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Modern polyesters [[electronic resource] ] : chemistry and technology of polyesters and copolyesters / / edited by John Scheirs and Timothy E. Long
Modern polyesters [[electronic resource] ] : chemistry and technology of polyesters and copolyesters / / edited by John Scheirs and Timothy E. Long
Pubbl/distr/stampa Hoboken, NJ, : John Wiley & Sons, c2003
Descrizione fisica 1 online resource (786 p.)
Disciplina 668.4225
Altri autori (Persone) ScheirsJohn
LongTimothy E. <1969->
Collana Wiley series in polymer science
Soggetto topico Polyesters
Soggetto genere / forma Electronic books.
ISBN 1-280-23893-3
9786610238934
0-470-09067-7
0-470-09068-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters; Contents; Contributors; Series Preface; Preface; About the Editors; I HISTORICAL OVERVIEW; 1 The Historical Development of Polyesters; 1 Introduction; 2 Alkyd and Related Resins; 3 Fibres from Partially Aromatic Polyesters; 3.1 Early Work Leading to Poly(ethylene Terephthalate); 3.2 Spread of Polyester Fibre Production; 3.3 Intermediates; 3.4 Continuous Polymerisation; 3.5 Solid-phase Polymerisation; 3.6 End-use Development; 3.7 High-speed Spinning; 3.8 Ultra-fine Fibres; 4 Other Uses for Semi-aromatic Polyesters
4.1 Films4.2 Moulding Products; 4.3 Bottles; 5 Liquid-crystalline Polyesters; 6 Polyesters as Components of Elastomers; 7 Surface-active Agents; 8 Absorbable Fibres; 9 Polycarbonates; 10 Natural Polyesters; 10.1 Occurrence; 10.2 Poly(b-hydroxyalkanoate)s; 11 Conclusion; References; II POLYMERIZATION AND POLYCONDENSATION; 2 Poly(ethylene Terephthalate) Polymerization - Mechanism, Catalysis, Kinetics, Mass Transfer and Reactor Design; Notation; 1 Introduction; 2 Chemistry, Reaction Mechanisms, Kinetics and Catalysis; 2.1 Esterification/Hydrolysis; 2.2 Transesterication/Glycolysis
2.3 Reactions with Co-monomers2.4 Formation of Short Chain Oligomers; 2.5 Formation of Diethylene Glycol and Dioxane; 2.6 Thermal Degradation of Diester Groups and Formation of Acetaldehyde; 2.7 Yellowing; 2.8 Chemical Recycling; 2.9 Conclusions; 3 Phase Equilibria, Molecular Diffusion and Mass Transfer; 3.1 Phase Equilibria; 3.2 Diffusion and Mass Transfer in Melt-phase Polycondensation; 3.2.1 Mass-transfer Models; 3.2.2 Diffusion Models; 3.2.3 Specific Surface Area; 3.3 Diffusion and Mass Transfer in Solid-state Polycondensation; 3.4 Conclusions
4 Polycondensation Processes and Polycondensation Plants4.1 Batch Processes; 4.1.1 Esterification; 4.1.2 Polycondensation; 4.2 Continuous Processes; 5 Reactor Design for Continuous Melt-phase Polycondensation; 5.1 Esterification Reactors; 5.2 Polycondensation Reactors for Low Melt Viscosity; 5.3 Polycondensation Reactors for High Melt Viscosity; 6 Future Developments and Scientific Requirements; Acknowledgements; References; 3 Synthesis and Polymerization of Cyclic Polyester Oligomers; 1 Introduction; 2 History; 3 Preparation of Polyester Cyclic Oligomers from Acid Chlorides
4 Polyester Cyclic Oligomers via Ring-Chain Equilibration (Depolymerization)5 Mechanism for Formation of Cyclics via Depolymerization; 6 Polymerization of Oligomeric Ester Cyclics; 7 Conclusions; References; 4 Continuous Solid-state Polycondensation of Polyesters; 1 Introduction; 2 The Chemical Reactions of PET in the Solid State; 2.1 Basic Chemistry; 2.2 Mechanism and Kinetics; 2.3 Parameters Affecting SSP; 2.3.1 Temperature; 2.3.2 Time; 2.3.3 Particle Size; 2.3.4 End Group Concentration; 2.3.5 Crystallinity; 2.3.6 Gas Type; 2.3.7 Gas Purity; 2.3.8 Catalyst; 2.3.9 Molecular Weight
3 Crystallization of PET
Record Nr. UNINA-9910146249903321
Hoboken, NJ, : John Wiley & Sons, c2003
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Modern polyesters [[electronic resource] ] : chemistry and technology of polyesters and copolyesters / / edited by John Scheirs and Timothy E. Long
Modern polyesters [[electronic resource] ] : chemistry and technology of polyesters and copolyesters / / edited by John Scheirs and Timothy E. Long
Pubbl/distr/stampa Hoboken, NJ, : John Wiley & Sons, c2003
Descrizione fisica 1 online resource (786 p.)
