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Organic redox systems : synthesis, properties, and applications / / edited by Tohru Nishinaga
| Organic redox systems : synthesis, properties, and applications / / edited by Tohru Nishinaga |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , [2016] |
| Descrizione fisica | 1 online resource (862 p.) |
| Disciplina | 547/.23 |
| Soggetto topico | Oxidation-reduction reaction |
| ISBN |
1-118-85885-9
1-118-85872-7 1-118-85898-0 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
TITLE PAGE; TABLE OF CONTENTS; LIST OF CONTRIBUTORS; PREFACE; 1 INTRODUCTION: BASIC CONCEPTS AND A BRIEF HISTORY OF ORGANIC REDOX SYSTEMS; 1.1 REDOX REACTION OF ORGANIC MOLECULES; 1.2 REDOX POTENTIAL IN NONAQUEOUS SOLVENTS; 1.3 A BRIEF HISTORY OF ORGANIC REDOX COMPOUNDS; REFERENCES; 2 REDOX-MEDIATED REVERSIBLE σ-BOND FORMATION/CLEAVAGE; 2.1 DYNAMIC REDOX ("DYREX") SYSTEMS; 2.2 ADVANCED ELECTROCHROMIC RESPONSE OF "ENDO"-TYPE DYREX SYSTEMS EXHIBITING REDOX SWITCHING OF A σ-BOND; 2.3 ADVANCED ELECTROCHROMIC RESPONSE OF "EXO"-TYPE DYREX SYSTEMS EXHIBITING REDOX SWITCHING OF A σ-BOND
2.4 PROSPECT: REDOX SYSTEMS WITH MULTIPLE DYREX UNITSREFERENCES; 3 REDOX-CONTROLLED INTRAMOLECULAR MOTIONS TRIGGERED BY π-DIMERIZATION AND PIMERIZATION PROCESSES; 3.1 INTRODUCTION; 3.2 OLIGOTHIOPHENES; 3.3 PHENOTHIAZINE; 3.4 NAPHTHALENE AND PERYLENE BISIMIDES; 3.5 para-PHENYLENEDIAMINE; 3.6 PYRIDINYL RADICALS; 3.7 VIOLOGEN DERIVATIVES; 3.8 VERDAZYL; 3.9 PHENALENYL; 3.10 PORPHYRINS; 3.11 BENZENOID; 3.12 CYCLOPHANE; 3.13 TETRATHIAFULVALENE; 3.14 CONCLUSION; ACKNOWLEDGMENTS; REFERENCES 4 TETRATHIAFULVALENE: A REDOX UNIT FOR FUNCTIONAL MATERIALS AND A BUILDING BLOCK FOR SUPRAMOLECULAR SELF-ASSEMBLY4.1 INTRODUCTION: PAST AND PRESENT OF TTF CHEMISTRY; 4.2 BASIC REDOX PROPERTIES OF TTF AND STACKED TTF; 4.3 TTF AS A FAITHFUL REDOX ACTIVE UNIT IN FUNCTIONAL MATERIALS; 4.4 ELECTROCONDUCTING PROPERTIES OF TTF DERIVATIVES BASED ON SUPRAMOLECULAR SELF-ASSEMBLY; 4.5 SUMMARY AND OUTLOOK; REFERENCES; 5 ROBUST AROMATIC CATION RADICALS AS REDOX TUNABLE OXIDANTS; 5.1 INTRODUCTION; 5.2 DESIGNING MOLECULES FOR THE FORMATION OF STABLE CATION RADICALS (CRs)-A CASE STUDY 5.3 METHODS OF PREPARATIVE ISOLATION OF AROMATIC CATION RADICALS5.4 QUANTITATIVE OXIDATION OF ELECTRON DONORS USING THE-ORANGE+· SbCl6- AS ONE-ELECTRON OXIDANT; 5.5 READILY AVAILABLE ELECTRON DONORS FOR THE REDOX-TUNABLE AROMATIC OXIDANTS; 5.6 CONCLUSION; REFERENCES; 6 AIR-STABLE REDOX-ACTIVE NEUTRAL RADICALS: TOPOLOGICAL SYMMETRY CONTROL OF ELECTRONIC-SPIN, MULTICENTERED CHEMICAL BONDING, AND ORGANIC BATTERY APPLICATION; 6.1 INTRODUCTION; 6.2 OPEN-SHELL GRAPHENE FRAGMENT: DESIGN AND SYNTHESIS OF AIR-STABLE CARBON-CENTERED NEUTRAL RADICALS BASED ON FUSED-POLYCYCLIC Π-SYSTEM 7.5 THE LENGTH OF THE BRIDGE |
| Record Nr. | UNINA-9910137222703321 |
