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Carbocation Chemistry
| Carbocation Chemistry |
| Pubbl/distr/stampa | [Place of publication not identified], : Wiley Interscience Imprint, 2004 |
| Descrizione fisica | 1 online resource (ix, 393 pages) : illustrations (some color) |
| Disciplina | 547/.1372 |
| Soggetto topico | Carbocations |
| ISBN | 0-471-67865-1 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | Historical perspective / Peter J. Stang -- 100 years of carbocations and their significance in chemistry / George A. Olah -- Zwitterionic "Neutral" and "Anionic" carbocation analogs / Chaitanya S. Wannere, Zhongfang Chen, and Paul von Rague Schleyer -- Recent studies of long-lived carbocations and carbodications / G.K. Surya Prakash and V. Prakash Reddy -- Antiaromaticity effects in cyclopentadienyl carbocations and free radicals / Annette D. Allen and Thomas T. Tidwell -- Long-lived carbocations in cold Siberia / Vyacheslav G. Shubin and Gennady I. Borodkin -- Polyfluorinated carbocations / Vitalij D. Shteingarts -- Carbocations, fast rearrangement reactions, and the isotopic perturbation method / Martin Saunders and Olga Kronja -- Stable ion chemistry of polycyclic aromatic hydrocarbons (PAHs) / Kenneth K. Laali -- Chromium tricarbonyl-coordinated carbocations / Bruce N. Hietbrink [and others] -- Carbocations in gold chemistry / Hubert Schmidbaur and Keith A. Porter -- Proton exchange between strong acids and alkanes / Jean Sommer and Alain Goeppert -- Electrophilicity scales for carbocations / Herbert Mayr and Armin R. Ofial -- Organic synthesis in superacids / Jean-Claude Jacquesy. |
| Record Nr. | UNINA-9910877062003321 |
| [Place of publication not identified], : Wiley Interscience Imprint, 2004 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Superacid chemistry [[electronic resource] /] / George A. Olah ... [et al.]
| Superacid chemistry [[electronic resource] /] / George A. Olah ... [et al.] |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2009 |
| Descrizione fisica | 1 online resource (872 p.) |
| Disciplina |
546.24
546/.24 |
| Altri autori (Persone) | OlahGeorge A <1927-2017> (George Andrew) |
| Soggetto topico | Superacids |
| Soggetto genere / forma | Electronic books |
| ISBN |
1-282-11300-3
9786612113000 0-470-42160-6 0-470-42154-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
SUPERACID CHEMISTRY; CONTENTS; Preface to the Second Edition; Preface to the First Edition; 1. General Aspects; 1.1. Defining Acidity; 1.1.1. Acids and Bases; 1.1.2. The pH Scale; 1.1.3. Acidity Functions; 1.2. Definition of Superacids; 1.2.1. Range of Acidities; 1.3. Types of Superacids; 1.3.1. Primary Superacids; 1.3.2. Binary Superacids; 1.3.3. Ternary Superacids; 1.3.4. Solid Superacids; 1.4. Experimental Techniques for Acidity Measurements (Protic Acids); 1.4.1. Spectrophotometric Method; 1.4.2. Nuclear Magnetic Resonance Methods; 1.4.2.1. Chemical Shift Measurements