Disciplina 668.4225
Altri autori (Persone) ScheirsJohn
LongTimothy E. <1969->
Collana Wiley series in polymer science
Soggetto topico Polyesters
ISBN 1-280-23893-3
9786610238934
0-470-09067-7
0-470-09068-5
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto Modern Polyesters: Chemistry and Technology of Polyesters and Copolyesters; Contents; Contributors; Series Preface; Preface; About the Editors; I HISTORICAL OVERVIEW; 1 The Historical Development of Polyesters; 1 Introduction; 2 Alkyd and Related Resins; 3 Fibres from Partially Aromatic Polyesters; 3.1 Early Work Leading to Poly(ethylene Terephthalate); 3.2 Spread of Polyester Fibre Production; 3.3 Intermediates; 3.4 Continuous Polymerisation; 3.5 Solid-phase Polymerisation; 3.6 End-use Development; 3.7 High-speed Spinning; 3.8 Ultra-fine Fibres; 4 Other Uses for Semi-aromatic Polyesters
4.1 Films4.2 Moulding Products; 4.3 Bottles; 5 Liquid-crystalline Polyesters; 6 Polyesters as Components of Elastomers; 7 Surface-active Agents; 8 Absorbable Fibres; 9 Polycarbonates; 10 Natural Polyesters; 10.1 Occurrence; 10.2 Poly(b-hydroxyalkanoate)s; 11 Conclusion; References; II POLYMERIZATION AND POLYCONDENSATION; 2 Poly(ethylene Terephthalate) Polymerization - Mechanism, Catalysis, Kinetics, Mass Transfer and Reactor Design; Notation; 1 Introduction; 2 Chemistry, Reaction Mechanisms, Kinetics and Catalysis; 2.1 Esterification/Hydrolysis; 2.2 Transesterication/Glycolysis
2.3 Reactions with Co-monomers2.4 Formation of Short Chain Oligomers; 2.5 Formation of Diethylene Glycol and Dioxane; 2.6 Thermal Degradation of Diester Groups and Formation of Acetaldehyde; 2.7 Yellowing; 2.8 Chemical Recycling; 2.9 Conclusions; 3 Phase Equilibria, Molecular Diffusion and Mass Transfer; 3.1 Phase Equilibria; 3.2 Diffusion and Mass Transfer in Melt-phase Polycondensation; 3.2.1 Mass-transfer Models; 3.2.2 Diffusion Models; 3.2.3 Specific Surface Area; 3.3 Diffusion and Mass Transfer in Solid-state Polycondensation; 3.4 Conclusions
4 Polycondensation Processes and Polycondensation Plants4.1 Batch Processes; 4.1.1 Esterification; 4.1.2 Polycondensation; 4.2 Continuous Processes; 5 Reactor Design for Continuous Melt-phase Polycondensation; 5.1 Esterification Reactors; 5.2 Polycondensation Reactors for Low Melt Viscosity; 5.3 Polycondensation Reactors for High Melt Viscosity; 6 Future Developments and Scientific Requirements; Acknowledgements; References; 3 Synthesis and Polymerization of Cyclic Polyester Oligomers; 1 Introduction; 2 History; 3 Preparation of Polyester Cyclic Oligomers from Acid Chlorides
4 Polyester Cyclic Oligomers via Ring-Chain Equilibration (Depolymerization)5 Mechanism for Formation of Cyclics via Depolymerization; 6 Polymerization of Oligomeric Ester Cyclics; 7 Conclusions; References; 4 Continuous Solid-state Polycondensation of Polyesters; 1 Introduction; 2 The Chemical Reactions of PET in the Solid State; 2.1 Basic Chemistry; 2.2 Mechanism and Kinetics; 2.3 Parameters Affecting SSP; 2.3.1 Temperature; 2.3.2 Time; 2.3.3 Particle Size; 2.3.4 End Group Concentration; 2.3.5 Crystallinity; 2.3.6 Gas Type; 2.3.7 Gas Purity; 2.3.8 Catalyst; 2.3.9 Molecular Weight
3 Crystallization of PET
Record Nr. UNINA-9910830719203321
Hoboken, NJ, : John Wiley & Sons, c2003
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Synthetic methods in step-growth polymers [[electronic resource] /] / edited by Martin E. Rogers, Timothy E. Long
Synthetic methods in step-growth polymers [[electronic resource] /] / edited by Martin E. Rogers, Timothy E. Long
Pubbl/distr/stampa Hoboken, N.J., : Wiley-Interscience, c2003
Descrizione fisica 1 online resource (619 p.)
