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Main group metals in organic synthesis [[electronic resource] /] / edited by Hisahi Yamamoto and Koichiro Oshima
| Main group metals in organic synthesis [[electronic resource] /] / edited by Hisahi Yamamoto and Koichiro Oshima |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, 2004 |
| Descrizione fisica | 1 online resource (907 p.) |
| Disciplina | 547.05 |
| Altri autori (Persone) |
YamamotoHisashi
OshimaKoichiro <1947-> |
| Soggetto topico |
Organometallic compounds - Synthesis
Organic compounds |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-52044-2
9786610520442 3-527-60535-5 3-527-60260-7 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Main Group Metals in Organic Synthesis; Contents; Preface; List of Contributors; Volume 1; 1 Lithium in Organic Synthesis; 1.1 Introduction; 1.2 Nature of Organolithium Compounds; 1.2.1 Overview; 1.2.2 Structural Features; 1.2.3 Configurational Stability; 1.2.4 Titration of Organolithium Compounds; 1.3 Methods for the Preparation of Organolithium Compounds; 1.3.1 Overview; 1.3.2 Reductive Lithiation using Lithium Metal; 1.3.3 Preparation of Organolithium Compounds from Another Organolithium Compounds; 1.3.3.1 Deprotonation; 1.3.3.2 Halogen-Lithium Exchange; 1.3.3.3 Transmetallation
1.3.3.4 Carbolithiation1.3.3.5 Miscellaneous; 1.4 Methods for Construction of Carbon Frameworks by Use of Organolithium Compounds; 1.4.1 Overview; 1.4.2 Stereospecificity; 1.4.3 Synthetic Application; 1.4.3.1 C-C Bond Formation: Conversion of C-Li to Halogen-Li; 1.4.3.2 C-C Bond Formation: Conversion of C-Li to O-Li; 1.4.3.3 C-C Bond Formation: Conversion of C-Li to N-Li; 1.5 References; 2 Rubidium and Cesium in Organic Synthesis; 2.1 Introduction; 2.2 Organo-, Silyl-, Germyl-, and Stannylmetal; 2.3 Fluoride Ion Source; 2.3.1 Nucleophilic Fluorination; 2.3.2 Desilylation Reactions 2.3.2.1 Carbanion Equivalent Formation2.3.2.2 Desilylation-Elimination; 2.4 Electrophilic Fluorination - Cesium Fluorosulfate; 2.5 Cesium Salts as Bases; 2.6 Cesium Enolate; 2.7 Catalytic Use; 2.8 Conclusion; 2.9 References; 3 Magnesium in Organic Synthesis; 3.1 Introduction; 3.2 Preparation of Organomagnesium Compounds; 3.2.1 Preparation from Alkyl Halides and Mg Metal; 3.2.2 Preparation with Rieke Magnesium; 3.2.3 Transmetalation; 3.2.4 Sulfoxide-Magnesium Exchange (Ligand Exchange Reaction of Sulfoxides with Grignard Reagent); 3.2.5 Hydromagnesation 3.2.6 Metalation (Deprotonation from Strong Carbon Acids)3.2.7 Other Preparative Methods; 3.3 Reaction of Organomagnesium Compounds; 3.3.1 Reaction with Organomagnesium Amides; 3.3.1.1 Preparation of Magnesium Monoamides and Bisamides; 3.3.1.2 Reaction with Organomagnesium Amide; 3.3.2 Cp(2)TiCl(2)- or Cp(2)ZrCl(2)-catalyzed Reaction with Grignard Reagents; 3.3.3 Substitution at Carbon by Organomagnesium Compounds; 3.3.4 Addition to Carbon-Carbon Multiple Bonds; 3.3.5 Addition of Organomagnesium Compounds to Carbonyl Groups; 3.4 Halogen-Magnesium Exchange Reactions 3.4.1 Practical Examples of Halogen-Magnesium Exchange Reactions3.4.1.1 Perfluoro Organomagnesium Reagents; 3.4.1.2 Polyhalogenated Arylmagnesium Reagents; 3.4.1.3 Exchange of Polyhalomethane Derivatives; 3.4.1.4 Preparation of Magnesiated Nitrogen-Heterocycles; 3.4.1.5 Formation of Enolates by Halogen-Magnesium Exchange; 3.4.1.6 Miscellaneous Reactions; 3.4.2 iPrMgBr-induced Halogen-Magnesium Exchange for the Preparation of Polyfunctional Organomagnesium Reagents; 3.4.2.1 Exchange Reaction of Aryl Halides; 3.4.2.2 Exchange Reaction of Heterocyclic Halides 3.4.2.3 Exchange Reaction of Alkenyl Halides |
| Record Nr. | UNINA-9910146241203321 |
