Principles and applications of asymmetric synthesis [[electronic resource] /] / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan |
Autore | Lin Guo-Qiang <1943-> |
Pubbl/distr/stampa | New York, : Wiley-Interscience, c2001 |
Descrizione fisica | 1 online resource (535 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) |
LiYue-Ming <1966->
ChanAlbert Sun-Chi <1950-> |
Soggetto topico |
Asymmetric synthesis
Organic compounds - Synthesis |
Soggetto genere / forma | Electronic books. |
ISBN |
1-280-36767-9
9786610367672 0-470-24631-6 0-471-46524-0 0-471-22042-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
PRINCIPLES AND APPLICATIONS OF ASYMMETRIC SYNTHESIS; CONTENTS; Preface; Abbreviations; 1 Introduction; 1.1 The Significance of Chirality and Stereoisomeric Discrimination; 1.2 Asymmetry; 1.2.1 Conditions for Asymmetry; 1.2.2 Nomenclature; 1.3 Determining Enantiomer Composition; 1.3.1 Measuring Specific Rotation; 1.3.2 The Nuclear Magnetic Resonance Method; 1.3.3 Some Other Reagents for Nuclear Magnetic Resonance Analysis; 1.3.4 Determining the Enantiomer Composition of Chiral Glycols or Cyclic Ketones; 1.3.5 Chromatographic Methods Using Chiral Columns
1.3.6 Capillary Electrophoresis with Enantioselective Supporting Electrolytes1.4 Determining Absolute Configuration; 1.4.1 X-Ray Diffraction Methods; 1.4.2 Chiroptical Methods; 1.4.3 The Chemical Interrelation Method; 1.4.4 Prelog's Method; 1.4.5 Horeau's Method; 1.4.6 Nuclear Magnetic Resonance Method for Relative Configuration Determination; 1.5 General Strategies for Asymmetric Synthesis; 1.5.1 ""Chiron"" Approaches; 1.5.2 Acyclic Diastereoselective Approaches; 1.5.3 Double Asymmetric Synthesis; 1.6 Examples of Some Complicated Compounds 1.7 Some Common Definitions in Asymmetric Synthesis and Stereochemistry1.8 References; 2 a-Alkylation and Catalytic Alkylation of Carbonyl Compounds; 2.1 Introduction; 2.2 Chirality Transfer; 2.2.1 Intra-annular Chirality Transfer; 2.2.2 Extra-annular Chirality Transfer; 2.2.3 Chelation-Enforced Intra-annular Chirality Transfer; 2.3 Preparation of Quaternary Carbon Centers; 2.4 Preparation of a-Amino Acids; 2.5 Nucleophilic Substitution of Chiral Acetal; 2.6 Chiral Catalyst-Induced Aldehyde Alkylation: Asymmetric Nucleophilic Addition 2.7 Catalytic Asymmetric Additions of Dialkylzinc to Ketones: Enantioselective Formation of Tertiary Alcohols2.8 Asymmetric Cyanohydrination; 2.9 Asymmetric a-Hydroxyphosphonylation; 2.10 Summary; 2.11 References; 3 Aldol and Related Reactions; 3.1 Introduction; 3.2 Substrate-Controlled Aldol Reaction; 3.2.1 Oxazolidones as Chiral Auxiliaries: Chiral Auxiliary-Mediated Aldol-Type Reactions; 3.2.2 Pyrrolidines as Chiral Auxiliaries; 3.2.3 Aminoalcohols as the Chiral Auxiliaries; 3.2.4 Acylsultam Systems as the Chiral Auxiliaries; 3.2.5 a-Silyl Ketones; 3.3 Reagent-Controlled Aldol Reactions 3.3.1 Aldol Condensations Induced by Chiral Boron Compounds3.3.2 Aldol Reactions Controlled by Corey's Reagents; 3.3.3 Aldol Condensations Controlled by Miscellaneous Reagents; 3.4 Chiral Catalyst-Controlled Asymmetric Aldol Reaction; 3.4.1 Mukaiyama's System; 3.4.2 Asymmetric Aldol Reactions with a Chiral Ferrocenylphosphine-Gold(I) Complex; 3.4.3 Asymmetric Aldol Reactions Catalyzed by Chiral Lewis Acids; 3.4.4 Catalytic Asymmetric Aldol Reaction Promoted by Bimetallic Catalysts: Shibasaki's System; 3.5 Double Asymmetric Aldol Reactions; 3.6 Asymmetric Allylation Reactions 3.6.1 The Roush Reaction |
Record Nr. | UNINA-9910142500303321 |
Lin Guo-Qiang <1943-> | ||
