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The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill
| The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (394 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | MaskillHoward |
| Soggetto topico |
Physical organic chemistry
Chemical reactions Chemical processes |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-281-32018-8
9786611320188 0-470-98867-3 0-470-99416-9 0-470-76261-6 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Investigation of Organic Reactions and Their Mechanisms; Contents; Contributors; Foreword; Preface; 1 Introduction and Overview; 1.1 Background; 1.2 The nature of mechanism and reactivity in organic chemistry; 1.3 The investigation of mechanism and the scope of this book; 1.3.1 Product analysis, reaction intermediates and isotopic labelling; 1.3.1.1 Example: the acid-catalysed decomposition of nitrosohydroxylamines; 1.3.2 Mechanisms and rate laws; 1.3.3 Computational chemistry; 1.3.3.1 Example: the acid- and base-catalysed decomposition of nitramide; 1.3.4 Kinetics in homogeneous solution
1.3.4.1 Example: the kinetics of the capture of pyridyl ketenes by n -butylamine1.3.5 Kinetics in multiphase systems; 1.3.6 Electrochemical and calorimetric methods; 1.3.7 Reactions involving radical intermediates; 1.3.8 Catalysed reactions; 1.4 Summary; Bibliography; References; 2 Investigation of Reaction Mechanisms by Product Studies; 2.1 Introduction and overview- why study organic reaction mechanisms?; 2.2 Product structure and yield; 2.2.1 Quantitative determination of product yields; 2.2.2 Product stabilities, and kinetic and thermodynamic control of product formation 2.3 Mechanistic information from more detailed studies of product structure2.3.1 Stereochemical considerations; 2.3.2 Use of isotopic labelling; 2.4 Mechanistic evidence from variations in reaction conditions; 2.5 Problems and opportunities arising from unsuccessful experiments or unexpected results; 2.6 Kinetic evidence from monitoring reactions; 2.6.1 Sampling and analysis for kinetics; 2.7 Case studies: more detailed mechanistic evidence from product studies; 2.7.1 Product-determining steps in SN1 reactions; 2.7.2 Selectivities; 2.7.3 Rate- product correlations; Bibliography; References 3 Experimental Methods for Investigating Kinetics3.1 Introduction; 3.2 Preliminaries; 3.2.1 Reaction rate, rate law and rate constant; 3.2.2 Reversible reactions, equilibrium and equilibrium constants; 3.2.3 Reaction mechanism, elementary step and rate-limiting step; 3.2.4 Transition structure and transition state; 3.3 How to obtain the rate equation and rate constant from experimental data; 3.3.1 Differential method; 3.3.1.1 Example:reaction between RBr and HO-; 3.3.2 Method of integration; 3.3.2.1 Data handling; 3.3.2.2 Example: decomposition of N2O5 in CCl4; 3.3.3 Isolation method 3.3.3.1 Example: oxidation of methionine by HOCl3.4 Reversible reactions and equilibrium constants; 3.4.1 Rate constants for forward and reverse directions, and equilibrium constants; 3.4.1.1 Example: cis-trans isomerisation of stilbene; 3.5 Experimental approaches; 3.5.1 Preliminary studies; 3.5.2 Variables to be controlled; 3.5.2.1 Volume; 3.5.2.2 Temperature; 3.5.2.3 pH; 3.5.2.4 Solvent; 3.5.2.5 Ionic strength; 3.5.2.6 Other experimental aspects; 3.6 Choosing an appropriate monitoring method; 3.6.1 Periodic monitoring; 3.6.2 Continuous on-line monitoring; 3.6.3 Continuous static monitoring 3.7 Experimental methods |
| Record Nr. | UNINA-9910145691703321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill
| The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (394 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | MaskillHoward |
| Soggetto topico |
Physical organic chemistry
Chemical reactions Chemical processes |
| ISBN |
1-281-32018-8
9786611320188 0-470-98867-3 0-470-99416-9 0-470-76261-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Investigation of Organic Reactions and Their Mechanisms; Contents; Contributors; Foreword; Preface; 1 Introduction and Overview; 1.1 Background; 1.2 The nature of mechanism and reactivity in organic chemistry; 1.3 The investigation of mechanism and the scope of this book; 1.3.1 Product analysis, reaction intermediates and isotopic labelling; 1.3.1.1 Example: the acid-catalysed decomposition of nitrosohydroxylamines; 1.3.2 Mechanisms and rate laws; 1.3.3 Computational chemistry; 1.3.3.1 Example: the acid- and base-catalysed decomposition of nitramide; 1.3.4 Kinetics in homogeneous solution
