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Phosphorus(III) ligands in homogeneous catalysis [[electronic resource] ] : design and synthesis / / edited by Paul Kamer & Piet W.N.M. van Leeuwen
| Phosphorus(III) ligands in homogeneous catalysis [[electronic resource] ] : design and synthesis / / edited by Paul Kamer & Piet W.N.M. van Leeuwen |
| Autore | Kamer Paul |
| Pubbl/distr/stampa | Chichester, West Sussex, United Kingdom, : John Wiley & Sons, Ltd., 2012 |
| Descrizione fisica | 1 online resource (567 p.) |
| Disciplina |
541.2242
546.712595 546/.712595 |
| Altri autori (Persone) | LeeuwenP. W. N. M. van (Piet W. N. M.) |
| Soggetto topico |
Phosphorus compounds
Ligands Catalysis TECHNOLOGY & ENGINEERING / Material Science |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-280-78471-7
9786613695109 1-118-29970-1 1-118-29971-X 1-118-29973-6 |
| Classificazione | TEC021000 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Phosphorus( III ) Ligands in Homogeneous Catalysis: Design and Synthesis; Contents; List of Contributors; Preface; 1 Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design; 1.1 Introduction; 1.2 Properties of phosphorus ligands; 1.2.1 Electronic ligand parameters; 1.2.2 Steric ligand parameters; 1.2.3 Bite angle effects; 1.2.4 Molecular electrostatic potential (MESP) approach; 1.3 Asymmetric ligands; 1.4 Rational ligand design in nickel-catalysed hydrocyanation; 1.4.1 Introduction; 1.4.2 Mechanistic insights; 1.4.3 Rational design; 1.5 Conclusions; References
2 Chiral Phosphines and Diphosphines2.1 Introduction; 2.1.1 Early developments; 2.2 Chiral chelating diphosphines with a linking scaffold; 2.2.1 Building chiral backbones from naturally available materials; 2.2.2 Design and synthesis of chiral backbones; 2.2.3 Synthesis from optical resolution of phosphine precursors or intermediates; 2.3 Chiral atropisomeric biaryl diphosphines; 2.3.1 Synthesis of BINAP and its derivatives; 2.3.2 Synthesis of atropisomeric biaryl ligands; 2.3.3 General strategies of synthesizing of atropisomeric biaryl ligands; 2.4 Chiral phosphacyclic diphosphines 2.4.1 Fundamental discovery and syntheses of BPE and DuPhos2.4.2 Design and synthesis of bisphosphetanes; 2.4.3 Design and synthesis of bisphospholanes; 2.4.4 Design and synthesis of bisphospholes; 2.4.5 Design and synthesis of bisphosphinanes; 2.4.6 Design and synthesis of bisphosphepines; 2.4.7 Summary of synthetic strategies of phosphacycles; 2.5 P-stereogenic diphosphine ligands; 2.6 Experimental procedures for the syntheses of selected diphosphine ligands; 2.6.1 Synthesis procedure for DIOP* ligand; 2.6.2 Synthesis procedure of SDP ligands; 2.6.3 Synthesis procedure of (R,R)-BICP 2.6.4 Synthesis procedure of SEGPHOS2.6.5 Synthesis procedure of Ph-BPE; 2.6.6 Synthesis procedure of TangPhos; 2.6.7 Synthesis procedure of Binaphane; 2.7 Concluding remarks; References; 3 Design and Synthesis of Phosphite Ligands for Homogeneous Catalysis; 3.1 Introduction; 3.2 Synthesis of phosphites; 3.2.1 Monophosphites; 3.2.2 Diphosphite ligands; 3.2.3 Triphosphites; 3.3 Highlights of catalytic applications of phosphite ligands; 3.3.1 Hydrogenation reactions; 3.3.2 Functionalization of alkenes: hydroformylation and hydrocyanation 3.3.3 Addition of