials; 2.3.2 Preparation of Designer Nanomaterials for the Production of Energy; 2.3.2.1 Biodiesel Preparation Using Metal Oxide Nanoparticles; 2.3.2.2 Fuels Prepared via Thermochemical Processes; 2.4 Future Prospects; 2.4.1 Future of the Preparation of SMNPs; 2.4.2 Applications of SMNPs for the Future; 2.4.2.1 Fuel Cells; 2.4.2.2 Catalysis of Platform Molecules; 2.4.2.3 Environmental Remediation; 2.4.2.4 Advanced NMR Applications; 2.5 Conclusions; Acknowledgments; References
3 Supramolecular Receptors for Fullerenes3.1 Introduction; 3.2 Classic Receptors for Fullerenes Based on Curved Recognizing Units; 3.3 Receptors for Fullerenes Based on Planar Recognizing Units; 3.4 Concave Receptors for Fullerenes; 3.5 Concave Electroactive Receptors for Fullerenes; 3.6 Conclusions and Future Perspectives; Acknowledgments; References; 4 Click Chemistry: A Quote for Function; 4.1 Introduction; 4.2 New Applications in Materials Synthesis; 4.2.1 Metal Adhesives; 4.2.2 Synthesis and Stabilization of Gels; 4.2.2.1 Strength Enhancement of Nanostructured Organogels
4.2.2.2 Synthesis of Polymer Thermoreversible Gels
Record Nr. UNINA-9910140705203321
Weinheim, : Wiley-VCH, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ideas in chemistry and molecular sciences Where chemistry meets life [[electronic resource] /] / edited by Bruno Pignataro
Ideas in chemistry and molecular sciences Where chemistry meets life [[electronic resource] /] / edited by Bruno Pignataro
Edizione [1st ed.]
Pubbl/distr/stampa Weinheim, : Wiley-VCH, 2010
Descrizione fisica 1 online resource (359 p.)
Disciplina 541.22
Altri autori (Persone) PignataroBruno
Soggetto topico Molecular theory
Chemistry - Social aspects
ISBN 1-283-14048-9
9786613140487
3-527-63051-1
3-527-63052-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ideas in Chemistry and Molecular Sciences; Contents; 5.2.6.1 Streptavidin-Biotin; Preface; List of Contributors; Part I Biochemical Studies; 1 The Role of Copper Ion and the Ubiquitin System in Neurodegenerative Disorders; 1.1 Introduction; 1.2 Metal Ions in the Brain; 1.3 Brain Copper Homeostasis; 1.4 Brain Copper and Neurodegenerative Disorders; 1.5 The Role of Ubiquitin in Protein Degradation; 1.6 Failure of the Ubiquitin System in Neurodegenerative Disorders; 1.7 Interaction of Ubiquitin with Metal Ions; 1.7.1 Thermal Stability of Ubiquitin
1.7.2 Spectroscopic Characterization of CuII Binding1.7.3 Possible Implications for the Polyubiquitination Process; 1.7.4 CuII-Induced Self-Oligomerization of Ub; 1.7.5 Cooperativity between CuII-Binding and Solvent Polarity; 1.7.6 Comparison with Other Metal Ions; 1.8 Biological Implications; 1.8.1 The Redox State of Cellular Copper; 1.8.2 Ubiquitin and Phospholipids; 1.9 Conclusions and Perspectives; Acknowledgments; References; 2 The Bioinorganic and Organometallic Chemistry of Copper(III); 2.1 Introduction; 2.2 Bioinorganic Implications of Copper(III)