1.3.4.1 Example: the kinetics of the capture of pyridyl ketenes by n -butylamine1.3.5 Kinetics in multiphase systems; 1.3.6 Electrochemical and calorimetric methods; 1.3.7 Reactions involving radical intermediates; 1.3.8 Catalysed reactions; 1.4 Summary; Bibliography; References; 2 Investigation of Reaction Mechanisms by Product Studies; 2.1 Introduction and overview- why study organic reaction mechanisms?; 2.2 Product structure and yield; 2.2.1 Quantitative determination of product yields; 2.2.2 Product stabilities, and kinetic and thermodynamic control of product formation 2.3 Mechanistic information from more detailed studies of product structure2.3.1 Stereochemical considerations; 2.3.2 Use of isotopic labelling; 2.4 Mechanistic evidence from variations in reaction conditions; 2.5 Problems and opportunities arising from unsuccessful experiments or unexpected results; 2.6 Kinetic evidence from monitoring reactions; 2.6.1 Sampling and analysis for kinetics; 2.7 Case studies: more detailed mechanistic evidence from product studies; 2.7.1 Product-determining steps in SN1 reactions; 2.7.2 Selectivities; 2.7.3 Rate- product correlations; Bibliography; References 3 Experimental Methods for Investigating Kinetics3.1 Introduction; 3.2 Preliminaries; 3.2.1 Reaction rate, rate law and rate constant; 3.2.2 Reversible reactions, equilibrium and equilibrium constants; 3.2.3 Reaction mechanism, elementary step and rate-limiting step; 3.2.4 Transition structure and transition state; 3.3 How to obtain the rate equation and rate constant from experimental data; 3.3.1 Differential method; 3.3.1.1 Example:reaction between RBr and HO-; 3.3.2 Method of integration; 3.3.2.1 Data handling; 3.3.2.2 Example: decomposition of N2O5 in CCl4; 3.3.3 Isolation method 3.3.3.1 Example: oxidation of methionine by HOCl3.4 Reversible reactions and equilibrium constants; 3.4.1 Rate constants for forward and reverse directions, and equilibrium constants; 3.4.1.1 Example: cis-trans isomerisation of stilbene; 3.5 Experimental approaches; 3.5.1 Preliminary studies; 3.5.2 Variables to be controlled; 3.5.2.1 Volume; 3.5.2.2 Temperature; 3.5.2.3 pH; 3.5.2.4 Solvent; 3.5.2.5 Ionic strength; 3.5.2.6 Other experimental aspects; 3.6 Choosing an appropriate monitoring method; 3.6.1 Periodic monitoring; 3.6.2 Continuous on-line monitoring; 3.6.3 Continuous static monitoring 3.7 Experimental methods |
| Record Nr. | UNISA-996197710203316 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. di Salerno | ||
| ||
The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill
| The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (394 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | MaskillHoward |
| Soggetto topico |
Physical organic chemistry
Chemical reactions Chemical processes |
| ISBN |
1-281-32018-8
9786611320188 0-470-98867-3 0-470-99416-9 0-470-76261-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Investigation of Organic Reactions and Their Mechanisms; Contents; Contributors; Foreword; Preface; 1 Introduction and Overview; 1.1 Background; 1.2 The nature of mechanism and reactivity in organic chemistry; 1.3 The investigation of mechanism and the scope of this book; 1.3.1 Product analysis, reaction intermediates and isotopic labelling; 1.3.1.1 Example: the acid-catalysed decomposition of nitrosohydroxylamines; 1.3.2 Mechanisms and rate laws; 1.3.3 Computational chemistry; 1.3.3.1 Example: the acid- and base-catalysed decomposition of nitramide; 1.3.4 Kinetics in homogeneous solution
1.3.4.1 Example: the kinetics of the capture of pyridyl ketenes by n -butylamine1.3.5 Kinetics in multiphase systems; 1.3.6 Electrochemical and calorimetric methods; 1.3.7 Reactions involving radical intermediates; 1.3.8 Catalysed reactions; 1.4 Summary; Bibliography; References; 2 Investigation of Reaction Mechanisms by Product Studies; 2.1 Introduction and overview- why study organic reaction mechanisms?; 2.2 Product structure and yield; 2.2.1 Quantitative determination of product yields; 2.2.2 Product stabilities, and kinetic and thermodynamic control of product formation 2.3 Mechanistic information from more detailed studies of product structure2.3.1 Stereochemical considerations; 2.3.2 Use of isotopic labelling; 2.4 Mechanistic evidence from variations in reaction conditions; 2.5 Problems and opportunities arising from unsuccessful experiments or unexpected results; 2.6 Kinetic evidence from monitoring reactions; 2.6.1 Sampling and analysis for kinetics; 2.7 Case studies: more detailed mechanistic evidence from product studies; 2.7.1 Product-determining steps in SN1 reactions; 2.7.2 Selectivities; 2.7.3 Rate- product correlations; Bibliography; References 3 Experimental Methods for Investigating Kinetics3.1 Introduction; 3.2 Preliminaries; 3.2.1 Reaction rate, rate law and rate constant; 3.2.2 Reversible reactions, equilibrium and equilibrium constants; 3.2.3 Reaction mechanism, elementary step and