nucleophiles to carbonyl compounds and derivatives3.3.4 Allylic substitution reactions; 3.3.5 Miscellaneous reactions; 3.4 General synthetic procedures; 3.4.1 Symmetrically substituted phosphites; 3.4.2 Nonsymmetrically substituted phosphites; 3.4.3 Phosphites bearing dioxaphospho-cyclic units; References; 4 Phosphoramidite Ligands; 4.1 Introduction; 4.1.1 History; 4.2 Synthesis of phosphoramidites; 4.3 Reactivity of the phosphoramidites; 4.4 Types of phosphoramidite ligands; 4.4.1 Acyclic monodentate phosphoramidites; 4.4.2 Cyclic monodentate phosphoramidites based on diols 4.4.3 Cyclic phosphoramidites based on amino alcohols |
| Record Nr. | UNINA-9910141261103321 |
Kamer Paul
|
||
| Chichester, West Sussex, United Kingdom, : John Wiley & Sons, Ltd., 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Phosphorus(III) ligands in homogeneous catalysis : design and synthesis / / edited by Paul Kamer & Piet W.N.M. van Leeuwen
| Phosphorus(III) ligands in homogeneous catalysis : design and synthesis / / edited by Paul Kamer & Piet W.N.M. van Leeuwen |
| Autore | Kamer Paul |
| Edizione | [1st ed.] |
| Pubbl/distr/stampa | Chichester, West Sussex, United Kingdom, : John Wiley & Sons, Ltd., 2012 |
| Descrizione fisica | 1 online resource (567 p.) |
| Disciplina |
541.2242
546.712595 546/.712595 |
| Altri autori (Persone) | LeeuwenP. W. N. M. van (Piet W. N. M.) |
| Soggetto topico |
Phosphorus compounds
Ligands Catalysis TECHNOLOGY & ENGINEERING / Material Science |
| ISBN |
1-280-78471-7
9786613695109 1-118-29970-1 1-118-29971-X 1-118-29973-6 |
| Classificazione | TEC021000 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Phosphorus( III ) Ligands in Homogeneous Catalysis: Design and Synthesis; Contents; List of Contributors; Preface; 1 Phosphorus Ligand Effects in Homogeneous Catalysis and Rational Catalyst Design; 1.1 Introduction; 1.2 Properties of phosphorus ligands; 1.2.1 Electronic ligand parameters; 1.2.2 Steric ligand parameters; 1.2.3 Bite angle effects; 1.2.4 Molecular electrostatic potential (MESP) approach; 1.3 Asymmetric ligands; 1.4 Rational ligand design in nickel-catalysed hydrocyanation; 1.4.1 Introduction; 1.4.2 Mechanistic insights; 1.4.3 Rational design; 1.5 Conclusions; References
2 Chiral Phosphines and Diphosphines2.1 Introduction; 2.1.1 Early developments; 2.2 Chiral chelating diphosphines with a linking scaffold; 2.2.1 Building chiral backbones from naturally available materials; 2.2.2 Design and synthesis of chiral backbones; 2.2.3 Synthesis from optical resolution of phosphine precursors or intermediates; 2.3 Chiral atropisomeric biaryl diphosphines; 2.3.1 Synthesis of BINAP and its derivatives; 2.3.2 Synthesis of atropisomeric biaryl ligands; 2.3.3 General strategies of synthesizing of atropisomeric biaryl ligands; 2.4 Chiral phosphacyclic diphosphines 2.4.1 Fundamental discovery and syntheses of BPE and DuPhos2.4.2 Design and synthesis of bisphosphetanes; 2.4.3 Design and synthesis of bisphospholanes; 2.4.4 Design and synthesis of bisphospholes; 2.4.5 Design and synthesis of bisphosphinanes; 2.4.6 Design and synthesis of bisphosphepines; 2.4.7 Summary of synthetic strategies of phosphacycles; 2.5 P-stereogenic diphosphine ligands; 2.6 Experimental procedures for the syntheses of