2.2.1 Dinuclear Type-3 Copper Enzymes2.2.2 Particulate Methano Monooxygenase (pMMO); 2.2.3 Mononuclear Monooxygenating Copper-based Enzymes; 2.2.4 Trinuclear Copper Models for Laccase; 2.3 Organometallic CuIII Species in Organic Transformations; 2.3.1 C-C Bond Formation in Organocuprate(I) Catalysis; 2.3.1.1 Conjugate Addition to α-Enones; 2.3.1.2 Acetylene Carbocupration; 2.3.1.3 SN2 and SN2 Alkylations; 2.3.2 Aryl-Heteroatom Bond Formation in Cu-mediated Cross-coupling Processes; 2.3.3 Aromatic and Aliphatic C-H Bond Organometallic Functionalizations; 2.3.3.1 Catalytic Systems
2.3.3.2 Stoichiometric Systems2.4 Miscellany: Cuprate Superconducting Materials; 2.5 Overview and Future Targets; References; 3 Chemical Protein Modi.cation; 3.1 Introducing Diversity by Posttranslational Modification; 3.2 Chemistry: A Route to Modi.ed Proteins; 3.3 Challenges in Chemical Protein Modification; 3.4 Traditional Methods for Protein Modification; 3.4.1 Lysine Modi.cation; 3.4.1.1 Activated Esters; 3.4.1.2 Isocyanates and Isothiocyanates; 3.4.1.3 Reductive Alkylation; 3.4.1.4 IME Reagents; 3.4.2 Glutamic and Aspartic Acid Modification; 3.4.3 Cysteine; 3.4.3.1 Alkylation
3.4.3.2 Disulfides3.4.3.3 Desulfurization at Cysteine; 3.5 Recent Innovations in Site-Selective Protein Modification; 3.5.1 Dehydroalanine: A Useful Chemical Handle for Protein Conjugation; 3.5.2 Metal-Mediated Protein Modification; 3.5.2.1 Modification at Natural Residues; 3.5.2.2 Iridium-Catalyzed Reductive Alkylation of Lysine; 3.5.2.3 Modification of Unnatural Residues; 3.5.2.4 Olefin Metathesis at S-Allyl Cysteine; 3.5.3 Metal-Free Methods for Modifying Unnatural Amino Acids; 3.5.3.1 Oxime Ligation at Aldehydes and Ketones; 3.5.3.2 Azide and Alkyne Modification
3.5.3.3 Selective Modification of Tetrazole-Containing Proteins
Record Nr. UNINA-9910140705003321
Weinheim, : Wiley-VCH, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ideas in chemistry and molecular sciences Advances in nanotechnology, materials and devices [[electronic resource] /] / edited by Bruno Pignataro
Ideas in chemistry and molecular sciences Advances in nanotechnology, materials and devices [[electronic resource] /] / edited by Bruno Pignataro
Pubbl/distr/stampa Weinheim, : Wiley-VCH, 2010
Descrizione fisica 1 online resource (434 p.)
Disciplina 540
Altri autori (Persone) PignataroBruno
Soggetto topico Chemistry
Nanotechnology - Technological innovations
ISBN 1-283-14049-7
9786613140494
3-527-63053-8
3-527-63054-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ideas in Chemistry and Molecular Sciences; Contents; Preface; List of Contributors; Part I Preparation of New Materials and Nanomaterials; 1 Self-Assembling Cyclic Peptide-Based Nanomaterials; 1.1 Introduction; 1.2 Types of Self-Assembling Cyclic Peptide Nanotubes; 1.2.1 Nanotubular Assemblies from Cyclic D,L-α-Peptides; 1.2.1.1 Solid-State Ensembles: Microcrystalline Cyclic Peptide Nanotubes; 1.2.1.2 Solution Phase Studies of Dimerization; 1.2.2 Nanotubular Assemblies from Cyclic β-Peptides; 1.2.3 Nanotubular Assemblies from Other Cyclic Peptides; 1.3 Applications of Cyclic Peptide Nanotubes
1.3.1 Antimicrobials1.3.2 Biosensors; 1.3.3 Biomaterials; 1.3.4 Electronic Devices; 1.3.5 Photoswitchable Materials; 1.3.6 Transmembrane Transport Channels; 1.4 Nanotubular Assemblies from Cyclic α, γ -Peptides; 1.4.1 Design; 1.4.2 Homodimers Formation; 1.4.3 Heterodimers Formation; 1.4.4 Applications; 1.4.4.1 Artificial Photosystems; 1.4.4.2 Multicomponent Networks: New Biosensors; 1.4.4.3 Other Applications; 1.5 Summary and Outlook; References; 2 Designer Nanomaterials for the Production of Energy and High Value-Added Chemicals; 2.1 Introduction
