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Design and synthesis of conjugated polymers [[electronic resource] /] / edited by Mario Leclerc, Jean-Francois Morin
| Design and synthesis of conjugated polymers [[electronic resource] /] / edited by Mario Leclerc, Jean-Francois Morin |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2010 |
| Descrizione fisica | 1 online resource (381 p.) |
| Disciplina |
620.19
620.19204297 |
| Altri autori (Persone) |
LeclercMario <1961->
MorinJean-Franc ʹois <1978-> |
| Soggetto topico |
Polymers - Electric properties
Polymers |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-78382-3
9786612783821 3-527-62978-5 3-527-62979-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Design and Synthesis of Conjugated Polymers; Contents; Preface; List of Contributors; 1 Synthesis and Functionality of Substituted Polyacetylenes; 1.1 Introduction; 1.2 Polymer Syntheses; 1.2.1 Catalysts; 1.2.2 Polymerization Behaviors; 1.2.3 Polymer Reactions; 1.3 Functional Properties; 1.3.1 Electrical Conductivity and Photoconductivity; 1.3.2 Liquid Crystallinity; 1.3.3 Luminescence; 1.3.4 Fluorescence Sensing; 1.3.5 Patterning and Imaging; 1.3.6 Chromism; 1.3.7 Optical Activity; 1.3.8 Supramolecular Assembly; 1.3.9 Optical Nonlinearity; 1.3.10 Biological Compatibility
1.4 Conclusions and ProspectsAcknowledgments; References; 2 Suzuki Polycondensation: A Powerful Tool for Polyarylene Synthesis; 2.1 Introduction; 2.2 General Remarks; 2.3 How to Do an SPC and Aspects of Characterization; 2.3.1 Monomer Purity, Stoichiometry, and Solvents; 2.3.2 Brief Note on Optimization; 2.3.3 Reduced Catalyst Amount and Product Purification; 2.3.4 Molar Mass Determination; 2.4 Methodological Developments; 2.4.1 Boronic Acid/Boronate Monomers; 2.4.2 Boron-Based Ate Complexes; 2.4.3 Halo and Related Monomers; 2.4.4 Catalysts; 2.4.5 Chain Growth SPC 2.4.6 Microwave and Technical Scale Microreactor Applications2.5 Selected Classes of Polyarylenes and Related Polymers; 2.5.1 Poly(para-phenylene)s; 2.5.2 Polyfluorenes; 2.5.3 Poly(para-meta-phenylene)s; 2.5.4 Shielded Polyarylenes; 2.5.5 Miscellaneous; 2.6 Conclusions and Outlook; Acknowledgments; References; 3 Advanced Functional Regioregular Polythiophenes; 3.1 Introduction; 3.2 Unsubstituted Polythiophene; 3.3 Poly(3-alkylthiophene)s; 3.4 Head-to-Tail Regioregular Poly(3-alkylthiophene)s (rrP3ATs); 3.4.1 Design and Synthesis of rrP3ATs; 3.4.1.1 McCullough Method; 3.4.1.2 Rieke Method 3.4.1.3 GRIM Method3.4.1.4 Other Methods; 3.4.2 Mechanism of the Nickel-Catalyzed Polymerization; 3.4.3 End Group Functionalization; 3.4.3.1 Postpolymerization End Group Functionalization; 3.4.3.2 In situ End Group Functionalization; 3.4.4 Fundamental Properties of rrP3ATs; 3.4.4.1 UV-vis Absorption; 3.4.4.2 Microstructure and Morphology in Thin Films; 3.4.4.3 Electrical Conductivity; 3.4.5 rrP3ATs in Electronic Devices; 3.4.5.1 rrP3ATs in PLEDs; 3.4.5.2 rrP3ATs in OFETs; 3.4.5.3 rrP3ATs in OPVs; 3.5 Regiosymmetric Poly(alkylthiophene)s 3.5.1 Head-to-Head-, Tail-to-Tail-Coupled Poly(alkylthiophene)s3.5.2 Regiosymmetric Alkylthiophene-Thiophene Copolymers; 3.6 Regiosymmetric Polythiophenes with (Hetero)aromatic Rings; 3.7 Polythiophene Block Copolymers; 3.7.1 All-Conjugated rrP3AT-Based Block Copolymers; 3.7.2 Conjugated-Nonconjugated rrP3AT-Based Block Copolymers; 3.8 Conclusion; References; 4 Poly(phenylenevinylenes); 4.1 Introduction; 4.2 Poly(p-phenylenevinylene)s via Polymerization Methods; 4.2.1 Gilch Approach; 4.2.2 The Wessling Method; 4.3 Poly(p-phenylenevinylene)s via Polycondensation 4.3.1 Wittig and Horner-Wadsworth-Emmons Reaction |
| Record Nr. | UNINA-9910140760503321 |
