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Palladium-catalyzed coupling reactions [[electronic resource] ] : practical aspects and future developments / / edited by Árpád Molnár
| Palladium-catalyzed coupling reactions [[electronic resource] ] : practical aspects and future developments / / edited by Árpád Molnár |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley, 2013 |
| Descrizione fisica | 1 online resource (533 p.) |
| Disciplina | 541.395 |
| Altri autori (Persone) | MolnárÁrpád |
| Soggetto topico |
Couplings
Catalysis |
| ISBN |
3-527-64828-3
3-527-64830-5 1-299-24131-X 3-527-64831-3 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Contents; Foreword; Preface; List of Contributors; 1 Palladium-Catalyzed Cross-Coupling Reactions - A General Introduction; 1.1 Introduction; 1.1.1 Historical Reflection; 1.1.2 Characteristics, Recent Developments, and Progress; 1.1.3 Literature Reviews and Organization of the Chapter; 1.2 Carbon-Carbon Cross-Coupling Reactions Catalyzed by Palladium; 1.2.1 Classification and Overview; 1.2.2 Common Mechanistic Features of Cross-Coupling Reactions and Reactivity of the Substrates
1.2.2.1 Choice of the Carbon Electrophile1.2.2.2 Choice of the Carbon Nucleophile - What Makes the Difference?; 1.3 The Catalysts; 1.3.1 The Particular Features of Palladium; 1.3.2 Classes of Palladium Catalysts Applied to Cross-Coupling Reactions; 1.3.2.1 Ligands and Palladium Complexes - Homogeneous Systems; 1.3.2.2 Immobilized or Supported Palladium Complexes and Particles - Heterogeneous Systems; 1.3.2.3 Palladium Colloids and (Nonsupported) Nanoparticles; 1.3.2.4 Activity of Heterogeneous Catalysts; 1.4 Mechanistic Aspects 1.4.1 General Mechanism of C C Cross-Coupling and Heck Reactions with Homogeneous Catalyst Precursors1.4.2 Models for Heck and Suzuki Reactions with Supported Pd Precursors; 1.4.3 Recent Results on the Reaction Mechanism and the Nature of the Active Pd Species; 1.4.3.1 Observation of Intermediates in Homogeneous Catalysis by Electrochemical Methods; 1.4.3.2 The Question of Pd Leaching; 1.4.3.3 Selectivity Pattern; 1.4.3.4 In Situ Observation by Spectroscopic Methods; 1.4.3.5 Immobilized Pd Pincer Complexes; 1.4.3.6 Palladium Bulk Materials (Pd Foil, Wire, Sponge) as Catalyst 1.5 Future ChallengesAbbreviations; References; 2 High-Turnover Heterogeneous Palladium Catalysts in Coupling Reactions: the Case of Pd Loaded on Dealuminated Y Zeolites; 2.1 Introduction; 2.2 Various Methodologies to Afford High Turnover Numbers Over Supported Pd Catalysts; 2.3 Structure and Characteristics of Ultrastable Y Zeolites; 2.4 Suzuki-Miyaura Reactions Catalyzed by Pd/USY; 2.4.1 Catalytic Performance of Pd/USY; 2.4.2 Pd Leaching from Pd/USY; 2.4.3 Selectivity in the Homocoupling Reactions; 2.4.4 Characterization of the Active Pd Species by X-Ray Absorption Spectroscopy 2.4.5 A Suggested Mechanism for the Formation of Active Pd Species in Suzuki-Miyaura Coupling Reactions2.5 Catalytic Performance of Pd/USY in Mizoroki-Heck Reactions; 2.5.1 Effect of H2 Bubbling on the Catalytic Reactions of Pd/USY; 2.5.2 Catalytic Reactions Using Chlorobenzene Derivatives; 2.5.3 Characterization of the Pd Species by X-Ray Absorption Spectroscopy; 2.6 Conclusion and Perspective; Abbreviations; References; 3 Palladium-Catalyzed Coupling Reactions with Magnetically Separable Nanocatalysts; 3.1 Introduction 3.2 General Considerations Concerning Magnetic Particles as Catalyst Supports |
| Record Nr. | UNINA-9910139235203321 |