2.2 State of the Art in the Preparation of Designer Nanomaterials for the Production of Energy and Chemicals2.2.1 Preparation of Nanomaterials; 2.2.1.1 Physical Routes; 2.2.1.2 Chemical Routes; 2.2.1.3 Physicochemical Routes; 2.2.2 Production of Energy and Chemicals: the Biorefinery Concept; 2.2.2.1 Energy; 2.2.2.2 Catalysis; 2.2.2.3 Other Applications; 2.3 Highlights of Own Research; 2.3.1 Sustainable Preparation of SMNP and Catalytic Activities in the Production of Fine Chemicals; 2.3.1.1 Supported Metallic Nanoparticles: Preparation and Catalytic Activities
2.3.1.2 Supported Metal Oxide Nanoparticles: Preparation and Catalytic Activities2.3.1.3 Other Related Nanomaterials; 2.3.2 Preparation of Designer Nanomaterials for the Production of Energy; 2.3.2.1 Biodiesel Preparation Using Metal Oxide Nanoparticles; 2.3.2.2 Fuels Prepared via Thermochemical Processes; 2.4 Future Prospects; 2.4.1 Future of the Preparation of SMNPs; 2.4.2 Applications of SMNPs for the Future; 2.4.2.1 Fuel Cells; 2.4.2.2 Catalysis of Platform Molecules; 2.4.2.3 Environmental Remediation; 2.4.2.4 Advanced NMR Applications; 2.5 Conclusions; Acknowledgments; References
3 Supramolecular Receptors for Fullerenes3.1 Introduction; 3.2 Classic Receptors for Fullerenes Based on Curved Recognizing Units; 3.3 Receptors for Fullerenes Based on Planar Recognizing Units; 3.4 Concave Receptors for Fullerenes; 3.5 Concave Electroactive Receptors for Fullerenes; 3.6 Conclusions and Future Perspectives; Acknowledgments; References; 4 Click Chemistry: A Quote for Function; 4.1 Introduction; 4.2 New Applications in Materials Synthesis; 4.2.1 Metal Adhesives; 4.2.2 Synthesis and Stabilization of Gels; 4.2.2.1 Strength Enhancement of Nanostructured Organogels
4.2.2.2 Synthesis of Polymer Thermoreversible Gels
Record Nr. UNINA-9910830398803321
Weinheim, : Wiley-VCH, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ideas in chemistry and molecular sciences Where chemistry meets life [[electronic resource] /] / edited by Bruno Pignataro
Ideas in chemistry and molecular sciences Where chemistry meets life [[electronic resource] /] / edited by Bruno Pignataro
Edizione [1st ed.]
Pubbl/distr/stampa Weinheim, : Wiley-VCH, 2010
Descrizione fisica 1 online resource (359 p.)
Disciplina 541.22
Altri autori (Persone) PignataroBruno
Soggetto topico Molecular theory
Chemistry - Social aspects
ISBN 1-283-14048-9
9786613140487
3-527-63051-1
3-527-63052-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ideas in Chemistry and Molecular Sciences; Contents; 5.2.6.1 Streptavidin-Biotin; Preface; List of Contributors; Part I Biochemical Studies; 1 The Role of Copper Ion and the Ubiquitin System in Neurodegenerative Disorders; 1.1 Introduction; 1.2 Metal Ions in the Brain; 1.3 Brain Copper Homeostasis; 1.4 Brain Copper and Neurodegenerative Disorders; 1.5 The Role of Ubiquitin in Protein Degradation; 1.6 Failure of the Ubiquitin System in Neurodegenerative Disorders; 1.7 Interaction of Ubiquitin with Metal Ions; 1.7.1 Thermal Stability of Ubiquitin