selected diphosphine ligands; 2.6.1 Synthesis procedure for DIOP* ligand; 2.6.2 Synthesis procedure of SDP ligands; 2.6.3 Synthesis procedure of (R,R)-BICP 2.6.4 Synthesis procedure of SEGPHOS2.6.5 Synthesis procedure of Ph-BPE; 2.6.6 Synthesis procedure of TangPhos; 2.6.7 Synthesis procedure of Binaphane; 2.7 Concluding remarks; References; 3 Design and Synthesis of Phosphite Ligands for Homogeneous Catalysis; 3.1 Introduction; 3.2 Synthesis of phosphites; 3.2.1 Monophosphites; 3.2.2 Diphosphite ligands; 3.2.3 Triphosphites; 3.3 Highlights of catalytic applications of phosphite ligands; 3.3.1 Hydrogenation reactions; 3.3.2 Functionalization of alkenes: hydroformylation and hydrocyanation 3.3.3 Addition of nucleophiles to carbonyl compounds and derivatives3.3.4 Allylic substitution reactions; 3.3.5 Miscellaneous reactions; 3.4 General synthetic procedures; 3.4.1 Symmetrically substituted phosphites; 3.4.2 Nonsymmetrically substituted phosphites; 3.4.3 Phosphites bearing dioxaphospho-cyclic units; References; 4 Phosphoramidite Ligands; 4.1 Introduction; 4.1.1 History; 4.2 Synthesis of phosphoramidites; 4.3 Reactivity of the phosphoramidites; 4.4 Types of phosphoramidite ligands; 4.4.1 Acyclic monodentate phosphoramidites; 4.4.2 Cyclic monodentate phosphoramidites based on diols 4.4.3 Cyclic phosphoramidites based on amino alcohols |
| Record Nr. | UNINA-9910810261803321 |
|
Kamer Paul
|
||
| Chichester, West Sussex, United Kingdom, : John Wiley & Sons, Ltd., 2012 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Rhodium catalyzed hydroformylation [[electronic resource] /] / edited by Piet W.N.M. van Leeuwen and Carmen Claver
| Rhodium catalyzed hydroformylation [[electronic resource] /] / edited by Piet W.N.M. van Leeuwen and Carmen Claver |
| Edizione | [1st ed. 2002.] |
| Pubbl/distr/stampa | Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 |
| Descrizione fisica | 1 online resource (299 p.) |
| Disciplina | 547/.1393 |
| Altri autori (Persone) |
LeeuwenP. W. N. M. van (Piet W. N. M.)
ClaverCarmen |
| Collana | Catalysis by metal complexes |
| Soggetto topico |
Hydroformylation
Rhodium catalysts |
| Soggetto genere / forma | Electronic books. |
| ISBN |
9786610205394
1-59124-840-X 9780306469472 1-280-20539-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | to hydroformylation -- Hydroformylation with unmodified rhodium catalysts -- Rhodium Phosphite Catalysts -- Phosphines as ligands -- Asymmetric hydroformylation -- Hydroformylation in Organic Synthesis -- Aqueous biphasic hydroformylation -- Process aspects of rhodium-catalyzed hydroformylation -- Catalyst preparation and decomposition -- Novel developments in hydroformylation. |
| Record Nr. | UNINA-9910454990403321 |
| Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Rhodium catalyzed hydroformylation [[electronic resource] /] / edited by Piet W.N.M. van Leeuwen and Carmen Claver
| Rhodium catalyzed hydroformylation [[electronic resource] /] / edited by Piet W.N.M. van Leeuwen and Carmen Claver |
| Edizione | [1st ed. 2002.] |
| Pubbl/distr/stampa | Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 |
| Descrizione fisica | 1 online resource (299 p.) |
| Disciplina | 547/.1393 |
| Altri autori (Persone) |
LeeuwenP. W. N. M. van (Piet W. N. M.)