Disciplina 547.7
668.4
Altri autori (Persone) LongTimothy E. <1969->
RogersMartin E
Soggetto topico Plastics
Polycondensation
ISBN 1-280-36677-X
9786610366774
0-470-24828-9
0-471-46137-7
0-471-22052-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto SYNTHETIC METHODS IN STEP-GROWTH POLYMERS; CONTRIBUTORS; CONTENTS; Preface; 1 Introduction to Synthetic Methods in Step-Growth Polymers; 1.1 Introduction; 1.2 Structure-Property Relationships in Step-Growth Polymers; 1.3 Synthesis of Step-Growth Polymers; References; 2 Polyesters; 2.1 Introduction; 2.2 Structure-Property Relationships; 2.3 Synthetic Methods; 2.4 Polyester Syntheses; References; 3 Polyamides; 3.1 Introduction; 3.2 Structure-Property Relationships; 3.3 Overview of Chemistry and Analytical Techniques; 3.4 Synthetic Methods; References; 4 Polyurethanes and Polyureas
4.1 Introduction4.2 Structure-Property Relationships; 4.3 Synthesis and Material Characterization; 4.4 Synthetic Methods; Acknowledgments; References; 5 Polyimides and Other High-Temperature Polymers; 5.1 Introduction; 5.2 Structure-Property Relationships; 5.3 Overview of Chemistry and Analytical Techniques; 5.4 Synthetic Methods; References; 6 Synthesis of Poly(arylene ether)s; 6.1 Introduction; 6.2 General Approaches for the Synthesis of Poly(arylene ether)s; 6.3 Control of Molecular Weight and/or Endgroups; 6.4 Control of Topologies; 6.5 Modification of Poly(arylene ether)s
6.6 Block and Graft Copolymers6.7 Miscellaneous Poly(arylene ether)s, Poly(arylene thioether)s, and Related Polymers; References; 7 Chemistry and Properties of Phenolic Resins and Networks; 7.1 Introduction; 7.2 Materials for the Synthesis of Novolac and Resole Phenolic Oligomers; 7.3 Novolac Resins; 7.4 Resole Resins and Networks; 7.5 Epoxy-Phenolic Networks; 7.6 Benzoxazines; 7.7 Phenolic Cyanate Resins; 7.8 Thermal and Thermo-Oxidative Degradation; References; 7.9 Appendix; 8 Nontraditional Step-Growth Polymerization: ADMET; 8.1 Introduction
8.2 Overview of Chemistry and Analytical Techniques8.3 Structure-Property Relationships; 8.4 Synthetic Methods: Silicon-Containing Polymers, Functionalized Polyolefins, and Telechelics; 8.5 Conclusions; References; 9 Nontraditional Step-Growth Polymerization: Transition Metal Coupling; 9.1 Introduction; 9.2 Structure-Property Relationships; 9.3 Overview of Chemistry and Analytic Techniques; 9.4 Synthetic Methods; Acknowledgment; References; 10 Depolymerization and Recycling; 10.1 Introduction; 10.2 Structure-Property Relationships
10.3 Factors Affecting the use of Recycled Monomers or Oligomers10.4 Chemistry and Catalysis; 10.5 Experimental Methods; 10.6 Synthetic Methods; References; Index
Record Nr. UNINA-9910143184503321
Hoboken, N.J., : Wiley-Interscience, c2003
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui
Synthetic methods in step-growth polymers [[electronic resource] /] / edited by Martin E. Rogers, Timothy E. Long
Synthetic methods in step-growth polymers [[electronic resource] /] / edited by Martin E. Rogers, Timothy E. Long
Pubbl/distr/stampa Hoboken, N.J., : Wiley-Interscience, c2003
Descrizione fisica 1 online resource (619 p.)