1.7.2 Spectroscopic Characterization of CuII Binding1.7.3 Possible Implications for the Polyubiquitination Process; 1.7.4 CuII-Induced Self-Oligomerization of Ub; 1.7.5 Cooperativity between CuII-Binding and Solvent Polarity; 1.7.6 Comparison with Other Metal Ions; 1.8 Biological Implications; 1.8.1 The Redox State of Cellular Copper; 1.8.2 Ubiquitin and Phospholipids; 1.9 Conclusions and Perspectives; Acknowledgments; References; 2 The Bioinorganic and Organometallic Chemistry of Copper(III); 2.1 Introduction; 2.2 Bioinorganic Implications of Copper(III)
2.2.1 Dinuclear Type-3 Copper Enzymes2.2.2 Particulate Methano Monooxygenase (pMMO); 2.2.3 Mononuclear Monooxygenating Copper-based Enzymes; 2.2.4 Trinuclear Copper Models for Laccase; 2.3 Organometallic CuIII Species in Organic Transformations; 2.3.1 C-C Bond Formation in Organocuprate(I) Catalysis; 2.3.1.1 Conjugate Addition to α-Enones; 2.3.1.2 Acetylene Carbocupration; 2.3.1.3 SN2 and SN2 Alkylations; 2.3.2 Aryl-Heteroatom Bond Formation in Cu-mediated Cross-coupling Processes; 2.3.3 Aromatic and Aliphatic C-H Bond Organometallic Functionalizations; 2.3.3.1 Catalytic Systems
2.3.3.2 Stoichiometric Systems2.4 Miscellany: Cuprate Superconducting Materials; 2.5 Overview and Future Targets; References; 3 Chemical Protein Modi.cation; 3.1 Introducing Diversity by Posttranslational Modification; 3.2 Chemistry: A Route to Modi.ed Proteins; 3.3 Challenges in Chemical Protein Modification; 3.4 Traditional Methods for Protein Modification; 3.4.1 Lysine Modi.cation; 3.4.1.1 Activated Esters; 3.4.1.2 Isocyanates and Isothiocyanates; 3.4.1.3 Reductive Alkylation; 3.4.1.4 IME Reagents; 3.4.2 Glutamic and Aspartic Acid Modification; 3.4.3 Cysteine; 3.4.3.1 Alkylation
3.4.3.2 Disulfides3.4.3.3 Desulfurization at Cysteine; 3.5 Recent Innovations in Site-Selective Protein Modification; 3.5.1 Dehydroalanine: A Useful Chemical Handle for Protein Conjugation; 3.5.2 Metal-Mediated Protein Modification; 3.5.2.1 Modification at Natural Residues; 3.5.2.2 Iridium-Catalyzed Reductive Alkylation of Lysine; 3.5.2.3 Modification of Unnatural Residues; 3.5.2.4 Olefin Metathesis at S-Allyl Cysteine; 3.5.3 Metal-Free Methods for Modifying Unnatural Amino Acids; 3.5.3.1 Oxime Ligation at Aldehydes and Ketones; 3.5.3.2 Azide and Alkyne Modification
3.5.3.3 Selective Modification of Tetrazole-Containing Proteins
Record Nr. UNINA-9910831174803321
Weinheim, : Wiley-VCH, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ideas in chemistry and molecular sciences Advances in synthetic chemistry / / edited by Bruno Pignataro
Ideas in chemistry and molecular sciences Advances in synthetic chemistry / / edited by Bruno Pignataro
Pubbl/distr/stampa Weinheim, : Wiley-VCH, 2010
Descrizione fisica 1 online resource (333 p.)
Disciplina 540
Altri autori (Persone) PignataroBruno
Soggetto topico Chemistry
Organic compounds - Synthesis
Inorganic compounds - Synthesis
ISBN 1-283-14050-0
9786613140500
3-527-63055-4
3-527-63056-2