| Hoboken, New Jersey : , : Wiley, , [2016] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Organic redox systems : synthesis, properties, and applications / / edited by Tohru Nishinaga
| Organic redox systems : synthesis, properties, and applications / / edited by Tohru Nishinaga |
| Pubbl/distr/stampa | Hoboken, New Jersey : , : Wiley, , [2016] |
| Descrizione fisica | 1 online resource (862 p.) |
| Disciplina | 547/.23 |
| Soggetto topico | Oxidation-reduction reaction |
| ISBN |
1-118-85885-9
1-118-85872-7 1-118-85898-0 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
TITLE PAGE; TABLE OF CONTENTS; LIST OF CONTRIBUTORS; PREFACE; 1 INTRODUCTION: BASIC CONCEPTS AND A BRIEF HISTORY OF ORGANIC REDOX SYSTEMS; 1.1 REDOX REACTION OF ORGANIC MOLECULES; 1.2 REDOX POTENTIAL IN NONAQUEOUS SOLVENTS; 1.3 A BRIEF HISTORY OF ORGANIC REDOX COMPOUNDS; REFERENCES; 2 REDOX-MEDIATED REVERSIBLE σ-BOND FORMATION/CLEAVAGE; 2.1 DYNAMIC REDOX ("DYREX") SYSTEMS; 2.2 ADVANCED ELECTROCHROMIC RESPONSE OF "ENDO"-TYPE DYREX SYSTEMS EXHIBITING REDOX SWITCHING OF A σ-BOND; 2.3 ADVANCED ELECTROCHROMIC RESPONSE OF "EXO"-TYPE DYREX SYSTEMS EXHIBITING REDOX SWITCHING OF A σ-BOND
2.4 PROSPECT: REDOX SYSTEMS WITH MULTIPLE DYREX UNITSREFERENCES; 3 REDOX-CONTROLLED INTRAMOLECULAR MOTIONS TRIGGERED BY π-DIMERIZATION AND PIMERIZATION PROCESSES; 3.1 INTRODUCTION; 3.2 OLIGOTHIOPHENES; 3.3 PHENOTHIAZINE; 3.4 NAPHTHALENE AND PERYLENE BISIMIDES; 3.5 para-PHENYLENEDIAMINE; 3.6 PYRIDINYL RADICALS; 3.7 VIOLOGEN DERIVATIVES; 3.8 VERDAZYL; 3.9 PHENALENYL; 3.10 PORPHYRINS; 3.11 BENZENOID; 3.12 CYCLOPHANE; 3.13 TETRATHIAFULVALENE; 3.14 CONCLUSION; ACKNOWLEDGMENTS; REFERENCES 4 TETRATHIAFULVALENE: A REDOX UNIT FOR FUNCTIONAL MATERIALS AND A BUILDING BLOCK FOR SUPRAMOLECULAR SELF-ASSEMBLY4.1 INTRODUCTION: PAST AND PRESENT OF TTF CHEMISTRY; 4.2 BASIC REDOX PROPERTIES OF TTF AND STACKED TTF; 4.3 TTF AS A FAITHFUL REDOX ACTIVE UNIT IN FUNCTIONAL MATERIALS; 4.4 ELECTROCONDUCTING PROPERTIES OF TTF DERIVATIVES BASED ON SUPRAMOLECULAR SELF-ASSEMBLY; 4.5 SUMMARY AND OUTLOOK; REFERENCES; 5 ROBUST AROMATIC CATION RADICALS AS REDOX TUNABLE OXIDANTS; 5.1 INTRODUCTION; 5.2 DESIGNING MOLECULES FOR THE FORMATION OF STABLE CATION RADICALS (CRs)-A CASE STUDY 5.3 METHODS OF PREPARATIVE ISOLATION OF AROMATIC CATION RADICALS5.4 QUANTITATIVE OXIDATION OF ELECTRON DONORS USING THE-ORANGE+· SbCl6- AS ONE-ELECTRON OXIDANT; 5.5 READILY AVAILABLE ELECTRON DONORS FOR THE REDOX-TUNABLE AROMATIC OXIDANTS; 5.6 CONCLUSION; REFERENCES; 6 AIR-STABLE REDOX-ACTIVE NEUTRAL RADICALS: TOPOLOGICAL SYMMETRY CONTROL OF ELECTRONIC-SPIN, MULTICENTERED CHEMICAL BONDING, AND ORGANIC BATTERY APPLICATION; 6.1 INTRODUCTION; 6.2 OPEN-SHELL GRAPHENE FRAGMENT: DESIGN AND SYNTHESIS OF AIR-STABLE CARBON-CENTERED NEUTRAL RADICALS BASED ON FUSED-POLYCYCLIC Π-SYSTEM 7.5 THE LENGTH OF THE BRIDGE |
| Record Nr. | UNINA-9910829994903321 |
| Hoboken, New Jersey : , : Wiley, , [2016] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||