ClaverCarmen |
| Collana | Catalysis by metal complexes |
| Soggetto topico |
Hydroformylation
Rhodium catalysts |
| ISBN |
9786610205394
1-59124-840-X 9780306469472 1-280-20539-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto | to hydroformylation -- Hydroformylation with unmodified rhodium catalysts -- Rhodium Phosphite Catalysts -- Phosphines as ligands -- Asymmetric hydroformylation -- Hydroformylation in Organic Synthesis -- Aqueous biphasic hydroformylation -- Process aspects of rhodium-catalyzed hydroformylation -- Catalyst preparation and decomposition -- Novel developments in hydroformylation. |
| Record Nr. | UNINA-9910779960203321 |
| Dordrecht [Netherlands] ; ; Boston, : Kluwer Academic Publishers, c2000 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Supramolecular catalysis : new directions and developments / / edited by Piet W. N. M. van Leeuwen, Matthieu Raynal
| Supramolecular catalysis : new directions and developments / / edited by Piet W. N. M. van Leeuwen, Matthieu Raynal |
| Pubbl/distr/stampa | Weinheim, Germany : , : WILEY-VCH, , [2022] |
| Descrizione fisica | 1 online resource (697 pages) |
| Disciplina | 541.395 |
| Soggetto topico |
Catalysis
Supramolecular chemistry |
| Soggetto genere / forma | Electronic books. |
| ISBN |
3-527-83204-1
3-527-83202-5 3-527-83203-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910555057003321 |
| Weinheim, Germany : , : WILEY-VCH, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Supramolecular catalysis : new directions and developments / / edited by Piet W. N. M. van Leeuwen, Matthieu Raynal
| Supramolecular catalysis : new directions and developments / / edited by Piet W. N. M. van Leeuwen, Matthieu Raynal |
| Pubbl/distr/stampa | Weinheim, Germany : , : WILEY-VCH, , [2022] |
| Descrizione fisica | 1 online resource (697 pages) |
| Disciplina | 541.395 |
| Soggetto topico |
Catalysis
Supramolecular chemistry |
| ISBN |
3-527-83204-1
3-527-83202-5 3-527-83203-3 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910686753603321 |
| Weinheim, Germany : , : WILEY-VCH, , [2022] | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Supramolecular catalysis / / edited by Piet W. N. M. van Leeuwen
| Supramolecular catalysis / / edited by Piet W. N. M. van Leeuwen |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (321 p.) |
| Disciplina | 541.395 |
| Soggetto topico |
Catalysis
Supramolecular chemistry |
| ISBN |
1-282-78442-0
9786612784422 3-527-62178-4 3-527-62179-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Supramolecular Catalysis; Contents; List of Authors; 1 Introduction to Supramolecular Catalysis; 1.1 Introduction; 1.2 Design Approaches to Supramolecular Catalysis; 1.2.1 Molecular Receptors that Place a Binding Site Close to a Catalytic Center; 1.2.2 Molecular Receptors that Promote the Reaction of two Simultaneously Complexed Reactants; 1.2.3 Preparation of the Catalyst Backbone via Supramolecular Interactions; 1.3 Artificial Biomacromolecules for Asymmetric Catalysis; 1.4 Summary and Outlook; References
2 Supramolecular Construction of Chelating Bidentate Ligand Libraries through Hydrogen Bonding: Concept and Applications in Homogeneous Metal Complex Catalysis2.1 Introduction; 2.2 Emulation of Chelation through Self-Assembly of Monodentate Ligands; 2.3 Tautomeric Self-Complementary Interligand Hydrogen Bonding; 2.3.1 Hydroformylation; 2.3.2 Room Temperature/Ambient Pressure Hydroformylation; 2.3.3 Asymmetric Hydrogenation; 2.4 A-T Base Pair Analogous Complementary Hydrogen Bonding for the Construction of Heterodimeric Self-Assembling Ligands; 2.4.1 Aminopyridine/Isoquinolone Platform 3.3.2 X-Ray and other Techniques for Structural Characterization in the Solid State3.3.3 Structural Characterization in Solution by NMR; 3.3.4 Anion Exchange in the Solid State; 3.4 Preparation of Coordination Polymers with 2,3-Pyrazolylquinoxalines or 