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ideas in Chemistry and Molecular Sciences; Contents; Preface; List of Contributors; Part I Innovative Processes in Organic Chemistry; 1 N-Hydroxy Derivatives: Key Organocatalysts for the Selective Free Radical Aerobic Oxidation of Organic Compounds; 1.1 Introduction; 1.2 General Reactivity of N-Hydroxy Derivatives; 1.3 Aerobic Oxidation Catalyzed by N-Hydroxy Amines; 1.3.1 Aerobic Oxidation of Alcohols to Aldehydes and Ketones; 1.4 Aerobic Oxidation Catalyzed by N-Hydroxy Amides; 1.4.1 Peroxidation of Polyunsaturated Fatty Acids; 1.5 Aerobic Oxidation Catalyzed by N-Hydroxy Imides
1.5.1 Oxidation of Benzylalcohols to Aldehydes1.5.2 Oxidation of Silanes; 1.5.3 Oxidation of N-Alkylamides; 1.5.4 Oxidation of Tertiary Benzylamines to Aldehydes; 1.5.5 Oxidative Functionalization of Alkylaromatics; 1.5.6 Oxidative Acylation of N-Heteroaromatic Bases; 1.5.7 Aerobic Synthesis of p-Hydroxybenzoic Acids and Diphenols; 1.5.8 Selective Halogenation of Alkanes; 1.5.9 Aerobic Oxidation of Cycloalkanes to Diacids; 1.5.10 Epoxidation of Olefins; 1.5.11 Oxidation of Alkylaromatics; 1.6 Conclusions; Acknowledgments; References
2 Gold-Catalyzed Intra- and Intermolecular Cycloadditions of Push-Pull Dienynes2.1 Introduction; 2.2 Gold-Catalyzed Enyne Cycloisomerizations; 2.2.1 General Remarks; 2.2.2 Influence of the Electronic Nature of the Alkyne Substituent; 2.2.3 Gold-Catalyzed Cycloaromatization of Push-Pull Dienyne Acids: Synthesis of 2,3-Disubstituted Phenols; 2.3 Gold-Catalyzed Intermolecular Cycloadditions; 2.3.1 Cycloadditions of Enynes, Propargyl Acetylenes, and Alkynyl Cyclopropanes
2.3.2 Gold-Catalyzed Intermolecular Hetero-Dehydro-Diels-Alder Cycloaddition of Push-Pull Dienynes with Nonactivated Nitriles: Regioselective Synthesis of Pyridines2.4 Conclusions and Future Perspectives; Acknowledgments; References; 3 N-Heterocyclic Carbenes in Copper-Catalyzed Reactions; 3.1 Introduction; 3.2 Preparation of NHC-Containing Copper Complexes; 3.3 Main Applications of [(NHC)Cu] Complexes in Catalysis; 3.4 Copper Hydride-Mediated Reactions; 3.4.1 Hydrosilylation of Carbonyl Compounds; 3.4.2 Mechanistic Considerations; 3.4.3 Related Transformations
3.5 [3 + 2] Cycloaddition of Azides and Alkynes3.5.1 Click Chemistry; 3.5.2 Use of Internal Alkynes: Mechanistic Implications; 3.6 Concluding Remarks; Acknowledgments; References; 4 Supported Organocatalysts as a Powerful Tool in Organic Synthesis; 4.1 Introduction; 4.2 l-Proline and its Derivatives on Ionic Liquid-Modified Silica Gels; 4.3 Polystyrene-Supported Proline as a Versatile and Recyclable Organocatalyst; 4.3.1 Nonasymmetric Reactions; 4.3.1.1 α-Selenenylation of Aldehydes; 4.3.1.2 Baylis-Hillman Reaction; 4.3.2 Asymmetric Reactions; 4.3.2.1 Aldol Reaction
4.4 Prolinamide-Supported Polystyrenes as Highly Stereoselective and Recyclable Organocatalysts for the Aldol Reaction
Altri titoli varianti Advances in synthetic chemistry
Record Nr. UNINA-9910140705103321
Weinheim, : Wiley-VCH, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Ideas in chemistry and molecular sciences Where chemistry meets life / / edited by Bruno Pignataro
Ideas in chemistry and molecular sciences Where chemistry meets life / / edited by Bruno Pignataro
Edizione [1st ed.]
Pubbl/distr/stampa Weinheim, : Wiley-VCH, 2010
Descrizione fisica 1 online resource (359 p.)