New York, : Wiley-Interscience, c2001 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Principles and applications of asymmetric synthesis [[electronic resource] /] / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan |
Autore | Lin Guo-Qiang <1943-> |
Pubbl/distr/stampa | New York, : Wiley-Interscience, c2001 |
Descrizione fisica | 1 online resource (535 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) |
LiYue-Ming <1966->
ChanAlbert Sun-Chi <1950-> |
Soggetto topico |
Asymmetric synthesis
Organic compounds - Synthesis |
ISBN |
1-280-36767-9
9786610367672 0-470-24631-6 0-471-46524-0 0-471-22042-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
PRINCIPLES AND APPLICATIONS OF ASYMMETRIC SYNTHESIS; CONTENTS; Preface; Abbreviations; 1 Introduction; 1.1 The Significance of Chirality and Stereoisomeric Discrimination; 1.2 Asymmetry; 1.2.1 Conditions for Asymmetry; 1.2.2 Nomenclature; 1.3 Determining Enantiomer Composition; 1.3.1 Measuring Specific Rotation; 1.3.2 The Nuclear Magnetic Resonance Method; 1.3.3 Some Other Reagents for Nuclear Magnetic Resonance Analysis; 1.3.4 Determining the Enantiomer Composition of Chiral Glycols or Cyclic Ketones; 1.3.5 Chromatographic Methods Using Chiral Columns
1.3.6 Capillary Electrophoresis with Enantioselective Supporting Electrolytes1.4 Determining Absolute Configuration; 1.4.1 X-Ray Diffraction Methods; 1.4.2 Chiroptical Methods; 1.4.3 The Chemical Interrelation Method; 1.4.4 Prelog's Method; 1.4.5 Horeau's Method; 1.4.6 Nuclear Magnetic Resonance Method for Relative Configuration Determination; 1.5 General Strategies for Asymmetric Synthesis; 1.5.1 ""Chiron"" Approaches; 1.5.2 Acyclic Diastereoselective Approaches; 1.5.3 Double Asymmetric Synthesis; 1.6 Examples of Some Complicated Compounds 1.7 Some Common Definitions in Asymmetric Synthesis and Stereochemistry1.8 References; 2 a-Alkylation and Catalytic Alkylation of Carbonyl Compounds; 2.1 Introduction; 2.2 Chirality Transfer; 2.2.1 Intra-annular Chirality Transfer; 2.2.2 Extra-annular Chirality Transfer; 2.2.3 Chelation-Enforced Intra-annular Chirality Transfer; 2.3 Preparation of Quaternary Carbon Centers; 2.4 Preparation of a-Amino Acids; 2.5 Nucleophilic Substitution of Chiral Acetal; 2.6 Chiral Catalyst-Induced Aldehyde Alkylation: Asymmetric Nucleophilic Addition 2.7 Catalytic Asymmetric Additions of Dialkylzinc to Ketones: Enantioselective Formation of Tertiary Alcohols2.8 Asymmetric Cyanohydrination; 2.9 Asymmetric a-Hydroxyphosphonylation; 2.10 Summary; 2.11 References; 3 Aldol and Related Reactions; 3.1 Introduction; 3.2 Substrate-Controlled Aldol Reaction; 3.2.1 Oxazolidones as Chiral Auxiliaries: Chiral Auxiliary-Mediated Aldol-Type Reactions; 3.2.2 Pyrrolidines as Chiral Auxiliaries; 3.2.3 Aminoalcohols as the Chiral Auxiliaries; 3.2.4 Acylsultam Systems as the Chiral Auxiliaries; 3.2.5 a-Silyl Ketones; 3.3 Reagent-Controlled Aldol Reactions 3.3.1 Aldol Condensations Induced by Chiral Boron Compounds3.3.2 Aldol Reactions Controlled by Corey's Reagents; 3.3.3 Aldol Condensations Controlled by Miscellaneous Reagents; 3.4 Chiral Catalyst-Controlled Asymmetric Aldol Reaction; 3.4.1 Mukaiyama's System; 3.4.2 Asymmetric Aldol Reactions with a Chiral Ferrocenylphosphine-Gold(I) Complex; 3.4.3 Asymmetric Aldol Reactions Catalyzed by Chiral Lewis Acids; 3.4.4 Catalytic Asymmetric Aldol Reaction Promoted by Bimetallic Catalysts: Shibasaki's System; 3.5 Double Asymmetric Aldol Reactions; 3.6 Asymmetric Allylation Reactions 3.6.1 The Roush Reaction |
Record Nr. | UNISA-996201196203316 |
Lin Guo-Qiang <1943-> | ||
New York, : Wiley-Interscience, c2001 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. di Salerno | ||