2,3-Pyrazolylpyrazines and Cu(I) or Ag(I); 3.4.1 Preparation and Characterization of Dinuclear Building Blocks and Coordination Polymers; 3.4.2 X-Ray and other Techniques for Structural Characterization; 3.5 Preparation of Supramolecular Structures with 2,4-Diamino-6-R-1,3,5-triazines and Ag(I); 3.5.1 Synthesis 3.5.2 X-Ray Structure Determination3.5.3 Structural Characterization in Solution by NMR; 3.6 Conclusions; References; 4 Chiral Metallocycles for Asymmetric Catalysis; 4.1 Introduction; 4.2 Thermodynamically-Controlled Metallocycles; 4.3 Kinetically-Controlled Metallocycles; 4.4 General Synthetic Strategies for Chiral Metallocycles; 4.5 Self- and Directed-Assembly of Chiral Pt-Alkynyl Metallocycles; 4.6 Chiral Pt-Alkynyl Metallocycles for Asymmetric Catalysis; 4.7 Concluding Remarks; References; 5 Catalysis of Acyl Transfer Processes by Crown-Ether Supported Alkaline-Earth Metal Ions 5.1 Introduction |
| Record Nr. | UNINA-9910146268103321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Supramolecular catalysis / / edited by Piet W. N. M. van Leeuwen
| Supramolecular catalysis / / edited by Piet W. N. M. van Leeuwen |
| Pubbl/distr/stampa | Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 |
| Descrizione fisica | 1 online resource (321 p.) |
| Disciplina | 541.395 |
| Soggetto topico |
Catalysis
Supramolecular chemistry |
| ISBN |
1-282-78442-0
9786612784422 3-527-62178-4 3-527-62179-2 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Supramolecular Catalysis; Contents; List of Authors; 1 Introduction to Supramolecular Catalysis; 1.1 Introduction; 1.2 Design Approaches to Supramolecular Catalysis; 1.2.1 Molecular Receptors that Place a Binding Site Close to a Catalytic Center; 1.2.2 Molecular Receptors that Promote the Reaction of two Simultaneously Complexed Reactants; 1.2.3 Preparation of the Catalyst Backbone via Supramolecular Interactions; 1.3 Artificial Biomacromolecules for Asymmetric Catalysis; 1.4 Summary and Outlook; References
2 Supramolecular Construction of Chelating Bidentate Ligand Libraries through Hydrogen Bonding: Concept and Applications in Homogeneous Metal Complex Catalysis2.1 Introduction; 2.2 Emulation of Chelation through Self-Assembly of Monodentate Ligands; 2.3 Tautomeric Self-Complementary Interligand Hydrogen Bonding; 2.3.1 Hydroformylation; 2.3.2 Room Temperature/Ambient Pressure Hydroformylation; 2.3.3 Asymmetric Hydrogenation; 2.4 A-T Base Pair Analogous Complementary Hydrogen Bonding for the Construction of Heterodimeric Self-Assembling Ligands; 2.4.1 Aminopyridine/Isoquinolone Platform 3.3.2 X-Ray and other Techniques for Structural Characterization in the Solid State3.3.3 Structural Characterization in Solution by NMR; 3.3.4 Anion Exchange in the Solid State; 3.4 Preparation of Coordination Polymers with 2,3-Pyrazolylquinoxalines or 2,3-Pyrazolylpyrazines and Cu(I) or Ag(I); 3.4.1 Preparation and Characterization of Dinuclear Building Blocks and Coordination Polymers; 3.4.2 X-Ray and other Techniques for Structural Characterization; 3.5 Preparation of Supramolecular Structures with 2,4-Diamino-6-R-1,3,5-triazines and Ag(I); 3.5.1 Synthesis 3.5.2 X-Ray Structure Determination3.5.3 Structural Characterization in Solution by NMR; 3.6 Conclusions; References; 4 Chiral Metallocycles for Asymmetric Catalysis; 4.1 Introduction; 4.2 Thermodynamically-Controlled Metallocycles; 4.3 Kinetically-Controlled Metallocycles; 4.4 General Synthetic Strategies for Chiral Metallocycles; 4.5 Self- and Directed-Assembly of Chiral Pt-Alkynyl Metallocycles; 4.6 Chiral Pt-Alkynyl Metallocycles for Asymmetric Catalysis; 4.7 Concluding Remarks; References; 5 Catalysis of Acyl Transfer Processes by Crown-Ether Supported Alkaline-Earth Metal Ions 5.1 Introduction |
| Record Nr. | UNINA-9910829933503321 |
| Weinheim, [Germany] : , : Wiley-VCH Verlag GmbH & Co. KGaA, , 2008 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||