1.4.2.2. Exchange Rate Measurements Based on Line-Shape Analysis (DNMR: Dynamic Nuclear Magnetic Resonance)1.4.3. Electrochemical Methods; 1.4.4. Chemical Kinetics; 1.4.5. Heats of Protonation of Weak Bases; 1.4.6. Theoretical Calculations and Superacidity in the Gas Phase; 1.4.7. Estimating the Strength of Lewis Acids; 1.4.8. Experimental Techniques Applied to Solid Acids; References; 2. Superacid Systems; 2.1. Primary Superacids; 2.1.1. Brønsted Superacids; 2.1.1.1 Perchloric Acid; 2.1.1.2. Chlorosulfuric Acid; 2.1.1.3. Fluorosulfuric Acid; 2.1.1.4. Perfluoroalkanesulfonic Acids 2.1.1.5. Hydrogen Fluoride2.1.1.6. Carborane Superacids H(CB(11)HR(5)X(6)); 2.1.2. Lewis Superacids; 2.1.2.1. Antimony Pentafluoride; 2.1.2.2. Arsenic Pentafluoride; 2.1.2.3. Phosphorus Pentafluoride; 2.1.2.4. Tantalum and Niobium Pentafluoride; 2.1.2.5. Boron Trifluoride; 2.1.2.6. Tris(pentafluorophenyl) Borane; 2.1.2.7. Boron Tris(trifluoromethanesulfonate); 2.1.2.8. Aprotic Organic Superacids (Vol'pin's Systems); 2.2. Binary Superacids; 2.2.1. Binary Brønsted Superacids; 2.2.1.1. Hydrogen Fluoride-Fluorosulfuric Acid; 2.2.1.2. Hydrogen Fluoride-Trifluoromethanesulfonic Acid 2.2.1.3. Tetra(Hydrogen Sulfato)Boric Acid-Sulfuric Acid2.2.2. Conjugate Brønsted-Lewis Superacids; 2.2.2.1. Oleums-Polysulfuric Acids; 2.2.2.2. Fluorosulfuric Acid-Antimony Pentafluoride (""Magic Acid""); 2.2.2.3. Fluorosulfuric Acid-Sulfur Trioxide; 2.2.2.4. HSO(3)F-MF(n)(SO(3)F)(5-n); n = 3, 4, M = Nb, Ta; 2.2.2.5. Fluorosulfuric Acid-Arsenic Pentafluoride; 2.2.2.6. Perfluoroalkanesulfonic Acid-Based Systems; 2.2.2.7. Hydrogen Fluoride-Antimony Pentafluoride (Fluoroantimonic Acid); 2.2.2.8. Hydrogen Fluoride- Phosphorus Pentafluoride; 2.2.2.9. Hydrogen Fluoride-Tantalum Pentafluoride 2.2.2.10. Hydrogen Fluoride-Boron Trifluoride (Tetrafluoroboric Acid)2.2.2.11. Conjugate Friedel-Crafts Acids (HX-AlX(3), etc.); 2.3. Ternary Superacids; 2.3.1. HSO(3)F-HF-SbF(5); 2.3.2. HSO(3)F-HF-CF(3)SO(3)H; 2.3.3. CF(3)SO(3)H-HF-Lewis Acid; 2.3.4. HSO(3)F-SbF(5)-SO(3); 2.4. Solid Superacids; 2.4.1. Zeolitic Acids; 2.4.2. Polymeric Resin Sulfonic Acids; 2.4.2.1. Lewis Acid-Complexed Sulfonic Acid Resins; 2.4.2.2. Perfluorinated Polymer Resin Acids; 2.4.3. Enhanced Acidity Solids; 2.4.3.1. Brønsted Acid-Modified Metal Oxides: TiO(2)-H(2)SO(4); ZrO(2)-H(2)SO(4) 2.4.3.2. Lewis Acid-Modified Metal Oxides and Mixed Oxides |
| Record Nr. | UNINA-9910145961603321 |
| Hoboken, N.J., : Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Superacid chemistry [[electronic resource] /] / George A. Olah ... [et al.]