rate-limiting step; 3.2.4 Transition structure and transition state; 3.3 How to obtain the rate equation and rate constant from experimental data; 3.3.1 Differential method; 3.3.1.1 Example:reaction between RBr and HO-; 3.3.2 Method of integration; 3.3.2.1 Data handling; 3.3.2.2 Example: decomposition of N2O5 in CCl4; 3.3.3 Isolation method 3.3.3.1 Example: oxidation of methionine by HOCl3.4 Reversible reactions and equilibrium constants; 3.4.1 Rate constants for forward and reverse directions, and equilibrium constants; 3.4.1.1 Example: cis-trans isomerisation of stilbene; 3.5 Experimental approaches; 3.5.1 Preliminary studies; 3.5.2 Variables to be controlled; 3.5.2.1 Volume; 3.5.2.2 Temperature; 3.5.2.3 pH; 3.5.2.4 Solvent; 3.5.2.5 Ionic strength; 3.5.2.6 Other experimental aspects; 3.6 Choosing an appropriate monitoring method; 3.6.1 Periodic monitoring; 3.6.2 Continuous on-line monitoring; 3.6.3 Continuous static monitoring 3.7 Experimental methods |
| Record Nr. | UNINA-9910831031203321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill
| The investigation of organic reactions and their mechanisms [[electronic resource] /] / edited by Howard Maskill |
| Pubbl/distr/stampa | Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 |
| Descrizione fisica | 1 online resource (394 p.) |
| Disciplina |
547.2
547/.2 |
| Altri autori (Persone) | MaskillHoward |
| Soggetto topico |
Physical organic chemistry
Chemical reactions Chemical processes |
| ISBN |
1-281-32018-8
9786611320188 0-470-98867-3 0-470-99416-9 0-470-76261-6 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
The Investigation of Organic Reactions and Their Mechanisms; Contents; Contributors; Foreword; Preface; 1 Introduction and Overview; 1.1 Background; 1.2 The nature of mechanism and reactivity in organic chemistry; 1.3 The investigation of mechanism and the scope of this book; 1.3.1 Product analysis, reaction intermediates and isotopic labelling; 1.3.1.1 Example: the acid-catalysed decomposition of nitrosohydroxylamines; 1.3.2 Mechanisms and rate laws; 1.3.3 Computational chemistry; 1.3.3.1 Example: the acid- and base-catalysed decomposition of nitramide; 1.3.4 Kinetics in homogeneous solution
1.3.4.1 Example: the kinetics of the capture of pyridyl ketenes by n -butylamine1.3.5 Kinetics in multiphase systems; 1.3.6 Electrochemical and calorimetric methods; 1.3.7 Reactions involving radical intermediates; 1.3.8 Catalysed reactions; 1.4 Summary; Bibliography; References; 2 Investigation of Reaction Mechanisms by Product Studies; 2.1 Introduction and overview- why study organic reaction mechanisms?; 2.2 Product structure and yield; 2.2.1 Quantitative determination of product yields; 2.2.2 Product stabilities, and kinetic and thermodynamic control of product formation 2.3 Mechanistic information from more detailed studies of product structure2.3.1 Stereochemical considerations; 2.3.2 Use of isotopic labelling; 2.4 Mechanistic evidence from variations in reaction conditions; 2.5 Problems and opportunities arising from unsuccessful experiments or unexpected results; 2.6 Kinetic evidence from monitoring reactions; 2.6.1 Sampling and analysis for kinetics; 2.7 Case studies: more detailed mechanistic evidence from product studies; 2.7.1 Product-determining steps in SN1 reactions; 2.7.2 Selectivities; 2.7.3 Rate- product correlations; Bibliography; References 3 Experimental Methods for Investigating Kinetics3.1 Introduction; 3.2 Preliminaries; 3.2.1 Reaction rate, rate law and rate constant; 3.2.2 Reversible reactions, equilibrium and equilibrium constants; 3.2.3 Reaction mechanism, elementary step and rate-limiting step; 3.2.4 Transition structure and transition state; 3.3 How to obtain the rate equation and rate constant from experimental data; 3.3.1 Differential method; 3.3.1.1 Example:reaction between RBr and HO-; 3.3.2 Method of integration; 3.3.2.1 Data handling; 3.3.2.2 Example: decomposition of N2O5 in CCl4; 3.3.3 Isolation method 3.3.3.1 Example: oxidation of methionine by HOCl3.4 Reversible reactions and equilibrium constants; 3.4.1 Rate constants for forward and reverse directions, and equilibrium constants; 3.4.1.1 Example: cis-trans isomerisation of stilbene; 3.5 Experimental approaches; 3.5.1 Preliminary studies; 3.5.2 Variables to be controlled; 3.5.2.1 Volume; 3.5.2.2 Temperature; 3.5.2.3 pH; 3.5.2.4 Solvent; 3.5.2.5 Ionic strength; 3.5.2.6 Other experimental aspects; 3.6 Choosing an appropriate monitoring method; 3.6.1 Periodic monitoring; 3.6.2 Continuous on-line monitoring; 3.6.3 Continuous static monitoring 3.7 Experimental methods |
| Record Nr. | UNINA-9910840598603321 |
| Oxford ; ; Ames, Iowa, : Blackwell Pub., 2006 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||