| Weinheim, Germany, : Wiley, 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Palladium-catalyzed coupling reactions : practical aspects and future developments / / edited by Árpád Molnár
| Palladium-catalyzed coupling reactions : practical aspects and future developments / / edited by Árpád Molnár |
| Edizione | [2nd ed.] |
| Pubbl/distr/stampa | Weinheim, Germany, : Wiley, 2013 |
| Descrizione fisica | 1 online resource (533 p.) |
| Disciplina | 541.395 |
| Altri autori (Persone) | MolnárÁrpád |
| Soggetto topico |
Couplings
Catalysis |
| ISBN |
3-527-64828-3
3-527-64830-5 1-299-24131-X 3-527-64831-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Palladium-Catalyzed Coupling Reactions: Practical Aspects and Future Developments; Contents; Foreword; Preface; List of Contributors; 1 Palladium-Catalyzed Cross-Coupling Reactions - A General Introduction; 1.1 Introduction; 1.1.1 Historical Reflection; 1.1.2 Characteristics, Recent Developments, and Progress; 1.1.3 Literature Reviews and Organization of the Chapter; 1.2 Carbon-Carbon Cross-Coupling Reactions Catalyzed by Palladium; 1.2.1 Classification and Overview; 1.2.2 Common Mechanistic Features of Cross-Coupling Reactions and Reactivity of the Substrates
1.2.2.1 Choice of the Carbon Electrophile1.2.2.2 Choice of the Carbon Nucleophile - What Makes the Difference?; 1.3 The Catalysts; 1.3.1 The Particular Features of Palladium; 1.3.2 Classes of Palladium Catalysts Applied to Cross-Coupling Reactions; 1.3.2.1 Ligands and Palladium Complexes - Homogeneous Systems; 1.3.2.2 Immobilized or Supported Palladium Complexes and Particles - Heterogeneous Systems; 1.3.2.3 Palladium Colloids and (Nonsupported) Nanoparticles; 1.3.2.4 Activity of Heterogeneous Catalysts; 1.4 Mechanistic Aspects 1.4.1 General Mechanism of C C Cross-Coupling and Heck Reactions with Homogeneous Catalyst Precursors1.4.2 Models for Heck and Suzuki Reactions with Supported Pd Precursors; 1.4.3 Recent Results on the Reaction Mechanism and the Nature of the Active Pd Species; 1.4.3.1 Observation of Intermediates in Homogeneous Catalysis by Electrochemical Methods; 1.4.3.2 The Question of Pd Leaching; 1.4.3.3 Selectivity Pattern; 1.4.3.4 In Situ Observation by Spectroscopic Methods; 1.4.3.5 Immobilized Pd Pincer Complexes; 1.4.3.6 Palladium Bulk Materials (Pd Foil, Wire, Sponge) as Catalyst 1.5 Future ChallengesAbbreviations; References; 2 High-Turnover Heterogeneous Palladium Catalysts in Coupling Reactions: the Case of Pd Loaded on Dealuminated Y Zeolites; 2.1 Introduction; 2.2 Various Methodologies to Afford High Turnover Numbers Over Supported Pd Catalysts; 2.3 Structure and Characteristics of Ultrastable Y Zeolites; 2.4 Suzuki-Miyaura Reactions Catalyzed by Pd/USY; 2.4.1 Catalytic Performance of Pd/USY; 2.4.2 Pd Leaching from Pd/USY; 2.4.3 Selectivity in the Homocoupling Reactions; 2.4.4 Characterization of the Active Pd Species by X-Ray Absorption Spectroscopy 2.4.5 A Suggested Mechanism for the Formation of Active Pd Species in Suzuki-Miyaura Coupling Reactions2.5 Catalytic Performance of Pd/USY in Mizoroki-Heck Reactions; 2.5.1 Effect of H2 Bubbling on the Catalytic Reactions of Pd/USY; 2.5.2 Catalytic Reactions Using Chlorobenzene Derivatives; 2.5.3 Characterization of the Pd Species by X-Ray Absorption Spectroscopy; 2.6 Conclusion and Perspective; Abbreviations; References; 3 Palladium-Catalyzed Coupling Reactions with Magnetically Separable Nanocatalysts; 3.1 Introduction 3.2 General Considerations Concerning Magnetic Particles as Catalyst Supports |
| Record Nr. | UNINA-9910822275603321 |
| Weinheim, Germany, : Wiley, 2013 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||