Disciplina 541.22
Altri autori (Persone) PignataroBruno
Soggetto topico Molecular theory
Chemistry - Social aspects
ISBN 1-283-14048-9
9786613140487
3-527-63051-1
3-527-63052-X
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ideas in Chemistry and Molecular Sciences; Contents; 5.2.6.1 Streptavidin-Biotin; Preface; List of Contributors; Part I Biochemical Studies; 1 The Role of Copper Ion and the Ubiquitin System in Neurodegenerative Disorders; 1.1 Introduction; 1.2 Metal Ions in the Brain; 1.3 Brain Copper Homeostasis; 1.4 Brain Copper and Neurodegenerative Disorders; 1.5 The Role of Ubiquitin in Protein Degradation; 1.6 Failure of the Ubiquitin System in Neurodegenerative Disorders; 1.7 Interaction of Ubiquitin with Metal Ions; 1.7.1 Thermal Stability of Ubiquitin
1.7.2 Spectroscopic Characterization of CuII Binding1.7.3 Possible Implications for the Polyubiquitination Process; 1.7.4 CuII-Induced Self-Oligomerization of Ub; 1.7.5 Cooperativity between CuII-Binding and Solvent Polarity; 1.7.6 Comparison with Other Metal Ions; 1.8 Biological Implications; 1.8.1 The Redox State of Cellular Copper; 1.8.2 Ubiquitin and Phospholipids; 1.9 Conclusions and Perspectives; Acknowledgments; References; 2 The Bioinorganic and Organometallic Chemistry of Copper(III); 2.1 Introduction; 2.2 Bioinorganic Implications of Copper(III)
2.2.1 Dinuclear Type-3 Copper Enzymes2.2.2 Particulate Methano Monooxygenase (pMMO); 2.2.3 Mononuclear Monooxygenating Copper-based Enzymes; 2.2.4 Trinuclear Copper Models for Laccase; 2.3 Organometallic CuIII Species in Organic Transformations; 2.3.1 C-C Bond Formation in Organocuprate(I) Catalysis; 2.3.1.1 Conjugate Addition to α-Enones; 2.3.1.2 Acetylene Carbocupration; 2.3.1.3 SN2 and SN2 Alkylations; 2.3.2 Aryl-Heteroatom Bond Formation in Cu-mediated Cross-coupling Processes; 2.3.3 Aromatic and Aliphatic C-H Bond Organometallic Functionalizations; 2.3.3.1 Catalytic Systems
2.3.3.2 Stoichiometric Systems2.4 Miscellany: Cuprate Superconducting Materials; 2.5 Overview and Future Targets; References; 3 Chemical Protein Modi.cation; 3.1 Introducing Diversity by Posttranslational Modification; 3.2 Chemistry: A Route to Modi.ed Proteins; 3.3 Challenges in Chemical Protein Modification; 3.4 Traditional Methods for Protein Modification; 3.4.1 Lysine Modi.cation; 3.4.1.1 Activated Esters; 3.4.1.2 Isocyanates and Isothiocyanates; 3.4.1.3 Reductive Alkylation; 3.4.1.4 IME Reagents; 3.4.2 Glutamic and Aspartic Acid Modification; 3.4.3 Cysteine; 3.4.3.1 Alkylation
3.4.3.2 Disulfides3.4.3.3 Desulfurization at Cysteine; 3.5 Recent Innovations in Site-Selective Protein Modification; 3.5.1 Dehydroalanine: A Useful Chemical Handle for Protein Conjugation; 3.5.2 Metal-Mediated Protein Modification; 3.5.2.1 Modification at Natural Residues; 3.5.2.2 Iridium-Catalyzed Reductive Alkylation of Lysine; 3.5.2.3 Modification of Unnatural Residues; 3.5.2.4 Olefin Metathesis at S-Allyl Cysteine; 3.5.3 Metal-Free Methods for Modifying Unnatural Amino Acids; 3.5.3.1 Oxime Ligation at Aldehydes and Ketones; 3.5.3.2 Azide and Alkyne Modification
3.5.3.3 Selective Modification of Tetrazole-Containing Proteins
Altri titoli varianti Where chemistry meets life
Record Nr. UNINA-9910877983403321
Weinheim, : Wiley-VCH, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Ideas in chemistry and molecular sciences Advances in nanotechnology, materials and devices / / edited by Bruno Pignataro
Ideas in chemistry and molecular sciences Advances in nanotechnology, materials and devices / / edited by Bruno Pignataro
Pubbl/distr/stampa Weinheim, : Wiley-VCH, 2010
Descrizione fisica 1 online resource (434 p.)