| Weinheim, : Wiley-VCH, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Design and synthesis of conjugated polymers [[electronic resource] /] / edited by Mario Leclerc, Jean-Francois Morin
| Design and synthesis of conjugated polymers [[electronic resource] /] / edited by Mario Leclerc, Jean-Francois Morin |
| Pubbl/distr/stampa | Weinheim, : Wiley-VCH, c2010 |
| Descrizione fisica | 1 online resource (381 p.) |
| Disciplina |
620.19
620.19204297 |
| Altri autori (Persone) |
LeclercMario <1961->
MorinJean-Franc ʹois <1978-> |
| Soggetto topico |
Polymers - Electric properties
Polymers |
| ISBN |
1-282-78382-3
9786612783821 3-527-62978-5 3-527-62979-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Design and Synthesis of Conjugated Polymers; Contents; Preface; List of Contributors; 1 Synthesis and Functionality of Substituted Polyacetylenes; 1.1 Introduction; 1.2 Polymer Syntheses; 1.2.1 Catalysts; 1.2.2 Polymerization Behaviors; 1.2.3 Polymer Reactions; 1.3 Functional Properties; 1.3.1 Electrical Conductivity and Photoconductivity; 1.3.2 Liquid Crystallinity; 1.3.3 Luminescence; 1.3.4 Fluorescence Sensing; 1.3.5 Patterning and Imaging; 1.3.6 Chromism; 1.3.7 Optical Activity; 1.3.8 Supramolecular Assembly; 1.3.9 Optical Nonlinearity; 1.3.10 Biological Compatibility
1.4 Conclusions and ProspectsAcknowledgments; References; 2 Suzuki Polycondensation: A Powerful Tool for Polyarylene Synthesis; 2.1 Introduction; 2.2 General Remarks; 2.3 How to Do an SPC and Aspects of Characterization; 2.3.1 Monomer Purity, Stoichiometry, and Solvents; 2.3.2 Brief Note on Optimization; 2.3.3 Reduced Catalyst Amount and Product Purification; 2.3.4 Molar Mass Determination; 2.4 Methodological Developments; 2.4.1 Boronic Acid/Boronate Monomers; 2.4.2 Boron-Based Ate Complexes; 2.4.3 Halo and Related Monomers; 2.4.4 Catalysts; 2.4.5 Chain Growth SPC 2.4.6 Microwave and Technical Scale Microreactor Applications2.5 Selected Classes of Polyarylenes and Related Polymers; 2.5.1 Poly(para-phenylene)s; 2.5.2 Polyfluorenes; 2.5.3 Poly(para-meta-phenylene)s; 2.5.4 Shielded Polyarylenes; 2.5.5 Miscellaneous; 2.6 Conclusions and Outlook; Acknowledgments; References; 3 Advanced Functional Regioregular Polythiophenes; 3.1 Introduction; 3.2 Unsubstituted Polythiophene; 3.3 Poly(3-alkylthiophene)s; 3.4 Head-to-Tail Regioregular Poly(3-alkylthiophene)s (rrP3ATs); 3.4.1 Design and Synthesis of rrP3ATs; 3.4.1.1 McCullough Method; 3.4.1.2 Rieke Method 3.4.1.3 GRIM Method3.4.1.4 Other Methods; 3.4.2 Mechanism of the Nickel-Catalyzed Polymerization; 3.4.3 End Group Functionalization; 3.4.3.1 Postpolymerization End Group Functionalization; 3.4.3.2 In situ End Group Functionalization; 3.4.4 Fundamental Properties of rrP3ATs; 3.4.4.1 UV-vis Absorption; 3.4.4.2 Microstructure and Morphology in Thin Films; 3.4.4.3 Electrical Conductivity; 3.4.5 rrP3ATs in Electronic Devices; 3.4.5.1 rrP3ATs in PLEDs; 3.4.5.2 rrP3ATs in OFETs; 3.4.5.3 rrP3ATs in OPVs; 3.5 Regiosymmetric Poly(alkylthiophene)s 3.5.1 Head-to-Head-, Tail-to-Tail-Coupled Poly(alkylthiophene)s3.5.2 Regiosymmetric Alkylthiophene-Thiophene Copolymers; 3.6 Regiosymmetric Polythiophenes with (Hetero)aromatic Rings; 3.7 Polythiophene Block Copolymers; 3.7.1 All-Conjugated rrP3AT-Based Block Copolymers; 3.7.2 Conjugated-Nonconjugated rrP3AT-Based Block Copolymers; 3.8 Conclusion; References; 4 Poly(phenylenevinylenes); 4.1 Introduction; 4.2 Poly(p-phenylenevinylene)s via Polymerization Methods; 4.2.1 Gilch Approach; 4.2.2 The Wessling Method; 4.3 Poly(p-phenylenevinylene)s via Polycondensation 4.3.1 Wittig and Horner-Wadsworth-Emmons Reaction |
| Record Nr. | UNINA-9910829994003321 |
| Weinheim, : Wiley-VCH, c2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||