| Superacid chemistry [[electronic resource] /] / George A. Olah ... [et al.] |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Hoboken, N.J., : Wiley, c2009 |
| Descrizione fisica | 1 online resource (872 p.) |
| Disciplina |
546.24
546/.24 |
| Altri autori (Persone) | OlahGeorge A <1927-2017> (George Andrew) |
| Soggetto topico | Superacids |
| ISBN |
1-282-11300-3
9786612113000 0-470-42160-6 0-470-42154-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
SUPERACID CHEMISTRY; CONTENTS; Preface to the Second Edition; Preface to the First Edition; 1. General Aspects; 1.1. Defining Acidity; 1.1.1. Acids and Bases; 1.1.2. The pH Scale; 1.1.3. Acidity Functions; 1.2. Definition of Superacids; 1.2.1. Range of Acidities; 1.3. Types of Superacids; 1.3.1. Primary Superacids; 1.3.2. Binary Superacids; 1.3.3. Ternary Superacids; 1.3.4. Solid Superacids; 1.4. Experimental Techniques for Acidity Measurements (Protic Acids); 1.4.1. Spectrophotometric Method; 1.4.2. Nuclear Magnetic Resonance Methods; 1.4.2.1. Chemical Shift Measurements
1.4.2.2. Exchange Rate Measurements Based on Line-Shape Analysis (DNMR: Dynamic Nuclear Magnetic Resonance)1.4.3. Electrochemical Methods; 1.4.4. Chemical Kinetics; 1.4.5. Heats of Protonation of Weak Bases; 1.4.6. Theoretical Calculations and Superacidity in the Gas Phase; 1.4.7. Estimating the Strength of Lewis Acids; 1.4.8. Experimental Techniques Applied to Solid Acids; References; 2. Superacid Systems; 2.1. Primary Superacids; 2.1.1. Brønsted Superacids; 2.1.1.1 Perchloric Acid; 2.1.1.2. Chlorosulfuric Acid; 2.1.1.3. Fluorosulfuric Acid; 2.1.1.4. Perfluoroalkanesulfonic Acids 2.1.1.5. Hydrogen Fluoride2.1.1.6. Carborane Superacids H(CB(11)HR(5)X(6)); 2.1.2. Lewis Superacids; 2.1.2.1. Antimony Pentafluoride; 2.1.2.2. Arsenic Pentafluoride; 2.1.2.3. Phosphorus Pentafluoride; 2.1.2.4. Tantalum and Niobium Pentafluoride; 2.1.2.5. Boron Trifluoride; 2.1.2.6. Tris(pentafluorophenyl) Borane; 2.1.2.7. Boron Tris(trifluoromethanesulfonate); 2.1.2.8. Aprotic Organic Superacids (Vol'pin's Systems); 2.2. Binary Superacids; 2.2.1. Binary Brønsted Superacids; 2.2.1.1. Hydrogen Fluoride-Fluorosulfuric Acid; 2.2.1.2. Hydrogen Fluoride-Trifluoromethanesulfonic Acid 2.2.1.3. Tetra(Hydrogen Sulfato)Boric Acid-Sulfuric Acid2.2.2. Conjugate Brønsted-Lewis Superacids; 2.2.2.1. Oleums-Polysulfuric Acids; 2.2.2.2. Fluorosulfuric Acid-Antimony Pentafluoride (""Magic Acid""); 2.2.2.3. Fluorosulfuric Acid-Sulfur Trioxide; 2.2.2.4. HSO(3)F-MF(n)(SO(3)F)(5-n); n = 3, 4, M = Nb, Ta; 2.2.2.5. Fluorosulfuric Acid-Arsenic Pentafluoride; 2.2.2.6. Perfluoroalkanesulfonic Acid-Based Systems; 2.2.2.7. Hydrogen Fluoride-Antimony Pentafluoride (Fluoroantimonic Acid); 2.2.2.8. Hydrogen Fluoride- Phosphorus Pentafluoride; 2.2.2.9. Hydrogen Fluoride-Tantalum Pentafluoride 2.2.2.10. Hydrogen Fluoride-Boron Trifluoride (Tetrafluoroboric Acid)2.2.2.11. Conjugate Friedel-Crafts Acids (HX-AlX(3), etc.); 2.3. Ternary Superacids; 2.3.1. HSO(3)F-HF-SbF(5); 2.3.2. HSO(3)F-HF-CF(3)SO(3)H; 2.3.3. CF(3)SO(3)H-HF-Lewis Acid; 2.3.4. HSO(3)F-SbF(5)-SO(3); 2.4. Solid Superacids; 2.4.1. Zeolitic Acids; 2.4.2. Polymeric Resin Sulfonic Acids; 2.4.2.1. Lewis Acid-Complexed Sulfonic Acid Resins; 2.4.2.2. Perfluorinated Polymer Resin Acids; 2.4.3. Enhanced Acidity Solids; 2.4.3.1. Brønsted Acid-Modified Metal Oxides: TiO(2)-H(2)SO(4); ZrO(2)-H(2)SO(4) 2.4.3.2. Lewis Acid-Modified Metal Oxides and Mixed Oxides |
| Record Nr. | UNINA-9910830452603321 |
| Hoboken, N.J., : Wiley, c2009 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||