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Introduction to Coordination Chemistry [[electronic resource]]
| Introduction to Coordination Chemistry [[electronic resource]] |
| Autore | Lawrance Geoffrey A |
| Pubbl/distr/stampa | Hoboken, : Wiley, 2010 |
| Descrizione fisica | 1 online resource (306 p.) |
| Collana | Inorganic Chemistry: A Textbook Series |
| Soggetto topico |
Chemistry
Coordination Coordination compounds Ligands |
| Soggetto genere / forma | Electronic books. |
| ISBN |
1-282-46098-6
9780470519318 9786612460982 0-470-68713-4 |
| Formato | Materiale a stampa  |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Nota di contenuto |
Introduction to Coordination Chemistry; Contents; Preface; Preamble; 1 The Central Atom; 1.1 Key Concepts in Coordination Chemistry; 1.2 A Who's Who of Metal Ions; 1.2.1 Commoners and 'Uncommoners'; 1.2.2 Redefining Commoners; 1.3 Metals in Molecules; 1.3.1 Metals in the Natural World; 1.3.2 Metals in Contrived Environments; 1.3.3 Natural or Made-to-Measure Complexes; 1.4 The Road Ahead; Concept Keys; Further Reading; 2 Ligands; 2.1 Membership: Being a Ligand; 2.1.1 What Makes a Ligand?; 2.1.2 Making Attachments - Coordination; 2.1.3 Putting the Bite on Metals - Chelation
2.1.4 Do I Look Big on That? - Chelate Ring Size2.1.5 Different Tribes - Donor Group Variation; 2.1.6 Ligands with More Bite - Denticity; 2.2 Monodentate Ligands - The Simple Type; 2.2.1 Basic Binders; 2.2.2 Amines Ain't Ammines - Ligand Families; 2.2.3 Meeting More Metals - Bridging Ligands; 2.3 Greed is Good - Polydentate Ligands; 2.3.1 The Simple Chelate; 2.3.2 More Teeth, Stronger Bite - Polydentates; 2.3.3 Many-Armed Monsters - Introducing Ligand Shape; 2.4 Polynucleating Species - Molecular Bigamists; 2.4.1 When One is Not Enough; 2.4.2 Vive la Difference - Mixed-metal Complexation 2.4.3 Supersized - Binding to Macromolecules2.5 A Separate Race - Organometallic Species; Concept Keys; Further Reading; 3 Complexes; 3.1 The Central Metal Ion; 3.2 Metal-Ligand Marriage; 3.2.1 The Coordinate Bond; 3.2.2 The Foundation of Coordination Chemistry; 3.2.3 Complex Shape - Not Just Any Which Way; 3.3 Holding On - The Nature of Bonding in Metal Complexes; 3.3.1 An Ionic Bonding Model - Introducing Crystal Field Theory; 3.3.2 A Covalent Bonding Model - Embracing Molecular Orbital Theory; 3.3.3 Ligand Field Theory - Making Compromises; 3.3.4 Bonding Models Extended 3.4 Coupling - Polymetallic Complexes3.5 Making Choices; 3.5.1 Selectivity - Of all the Molecules in all the World, Why This One?; 3.5.2 Preferences - Do You Like What I Like?; 3.5.3 Complex Lifetimes - Together, Forever?; 3.6 Complexation Consequences; Concept Keys; Further Reading; 4 Shape; 4.1 Getting in Shape; 4.2 Forms of Complex Life - Coordination Number and Shape; 4.2.1 One Coordination (ML); 4.2.2 Two Coordination (ML2); 4.2.3 Three Coordination (ML3); 4.2.4 Four Coordination (ML4); 4.2.5 Five Coordination (ML5); 4.2.6 Six Coordination (ML6) 4.2.7 Higher Coordination Numbers (ML7 to ML9)4.3 Influencing Shape; 4.3.1 Metallic Genetics - Metal Ion Influences; 4.3.2 Moulding a Relationship - Ligand Influences; 4.3.3 Chameleon Complexes; 4.4 Isomerism - Real 3D Effects; 4.4.1 Introducing Stereoisomers; 4.4.2 Constitutional (Structural) Isomerism; 4.4.3 Stereoisomerism: in Place - Positional Isomers; in Space - Optical Isomers; 4.4.4 What's Best? - Isomer Preferences; 4.5 Sophisticated Shapes; 4.5.1 Compounds of Polydentate Ligands; 4.5.2 Encapsulation Compounds; 4.5.3 Host-Guest Molecular Assemblies; 4.6 Defining Shape; Concept Keys Further Reading |
| Record Nr. | UNINA-9910455102703321 |
Lawrance Geoffrey A
|
||
| Hoboken, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||
Introduction to coordination chemistry [[electronic resource] /] / Geoffrey A. Lawrance
| Introduction to coordination chemistry [[electronic resource] /] / Geoffrey A. Lawrance |
| Autore | Lawrance Geoffrey A |
| Pubbl/distr/stampa | Chichester, West Sussex, : Wiley, 2010 |
| Descrizione fisica | xiii, 290 p. : ill |
| Soggetto topico |
Complex compounds
Coordination compounds |
| ISBN |
0-470-68712-6
1-118-68140-1 |
| Formato | Materiale a stampa |
| Livello bibliografico | Monografia |
| Lingua di pubblicazione | eng |
| Record Nr. | UNINA-9910713829803321 |
|
Lawrance Geoffrey A
|
||
| Chichester, West Sussex, : Wiley, 2010 | ||
| Materiale a stampa | ||
| Lo trovi qui: Univ. Federico II | ||
| ||