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Kinetics and thermodynamics of multistep nucleation and self-assembly in nanoscale materials [[electronic resource] /] / edited by Gregoire Nicolis and Dominique Maes
| Kinetics and thermodynamics of multistep nucleation and self-assembly in nanoscale materials [[electronic resource] /] / edited by Gregoire Nicolis and Dominique Maes |
| Pubbl/distr/stampa | Hoboken, N.J., : John Wiley & Sons, 2012 |
| Descrizione fisica | 1 online resource (353 p.) |
| Disciplina | 541 |
| Altri autori (Persone) |
NicolisGregoire
MaesDominique |
| Collana | Advances in chemical physics |
| Soggetto topico |
Nucleation
Dynamics Thermodynamics |
| ISBN |
1-280-58949-3
9786613619327 1-118-30948-0 1-118-30951-0 1-118-30947-2 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Kinetics and Thermodynamics of Multistep Nucleation and Self-Assembly in Nanoscale Materials: Advances in Chemical Physics Volume 151; CONTRIBUTORS; PREFACE; PREFACE TO THE SERIES; CONTENTS; KINETICS AND THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS IN MULTISTABLE SYSTEMS; I. INTRODUCTION; II. FORMULATION; A. Stationary Distribution; B. Exit from an Attraction Basin; III. CLOSED SYSTEMS AND DETAILED BALANCE; IV. GENERIC POTENTIALS AND THEIR UNFOLDINGS; A. Transitions from 1 to 3 Occur Necessarily Through State 2; B. Transitions from 1 to 3 Need Not Occur Through State 2
V. KINETICS OF TRANSITIONS BETWEEN STATES: MAPPING INTO A DISCRETE MARKOV PROCESSA. Three Simultaneously Stable States (Seven-Steady-State Region); B. Two Simultaneously Stable States (Five-Steady-State Region); C. Two Simultaneously Stable States (Three-Steady-State Region); VI. IRREVERSIBLE THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS; VII. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; DYNAMICAL RARE EVENT SIMULATION TECHNIQUES FOR EQUILIBRIUM AND NONEQUILIBRIUM SYSTEMS; I. INTRODUCTION; II. REACTIVE FLUX METHOD; III. TRANSITION PATH SAMPLING; IV. TRANSITION INTERFACE SAMPLING V. PARTIAL PATH SAMPLINGVI. FORWARD FLUX SAMPLING; VII. REPLICA EXCHANGE TIS; VIII. NUMERICAL EXAMPLE; IX. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; CONFOCAL DEPOLARIZED DYNAMIC LIGHT SCATTERING; I. INTRODUCTION; II. FUNDAMENTALS OF DEPOLARIZED SCATTERING: THE STATE OF THE ART; III. THE TRADITIONAL APPROACH; IV. THE NOVEL APPROACH; V. THE OPTICAL LAYOUT; VI. DATA REDUCTION SCHEME; VII. RESULTS; VIII. CONCLUSIONS; ACKNOWLEDGMENT; REFERENCES; THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL FOR NUCLEATION OF CRYSTALS IN SOLUTION; I. INTRODUCTION; II. THE CLASSICAL NUCLEATION THEORY A. The Crystallization Driving ForceB. The Thermodynamic Theory of J.W. Gibbs; C. The Rate of Crystal Nucleation; III. THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL; A. Experimental Data on the Rate of Nucleation of Crystals; B. The Nucleus Size and Solution-to-Crystal Spinodal; C. The Classical Theory Overestimates the Crystal Nucleation Rate by 10 Orders of Magnitude; D. The Two-Step Mechanism of Nucleation of Crystal in Solution; E. Dense Liquid Clusters; F. The Rate Law for the Two-Step Mechanism of Crystal Nucleation G. The Rate-determining Step in the Two-Step Nucleation MechanismH. The Role of Heterogeneous Nucleation Substrates; I. The Broad Applicability of the Two-Step Nucleation Mechanism; IV. SUMMARY AND CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; EXPERIMENTAL STUDIES OF TWO-STEP NUCLEATION DURING TWO-DIMENSIONAL CRYSTALLIZATION OF COLLOIDAL PARTICLES WITH SHORT-RANGE ATTRACTION; I. INTRODUCTION; II. EXPERIMENTAL METHODS: SAMPLE PREPARATION AND IMAGING; III. ANALYSIS OF IMAGES: PARTICLE COORDINATES, AREA FRACTION, CLUSTER SIZES, AND CRYSTALLINE ORDER; IV. RESULTS A. Single-Step and Two-Step Nucleation of Crystallites |
| Record Nr. | UNINA-9910141266403321 |