Disciplina 547.7
668.4
Altri autori (Persone) LongTimothy E. <1969->
RogersMartin E
Soggetto topico Plastics
Polycondensation
ISBN 1-280-36677-X
9786610366774
0-470-24828-9
0-471-46137-7
0-471-22052-3
Formato Materiale a stampa
Livello bibliografico Monografia
Lingua di pubblicazione eng
Nota di contenuto SYNTHETIC METHODS IN STEP-GROWTH POLYMERS; CONTRIBUTORS; CONTENTS; Preface; 1 Introduction to Synthetic Methods in Step-Growth Polymers; 1.1 Introduction; 1.2 Structure-Property Relationships in Step-Growth Polymers; 1.3 Synthesis of Step-Growth Polymers; References; 2 Polyesters; 2.1 Introduction; 2.2 Structure-Property Relationships; 2.3 Synthetic Methods; 2.4 Polyester Syntheses; References; 3 Polyamides; 3.1 Introduction; 3.2 Structure-Property Relationships; 3.3 Overview of Chemistry and Analytical Techniques; 3.4 Synthetic Methods; References; 4 Polyurethanes and Polyureas
4.1 Introduction4.2 Structure-Property Relationships; 4.3 Synthesis and Material Characterization; 4.4 Synthetic Methods; Acknowledgments; References; 5 Polyimides and Other High-Temperature Polymers; 5.1 Introduction; 5.2 Structure-Property Relationships; 5.3 Overview of Chemistry and Analytical Techniques; 5.4 Synthetic Methods; References; 6 Synthesis of Poly(arylene ether)s; 6.1 Introduction; 6.2 General Approaches for the Synthesis of Poly(arylene ether)s; 6.3 Control of Molecular Weight and/or Endgroups; 6.4 Control of Topologies; 6.5 Modification of Poly(arylene ether)s
6.6 Block and Graft Copolymers6.7 Miscellaneous Poly(arylene ether)s, Poly(arylene thioether)s, and Related Polymers; References; 7 Chemistry and Properties of Phenolic Resins and Networks; 7.1 Introduction; 7.2 Materials for the Synthesis of Novolac and Resole Phenolic Oligomers; 7.3 Novolac Resins; 7.4 Resole Resins and Networks; 7.5 Epoxy-Phenolic Networks; 7.6 Benzoxazines; 7.7 Phenolic Cyanate Resins; 7.8 Thermal and Thermo-Oxidative Degradation; References; 7.9 Appendix; 8 Nontraditional Step-Growth Polymerization: ADMET; 8.1 Introduction
8.2 Overview of Chemistry and Analytical Techniques8.3 Structure-Property Relationships; 8.4 Synthetic Methods: Silicon-Containing Polymers, Functionalized Polyolefins, and Telechelics; 8.5 Conclusions; References; 9 Nontraditional Step-Growth Polymerization: Transition Metal Coupling; 9.1 Introduction; 9.2 Structure-Property Relationships; 9.3 Overview of Chemistry and Analytic Techniques; 9.4 Synthetic Methods; Acknowledgment; References; 10 Depolymerization and Recycling; 10.1 Introduction; 10.2 Structure-Property Relationships
10.3 Factors Affecting the use of Recycled Monomers or Oligomers10.4 Chemistry and Catalysis; 10.5 Experimental Methods; 10.6 Synthetic Methods; References; Index
Record Nr. UNINA-9910830208003321
Hoboken, N.J., : Wiley-Interscience, c2003
Materiale a stampa
Lo trovi qui: Univ. Federico II
Opac: Controlla la disponibilità qui