Disciplina 540
Altri autori (Persone) PignataroBruno
Soggetto topico Chemistry
Nanotechnology - Technological innovations
ISBN 1-283-14049-7
9786613140494
3-527-63053-8
3-527-63054-6
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Ideas in Chemistry and Molecular Sciences; Contents; Preface; List of Contributors; Part I Preparation of New Materials and Nanomaterials; 1 Self-Assembling Cyclic Peptide-Based Nanomaterials; 1.1 Introduction; 1.2 Types of Self-Assembling Cyclic Peptide Nanotubes; 1.2.1 Nanotubular Assemblies from Cyclic D,L-α-Peptides; 1.2.1.1 Solid-State Ensembles: Microcrystalline Cyclic Peptide Nanotubes; 1.2.1.2 Solution Phase Studies of Dimerization; 1.2.2 Nanotubular Assemblies from Cyclic β-Peptides; 1.2.3 Nanotubular Assemblies from Other Cyclic Peptides; 1.3 Applications of Cyclic Peptide Nanotubes
1.3.1 Antimicrobials1.3.2 Biosensors; 1.3.3 Biomaterials; 1.3.4 Electronic Devices; 1.3.5 Photoswitchable Materials; 1.3.6 Transmembrane Transport Channels; 1.4 Nanotubular Assemblies from Cyclic α, γ -Peptides; 1.4.1 Design; 1.4.2 Homodimers Formation; 1.4.3 Heterodimers Formation; 1.4.4 Applications; 1.4.4.1 Artificial Photosystems; 1.4.4.2 Multicomponent Networks: New Biosensors; 1.4.4.3 Other Applications; 1.5 Summary and Outlook; References; 2 Designer Nanomaterials for the Production of Energy and High Value-Added Chemicals; 2.1 Introduction
2.2 State of the Art in the Preparation of Designer Nanomaterials for the Production of Energy and Chemicals2.2.1 Preparation of Nanomaterials; 2.2.1.1 Physical Routes; 2.2.1.2 Chemical Routes; 2.2.1.3 Physicochemical Routes; 2.2.2 Production of Energy and Chemicals: the Biorefinery Concept; 2.2.2.1 Energy; 2.2.2.2 Catalysis; 2.2.2.3 Other Applications; 2.3 Highlights of Own Research; 2.3.1 Sustainable Preparation of SMNP and Catalytic Activities in the Production of Fine Chemicals; 2.3.1.1 Supported Metallic Nanoparticles: Preparation and Catalytic Activities
2.3.1.2 Supported Metal Oxide Nanoparticles: Preparation and Catalytic Activities2.3.1.3 Other Related Nanomaterials; 2.3.2 Preparation of Designer Nanomaterials for the Production of Energy; 2.3.2.1 Biodiesel Preparation Using Metal Oxide Nanoparticles; 2.3.2.2 Fuels Prepared via Thermochemical Processes; 2.4 Future Prospects; 2.4.1 Future of the Preparation of SMNPs; 2.4.2 Applications of SMNPs for the Future; 2.4.2.1 Fuel Cells; 2.4.2.2 Catalysis of Platform Molecules; 2.4.2.3 Environmental Remediation; 2.4.2.4 Advanced NMR Applications; 2.5 Conclusions; Acknowledgments; References
3 Supramolecular Receptors for Fullerenes3.1 Introduction; 3.2 Classic Receptors for Fullerenes Based on Curved Recognizing Units; 3.3 Receptors for Fullerenes Based on Planar Recognizing Units; 3.4 Concave Receptors for Fullerenes; 3.5 Concave Electroactive Receptors for Fullerenes; 3.6 Conclusions and Future Perspectives; Acknowledgments; References; 4 Click Chemistry: A Quote for Function; 4.1 Introduction; 4.2 New Applications in Materials Synthesis; 4.2.1 Metal Adhesives; 4.2.2 Synthesis and Stabilization of Gels; 4.2.2.1 Strength Enhancement of Nanostructured Organogels
4.2.2.2 Synthesis of Polymer Thermoreversible Gels
Altri titoli varianti Advances in nanotechnology, materials and devices
Record Nr. UNINA-9910876954303321
Weinheim, : Wiley-VCH, 2010
Materiale a stampa
Lo trovi qui: Univ. Federico II
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Molecules at work [[electronic resource] ] : selfassembly, nanomaterials, molecular machinery / / edited by Bruno Pignataro
Molecules at work [[electronic resource] ] : selfassembly, nanomaterials, molecular machinery / / edited by Bruno Pignataro
Autore Pignataro Bruno
Pubbl/distr/stampa Weinheim, : Wiley-VCH Verlag GmbH & Co. KGaA, c2012
Descrizione fisica 1 online resource (417 p.)
Disciplina 540
620.11
Altri autori (Persone) PignataroBruno
Soggetto topico Molecules
ISBN 3-527-64580-2
1-280-67929-8
9786613656223
3-527-64581-0
3-527-64578-0
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto pt. 1. Self assembly -- pt. 2. Nanomaterials -- pt. 3. Molecular machinery.
Record Nr. UNINA-9910137628203321
Pignataro Bruno  
Weinheim, : Wiley-VCH Verlag GmbH & Co. KGaA, c2012
Materiale a stampa
Lo trovi qui: Univ. Federico II
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