| Weinheim, Germany, : Wiley-VCH, 2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Main group metals in organic synthesis / / edited by Hisahi Yamamoto and Koichiro Oshima
| Main group metals in organic synthesis / / edited by Hisahi Yamamoto and Koichiro Oshima |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley-VCH, 2004 |
| Descrizione fisica | 1 online resource (907 p.) |
| Disciplina | 547.05 |
| Altri autori (Persone) |
YamamotoHisashi
OshimaKoichiro <1947-> |
| Soggetto topico |
Organometallic compounds - Synthesis
Organic compounds |
| ISBN |
9786610520442
9781280520440 1280520442 9783527605354 3527605355 9783527602605 3527602607 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Main Group Metals in Organic Synthesis; Contents; Preface; List of Contributors; Volume 1; 1 Lithium in Organic Synthesis; 1.1 Introduction; 1.2 Nature of Organolithium Compounds; 1.2.1 Overview; 1.2.2 Structural Features; 1.2.3 Configurational Stability; 1.2.4 Titration of Organolithium Compounds; 1.3 Methods for the Preparation of Organolithium Compounds; 1.3.1 Overview; 1.3.2 Reductive Lithiation using Lithium Metal; 1.3.3 Preparation of Organolithium Compounds from Another Organolithium Compounds; 1.3.3.1 Deprotonation; 1.3.3.2 Halogen-Lithium Exchange; 1.3.3.3 Transmetallation
1.3.3.4 Carbolithiation1.3.3.5 Miscellaneous; 1.4 Methods for Construction of Carbon Frameworks by Use of Organolithium Compounds; 1.4.1 Overview; 1.4.2 Stereospecificity; 1.4.3 Synthetic Application; 1.4.3.1 C-C Bond Formation: Conversion of C-Li to Halogen-Li; 1.4.3.2 C-C Bond Formation: Conversion of C-Li to O-Li; 1.4.3.3 C-C Bond Formation: Conversion of C-Li to N-Li; 1.5 References; 2 Rubidium and Cesium in Organic Synthesis; 2.1 Introduction; 2.2 Organo-, Silyl-, Germyl-, and Stannylmetal; 2.3 Fluoride Ion Source; 2.3.1 Nucleophilic Fluorination; 2.3.2 Desilylation Reactions 2.3.2.1 Carbanion Equivalent Formation2.3.2.2 Desilylation-Elimination; 2.4 Electrophilic Fluorination - Cesium Fluorosulfate; 2.5 Cesium Salts as Bases; 2.6 Cesium Enolate; 2.7 Catalytic Use; 2.8 Conclusion; 2.9 References; 3 Magnesium in Organic Synthesis; 3.1 Introduction; 3.2 Preparation of Organomagnesium Compounds; 3.2.1 Preparation from Alkyl Halides and Mg Metal; 3.2.2 Preparation with Rieke Magnesium; 3.2.3 Transmetalation; 3.2.4 Sulfoxide-Magnesium Exchange (Ligand Exchange Reaction of Sulfoxides with Grignard Reagent); 3.2.5 Hydromagnesation 3.2.6 Metalation (Deprotonation from Strong Carbon Acids)3.2.7 Other Preparative Methods; 3.3 Reaction of Organomagnesium Compounds; 3.3.1 Reaction with Organomagnesium Amides; 3.3.1.1 Preparation of Magnesium Monoamides and Bisamides; 3.3.1.2 Reaction with Organomagnesium Amide; 3.3.2 Cp(2)TiCl(2)- or Cp(2)ZrCl(2)-catalyzed Reaction with Grignard Reagents; 3.3.3 Substitution at Carbon by Organomagnesium Compounds; 3.3.4 Addition to Carbon-Carbon Multiple Bonds; 3.3.5 Addition of Organomagnesium Compounds to Carbonyl Groups; 3.4 Halogen-Magnesium Exchange Reactions 3.4.1 Practical Examples of Halogen-Magnesium Exchange Reactions3.4.1.1 Perfluoro Organomagnesium Reagents; 3.4.1.2 Polyhalogenated Arylmagnesium Reagents; 3.4.1.3 Exchange of Polyhalomethane Derivatives; 3.4.1.4 Preparation of Magnesiated Nitrogen-Heterocycles; 3.4.1.5 Formation of Enolates by Halogen-Magnesium Exchange; 3.4.1.6 Miscellaneous Reactions; 3.4.2 iPrMgBr-induced Halogen-Magnesium Exchange for the Preparation of Polyfunctional Organomagnesium Reagents; 3.4.2.1 Exchange Reaction of Aryl Halides; 3.4.2.2 Exchange Reaction of Heterocyclic Halides 3.4.2.3 Exchange Reaction of Alkenyl Halides |
| Record Nr. | UNINA-9911018976103321 |
| Weinheim, Germany, : Wiley-VCH, 2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||