|
Principles and applications of asymmetric synthesis [[electronic resource] /] / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan |
Autore | Lin Guo-Qiang <1943-> |
Pubbl/distr/stampa | New York, : Wiley-Interscience, c2001 |
Descrizione fisica | 1 online resource (535 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) |
LiYue-Ming <1966->
ChanAlbert Sun-Chi <1950-> |
Soggetto topico |
Asymmetric synthesis
Organic compounds - Synthesis |
ISBN |
1-280-36767-9
9786610367672 0-470-24631-6 0-471-46524-0 0-471-22042-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
PRINCIPLES AND APPLICATIONS OF ASYMMETRIC SYNTHESIS; CONTENTS; Preface; Abbreviations; 1 Introduction; 1.1 The Significance of Chirality and Stereoisomeric Discrimination; 1.2 Asymmetry; 1.2.1 Conditions for Asymmetry; 1.2.2 Nomenclature; 1.3 Determining Enantiomer Composition; 1.3.1 Measuring Specific Rotation; 1.3.2 The Nuclear Magnetic Resonance Method; 1.3.3 Some Other Reagents for Nuclear Magnetic Resonance Analysis; 1.3.4 Determining the Enantiomer Composition of Chiral Glycols or Cyclic Ketones; 1.3.5 Chromatographic Methods Using Chiral Columns
1.3.6 Capillary Electrophoresis with Enantioselective Supporting Electrolytes1.4 Determining Absolute Configuration; 1.4.1 X-Ray Diffraction Methods; 1.4.2 Chiroptical Methods; 1.4.3 The Chemical Interrelation Method; 1.4.4 Prelog's Method; 1.4.5 Horeau's Method; 1.4.6 Nuclear Magnetic Resonance Method for Relative Configuration Determination; 1.5 General Strategies for Asymmetric Synthesis; 1.5.1 ""Chiron"" Approaches; 1.5.2 Acyclic Diastereoselective Approaches; 1.5.3 Double Asymmetric Synthesis; 1.6 Examples of Some Complicated Compounds 1.7 Some Common Definitions in Asymmetric Synthesis and Stereochemistry1.8 References; 2 a-Alkylation and Catalytic Alkylation of Carbonyl Compounds; 2.1 Introduction; 2.2 Chirality Transfer; 2.2.1 Intra-annular Chirality Transfer; 2.2.2 Extra-annular Chirality Transfer; 2.2.3 Chelation-Enforced Intra-annular Chirality Transfer; 2.3 Preparation of Quaternary Carbon Centers; 2.4 Preparation of a-Amino Acids; 2.5 Nucleophilic Substitution of Chiral Acetal; 2.6 Chiral Catalyst-Induced Aldehyde Alkylation: Asymmetric Nucleophilic Addition 2.7 Catalytic Asymmetric Additions of Dialkylzinc to Ketones: Enantioselective Formation of Tertiary Alcohols2.8 Asymmetric Cyanohydrination; 2.9 Asymmetric a-Hydroxyphosphonylation; 2.10 Summary; 2.11 References; 3 Aldol and Related Reactions; 3.1 Introduction; 3.2 Substrate-Controlled Aldol Reaction; 3.2.1 Oxazolidones as Chiral Auxiliaries: Chiral Auxiliary-Mediated Aldol-Type Reactions; 3.2.2 Pyrrolidines as Chiral Auxiliaries; 3.2.3 Aminoalcohols as the Chiral Auxiliaries; 3.2.4 Acylsultam Systems as the Chiral Auxiliaries; 3.2.5 a-Silyl Ketones; 3.3 Reagent-Controlled Aldol Reactions 3.3.1 Aldol Condensations Induced by Chiral Boron Compounds3.3.2 Aldol Reactions Controlled by Corey's Reagents; 3.3.3 Aldol Condensations Controlled by Miscellaneous Reagents; 3.4 Chiral Catalyst-Controlled Asymmetric Aldol Reaction; 3.4.1 Mukaiyama's System; 3.4.2 Asymmetric Aldol Reactions with a Chiral Ferrocenylphosphine-Gold(I) Complex; 3.4.3 Asymmetric Aldol Reactions Catalyzed by Chiral Lewis Acids; 3.4.4 Catalytic Asymmetric Aldol Reaction Promoted by Bimetallic Catalysts: Shibasaki's System; 3.5 Double Asymmetric Aldol Reactions; 3.6 Asymmetric Allylation Reactions 3.6.1 The Roush Reaction |
Record Nr. | UNINA-9910830879503321 |
Lin Guo-Qiang <1943-> | ||
New York, : Wiley-Interscience, c2001 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|