| Hoboken, N.J., : John Wiley & Sons, 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Kinetics and thermodynamics of multistep nucleation and self-assembly in nanoscale materials / / edited by Gregoire Nicolis and Dominique Maes
| Kinetics and thermodynamics of multistep nucleation and self-assembly in nanoscale materials / / edited by Gregoire Nicolis and Dominique Maes |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Hoboken, N.J., : John Wiley & Sons, 2012 |
| Descrizione fisica | 1 online resource (353 p.) |
| Disciplina | 541 |
| Altri autori (Persone) |
NicolisGregoire
MaesDominique |
| Collana | Advances in chemical physics |
| Soggetto topico |
Nucleation
Dynamics Thermodynamics |
| ISBN |
9786613619327
9781280589492 1280589493 9781118309483 1118309480 9781118309513 1118309510 9781118309476 1118309472 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Kinetics and Thermodynamics of Multistep Nucleation and Self-Assembly in Nanoscale Materials: Advances in Chemical Physics Volume 151; CONTRIBUTORS; PREFACE; PREFACE TO THE SERIES; CONTENTS; KINETICS AND THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS IN MULTISTABLE SYSTEMS; I. INTRODUCTION; II. FORMULATION; A. Stationary Distribution; B. Exit from an Attraction Basin; III. CLOSED SYSTEMS AND DETAILED BALANCE; IV. GENERIC POTENTIALS AND THEIR UNFOLDINGS; A. Transitions from 1 to 3 Occur Necessarily Through State 2; B. Transitions from 1 to 3 Need Not Occur Through State 2
V. KINETICS OF TRANSITIONS BETWEEN STATES: MAPPING INTO A DISCRETE MARKOV PROCESSA. Three Simultaneously Stable States (Seven-Steady-State Region); B. Two Simultaneously Stable States (Five-Steady-State Region); C. Two Simultaneously Stable States (Three-Steady-State Region); VI. IRREVERSIBLE THERMODYNAMICS OF FLUCTUATION-INDUCED TRANSITIONS; VII. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; DYNAMICAL RARE EVENT SIMULATION TECHNIQUES FOR EQUILIBRIUM AND NONEQUILIBRIUM SYSTEMS; I. INTRODUCTION; II. REACTIVE FLUX METHOD; III. TRANSITION PATH SAMPLING; IV. TRANSITION INTERFACE SAMPLING V. PARTIAL PATH SAMPLINGVI. FORWARD FLUX SAMPLING; VII. REPLICA EXCHANGE TIS; VIII. NUMERICAL EXAMPLE; IX. CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; CONFOCAL DEPOLARIZED DYNAMIC LIGHT SCATTERING; I. INTRODUCTION; II. FUNDAMENTALS OF DEPOLARIZED SCATTERING: THE STATE OF THE ART; III. THE TRADITIONAL APPROACH; IV. THE NOVEL APPROACH; V. THE OPTICAL LAYOUT; VI. DATA REDUCTION SCHEME; VII. RESULTS; VIII. CONCLUSIONS; ACKNOWLEDGMENT; REFERENCES; THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL FOR NUCLEATION OF CRYSTALS IN SOLUTION; I. INTRODUCTION; II. THE CLASSICAL NUCLEATION THEORY A. The Crystallization Driving ForceB. The Thermodynamic Theory of J.W. Gibbs; C. The Rate of Crystal Nucleation; III. THE TWO-STEP MECHANISM AND THE SOLUTION-CRYSTAL SPINODAL; A. Experimental Data on the Rate of Nucleation of Crystals; B. The Nucleus Size and Solution-to-Crystal Spinodal; C. The Classical Theory Overestimates the Crystal Nucleation Rate by 10 Orders of Magnitude; D. The Two-Step Mechanism of Nucleation of Crystal in Solution; E. Dense Liquid Clusters; F. The Rate Law for the Two-Step Mechanism of Crystal Nucleation G. The Rate-determining Step in the Two-Step Nucleation MechanismH. The Role of Heterogeneous Nucleation Substrates; I. The Broad Applicability of the Two-Step Nucleation Mechanism; IV. SUMMARY AND CONCLUSIONS; ACKNOWLEDGMENTS; REFERENCES; EXPERIMENTAL STUDIES OF TWO-STEP NUCLEATION DURING TWO-DIMENSIONAL CRYSTALLIZATION OF COLLOIDAL PARTICLES WITH SHORT-RANGE ATTRACTION; I. INTRODUCTION; II. EXPERIMENTAL METHODS: SAMPLE PREPARATION AND IMAGING; III. ANALYSIS OF IMAGES: PARTICLE COORDINATES, AREA FRACTION, CLUSTER SIZES, AND CRYSTALLINE ORDER; IV. RESULTS A. Single-Step and Two-Step Nucleation of Crystallites |
| Record Nr. | UNINA-9910817240503321 |
| Hoboken, N.J., : John Wiley & Sons, 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||