Principles and applications of asymmetric synthesis / / Guo-Qiang Lin, Yue-Ming Li, Albert S.C. Chan |
Autore | Lin Guo-Qiang <1943-> |
Pubbl/distr/stampa | New York, : Wiley-Interscience, c2001 |
Descrizione fisica | 1 online resource (535 p.) |
Disciplina |
547.2
547/.2 |
Altri autori (Persone) |
LiYue-Ming <1966->
ChanAlbert Sun-Chi <1950-> |
Soggetto topico |
Asymmetric synthesis
Organic compounds - Synthesis |
ISBN |
1-280-36767-9
9786610367672 0-470-24631-6 0-471-46524-0 0-471-22042-6 |
Formato | Materiale a stampa |
Livello bibliografico | Monografia |
Lingua di pubblicazione | eng |
Nota di contenuto |
PRINCIPLES AND APPLICATIONS OF ASYMMETRIC SYNTHESIS; CONTENTS; Preface; Abbreviations; 1 Introduction; 1.1 The Significance of Chirality and Stereoisomeric Discrimination; 1.2 Asymmetry; 1.2.1 Conditions for Asymmetry; 1.2.2 Nomenclature; 1.3 Determining Enantiomer Composition; 1.3.1 Measuring Specific Rotation; 1.3.2 The Nuclear Magnetic Resonance Method; 1.3.3 Some Other Reagents for Nuclear Magnetic Resonance Analysis; 1.3.4 Determining the Enantiomer Composition of Chiral Glycols or Cyclic Ketones; 1.3.5 Chromatographic Methods Using Chiral Columns
1.3.6 Capillary Electrophoresis with Enantioselective Supporting Electrolytes1.4 Determining Absolute Configuration; 1.4.1 X-Ray Diffraction Methods; 1.4.2 Chiroptical Methods; 1.4.3 The Chemical Interrelation Method; 1.4.4 Prelog's Method; 1.4.5 Horeau's Method; 1.4.6 Nuclear Magnetic Resonance Method for Relative Configuration Determination; 1.5 General Strategies for Asymmetric Synthesis; 1.5.1 ""Chiron"" Approaches; 1.5.2 Acyclic Diastereoselective Approaches; 1.5.3 Double Asymmetric Synthesis; 1.6 Examples of Some Complicated Compounds 1.7 Some Common Definitions in Asymmetric Synthesis and Stereochemistry1.8 References; 2 a-Alkylation and Catalytic Alkylation of Carbonyl Compounds; 2.1 Introduction; 2.2 Chirality Transfer; 2.2.1 Intra-annular Chirality Transfer; 2.2.2 Extra-annular Chirality Transfer; 2.2.3 Chelation-Enforced Intra-annular Chirality Transfer; 2.3 Preparation of Quaternary Carbon Centers; 2.4 Preparation of a-Amino Acids; 2.5 Nucleophilic Substitution of Chiral Acetal; 2.6 Chiral Catalyst-Induced Aldehyde Alkylation: Asymmetric Nucleophilic Addition 2.7 Catalytic Asymmetric Additions of Dialkylzinc to Ketones: Enantioselective Formation of Tertiary Alcohols2.8 Asymmetric Cyanohydrination; 2.9 Asymmetric a-Hydroxyphosphonylation; 2.10 Summary; 2.11 References; 3 Aldol and Related Reactions; 3.1 Introduction; 3.2 Substrate-Controlled Aldol Reaction; 3.2.1 Oxazolidones as Chiral Auxiliaries: Chiral Auxiliary-Mediated Aldol-Type Reactions; 3.2.2 Pyrrolidines as Chiral Auxiliaries; 3.2.3 Aminoalcohols as the Chiral Auxiliaries; 3.2.4 Acylsultam Systems as the Chiral Auxiliaries; 3.2.5 a-Silyl Ketones; 3.3 Reagent-Controlled Aldol Reactions 3.3.1 Aldol Condensations Induced by Chiral Boron Compounds3.3.2 Aldol Reactions Controlled by Corey's Reagents; 3.3.3 Aldol Condensations Controlled by Miscellaneous Reagents; 3.4 Chiral Catalyst-Controlled Asymmetric Aldol Reaction; 3.4.1 Mukaiyama's System; 3.4.2 Asymmetric Aldol Reactions with a Chiral Ferrocenylphosphine-Gold(I) Complex; 3.4.3 Asymmetric Aldol Reactions Catalyzed by Chiral Lewis Acids; 3.4.4 Catalytic Asymmetric Aldol Reaction Promoted by Bimetallic Catalysts: Shibasaki's System; 3.5 Double Asymmetric Aldol Reactions; 3.6 Asymmetric Allylation Reactions 3.6.1 The Roush Reaction |
Record Nr. | UNINA-9910877612503321 |
Lin Guo-Qiang <1943-> | ||
New York, : Wiley-Interscience, c2001 | ||
Materiale a stampa | ||
Lo trovi qui: Univ. Federico II | ||
|